CN107668190A - A kind of nano normal temperature fresh-keeping corrugated box - Google Patents

A kind of nano normal temperature fresh-keeping corrugated box Download PDF

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Publication number
CN107668190A
CN107668190A CN201710908930.0A CN201710908930A CN107668190A CN 107668190 A CN107668190 A CN 107668190A CN 201710908930 A CN201710908930 A CN 201710908930A CN 107668190 A CN107668190 A CN 107668190A
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China
Prior art keywords
fresh
keeping
normal temperature
corrugated box
nano
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CN201710908930.0A
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Chinese (zh)
Inventor
张晓斌
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Guangdong Zhong Sui Paper Products Co Ltd
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Guangdong Zhong Sui Paper Products Co Ltd
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Priority to CN201710908930.0A priority Critical patent/CN107668190A/en
Publication of CN107668190A publication Critical patent/CN107668190A/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/144Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • A23B7/152Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere comprising other gases in addition to CO2, N2, O2 or H2O ; Elimination of such other gases
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/153Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
    • A23B7/154Organic compounds; Microorganisms; Enzymes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D5/00Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
    • B65D5/42Details of containers or of foldable or erectable container blanks
    • B65D5/56Linings or internal coatings, e.g. pre-formed trays provided with a blow- or thermoformed layer
    • B65D5/563Laminated linings; Coatings

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Zoology (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Mechanical Engineering (AREA)
  • Microbiology (AREA)
  • Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
  • Storage Of Fruits Or Vegetables (AREA)
  • Packages (AREA)

Abstract

The present invention proposes a kind of nano normal temperature fresh-keeping corrugated box, including casing and the polylith ethylene absorption cloth that is arranged in the casing, the interior are coated with nanometer fresh-keeping layer, and the nanometer fresh-keeping layer includes following raw material components:Nano diatomite, sodium acid carbonate, polyethyleneimine, antiseptic, deionized water, the ethylene absorption cloth surface is sequentially coated with water evaporation inhibitor and ethene adsorbent, the present invention is matched by the design of rational box house and coating material, effectively increase the fresh-keeping effect of fruits and vegetables under normal temperature, anti-oxidant, antibacterial, anti-corrosion, water conservation, freshness be respectively provided with are obviously improved, it can extend the fresh-keeping storage phase of 3 20 days for the agricultural product of different cultivars, there is good market popularization value.

Description

A kind of nano normal temperature fresh-keeping corrugated box
Technical field
The present invention relates to fruit preservation paper box technical field, and in particular to a kind of nano normal temperature fresh-keeping corrugated box.
Background technology
More and more extensive with the individual demand of commodity, feature corrugated case also increasingly attracts attention, so-called Feature corrugated case refers to using the packing container made of corrugated board with specific function, typically with lot of advantages, It is such as in light weight, structural behaviour is good, science is environmentally friendly, its internal corrugated structure is similar to domes, to packaging product energy Play a part of bumper and absorbing shock, there is good mechanical property.Meanwhile he also has many good protection work(to packing article Can, for example, moistureproof, radiating, it is fresh-keeping, refrigerate, be easily portable, freight is lower, and is easily achieved packaging and the machinery of transport Change and automation, the change of specification and size are more easily implemented, the packaging of all kinds of articles can be rapidly adapted to, joint sealing, tired bundle are square Just, it is easy to automated job, adapts to the decoration printing of various types of ambitions, can solve commodity protection and promotion is asked Topic, useless case are easily recycled, and meet environmental requirement, can be by being combined with various coverings or barrier material, so as to significantly Extend its scope of application.
300,000,000 tons annual of yield of vegetables of China, fruits output, because fresh-keeping industry falls behind, have every year more than 60,000,000 tons 80000000 tons of fruits and vegetables rot, and lose nearly 80,000,000,000 yuan of total value.At present, existing preserving fruit and vegetable utilizing carton is typically put in carton Antistaling agent is put, but so fresh-keeping scope is small, whard to control, and it is fresh-keeping uneven, still easily there is phenomena such as rotten of addling, then Also to there is some coating fresh-keeping technologies in recent years, i.e., applying last layer in fruit and vegetable surfaces has the edibility film of preservation, but There is also it is many problem of, such as coating thickness is whard to control, drying time is long, easy cooperating microorganisms, and in fruit and vegetable surfaces Film is not easy to be esthetically acceptable to the consumers.
The content of the invention
For above-mentioned problem, the present invention proposes a kind of nano normal temperature fresh-keeping corrugated box, by rational casing Portion designs and coating material proportioning, effectively increases the fresh-keeping effect of fruits and vegetables under normal temperature, anti-oxidant, antibacterial, anti-corrosion, water conservation, guarantor Fresh property, which is respectively provided with, to be obviously improved, and can extend the fresh-keeping storage phase of 3-20 days for the agricultural product of different cultivars, is had well Market popularization value.
In order to realize above-mentioned purpose, the present invention uses following technical scheme:
A kind of nano normal temperature fresh-keeping corrugated box, including casing and the polylith ethylene absorption cloth that is arranged in the casing, it is described Interior is coated with nanometer fresh-keeping layer, and the nanometer fresh-keeping layer includes following raw material components:Nano diatomite, bicarbonate Sodium, polyethyleneimine, antiseptic, deionized water, the ethylene absorption cloth surface are sequentially coated with water evaporation inhibitor and second Alkene adsorbent.Wherein, ethylene absorption cloth is layered when being cased for fruits and vegetables to fruits and vegetables every putting;Nanometer fresh-keeping layer coated weight be 0.6-0.8L/m2, water evaporation inhibitor coated weight is 0.3-0.4L/m2, ethene adsorbent coated weight is 0.1-0.3L/m2.This Invention nano normal temperature fresh-keeping corrugated box uses 600 × 400 × 500 (mm) specification, and ethylene absorption cloth is 600 × 400 (mm).
Preferably, the ethylene absorption cloth uses cotton fiber or flaxen fiber material, and the ethylene absorption cloth is at least provided with one Block.
Preferably, each raw material percentage composition ratio is in the nanometer fresh-keeping layer:Nano diatomite 20-40%, sodium acid carbonate 5-10%, polyethyleneimine 8-11%, antiseptic 9-13%, deionized water surplus.Specific nanometer fresh-keeping layer preparation technology is such as Under:Raw material is first weighed by weight, nano-bentonite is added in deionized water, 30 DEG C of isothermal vibrations 30-40min, Ran Hou The sodium acid carbonate of 1/3 dosage is slowly added under stirring condition, is then warming up to 52 DEG C, insulated and stirred 2-3min with 1-2 DEG C/min, Then 25 DEG C or so are naturally cooling under stirring condition, adds polyethyleneimine and antiseptic thereto successively, stirring (can be artificial Stirring, at least 30min, or use ultrasonic disperse 5-10min) uniformly after produce the fresh-keeping coating of nanometer, coating is using preceding needing Stir.
Preferably, the antiseptic is one or more combinations in Tea Polyphenols, allicin, eugenol, beeswax, eucalyptus oil Thing.
Preferably, the antiseptic is the composition of Tea Polyphenols, beeswax and eucalyptus oil, and it is 0.8 that three, which adds mass ratio,: 0.5:1-2.
Preferably, the water evaporation inhibitor be alcohols solvent, Sodium Polyacrylate, the combination solution of deionized water, three It is 2 that person, which adds volume ratio,:4:5.
Preferably, the alcohols solvent is the unitary alcohol mixture that carbon number is 4-18, is preferably volume ratio 1-2:1 Butanol and mixture or the volume/mass ratio of lauryl alcohol be 1-3:1 butanol and the mixture of octadecyl alcolol, the polyacrylic acid Sodium relative molecular mass is 50-200.
Preferably, the ethene adsorbent be vermiculite power, iron powder and liquor potassic permanganate mixture, three's mass/matter Amount/volume ratio is 6g/1.2-2g/120mL.
Preferably, the liquor potassic permanganate mass fraction is 0.05-0.1%.
Due to using above-mentioned technical scheme, the beneficial effects of the invention are as follows:The present invention is set by rational box house Meter and coating material proportioning, the fresh-keeping effect of fruits and vegetables under normal temperature is effectively increased, and overall fresh-keeping effect homogeneity is high, fresh-keeping model Enclose extensively, anti-oxidant, antibacterial, anti-corrosion, water conservation, freshness be respectively provided with are obviously improved, and can extend for the agricultural product of different cultivars The fresh-keeping storage phase of 3-20 days, there is good market popularization value.
Nanometer fresh-keeping layer is using diatomite as main porous carrier, and wherein on the one hand sodium acid carbonate supplies alkali with good Property, moisture absorption suppress growth of microorganism, and on the other hand with excellent foaming effect, coordinate the high reaction activity of polyethyleneimine, The blended cross linking effect between diatomite is effectively strengthened, and loose structure stability strengthens, and is advantageous to the further of antiseptic It is uniformly distributed blending.In addition, polyethyleneimine has good enhancement and hygroscopicity, the locking of fruits and vegetables moisture is ensure that, then Coordinate the water evaporation inhibitor on ethylene absorption cloth surface water replenishment effectively can be carried out to fruits and vegetables for a long time, significantly extend Fresh keeping time, and polyethyleneimine can be chemically bonded with hydroxyl, further increase the knot between fresh-keeping coating and carton With joint efforts, it is of good preservation effect, service life length.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention, Technical scheme in the embodiment of the present invention is clearly and completely described.Based on embodiments of the invention, the common skill in this area The every other embodiment that art personnel are obtained under the premise of creative work is not made, belong to the model that the present invention protects Enclose.
Embodiment 1:
A kind of nano normal temperature fresh-keeping corrugated box, including casing (use with one piece of ethylene absorption cloth being arranged in the casing It is prepared by flaxen fiber), the interior is coated with nanometer fresh-keeping layer, and the nanometer fresh-keeping layer includes following raw material components:Receive Rice diatomite, sodium acid carbonate, polyethyleneimine, antiseptic, deionized water, the ethylene absorption cloth surface is sequentially coated with moisture Evaporation suppressor and ethene adsorbent.Nanometer fresh-keeping layer coated weight is 0.65L/m2, water evaporation inhibitor coated weight is 0.32L/m2, ethene adsorbent coated weight is 0.2L/m2
Wherein, each raw material percentage composition ratio is in nanometer fresh-keeping layer:Nano diatomite 25%, sodium acid carbonate 8%, polyethylene Imines 8%, antiseptic 9%, deionized water surplus;Antiseptic is the composition of Tea Polyphenols, beeswax and eucalyptus oil, and three adds matter Amount is than being 0.8:0.5:1.
Water evaporation inhibitor is alcohols solvent, Sodium Polyacrylate, the combination solution of deionized water, and three adds volume ratio For 2:4:5, wherein alcohols solvent is volume ratio 2:1 butanol and the mixture of lauryl alcohol, the Sodium Polyacrylate average molecular Quality is 150.
Ethene adsorbent is the mixture of vermiculite power, iron powder and liquor potassic permanganate, and three's mass/mass/volume ratio is 6g/1.2g/120mL, wherein liquor potassic permanganate mass fraction are 0.05%.
Embodiment 2:
A kind of nano normal temperature fresh-keeping corrugated box, including casing (use with one piece of ethylene absorption cloth being arranged in the casing It is prepared by flaxen fiber), the interior is coated with nanometer fresh-keeping layer, and the nanometer fresh-keeping layer includes following raw material components:Receive Rice diatomite, sodium acid carbonate, polyethyleneimine, antiseptic, deionized water, the ethylene absorption cloth surface is sequentially coated with moisture Evaporation suppressor and ethene adsorbent.Nanometer fresh-keeping layer coated weight is 0.8L/m2, water evaporation inhibitor coated weight is 0.38L/ m2, ethene adsorbent coated weight is 0.26L/m2
Wherein, each raw material percentage composition ratio is in nanometer fresh-keeping layer:Nano diatomite 40%, sodium acid carbonate 5%, polyethylene Imines 10%, antiseptic 10%, deionized water surplus;Antiseptic is the composition of Tea Polyphenols, beeswax and eucalyptus oil, and three adds Mass ratio is 0.8:0.5:1.5.
Water evaporation inhibitor is alcohols solvent, Sodium Polyacrylate, the combination solution of deionized water, and three adds volume ratio For 2:4:5, wherein alcohols solvent is volume ratio 1:1 butanol and the mixture of lauryl alcohol, the Sodium Polyacrylate average molecular Quality is 200.
Ethene adsorbent is the mixture of vermiculite power, iron powder and liquor potassic permanganate, and three's mass/mass/volume ratio is 6g/1.6g/120mL, wherein liquor potassic permanganate mass fraction are 0.05%.
Embodiment 3:
A kind of nano normal temperature fresh-keeping corrugated box, including casing (use with one piece of ethylene absorption cloth being arranged in the casing It is prepared by flaxen fiber), the interior is coated with nanometer fresh-keeping layer, and the nanometer fresh-keeping layer includes following raw material components:Receive Rice diatomite, sodium acid carbonate, polyethyleneimine, antiseptic, deionized water, the ethylene absorption cloth surface is sequentially coated with moisture Evaporation suppressor and ethene adsorbent.Nanometer fresh-keeping layer coated weight is 0.7L/m2, water evaporation inhibitor coated weight is 0.4L/ m2, ethene adsorbent coated weight is 0.16L/m2
Wherein, each raw material percentage composition ratio is in nanometer fresh-keeping layer:Nano diatomite 30%, sodium acid carbonate 8%, polyethylene Imines 11%, antiseptic 12%, deionized water surplus;Antiseptic is the composition of Tea Polyphenols, beeswax and eucalyptus oil, and three adds Mass ratio is 0.8:0.5:2.
Water evaporation inhibitor is alcohols solvent, Sodium Polyacrylate, the combination solution of deionized water, and three adds volume ratio For 2:4:5, wherein alcohols solvent is that volume/mass ratio is 2:1 butanol and the mixture of octadecyl alcolol, the Sodium Polyacrylate phase It is 50 to molecular mass.
Ethene adsorbent is the mixture of vermiculite power, iron powder and liquor potassic permanganate, and three's mass/mass/volume ratio is 6g/2g/120mL, wherein liquor potassic permanganate mass fraction are 0.1%.
Embodiment 4:
A kind of nano normal temperature fresh-keeping corrugated box, including casing (use with one piece of ethylene absorption cloth being arranged in the casing It is prepared by flaxen fiber), the interior is coated with nanometer fresh-keeping layer, and the nanometer fresh-keeping layer includes following raw material components:Receive Rice diatomite, sodium acid carbonate, polyethyleneimine, antiseptic, deionized water, the ethylene absorption cloth surface is sequentially coated with moisture Evaporation suppressor and ethene adsorbent.Nanometer fresh-keeping layer coated weight is 0.66L/m2, water evaporation inhibitor coated weight is 0.35L/m2, ethene adsorbent coated weight is 0.24L/m2
Wherein, each raw material percentage composition ratio is in nanometer fresh-keeping layer:Nano diatomite 20%, sodium acid carbonate 6%, polyethylene Imines 10%, antiseptic 13%, deionized water surplus;Antiseptic is the composition of Tea Polyphenols, beeswax and eucalyptus oil, and three adds Mass ratio is 0.8:0.5:2.
Water evaporation inhibitor is alcohols solvent, Sodium Polyacrylate, the combination solution of deionized water, and three adds volume ratio For 2:4:5, wherein alcohols solvent is that volume/mass ratio is 3:1 butanol and the mixture of octadecyl alcolol, the Sodium Polyacrylate phase It is 100 to molecular mass.
Ethene adsorbent is the mixture of vermiculite power, iron powder and liquor potassic permanganate, and three's mass/mass/volume ratio is 6g/1.8g/120mL, wherein liquor potassic permanganate mass fraction are 0.1%.
Embodiment 5:
A kind of nano normal temperature fresh-keeping corrugated box, including casing (use with one piece of ethylene absorption cloth being arranged in the casing It is prepared by flaxen fiber), the interior is coated with nanometer fresh-keeping layer, and the nanometer fresh-keeping layer includes following raw material components:Receive Rice diatomite, sodium acid carbonate, polyethyleneimine, antiseptic, deionized water, the ethylene absorption cloth surface is sequentially coated with moisture Evaporation suppressor and ethene adsorbent.Nanometer fresh-keeping layer coated weight is 0.65L/m2, water evaporation inhibitor coated weight is 0.35L/m2, ethene adsorbent coated weight is 0.1L/m2
Wherein, each raw material percentage composition ratio is in nanometer fresh-keeping layer:Nano diatomite 30%, sodium acid carbonate 10%, poly- second Alkene imines 8%, antiseptic 12%, deionized water surplus;Antiseptic be Tea Polyphenols, beeswax and eucalyptus oil composition, San Zhetian It is 0.8 to add mass ratio:0.5:1.5.
Water evaporation inhibitor is alcohols solvent, Sodium Polyacrylate, the combination solution of deionized water, and three adds volume ratio For 2:4:5, wherein alcohols solvent is that volume/mass ratio is 1:1 butanol and the mixture of octadecyl alcolol, the Sodium Polyacrylate phase It is 150 to molecular mass.
Ethene adsorbent is the mixture of vermiculite power, iron powder and liquor potassic permanganate, and three's mass/mass/volume ratio is 6g/1.5g/120mL, wherein liquor potassic permanganate mass fraction are 0.1%.
Fresh-keeping corrugated box made from the embodiment of the present invention is equally used for the storage of fruits and vegetables with conventional untreated common carton, Fresh keeping time extends 10-20 days;By fresh-keeping corrugated box made from the embodiment of the present invention and the simple carton for being only coated with fresh-keeping layer The storage of fruits and vegetables is equally used for, fresh keeping time extends 3-11 days;By fresh-keeping corrugated box made from the embodiment of the present invention and simple The carton for being equipped with ethylene absorption cloth is equally used for the storage of fruits and vegetables, and fresh keeping time extends 8-12 days.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments The present invention is described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic;And these modification or Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (9)

1. a kind of nano normal temperature fresh-keeping corrugated box, it is characterised in that inhaled including casing and the polylith ethene being arranged in the casing Attached cloth, the interior are coated with nanometer fresh-keeping layer, and the nanometer fresh-keeping layer includes following raw material components:Nanometer diatom Soil, sodium acid carbonate, polyethyleneimine, antiseptic, deionized water, the ethylene absorption cloth surface are sequentially coated with moisture evaporation suppression Preparation and ethene adsorbent.
2. nano normal temperature fresh-keeping corrugated box according to claim 1, it is characterised in that:The ethylene absorption cloth uses cotton fiber Or flaxen fiber material, the ethylene absorption cloth is at least provided with one piece.
3. nano normal temperature fresh-keeping corrugated box according to claim 1, it is characterised in that each raw material hundred in the nanometer fresh-keeping layer Point content ratio is:Nano diatomite 20-40%, sodium acid carbonate 5-10%, polyethyleneimine 8-11%, antiseptic 9-13%, go Ion water surplus.
4. nano normal temperature fresh-keeping corrugated box according to claim 3, it is characterised in that:The antiseptic is Tea Polyphenols, garlic One or more compositions in element, eugenol, beeswax, eucalyptus oil.
5. nano normal temperature fresh-keeping corrugated box according to claim 4, it is characterised in that:The antiseptic is Tea Polyphenols, beeswax With the composition of eucalyptus oil, it is 0.8 that three, which adds mass ratio,:0.5:1-2.
6. nano normal temperature fresh-keeping corrugated box according to claim 1, it is characterised in that:The water evaporation inhibitor is alcohols Solvent, Sodium Polyacrylate, the combination solution of deionized water, it is 2 that three, which adds volume ratio,:4:5.
7. nano normal temperature fresh-keeping corrugated box according to claim 6, it is characterised in that:The alcohols solvent is that carbon number is 4-18 unitary alcohol mixture, the Sodium Polyacrylate relative molecular mass are 50-200.
8. nano normal temperature fresh-keeping corrugated box according to claim 1, it is characterised in that:The ethene adsorbent be vermiculite power, The mixture of iron powder and liquor potassic permanganate, three's mass/mass/volume ratio are 6g/1.2-2g/120mL.
9. nano normal temperature fresh-keeping corrugated box according to claim 8, it is characterised in that:The liquor potassic permanganate mass fraction For 0.05-0.1%.
CN201710908930.0A 2017-09-29 2017-09-29 A kind of nano normal temperature fresh-keeping corrugated box Pending CN107668190A (en)

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CN111235899A (en) * 2020-03-10 2020-06-05 贾晶晶 Environment-friendly easily-degradable fresh-keeping cloth
CN114304257A (en) * 2021-12-21 2022-04-12 广西东鸣现代农业发展有限公司 Method for preserving kumquats in winter through long-distance transportation
CN115636985A (en) * 2022-09-08 2023-01-24 广西大学 Preparation method and application of antibacterial breathable biomass-based packaging film

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111235899A (en) * 2020-03-10 2020-06-05 贾晶晶 Environment-friendly easily-degradable fresh-keeping cloth
CN114304257A (en) * 2021-12-21 2022-04-12 广西东鸣现代农业发展有限公司 Method for preserving kumquats in winter through long-distance transportation
CN115636985A (en) * 2022-09-08 2023-01-24 广西大学 Preparation method and application of antibacterial breathable biomass-based packaging film
CN115636985B (en) * 2022-09-08 2023-08-04 广西大学 Preparation method and application of antibacterial breathable biomass-based packaging film

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Application publication date: 20180209