CN103602060A - Heat-conducting, wear-resistant and insulated nylon 6 composite material and preparation method thereof - Google Patents
Heat-conducting, wear-resistant and insulated nylon 6 composite material and preparation method thereof Download PDFInfo
- Publication number
- CN103602060A CN103602060A CN201310541445.6A CN201310541445A CN103602060A CN 103602060 A CN103602060 A CN 103602060A CN 201310541445 A CN201310541445 A CN 201310541445A CN 103602060 A CN103602060 A CN 103602060A
- Authority
- CN
- China
- Prior art keywords
- heat
- heat conduction
- conducting
- insulating
- matrix material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a heat-conducting, wear-resistant and insulated nylon 6 composite material and a preparation method thereof. The material is composed of the following raw materials in percentage by weight: 20-50% of PA 6, 10-30% of fibrous heat-conducting fillers, 15-30% of insulated heat-conducting powder A, 5-10% of insulated heat-conducting powder B, 5-15% of heat-conducting wear-resistant powder, 0.75-1.5% of coupling agent, 3-10% of compatibilizer, 0.2-0.5% of antioxidant and 0.2-0.5% of lubricant. According to the heat-conducting, wear-resistant and insulated nylon 6 composite material provided by the invention, heat-conducting fillers with different particle sizes, different shapes and different draw ratios are compounded so that the fillers are more uniformly distributed in a plastic matrix so as to form a heat-conducting network more easily. Since a low-feeding high-shearing extrusion process is used in the invention, an extruder is at a hungry state to achieve an effect of dispersing the fillers more uniformly. When the fibrous heat conducting fillers are added, a single screw extruder is used, so that the fibers can be sheared into smaller size, the damage is smaller, and meanwhile, the fillers are dispersed more uniformly by extruding the fillers by the extruder for the second time; and the heat-conducting, wear-resistant and insulated nylon 6 composite material provided by the invention has the advantages of good heat conducting effect, excellent wear resistance, easy workability, etc.
Description
Technical field
The present invention relates to a kind of heat conduction abrasion-proof insulating nylon 6 composite material and preparation method thereof.
Background technology
Along with the fast development of circuit card large scale integration and micro-packaging technology, electronic devices and components volume constantly dwindles, and packing density is more and more higher, and power is in continuous increase, and thermal value also increases thereupon.Therefore, heat radiation becomes a major issue in electronic industry, has metal, pottery and the carbon material of excellent heat conductivity performance, due to electrical insulating property or the poor restriction of machine-shaping property, has been difficult to meet the demand of hyundai electronics industry.Nylon 6 has superior over-all properties, comprises physical strength, rigidity, toughness, mechanical shock absorption and wear resistance.These characteristics, add good electrical isolation capabilities and chemical resistant properties, nylon 6 is widely used, but its thermal conductivity are lower, only have 0.30 W/mK, have limited its application in heat radiation, heat conduction field.
For the low situation of nylon guide heating rate, Chinese scholars has been done a large amount of research, conventional method is to add heat conductive filler to reach the object that improves nylon guide heating rate now, but be all difficult to accomplish that thermal conductivity, mechanical property, electrical insulation capability and wear resisting property are all very excellent, majority can only be accomplished wherein one or two excellent performance.
Patent CN1775860A has introduced a kind of injection molding moulded heat-conductive insulated plastics that can be used for, utilize heat conductive filler composite of large particle diameter heat conductive filler and small particle size, can access thermal conductivity is 3.469 W/mk, has the moulded heat-conductive insulated plastics of certain mechanical property and processing characteristics.It is larger that but its mechanical property and wear resisting property all lose.
Summary of the invention
One of object of the present invention is for deficiency of the prior art, and a kind of heat conduction abrasion-proof insulating nylon 6 composite material is provided.
Two of object of the present invention is to provide a kind of preparation method of this heat conduction abrasion-proof insulating nylon 6 composite material.
For achieving the above object, the technical scheme that the present invention takes is:
The resistance to insulation mill of a heat conduction nylon 6 composite material, the composition that it is characterized in that this matrix material is that quality percentage composition is as follows:
PA6 20-50%，
Fibrous heat conductive filler 10-30%,
Insulating heat-conductive powder A 15-30%,
Insulating heat-conductive powder B 5-10%,
Heat conduction abrasion-resistant powder 5-15%,
Coupling agent 0.75-1.5%,
Compatilizer 3-10%,
Oxidation inhibitor 0.2-0.5%,
Lubricant 0.2-0.5%;
The quality percentage composition sum of each component is 100% above.
The relative viscosity of above-mentioned nylon 6 is 2.40-3.43.
Above-mentioned fibrous heat conductive filler is carbon fiber.
Above-mentioned insulating heat-conductive powder A is at least one in silicon carbide, magnesium oxide, aluminum oxide, and particle diameter is at 50～100 μ m.
Above-mentioned insulating heat-conductive powder B is at least one in boron nitride, magnesium oxide, aluminum oxide, and particle diameter is at 1-10 μ m.
Above-mentioned heat conduction abrasion-resistant powder is at least one in expanded graphite, crystalline flake graphite, and particle diameter is at 50-200 μ m.
Above-mentioned coupling agent is at least one in silicane, titanate ester or aluminate coupling agent.
Above-mentioned compatilizer is CMG9805.
Above-mentioned oxidation inhibitor be Hinered phenols antioxidant and phosphite ester kind antioxidant is composite or antioxidant 1010 and irgasfos 168 composite.
Above-mentioned lubricant is silicone powder MB-4 or TAF.
A method of preparing above-mentioned heat conduction abrasion-proof insulating PA6 matrix material, is characterized in that the concrete steps of the method are:
A. by PA6 raw material stoving;
B. for insulating heat-conductive powder A, insulating heat-conductive powder B, heat conduction abrasion-resistant powder and coupling agent fully mix, obtain heat conductive filler;
C. fibrous heat conductive filler is immersed in to 30min in coupling agent, takes out standby;
D. by step b gained heat conductive filler and PA6, compatilizer, oxidation inhibitor, mix lubricant evenly after, through extruding water-cooled granulation, the frequency of main frame is 35-45Hz, feeding frequency is 5-11Hz, temperature is 215-235 ℃, obtains granulation material one time;
E. by the dry extruding pelletization together with the fibrous heat conductive filler of step c gained afterwards of granulation material of steps d gained, obtain heat conduction abrasion-proof insulating PA6 matrix material.。
The invention has the advantages that:
1, the nylon 6 composite material that prepared by present method, volume resistance can reach 10
12Ω * cm;
2, the nylon 6 composite material that prepared by present method, guarantees that volume resistance can reach 10
12in the time of Ω * cm, its thermal conductivity can reach 6 W/mK.
3, the nylon 6 composite material that prepared by present method, in the situation that guaranteeing above-mentioned 2 performances, the frictional coefficient of nylon 6 composite material can reach 0.13.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but the present invention's scope required for protection is not limited to the scope that embodiment records.
embodiment 1
(1) take by weight ratio raw material: PA6:20%, 50 μ m magnesium oxide 30%, 3 μ m aluminum oxide 10%, 50 μ m crystalline flake graphites 10%, carbon fiber 25%, Compatibilizer C MG9805 3.5% silane coupling agent 1.5%, MB-4 0.2%, 16,8/1,010 0.4%.
(2) by above-mentioned magnesium oxide, aluminum oxide, crystalline flake graphite joins in high-speed mixer, then adds silane coupling agent to mix standby.
(3) the above-mentioned heat conductive filler mixing is joined in high-speed mixer and mixed together with PA6, processing aid, compatilizer, join in twin-screw extrusion owner hello barrel.
(4) above-mentioned material is extruded and granulation through twin screw extruder, obtains granulation material one time, and the frequency of twin screw main frame is 42Hz, and feeding frequency is 7Hz, and temperature is 225 ℃.
(5) a granulation material is joined to the main hello barrel of single screw extrusion machine, extruding pelletization together with the carbon fiber good with coupling agent treatment, obtains the moulded heat-conductive insulated plastics for injection moulding.
embodiment 2
((1) takes raw material: PA6:30% by weight ratio, 50 μ m aluminum oxide 20%, 3 μ m boron nitride 10%, 50 μ m crystalline flake graphites 15%, and carbon fiber 20%, Compatibilizer C MG9805 3.5% silane coupling agent 1.5%, MB-4 0.2%, 16,8/1,010 0.4%.
(2) by above-mentioned aluminum oxide, boron nitride, crystalline flake graphite joins in high-speed mixer, then adds silane coupling agent to mix standby.
(3) the above-mentioned heat conductive filler mixing is joined in high-speed mixer and mixed together with PA6, processing aid, compatilizer, join in twin-screw extrusion owner hello barrel.
(4) above-mentioned material is extruded and granulation through twin screw extruder, obtains granulation material one time, and the frequency of twin screw main frame is 40Hz, and feeding frequency is 9Hz, and temperature is 235 ℃.
(5) a granulation material is joined to the main hello barrel of single screw extrusion machine, extruding pelletization together with the carbon fiber good with coupling agent treatment, obtains the moulded heat-conductive insulated plastics for injection moulding.
embodiment 3
(1) take by weight ratio raw material: PA6:40%, 50 μ m magnesium oxide 20%, 5 μ m magnesium oxide 10%, 50 μ m expanded graphites 10%, carbon fiber 15%, Compatibilizer C MG9805 3.5% silane coupling agent 1.5%, MB-4 0.2%, 16,8/1,010 0.4%.
(2) by above-mentioned magnesium oxide, expanded graphite joins in high-speed mixer, then adds silane coupling agent to mix standby.
(3) the above-mentioned heat conductive filler mixing is joined in high-speed mixer and mixed together with PA6, processing aid, compatilizer, join in twin-screw extrusion owner hello barrel.
(4) above-mentioned material is extruded and granulation through twin screw extruder, obtains granulation material one time, and the frequency of twin screw main frame is 40Hz, and feeding frequency is 10Hz, and temperature is 235 ℃.
(5) a granulation material is joined to the main hello barrel of single screw extrusion machine, extruding pelletization together with the carbon fiber good with coupling agent treatment, obtains the moulded heat-conductive insulated plastics for injection moulding.
embodiment 4
(1) take by weight ratio raw material: PA6:50%, 50 μ m silicon carbide 20%, 3 μ m boron nitride 10%, 50 μ m expanded graphites 5%, carbon fiber 10%, Compatibilizer C MG9805 3.5% silane coupling agent 1.5%, TAF 0.2%, 16,8/1,010 0.4%.
(2) by above-mentioned silicon carbide, boron nitride, expanded graphite joins in high-speed mixer, then adds silane coupling agent to mix standby.
(3) the above-mentioned heat conductive filler mixing is joined in high-speed mixer and mixed together with PA6, processing aid, compatilizer, join in twin-screw extrusion owner hello barrel.
(4) above-mentioned material is extruded and granulation through twin screw extruder, obtains granulation material one time, and the frequency of twin screw main frame is 45Hz, and feeding frequency is 10Hz, and temperature is 215 ℃.
(5) a granulation material is joined to the main hello barrel of single screw extrusion machine, extruding pelletization together with the carbon fiber good with coupling agent treatment, obtains the moulded heat-conductive insulated plastics for injection moulding.
comparative example 1
(1) take by weight ratio raw material: PA6:40%, 50 μ m magnesium oxide 20%, 5 μ m magnesium oxide 10%, 50 μ m expanded graphites 15%, carbon fiber 10%, Compatibilizer C MG9805 3.5% silane coupling agent 1.5%, MB-4 0.2%, 16,8/1,010 0.4%.
(2) by above-mentioned magnesium oxide, expanded graphite joins in high-speed mixer, then adds silane coupling agent to mix standby.
(3) the above-mentioned heat conductive filler mixing is joined in high-speed mixer and mixed together with PA6, processing aid, compatilizer, join in twin-screw extrusion owner hello barrel.
(4) above-mentioned material is extruded and granulation through twin screw extruder, obtains granulation material one time, and the frequency of twin screw main frame is 40Hz, and feeding frequency is 10Hz, and temperature is 235 ℃.
(5) a granulation material is joined to the main hello barrel of single screw extrusion machine, extruding pelletization together with the carbon fiber good with coupling agent treatment, obtains the moulded heat-conductive insulated plastics for injection moulding.
comparative example 2
(1) take by weight ratio raw material: PA6:40%, 50 μ m magnesium oxide 20%, 5 μ m magnesium oxide 10%, 50 μ m expanded graphites 15%, carbon fiber 10%, Compatibilizer C MG9805 3.5% silane coupling agent 1.5%, MB-4 0.2%, 16,8/1,010 0.4%.
(2) by above-mentioned magnesium oxide, expanded graphite joins in high-speed mixer, then adds silane coupling agent to mix standby.
(3) the above-mentioned heat conductive filler mixing is joined in high-speed mixer and mixed together with PA6, processing aid, compatilizer, join in twin-screw extrusion owner hello barrel.
(4) together with the carbon fiber that above-mentioned material is good with coupling agent treatment, through twin screw extruder, extrude and granulation, obtain the moulded heat-conductive insulated plastics for injection moulding, the frequency of twin screw main frame is 40Hz, and feeding frequency is 10Hz, and temperature is 235 ℃.
The physicals of the wear-resisting PA6 of heat conductive insulating prepared by comparative example 1-2 and embodiment 1-4 sees the following form 1.
The physicals of the wear-resisting PA6 of heat conductive insulating prepared by table 1 comparative example 1-2 and embodiment 1-5
The present invention adopts special complete processing and suitable compatilizer, has improved the consistency between PA6 and heat conductive filler and heat conducting fiber, has optimized the processing characteristics of alloy and the dispersiveness of filler; This heat conduction abrasion-proof insulating nylon 6 composite material has the advantages such as good mechanical property, wear resistance, insulativity, high heat conduction and easy machine-shaping.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, do not departing under the prerequisite of the inventive method; can also make some improvement and supplement, these improvement and supplement and also should be considered as protection scope of the present invention.
Claims (11)
1. a nylon 6 composite material is ground in the resistance to insulation of heat conduction, and the composition that it is characterized in that this matrix material is that quality percentage composition is as follows:
PA6 20-50%，
Fibrous heat conductive filler 10-30%,
Insulating heat-conductive powder A 15-30%,
Insulating heat-conductive powder B 5-10%,
Heat conduction abrasion-resistant powder 5-15%,
Coupling agent 0.75-1.5%,
Compatilizer 3-10%,
Oxidation inhibitor 0.2-0.5%,
Lubricant 0.2-0.5%;
The quality percentage composition sum of each component is 100% above.
2. heat conduction abrasion-proof insulating PA6 matrix material according to claim 1, is characterized in that the relative viscosity of described nylon 6 is 2.40-3.43.
3. heat conduction abrasion-proof insulating PA6 matrix material according to claim 1, is characterized in that described fibrous heat conductive filler is carbon fiber.
4. heat conduction abrasion-proof insulating PA6 matrix material according to claim 1, is characterized in that described insulating heat-conductive powder A is at least one in silicon carbide, magnesium oxide, aluminum oxide, and particle diameter is at 50～100 μ m.
5. heat conduction abrasion-proof insulating PA6 matrix material according to claim 1, is characterized in that described insulating heat-conductive powder B is at least one in boron nitride, magnesium oxide, aluminum oxide, and particle diameter is at 1-10 μ m.
6. heat conduction abrasion-proof insulating PA6 matrix material according to claim 1, is characterized in that described heat conduction abrasion-resistant powder is at least one in expanded graphite, crystalline flake graphite, and particle diameter is at 50-200 μ m.
7. heat conduction abrasion-proof insulating PA6 matrix material according to claim 1, is characterized in that described coupling agent is at least one in silicane, titanate ester or aluminate coupling agent.
8. heat conduction abrasion-proof insulating PA6 matrix material according to claim 1, is characterized in that described compatilizer is CMG9805.
9. heat conduction abrasion-proof insulating PA6 matrix material according to claim 1, it is characterized in that described oxidation inhibitor be Hinered phenols antioxidant and phosphite ester kind antioxidant is composite or antioxidant 1010 and irgasfos 168 composite.
10. heat conduction abrasion-proof insulating PA6 matrix material according to claim 1, is characterized in that described lubricant is silicone powder MB-4 or TAF.
Prepare according to the method for the heat conduction abrasion-proof insulating PA6 matrix material described in any one in claim 1-10, its spy for 11. 1 kinds
Levy and be that the concrete steps of the method are:
A. by PA6 raw material stoving;
B. for insulating heat-conductive powder A, insulating heat-conductive powder B, heat conduction abrasion-resistant powder and coupling agent fully mix, obtain heat conductive filler;
C. fibrous heat conductive filler is immersed in to 30min in coupling agent, takes out standby;
D. by step b gained heat conductive filler and PA6, compatilizer, oxidation inhibitor, mix lubricant evenly after, through extruding water-cooled granulation, the frequency of main frame is 35-45Hz, feeding frequency is 5-11Hz, temperature is 215-235 ℃, obtains granulation material one time;
E. by the dry extruding pelletization together with the fibrous heat conductive filler of step c gained afterwards of granulation material of steps d gained, obtain heat conduction abrasion-proof insulating PA6 matrix material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310541445.6A CN103602060B (en) | 2013-11-06 | 2013-11-06 | Heat conduction abrasion-proof insulating nylon 6 composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310541445.6A CN103602060B (en) | 2013-11-06 | 2013-11-06 | Heat conduction abrasion-proof insulating nylon 6 composite material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103602060A true CN103602060A (en) | 2014-02-26 |
| CN103602060B CN103602060B (en) | 2016-08-17 |
Family
ID=50120331
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310541445.6A Expired - Fee Related CN103602060B (en) | 2013-11-06 | 2013-11-06 | Heat conduction abrasion-proof insulating nylon 6 composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103602060B (en) |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104017331A (en) * | 2014-05-23 | 2014-09-03 | 青岛科柏利高性能聚合物有限公司 | Insulation heat-conduction plastic and preparation method thereof |
| CN104046002A (en) * | 2014-07-10 | 2014-09-17 | 苏州新区华士达工程塑胶有限公司 | Heat-conduction polyamide |
| CN104151707A (en) * | 2014-08-13 | 2014-11-19 | 上海交通大学 | Carbon fiber reinforced resin composite material with superior heat-conducting property and preparation method thereof |
| CN104387761A (en) * | 2014-11-11 | 2015-03-04 | 惠州市沃特新材料有限公司 | High-thermal conductivity polyamide composite material and preparation method thereof |
| CN104559145A (en) * | 2014-12-16 | 2015-04-29 | 惠州力王佐信科技有限公司 | High-toughness and high-thermal-conductivity polymer material and preparation method thereof |
| CN104559149A (en) * | 2014-12-16 | 2015-04-29 | 惠州力王佐信科技有限公司 | Carbon composite high-thermal-conductivity plastic material and preparation method thereof |
| CN104788951A (en) * | 2015-05-04 | 2015-07-22 | 武汉轻工大学 | LED (light-emitting diode) high-thermal-conductivity composite material and preparation method thereof |
| CN105111726A (en) * | 2015-09-01 | 2015-12-02 | 南通拜林新材料科技有限公司 | Heat conducting nylon composite material and preparation method thereof |
| CN105315668A (en) * | 2014-05-27 | 2016-02-10 | 大信科技有限公司 | Highly thermally conductive inorganic-polymer complex composition applied to lighting LED that contains expanded graphite and manufacturing method thereof |
| CN105419322A (en) * | 2015-12-08 | 2016-03-23 | 安徽天瑞塑业有限公司 | Nylon abrasive filament and manufacturing method thereof |
| CN105838060A (en) * | 2015-11-05 | 2016-08-10 | 东莞市伟的工程塑料有限公司 | Crystal fiber mixed heat conduction plastic material and preparation method thereof |
| CN105924952A (en) * | 2016-05-16 | 2016-09-07 | 南通市东方塑胶有限公司 | Heat conductive and insulating composite material for LED and preparation method thereof |
| CN106009651A (en) * | 2016-07-12 | 2016-10-12 | 蚌埠高华电子股份有限公司 | Silicon carbide-polyamide thermal conductive composite material for LED lamps and preparation method of material |
| CN106009652A (en) * | 2016-07-12 | 2016-10-12 | 蚌埠高华电子股份有限公司 | Aluminum oxide-nylon heat conduction composite material for LED lamp and preparing method thereof |
| CN106046770A (en) * | 2016-07-12 | 2016-10-26 | 蚌埠高华电子股份有限公司 | Wave-absorbing LED-lamp nylon heat-conduction composite and preparing method thereof |
| CN106189209A (en) * | 2016-08-24 | 2016-12-07 | 浙江佳华精化股份有限公司 | Polyamide compoiste material that a kind of high heat conduction Organic Black Masterbatch adds and preparation method thereof |
| CN107033587A (en) * | 2017-03-06 | 2017-08-11 | 苏州隆芝耀新材料有限公司 | A kind of Heat conduction nylon composite material and preparation method thereof |
| CN107254168A (en) * | 2017-07-10 | 2017-10-17 | 余姚市顺迪塑料模具厂 | The fire-retardant nylon and preparation method of a kind of rub resistance |
| CN107880542A (en) * | 2017-11-28 | 2018-04-06 | 苏州科茂电子材料科技有限公司 | Wear-resisting, heat conduction the assembling base-material and preparation method of use for electronic products |
| CN108659523A (en) * | 2018-05-05 | 2018-10-16 | 安徽旭升新材料有限公司 | A kind of highly-conductive hot carbon fiber PA6 composite material and preparation methods |
| CN109456593A (en) * | 2017-09-06 | 2019-03-12 | 中南大学 | A kind of PA6 base heat-conductive composite material and preparation method thereof |
| CN110734644A (en) * | 2019-06-24 | 2020-01-31 | 上海大学 | heat-conducting insulating boron nitride polymer composite material and preparation method thereof |
| CN111040324A (en) * | 2019-12-31 | 2020-04-21 | 深圳第三代半导体研究院 | Composite heat dissipation material for semiconductor and preparation method thereof |
| CN114410104A (en) * | 2022-01-13 | 2022-04-29 | 南京聚隆科技股份有限公司 | Wear-resistant antistatic PA6-GF30 composite material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63270761A (en) * | 1987-04-28 | 1988-11-08 | Unitika Ltd | Polyamide resin composition of good thermal conductivity |
| CN1775860A (en) * | 2005-11-25 | 2006-05-24 | 华南理工大学 | Injection moulded heat-conductive insulated plastics |
| CN101899209A (en) * | 2010-03-30 | 2010-12-01 | 金发科技股份有限公司 | Heat conductive insulation material and preparation method thereof |
| CN102719099A (en) * | 2012-06-08 | 2012-10-10 | 金发科技股份有限公司 | Thermal conductive molding compound and preparation method thereof |
-
2013
- 2013-11-06 CN CN201310541445.6A patent/CN103602060B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63270761A (en) * | 1987-04-28 | 1988-11-08 | Unitika Ltd | Polyamide resin composition of good thermal conductivity |
| CN1775860A (en) * | 2005-11-25 | 2006-05-24 | 华南理工大学 | Injection moulded heat-conductive insulated plastics |
| CN101899209A (en) * | 2010-03-30 | 2010-12-01 | 金发科技股份有限公司 | Heat conductive insulation material and preparation method thereof |
| CN102719099A (en) * | 2012-06-08 | 2012-10-10 | 金发科技股份有限公司 | Thermal conductive molding compound and preparation method thereof |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104017331A (en) * | 2014-05-23 | 2014-09-03 | 青岛科柏利高性能聚合物有限公司 | Insulation heat-conduction plastic and preparation method thereof |
| CN104017331B (en) * | 2014-05-23 | 2016-06-01 | 青岛瑞益信新材料科技有限公司 | A kind of insulating and heat-conducting plastics and its preparation method |
| CN105315668A (en) * | 2014-05-27 | 2016-02-10 | 大信科技有限公司 | Highly thermally conductive inorganic-polymer complex composition applied to lighting LED that contains expanded graphite and manufacturing method thereof |
| CN104046002A (en) * | 2014-07-10 | 2014-09-17 | 苏州新区华士达工程塑胶有限公司 | Heat-conduction polyamide |
| CN104151707A (en) * | 2014-08-13 | 2014-11-19 | 上海交通大学 | Carbon fiber reinforced resin composite material with superior heat-conducting property and preparation method thereof |
| CN104387761A (en) * | 2014-11-11 | 2015-03-04 | 惠州市沃特新材料有限公司 | High-thermal conductivity polyamide composite material and preparation method thereof |
| CN104559145A (en) * | 2014-12-16 | 2015-04-29 | 惠州力王佐信科技有限公司 | High-toughness and high-thermal-conductivity polymer material and preparation method thereof |
| CN104559149A (en) * | 2014-12-16 | 2015-04-29 | 惠州力王佐信科技有限公司 | Carbon composite high-thermal-conductivity plastic material and preparation method thereof |
| CN104788951A (en) * | 2015-05-04 | 2015-07-22 | 武汉轻工大学 | LED (light-emitting diode) high-thermal-conductivity composite material and preparation method thereof |
| CN105111726A (en) * | 2015-09-01 | 2015-12-02 | 南通拜林新材料科技有限公司 | Heat conducting nylon composite material and preparation method thereof |
| CN105838060A (en) * | 2015-11-05 | 2016-08-10 | 东莞市伟的工程塑料有限公司 | Crystal fiber mixed heat conduction plastic material and preparation method thereof |
| CN105419322A (en) * | 2015-12-08 | 2016-03-23 | 安徽天瑞塑业有限公司 | Nylon abrasive filament and manufacturing method thereof |
| CN105924952A (en) * | 2016-05-16 | 2016-09-07 | 南通市东方塑胶有限公司 | Heat conductive and insulating composite material for LED and preparation method thereof |
| CN106009652A (en) * | 2016-07-12 | 2016-10-12 | 蚌埠高华电子股份有限公司 | Aluminum oxide-nylon heat conduction composite material for LED lamp and preparing method thereof |
| CN106046770A (en) * | 2016-07-12 | 2016-10-26 | 蚌埠高华电子股份有限公司 | Wave-absorbing LED-lamp nylon heat-conduction composite and preparing method thereof |
| CN106009651A (en) * | 2016-07-12 | 2016-10-12 | 蚌埠高华电子股份有限公司 | Silicon carbide-polyamide thermal conductive composite material for LED lamps and preparation method of material |
| CN106189209B (en) * | 2016-08-24 | 2018-08-03 | 浙江佳华精化股份有限公司 | A kind of polyamide compoiste material and preparation method thereof of the organic black agglomerate addition of high heat conduction |
| CN106189209A (en) * | 2016-08-24 | 2016-12-07 | 浙江佳华精化股份有限公司 | Polyamide compoiste material that a kind of high heat conduction Organic Black Masterbatch adds and preparation method thereof |
| CN107033587A (en) * | 2017-03-06 | 2017-08-11 | 苏州隆芝耀新材料有限公司 | A kind of Heat conduction nylon composite material and preparation method thereof |
| CN107254168A (en) * | 2017-07-10 | 2017-10-17 | 余姚市顺迪塑料模具厂 | The fire-retardant nylon and preparation method of a kind of rub resistance |
| CN109456593A (en) * | 2017-09-06 | 2019-03-12 | 中南大学 | A kind of PA6 base heat-conductive composite material and preparation method thereof |
| CN107880542A (en) * | 2017-11-28 | 2018-04-06 | 苏州科茂电子材料科技有限公司 | Wear-resisting, heat conduction the assembling base-material and preparation method of use for electronic products |
| CN108659523A (en) * | 2018-05-05 | 2018-10-16 | 安徽旭升新材料有限公司 | A kind of highly-conductive hot carbon fiber PA6 composite material and preparation methods |
| CN110734644A (en) * | 2019-06-24 | 2020-01-31 | 上海大学 | heat-conducting insulating boron nitride polymer composite material and preparation method thereof |
| CN111040324A (en) * | 2019-12-31 | 2020-04-21 | 深圳第三代半导体研究院 | Composite heat dissipation material for semiconductor and preparation method thereof |
| CN114410104A (en) * | 2022-01-13 | 2022-04-29 | 南京聚隆科技股份有限公司 | Wear-resistant antistatic PA6-GF30 composite material and preparation method thereof |
| CN114410104B (en) * | 2022-01-13 | 2024-04-16 | 南京聚隆科技股份有限公司 | Wear-resistant antistatic PA6-GF30 composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103602060B (en) | 2016-08-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103602060A (en) | Heat-conducting, wear-resistant and insulated nylon 6 composite material and preparation method thereof | |
| CN104559148A (en) | High-thermal-diffusion-coefficient high molecular material and preparation method thereof | |
| CN104151707B (en) | Carbon fiber reinforced resin composite material with superior heat-conducting property and preparation method thereof | |
| CN104559145A (en) | High-toughness and high-thermal-conductivity polymer material and preparation method thereof | |
| CN108250747B (en) | Thermoplastic polyetherimide insulating and heat-conducting composite material and preparation method thereof | |
| CN104559150A (en) | Antistatic caprolactam heat-conducting material and preparation method thereof | |
| CN104629187A (en) | Multifunctional polypropylene composite material and preparation method thereof | |
| CN104610714B (en) | A kind of polybutylene terephthalate (PBT)/Merlon insulating heat-conductive composite and preparation method thereof | |
| CN105295317A (en) | High-temperature resistance and low-temperature resistance PBT heat conduction and heat dissipating material, preparation method and applications thereof | |
| CN102604371B (en) | Insulating and heat conducting polyamide composite material with high cost performance and preparation method thereof | |
| CN104151768A (en) | Carbon fiber reinforced ABS (Acrylonitrile Butadiene Styrene) resin composite material with superior heat conductivity and preparation method | |
| CN102643480B (en) | Anti-static alloy composite material and preparation method thereof | |
| CN106675008B (en) | High-thermal-conductivity nylon 6 composite material and preparation method thereof | |
| CN103613923A (en) | High heat conducting nylon composite material and preparation method thereof | |
| CN105400192A (en) | Nylon blended polypropylene powder for selective laser sintering and preparation method thereof | |
| CN103642219A (en) | High-heat-conduction and high-temperature-resistant PPO (polyphenylene oxide)/PA (polyamide) alloy and preparation method thereof | |
| CN104072966A (en) | Multi-element composite heat-conducting functional master batch and preparation method thereof | |
| CN103862589A (en) | Method for preparing polyamide-based heat conduction composite material through melt blending | |
| CN105440665A (en) | Low-filling high-heat conductivity insulating nylon/polyphenyl ether alloy and preparation method thereof | |
| CN103435895A (en) | Method for preparing insulating high-thermal-conductivity composite material | |
| CN107383615A (en) | A kind of modified polypropylene material and preparation method thereof | |
| CN108929536A (en) | A kind of heat conductive electronic equipment graphene/polyamide compoiste material and preparation method | |
| CN105111727A (en) | Heat conducting nylon composite material and preparation method thereof | |
| CN105086155A (en) | Thermally conductive polypropylene-based composite material and preparation method thereof | |
| CN109294032B (en) | Multi-element composite filling particle modified heat-conducting PE composite material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160817 Termination date: 20181106 |