CN103613291A - Glass mildew isolation powder and preparation method thereof - Google Patents

Glass mildew isolation powder and preparation method thereof Download PDF

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Publication number
CN103613291A
CN103613291A CN201310555092.5A CN201310555092A CN103613291A CN 103613291 A CN103613291 A CN 103613291A CN 201310555092 A CN201310555092 A CN 201310555092A CN 103613291 A CN103613291 A CN 103613291A
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China
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parts
glass
insulating powder
proof insulating
filler
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CN201310555092.5A
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CN103613291B (en
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陈得军
李向南
张会双
刘玉民
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Henan Normal University
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Henan Normal University
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Abstract

The invention discloses glass mildew isolation powder and a preparation method thereof. The technical scheme is as follows: the glass mildew isolation powder contains the following components in parts by weight: 2-6 parts of bactericide, 10-20 parts of antifouling and scratch-resistant agent, 20-40 parts of hard filler and 40-60 parts of soft filler, wherein the bactericide is one or more selected from benzisothiazolone, sodium pyrithione, 8-quinolinol and hexahydro-1, 3, 5-tris(2-hydroxyethyl)-s-triazine, the antifouling and scratch-resistant agent is one or more selected from methyl polytetrafluoroethylene, polyethylene wax and rosin, the hard filler is one or more selected from quartz sand, boron nitride and boron carbide, and the soft filler is one or more selected from lithium carbonate, lithium sulfate and organic bentonite. The invention also discloses the preparation method of the glass mildew isolation powder. The glass mildew isolation powder has the advantages of excellent mildew resistance, good flowability, strong adhesivity, easiness for cleaning, high efficiency and environmental friendliness.

Description

A kind of glass fungus-proof insulating powder and preparation method thereof
Technical field
The invention belongs to fine chemical technology field, be specifically related to a kind of glass fungus-proof insulating powder and preparation method thereof.
Background technology
The go mouldy problem of glass in storage, transportation is a great problem of glass industry always, especially at high temperature wet season, if glass is not carried out to mildew-resistant, process the quality that will have a strong impact on glasswork, cause glass enterprise image in the client of downstream to be had a greatly reduced quality, more affected finished product price.The glass generation chemical reaction that goes mouldy, changes glass surface character, and the glass article surface after mouldy can tarnish, and transparency reduces, and presents rainbow, hickie or paster phenomenon (not easily separated) etc., has had a strong impact on the quality of glassy product.Therefore, select a kind of good glass fungus-proof product particularly important.
At present, glass fungus-proof protection mainly contains every paper mildew-resistant, mildew-retarding liquid mildew-resistant, fungus-proof insulating powder mildew-resistant three major types: every paper mildew-resistant, although there is the advantages such as simple to operate, anti-mold effect is good, recoverable, because its use cost is too high, storage period, long easily to produce the shortcomings such as paper seal particularly evident; Mildew-retarding liquid product is still not mature enough at present, and market rate of utilization is not high, has the shortcomings such as overlong time easily causes not washing clean clearly; Fungus-proof insulating powder is used in and in glass sandwich, can kills or the growth of mould fungus inhibition, and has mildew-resistant, protection against the tide, corrosion resistant effect, has also played the liner effect that rubs between glass of preventing simultaneously.In addition, glass fungus-proof insulating powder consumption is few, cost is low.
Due to the continuous expansion of glass purposes with to the improving constantly of glass requirements, produce that a kind of fungicidal properties is good, good fluidity, adhesive power are strong, the novel glass fungus-proof insulating powder of easy cleaning and high-efficiency environment friendly is with a wide range of applications.
Summary of the invention
The present invention provides for overcoming the deficiency of existing glass fungus-proof insulating powder product that a kind of fungicidal properties is good, good fluidity, adhesivity are strong, the glass fungus-proof insulating powder of easy cleaning and high-efficiency environment friendly, and the present invention also provides the preparation method of this glass fungus-proof insulating powder.
Technical scheme of the present invention is: a kind of glass fungus-proof insulating powder, it is characterized in that the component that this glass fungus-proof insulating powder contains following weight part: sterilant 2-6 part, antifouling anti-zoned dose of 10-20 part, hard filler 20-40 part and soft filler 40-60 part, wherein sterilant is BIT, sodium pyrithione, oxine or six hydrogen-1, 3, one or more in 5-tri-(2-hydroxyethyl) s-triazine, antifouling anti-zoned dose is methyl tetrafluoroethylene, one or more in polyethylene wax or rosin, hard filler is quartz sand, one or more in boron nitride or norbide, soft filler is Quilonum Retard, one or more in Lithium Sulphate or organobentonite.
The component that glass fungus-proof insulating powder of the present invention contains following weight part: 20 parts of 1 part of sodium pyrithione, 3 parts of oxines, 7 parts of methyl tetrafluoroethylene, 4 parts of polyethylene waxs, 5 parts of rosin, 10 parts of quartz sands, 10 parts of boron nitride, 10 parts of norbides, 20 parts of Quilonum Retards, 10 parts of Lithium Sulphates and organobentonites.
The preparation method of glass fungus-proof insulating powder of the present invention, it is characterized in that concrete steps are: the raw material that takes respectively following weight part, sterilant 2-6 part, antifouling anti-zoned dose of 10-20 part, hard filler 20-40 part and soft filler 40-60 part, wherein sterilant is BIT, sodium pyrithione, oxine or six hydrogen-1, 3, one or more in 5-tri-(2-hydroxyethyl) s-triazine, antifouling anti-zoned dose is methyl tetrafluoroethylene, one or more in polyethylene wax or rosin, hard filler is quartz sand, one or more in boron nitride or norbide, soft filler is Quilonum Retard, one or more in Lithium Sulphate or organobentonite, after the raw material taking is mixed, be crushed to 325 orders and make below glass fungus-proof insulating powder.
The preparation method's of glass fungus-proof insulating powder of the present invention concrete steps are: the raw material that takes respectively following weight part, 20 parts of 1 part of sodium pyrithione, 3 parts of oxines, 7 parts of methyl tetrafluoroethylene, 4 parts of polyethylene waxs, 5 parts of rosin, 10 parts of quartz sands, 10 parts of boron nitride, 10 parts of norbides, 20 parts of Quilonum Retards, 10 parts of Lithium Sulphates and organobentonites, be crushed to 325 orders after the raw material taking is mixed and make below glass fungus-proof insulating powder.
Beneficial effect of the present invention is:
1, glass fungus-proof insulating powder is state-of-the art chemosynthesis pulvis, there is the features such as environmental protection, efficient, easy cleaning, its use cost only has 1/10th of glass holding paper, compares every paper method with tradition, and it has reducing costs, improves the obviously advantage such as effect and environmental protection;
2, the good fluidity of product of the present invention, adhesive power are strong, have excellent friction gasket performance simultaneously, and the glass that dusts can effectively carry out isolation and protection by glass and the wiping scuffing that can not produce glass surface in normal storing;
3, in product of the present invention, contain special anti-mouldy material composition, can effectively stop the reaction of going mouldy of glass surface, there is good anti-mold effect;
4, the uniform particles of product of the present invention, consumption is few, cost is low, does not endanger in process of production operator, safe and environment friendly and pollution-free.
Embodiment
The embodiment of form, is described in further details foregoing of the present invention by the following examples, but this should be interpreted as to the scope of the above-mentioned theme of the present invention only limits to following embodiment.All technology realizing based on foregoing of the present invention all belong to scope of the present invention.
Embodiment
Take respectively following raw material (kilogram):
1, BIT 2, methyl tetrafluoroethylene 20, quartz sand 20 and Quilonum Retard 60;
2, six hydrogen-1,3,5-tri-(2-hydroxyethyl) s-triazine 6, rosin 10, norbide 40 and organobentonite 40;
3, sodium pyrithione 4, polyethylene wax 15, boron nitride 30 and Lithium Sulphate 50;
4, BIT 2, six hydrogen-1,3,5-tri-(2-hydroxyethyl) s-triazine 2, polyethylene wax 10, rosin 5, quartz sand 10, boron nitride 10, norbide 10, Quilonum Retard 20, Lithium Sulphate 10 and organobentonite 20;
5, BIT 2, sodium pyrithione 3, methyl tetrafluoroethylene 7, polyethylene wax 5, boron nitride 10, norbide 15, Quilonum Retard 20 and Lithium Sulphate 30;
6, sodium pyrithione 1, oxine 3, methyl tetrafluoroethylene 7, polyethylene wax 4, rosin 5, quartz sand 10, boron nitride 10, norbide 10, Quilonum Retard 20, Lithium Sulphate 10 and organobentonite 20.
After the above-mentioned raw material taking is mixed respectively, be crushed to 325 orders and make below glass fungus-proof insulating powder.
Above embodiment has described ultimate principle of the present invention, principal character and advantage.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that in above-described embodiment and specification sheets, describes just illustrates principle of the present invention; do not departing under the scope of the principle of the invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the scope of protection of the invention.

Claims (4)

1. a glass fungus-proof insulating powder, it is characterized in that the component that this glass fungus-proof insulating powder contains following weight part: sterilant 2-6 part, antifouling anti-zoned dose of 10-20 part, hard filler 20-40 part and soft filler 40-60 part, wherein sterilant is BIT, sodium pyrithione, oxine or six hydrogen-1, 3, one or more in 5-tri-(2-hydroxyethyl) s-triazine, antifouling anti-zoned dose is methyl tetrafluoroethylene, one or more in polyethylene wax or rosin, hard filler is quartz sand, one or more in boron nitride or norbide, soft filler is Quilonum Retard, one or more in Lithium Sulphate or organobentonite.
2. glass fungus-proof insulating powder according to claim 1, is characterized in that the component that described glass fungus-proof insulating powder contains following weight part: 20 parts of 1 part of sodium pyrithione, 3 parts of oxines, 7 parts of methyl tetrafluoroethylene, 4 parts of polyethylene waxs, 5 parts of rosin, 10 parts of quartz sands, 10 parts of boron nitride, 10 parts of norbides, 20 parts of Quilonum Retards, 10 parts of Lithium Sulphates and organobentonites.
3. the preparation method of a glass fungus-proof insulating powder claimed in claim 1, it is characterized in that concrete steps are: the raw material that takes respectively following weight part, sterilant 2-6 part, antifouling anti-zoned dose of 10-20 part, hard filler 20-40 part and soft filler 40-60 part, wherein sterilant is BIT, sodium pyrithione, oxine or six hydrogen-1, 3, one or more in 5-tri-(2-hydroxyethyl) s-triazine, antifouling anti-zoned dose is methyl tetrafluoroethylene, one or more in polyethylene wax or rosin, hard filler is quartz sand, one or more in boron nitride or norbide, soft filler is Quilonum Retard, one or more in Lithium Sulphate or organobentonite, after the raw material taking is mixed, be crushed to 325 orders and make below glass fungus-proof insulating powder.
4. the preparation method of glass fungus-proof insulating powder according to claim 3, it is characterized in that concrete steps are: the raw material that takes respectively following weight part, 20 parts of 1 part of sodium pyrithione, 3 parts of oxines, 7 parts of methyl tetrafluoroethylene, 4 parts of polyethylene waxs, 5 parts of rosin, 10 parts of quartz sands, 10 parts of boron nitride, 10 parts of norbides, 20 parts of Quilonum Retards, 10 parts of Lithium Sulphates and organobentonites, be crushed to 325 orders after the raw material taking is mixed and make below glass fungus-proof insulating powder.
CN201310555092.5A 2013-11-11 2013-11-11 Glass mildew isolation powder and preparation method thereof Expired - Fee Related CN103613291B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559274A (en) * 2014-07-23 2015-04-29 南京汉旗新材料科技有限公司 Long-acting moldproof low-hygroscopicity high-adsorptivity plant fiber material type glass moldproof parting powder
CN108863106A (en) * 2018-08-10 2018-11-23 佛山腾鲤新能源科技有限公司 A kind of preparation method of solar energy rolled glass special mildewproof isolated material
CN117105539A (en) * 2023-08-15 2023-11-24 湖南旗滨光能科技有限公司 Glass mildew-proof powder and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6509057B2 (en) * 1998-04-01 2003-01-21 Sumitomo Osaka Cement, Co., Ltd. Antibacterial, antifungal or antialgal article and process for producing same
CN101113078A (en) * 2007-07-10 2008-01-30 程道远 Novel glass fungus-proof insulating powder
CN102924942A (en) * 2012-10-25 2013-02-13 南京汉旗新材料科技有限公司 Modified plant fiber material type glass moldproof parting powder

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6509057B2 (en) * 1998-04-01 2003-01-21 Sumitomo Osaka Cement, Co., Ltd. Antibacterial, antifungal or antialgal article and process for producing same
CN101113078A (en) * 2007-07-10 2008-01-30 程道远 Novel glass fungus-proof insulating powder
CN102924942A (en) * 2012-10-25 2013-02-13 南京汉旗新材料科技有限公司 Modified plant fiber material type glass moldproof parting powder

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李勇等: "太阳能玻璃专用防霉隔离粉研究思路", 《玻璃》, no. 7, 31 July 2009 (2009-07-31), pages 9 - 12 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559274A (en) * 2014-07-23 2015-04-29 南京汉旗新材料科技有限公司 Long-acting moldproof low-hygroscopicity high-adsorptivity plant fiber material type glass moldproof parting powder
CN108863106A (en) * 2018-08-10 2018-11-23 佛山腾鲤新能源科技有限公司 A kind of preparation method of solar energy rolled glass special mildewproof isolated material
CN117105539A (en) * 2023-08-15 2023-11-24 湖南旗滨光能科技有限公司 Glass mildew-proof powder and preparation method thereof
CN117105539B (en) * 2023-08-15 2024-06-04 湖南旗滨光能科技有限公司 Glass mildew-proof powder and preparation method thereof

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