CN103614000A - Alcohol-soluble flexible printing ink - Google Patents

Alcohol-soluble flexible printing ink Download PDF

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Publication number
CN103614000A
CN103614000A CN201310630655.2A CN201310630655A CN103614000A CN 103614000 A CN103614000 A CN 103614000A CN 201310630655 A CN201310630655 A CN 201310630655A CN 103614000 A CN103614000 A CN 103614000A
Authority
CN
China
Prior art keywords
mixture
resin
ink
additive
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310630655.2A
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Chinese (zh)
Inventor
龙小柱
王利军
龙钰
李海洋
袁刚
唐动成
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenyang University of Chemical Technology
Original Assignee
Shenyang University of Chemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenyang University of Chemical Technology filed Critical Shenyang University of Chemical Technology
Priority to CN201310630655.2A priority Critical patent/CN103614000A/en
Publication of CN103614000A publication Critical patent/CN103614000A/en
Pending legal-status Critical Current

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Abstract

The invention discloses an alcohol-soluble flexible printing ink, and relates to a printing ink. The ink comprises the following components by mass percent: 40-60% of reactive oligomer, 20-40% of activated monomer, 3-6% of photoinitiator, 5-20% of coloring agent and 5-10% of additive, and also comprises 2-5% of surfactant and a mixture thereof, wherein the reactive oligomer is acrylic resin or keto-aldehyde resin or polyamide resin or maleic anhydride resin or a mixture thereof; the activated monomer is tripropylene glycol diacrylate; the photoinitiator is diphenyl ketone, benzoin methyl ether, phenylacetophenone or a mixture thereof; the additive is an activator, a viscosity thickener and an electrostatic remover; the surfactant is silicide, or paraffin wax or a mixture thereof. According to the ink disclosed by the invention, alcohol-soluble polyamide resin is adopted, and the traditional benzene-soluble polyamide resin is replaced, so that the toxicity is reduced, and the problems that the traditional ink is deep in color, serious in gel tendency, poor in restorative property and the like are solved.

Description

A kind of alcohol dissolubility flexible printing ink
Technical field
The present invention relates to a kind of printing-ink, particularly relate to a kind of alcohol dissolubility flexible printing ink.
Background technology
Along with the development of printing, plastic wrapping and decorate the culture, high-grade Special colored ink has obtained very fast development, and alcohol-soluble polyamide resin is the main raw material of preparing flexible printing humour.Adding appropriate pigment and additive, can prepare various high-quality ink, and improve the quality of products, reduce toxicity, is very important.
Summary of the invention
The object of the present invention is to provide a kind of alcohol dissolubility flexible printing ink, ink of the present invention adopts alcohol-soluble polyamide resin, substitute traditional benzene soluble polyamide, reduced toxicity, solved the problems such as traditional ink colors is dark, gel tendency is serious, the restorative difference of gel.
The object of the invention is to be achieved through the following technical solutions:
An alcohol dissolubility flexible printing ink, each component of described ink and mass percent thereof are: reactive oligopolymer 40 ~ 60%, reactive monomer 20 ~ 40%, light trigger 3 ~ 6%, tinting material 5 ~ 20%, additive 5 ~ 10%, also comprises tensio-active agent of 2 ~ 5% and composition thereof.
Reactive oligopolymer is acrylic resin, or aldehyde ketone resin, or polyamide resin, or maleic anhydride resin, or its mixture.
Reactive monomer is tri (propylene glycol) diacrylate.
Light trigger is benzophenone, benzoin methyl ether, phenylbenzene ethyl ketone or its mixture.
Additive is quick dry agent, viscosity thickener, static eliminating agent.
Tensio-active agent is silicide, or paraffin or its mixture.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
The flexible printing ink that the present invention is designed, comprises each component and mass percent thereof: reactive oligopolymer 40 ~ 60%, and reactive monomer 20 ~ 40%, light trigger 3 ~ 6%, tinting material 5 ~ 20%, additive 5 ~ 10%, also comprises tensio-active agent of 2 ~ 5% and composition thereof.Described reactive oligopolymer is acrylic resin, aldehyde ketone resin, polyamide resin, maleic anhydride resin, or its mixture; Described reactive monomer is tri (propylene glycol) diacrylate; Described light trigger is benzophenone, benzoin methyl ether, phenylbenzene ethyl ketone or its mixture; Described additive is quick dry agent, viscosity thickener, static eliminating agent; Described tensio-active agent also comprises silicide, paraffin or its mixture.
Embodiment 1:
The present invention be take oleic acid and quadrol and is prepared amine hydroxybenzene as main raw material, take carboxyl and the amount of substance of amido ratio as 1:1 be benchmark, preparating acid mixed solution and amine mixed solution.Sour mixed solution is added in reactor fully and stirred, be slowly warmed up to 130 ± 2 ℃ and drip amine mixed solutions, isothermal reaction, reaction 3h, until stop heating after going out without obvious water droplet in water trap, starts to vacuumize, and obtains solid shape polyamide resin after cooling.
Take polyamide resin as main raw material, add additive, light trigger, tensio-active agent, prepare printing-ink.
It should be noted that: for departing from any subtle change of under prerequisite, it being done under the present invention's design and being equal to replacement, all belong to protection scope of the present invention.

Claims (1)

1. an alcohol dissolubility flexible printing ink, is characterized in that, each component of described ink and mass percent thereof are: reactive oligopolymer 40 ~ 60%, reactive monomer 20 ~ 40%, light trigger 3 ~ 6%, tinting material 5 ~ 20%, additive 5 ~ 10%, also comprises tensio-active agent of 2 ~ 5% and composition thereof; Reactive oligopolymer is acrylic resin, or aldehyde ketone resin, or polyamide resin, or maleic anhydride resin, or its mixture; Reactive monomer is tri (propylene glycol) diacrylate; Initiator is benzophenone, benzoin methyl ether, phenylbenzene ethyl ketone or its mixture; Additive is quick dry agent, viscosity thickener, static eliminating agent; Tensio-active agent is silicide, or paraffin or its mixture.
CN201310630655.2A 2013-12-02 2013-12-02 Alcohol-soluble flexible printing ink Pending CN103614000A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310630655.2A CN103614000A (en) 2013-12-02 2013-12-02 Alcohol-soluble flexible printing ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310630655.2A CN103614000A (en) 2013-12-02 2013-12-02 Alcohol-soluble flexible printing ink

Publications (1)

Publication Number Publication Date
CN103614000A true CN103614000A (en) 2014-03-05

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310630655.2A Pending CN103614000A (en) 2013-12-02 2013-12-02 Alcohol-soluble flexible printing ink

Country Status (1)

Country Link
CN (1) CN103614000A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105315772A (en) * 2015-10-14 2016-02-10 大连实利德化工科技有限公司 Alcohol-soluble PET tangle film plastic transparent table printing ink and preparation method thereof
CN106928417A (en) * 2017-04-21 2017-07-07 苏州雄鹰笔墨科技有限公司 A kind of modified aldehyde ketone resin, preparation method and the application in writing ink
CN114058214A (en) * 2021-12-15 2022-02-18 乐凯华光印刷科技有限公司 UV (ultraviolet) curing inkjet ink and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101709182A (en) * 2009-12-29 2010-05-19 北京印刷学院 Water-based ultraviolet dry plastics printing ink
CN102241914A (en) * 2011-05-26 2011-11-16 西安理工大学 Water-based UV (ultraviolet) ink and preparation method thereof
CN103102745A (en) * 2012-12-27 2013-05-15 龙门多泰工业有限公司 Screen printing ink
CN103102734A (en) * 2012-12-27 2013-05-15 龙门多泰工业有限公司 Screen printing ink

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101709182A (en) * 2009-12-29 2010-05-19 北京印刷学院 Water-based ultraviolet dry plastics printing ink
CN102241914A (en) * 2011-05-26 2011-11-16 西安理工大学 Water-based UV (ultraviolet) ink and preparation method thereof
CN103102745A (en) * 2012-12-27 2013-05-15 龙门多泰工业有限公司 Screen printing ink
CN103102734A (en) * 2012-12-27 2013-05-15 龙门多泰工业有限公司 Screen printing ink

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105315772A (en) * 2015-10-14 2016-02-10 大连实利德化工科技有限公司 Alcohol-soluble PET tangle film plastic transparent table printing ink and preparation method thereof
CN105315772B (en) * 2015-10-14 2018-02-27 大连实利德漆业有限公司 Molten PET torsion films plastic, transparent table printing ink of alcohol and preparation method thereof
CN106928417A (en) * 2017-04-21 2017-07-07 苏州雄鹰笔墨科技有限公司 A kind of modified aldehyde ketone resin, preparation method and the application in writing ink
CN114058214A (en) * 2021-12-15 2022-02-18 乐凯华光印刷科技有限公司 UV (ultraviolet) curing inkjet ink and preparation method thereof

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Application publication date: 20140305