CN103613984A - Cleaning agent for cleaning printing ink of printing equipment and preparation method thereof - Google Patents
Cleaning agent for cleaning printing ink of printing equipment and preparation method thereof Download PDFInfo
- Publication number
- CN103613984A CN103613984A CN201310579649.9A CN201310579649A CN103613984A CN 103613984 A CN103613984 A CN 103613984A CN 201310579649 A CN201310579649 A CN 201310579649A CN 103613984 A CN103613984 A CN 103613984A
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- cleaning
- cleaning agent
- acid
- mixing kettle
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- 238000004140 cleaning Methods 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000012459 cleaning agent Substances 0.000 title abstract description 8
- 238000007639 printing Methods 0.000 title abstract description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 21
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- AOKRXIIIYJGNNU-UHFFFAOYSA-N 3-methylcyclopentan-1-one Chemical compound CC1CCC(=O)C1 AOKRXIIIYJGNNU-UHFFFAOYSA-N 0.000 claims abstract description 7
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910021538 borax Inorganic materials 0.000 claims abstract description 7
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229920001515 polyalkylene glycol Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 7
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 7
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 5
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 claims abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 239000012752 auxiliary agent Substances 0.000 claims description 11
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 6
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 6
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 6
- 235000019800 disodium phosphate Nutrition 0.000 claims description 6
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 6
- 229960003656 ricinoleic acid Drugs 0.000 claims description 6
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 2
- 230000006378 damage Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract description 2
- 230000002588 toxic effect Effects 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 2
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- 241000779819 Syncarpia glomulifera Species 0.000 abstract 1
- 230000003749 cleanliness Effects 0.000 abstract 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 1
- 239000001739 pinus spp. Substances 0.000 abstract 1
- 229940036248 turpentine Drugs 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 5
- 239000003502 gasoline Substances 0.000 description 4
- 239000003350 kerosene Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention discloses a cleaning agent for cleaning printing ink of printing equipment. The cleaning agent is characterized by being prepared from the following raw materials in parts by weight: 6-8 parts of turpentine, 10-12 parts of 3-methyl cyclopentanone, 3-4 parts of disodium hydrogen phosphate, 2-3 parts of borax, 3-4 parts of p-nitrobenzoic acid, 2-3 parts of sodium thiocyanate, 1-2 parts of aniline, 3-4 parts of melamine, 2-3 parts of sodium sulfate, 3-4 parts of citric acid, 10-12 parts of poly alkylene glycol, 4-5 parts of additive and 100-110 parts of water. The processing property of the cleaning agent is improved by adding the additive; the toxic and side effects and the pollution to environments of the cleaning agent are reduced; the cleaning agent has the advantages of being capable of reducing oil consumption, reducing the cost and equipment damage, improving the surface smoothness and cleanliness, being non-toxic and harmless to human bodies and having low volatility and wide prospect.
Description
Technical field
The present invention relates to print cleaning technique field, particularly a kind of clean-out system for cleaning of graphic arts equipment ink and preparation method thereof.
Background technology
In printing industry, often use now for printing machinery forme, rubber roll, blanket etc., to have the element purge of ink be to clean with organic solvents such as gasoline, kerosene, acetone, alcohol; Such clean-out system exists inflammable, explosive, contaminate environment, harm bedding sack is healthy, and to cleaning part, as: glue rod, blanket surface burn into swelling action, to parts damages, shorten work-ing life widely, simultaneously to using workman's skin of hand burn into injury of solvent, this solvent cleaning weak effect, gasoline, coal are the products of petroleum refining, and ballooning oil prices, can cause the waste of Nonrenewable resources petroleum-based energy so now.At present, the widely used clean-out system in market, is not that to be acidity be exactly to be alkalescence, is acid clean-out system and can has a strong impact on original true qualities and smooth finish, is alkaline clean-out system and can permeates cleaning objects, causes object corrosion, even comes off.
Novel printing ink cleaning agent is compared with kerosene with gasoline, and cleaning performance is good, and safety performance is high, and little to the pollution hazard of human body and environment.Novel printing ink cleaning agent normally consists of solvent, tensio-active agent, auxiliary agent, water.At present conventional solvent is still from non-renewable solvent oil, and such as kerosene, smell is large, and degradation property is poor, and environment is still existed to certain threat.
Summary of the invention
The object of this invention is to provide a kind of clean-out system for cleaning of graphic arts equipment ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
For a clean-out system for cleaning of graphic arts equipment ink, by the raw material of following weight part, made: turps 6-8,3-methyl-cyclopentanone 10-12, Sodium phosphate dibasic 3-4, borax 2-3, p-nitrobenzoic acid 3-4, Sodium Thiocyanate 99 2-3, aniline 1-2, trimeric cyanamide 3-4, sodium sulfate 2-3, citric acid 3-4, polyalkylene glycol 10-12, auxiliary agent 4-5, water 100-110;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, ricinolic acid 2-3, tea-polyphenol 2-3, glyceryl monostearate 4-5, neopentyl glycol 2-3, p-tert-butyl benzoic acid 3-4, oxidation inhibitor 1035 1-2, ethanol 15-18; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
Clean-out system for cleaning of graphic arts equipment ink of the present invention, by following concrete steps, made:
(1) at room temperature turps, 3-methyl-cyclopentanone, Sodium phosphate dibasic, borax, p-nitrobenzoic acid 3, Sodium Thiocyanate 99, aniline, trimeric cyanamide are added in mixing kettle, after the water of half amount is heated to 65-75 ℃, add in mixing kettle, be stirred to completely and dissolve;
(2) sodium sulfate, citric acid, polyalkylene glycol are added in mixing kettle, add the water of 80-90 ℃ of being heated to of surplus, with the speed of 1300-1500 rev/min, stir 4-5 minute;
(3) finally auxiliary agent and all the other remaining components are added in mixing kettle, stir, naturally cooling.
Excellent effect of the present invention is: the present invention adds auxiliary agent, has improved the processing performance of clean-out system, reduces its toxic side effect and the pollution to environment; Scavenging solution of the present invention can reduce oil consumption, reduces cost, reduce structure deteriorate, improves surface smoothness, strengthens degree of cleaning, nontoxic, volatilize little, harmlessly, and application prospect is extensive.
Embodiment
Below by specific examples, the present invention is described in detail.
For a clean-out system for cleaning of graphic arts equipment ink, by following weight part (kilogram) raw material make: turps 6,3-methyl-cyclopentanone 10, Sodium phosphate dibasic 3, borax 2, p-nitrobenzoic acid 3, Sodium Thiocyanate 99 2, aniline 1, trimeric cyanamide 3, sodium sulfate 2, citric acid 3, polyalkylene glycol 10, auxiliary agent 4, water 100;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 3, ricinolic acid 2, tea-polyphenol 2, glyceryl monostearate 4, neopentyl glycol 2, p-tert-butyl benzoic acid 4, oxidation inhibitor 1,035 1, ethanol 15; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
Clean-out system for cleaning of graphic arts equipment ink of the present invention, by following concrete steps, made:
(1) at room temperature turps, 3-methyl-cyclopentanone, Sodium phosphate dibasic, borax, p-nitrobenzoic acid 3, Sodium Thiocyanate 99, aniline, trimeric cyanamide are added in mixing kettle, after the water of half amount is heated to 65-75 ℃, add in mixing kettle, be stirred to completely and dissolve;
(2) sodium sulfate, citric acid, polyalkylene glycol are added in mixing kettle, add the water of 80-90 ℃ of being heated to of surplus, with the speed of 1300-1500 rev/min, stir 4-5 minute;
(3) finally auxiliary agent and all the other remaining components are added in mixing kettle, stir, naturally cooling.
Ink is applied on the stainless steel metal thin slice of certain mass, under state of nature, dries, steel disc is placed in to the beaker that fills clean-out system, at 25 ℃, soak after 5 minutes, more at the uniform velocity vibrate 5 minutes, obtaining cleaning soil removal efficiency is 93.1%, and cleansing power is good.With this clean-out system with gasoline, kerosene, compare, rubber cloth increases the service life 2 years, ink roller can increase the service life 2 years.
Claims (2)
1. the clean-out system for cleaning of graphic arts equipment ink, it is characterized in that, by the raw material of following weight part, made: turps 6-8,3-methyl-cyclopentanone 10-12, Sodium phosphate dibasic 3-4, borax 2-3, p-nitrobenzoic acid 3-4, Sodium Thiocyanate 99 2-3, aniline 1-2, trimeric cyanamide 3-4, sodium sulfate 2-3, citric acid 3-4, polyalkylene glycol 10-12, auxiliary agent 4-5, water 100-110;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, ricinolic acid 2-3, tea-polyphenol 2-3, glyceryl monostearate 4-5, neopentyl glycol 2-3, p-tert-butyl benzoic acid 3-4, oxidation inhibitor 1035 1-2, ethanol 15-18; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. according to claim 1 for the clean-out system of cleaning of graphic arts equipment ink, it is characterized in that, by following concrete steps, made:
(1) at room temperature turps, 3-methyl-cyclopentanone, Sodium phosphate dibasic, borax, p-nitrobenzoic acid 3, Sodium Thiocyanate 99, aniline, trimeric cyanamide are added in mixing kettle, after the water of half amount is heated to 65-75 ℃, add in mixing kettle, be stirred to completely and dissolve;
(2) sodium sulfate, citric acid, polyalkylene glycol are added in mixing kettle, add the water of 80-90 ℃ of being heated to of surplus, with the speed of 1300-1500 rev/min, stir 4-5 minute;
(3) finally auxiliary agent and all the other remaining components are added in mixing kettle, stir, naturally cooling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310579649.9A CN103613984B (en) | 2013-11-19 | 2013-11-19 | A kind of cleaning agent for cleaning of graphic arts equipment ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310579649.9A CN103613984B (en) | 2013-11-19 | 2013-11-19 | A kind of cleaning agent for cleaning of graphic arts equipment ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103613984A true CN103613984A (en) | 2014-03-05 |
| CN103613984B CN103613984B (en) | 2016-05-25 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310579649.9A Active CN103613984B (en) | 2013-11-19 | 2013-11-19 | A kind of cleaning agent for cleaning of graphic arts equipment ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103613984B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101050323A (en) * | 2007-04-24 | 2007-10-10 | 华南理工大学 | Cleaning agent for ink printed on surface of plastic and preparation method |
| CN101089168A (en) * | 2007-06-19 | 2007-12-19 | 吕连新 | Multifunctional cleaning agent |
| CN101434764A (en) * | 2007-11-15 | 2009-05-20 | 中国石油化工股份有限公司 | Printing ink cleaning agent |
| CN102558941A (en) * | 2010-12-31 | 2012-07-11 | 宋国新 | Printing ink cleaning agent |
-
2013
- 2013-11-19 CN CN201310579649.9A patent/CN103613984B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101050323A (en) * | 2007-04-24 | 2007-10-10 | 华南理工大学 | Cleaning agent for ink printed on surface of plastic and preparation method |
| CN101089168A (en) * | 2007-06-19 | 2007-12-19 | 吕连新 | Multifunctional cleaning agent |
| CN101434764A (en) * | 2007-11-15 | 2009-05-20 | 中国石油化工股份有限公司 | Printing ink cleaning agent |
| CN102558941A (en) * | 2010-12-31 | 2012-07-11 | 宋国新 | Printing ink cleaning agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103613984B (en) | 2016-05-25 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Cleaning agent for cleaning printing ink of printing equipment and preparation method thereof Effective date of registration: 20170818 Granted publication date: 20160525 Pledgee: Huizhou Merchants Bank, Limited by Share Ltd, Fuyang Ying River West Road subbranch Pledgor: ANHUI BENSE PRINTING CO., LTD. Registration number: 2017340000164 |
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Date of cancellation: 20181012 Granted publication date: 20160525 Pledgee: Huizhou Merchants Bank, Limited by Share Ltd, Fuyang Ying River West Road subbranch Pledgor: ANHUI BENSE PRINTING CO., LTD. Registration number: 2017340000164 |
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Denomination of invention: Cleaning agent for cleaning printing ink of printing equipment and preparation method thereof Effective date of registration: 20181017 Granted publication date: 20160525 Pledgee: Huizhou Merchants Bank, Limited by Share Ltd, Fuyang Ying River West Road subbranch Pledgor: ANHUI BENSE PRINTING CO., LTD. Registration number: 2018330000311 |
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Date of cancellation: 20191203 Granted publication date: 20160525 Pledgee: Huizhou Merchants Bank, Limited by Share Ltd, Fuyang Ying River West Road subbranch Pledgor: ANHUI BENSE PRINTING CO., LTD. Registration number: 2018330000311 |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
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Denomination of invention: Cleaning agent for cleaning printing ink of printing equipment and preparation method thereof Effective date of registration: 20191205 Granted publication date: 20160525 Pledgee: Huizhou Merchants Bank, Limited by Share Ltd, Fuyang Ying River West Road subbranch Pledgor: ANHUI BENSE PRINTING CO., LTD. Registration number: Y2019330000253 |
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Date of cancellation: 20201016 Granted publication date: 20160525 Pledgee: Huizhou Merchants Bank Limited by Share Ltd. Fuyang Ying River West Road subbranch Pledgor: ANHUI COLOR PRINTING Co.,Ltd. Registration number: Y2019330000253 |
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Denomination of invention: A cleaning agent for cleaning printing ink and its preparation method Effective date of registration: 20201019 Granted publication date: 20160525 Pledgee: Huizhou Merchants Bank Limited by Share Ltd. Fuyang Ying River West Road subbranch Pledgor: ANHUI COLOR PRINTING Co.,Ltd. Registration number: Y2020980006903 |