CN103589363B - Cold-pressed self-adhesive tape - Google Patents

Cold-pressed self-adhesive tape Download PDF

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Publication number
CN103589363B
CN103589363B CN201310562154.5A CN201310562154A CN103589363B CN 103589363 B CN103589363 B CN 103589363B CN 201310562154 A CN201310562154 A CN 201310562154A CN 103589363 B CN103589363 B CN 103589363B
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parts
colding pressing
coated foam
line
layer
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CN103589363A (en
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江日新
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Huizhou Reed new materials Polytron Technologies Inc
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HUIZHOU XINHAOYUAN DEVELOPMENT Co Ltd
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  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to a tape, in particular to a self-adhesive tape with improved performance and an improved structure. The cold-pressed self-adhesive tape comprises a PET (polyethylene terephthalate) film layer, a bonding agent layer, a cotton paper layer and an emulsion layer sequentially from top to bottom. The cold-pressed self-adhesive tape which adopts the PET film as a substrate layer and has superior tensile strength and good toughness is provided.

Description

The one single-coated foam of colding pressing
Technical field
The present invention relates to adhesive tape, be specifically related to a kind of single-coated foam that improves performance and structure.
Background technology
The single-coated foam of colding pressing is a kind ofly under less reactive force, just can form more firmly bonding force.The bonding force of single-coated foam is mainly Van der Waals force, and therefore, after bonding plane forms, the structure of gluing of surfaces can be not destroyed.Single-coated foam is to presser sensor, do not need heating, do not need solvent, do not need larger pressure, only need pressurize a little or with pointing once by realizing bonding a kind of adhesive tape.Be characterized in gluing being not difficult, shelling and not damaging of easily, taking off.
But in existing cold-pressed adhesive tape, multiplex kraft paper, as substrate layer, causes the shortcomings such as adhesive tape thickness is thickeied, and it is not strong that adhesive tape has toughness, and tensile strength is poor like this.And be wrapped on a round core when cold-pressed adhesive tape, while being bent to form an adhesive tape disc, because kraft paper thickness is larger, cause entire volume length of tape shorter.
Summary of the invention
Technical problem to be solved by this invention be to provide a kind of taking PET film as substrate layer, there is the single-coated foam of colding pressing of good tensile strength, good toughness.
Technical problem to be solved by this invention is achieved by the following technical programs:
The one single-coated foam of colding pressing, is followed successively by PET rete, binder layer, cotton paper layer, emulsion layer from top to bottom.
Further, described binder layer is acrylic pressure sensitive glue-line.
Further, described acrylic pressure sensitive glue-line is made up of the component of following parts by weight:
25 ~ 35 parts of butyl acrylates;
120 ~ 140 parts of Isooctyl acrylate monomers;
15 ~ 23 parts of vinyl acetate between to for plastics;
4 ~ 7 parts of methacrylic acids;
4 ~ 7 parts of Rocryl 410s;
2 ~ 4 parts of glycidyl methacrylate;
1 ~ 3 part of acrylamide;
0.1 ~ 0.3 part of Diisopropyl azodicarboxylate;
0.3 ~ 0.5 part of dibenzoyl peroxide;
65 ~ 90 parts of toluene;
100 ~ 130 parts of ethyl acetate;
1 ~ 5 part of isocyanic ester.
Further, described emulsion layer is genuine milk glue-line.
Further, described genuine milk glue-line is made up of the component of following parts by weight:
80 ~ 120 parts of natural emulsions;
20 ~ 40 parts of rosin milks;
1 ~ 3 part of p-cresol and dicyclopentadiene copolymer.
Further, described PET thicknesses of layers is 20 ~ 30 μ m.
Further, described binder layer thickness is 18 ~ 25 μ m.
Further, described cotton paper layer thickness is 15 ~ 20 μ m.
Further, described emulsion layer thickness is 15 ~ 20 μ m.
Traditional single-coated foam of colding pressing is using kraft paper as substrate layer, and the thickness of single kraft paper is just greater than 100 μ m; And in the present invention, contriver adopts PET film as substrate layer, its thickness is less, but itself and the gluing polar phase of genuine milk are poor large, cause bonding force poor, easily come unstuck.Therefore, contriver increases acrylic pressure sensitive glue-line and cotton paper layer cleverly in the middle of PET rete and genuine milk glue-line.Utilize the effect of acrylate pressure sensitive adhesive that PET film and cotton paper can be connected and composed successively; In addition, natural emulsion can be combined closely with cotton paper layer by rolling technology again, and natural emulsion has obvious infiltration effect on cotton paper, can further strengthen bonding force between the two, strengthens sticking power.Finally form the single-coated foam of colding pressing using PET film as substrate layer.
The present invention has following beneficial effect:
The single-coated foam of colding pressing of the present invention is just sticky little, when use two adhesive tapes to sticky, firm pasting, clinging power >=5N/in, pastes easily, retentivity is good, without cull, good toughness, tension is effective, tensile strength >=150N/in does not have phenomenon of rupture.And the single-coated foam thin thickness of colding pressing of the present invention, entire volume length of tape, up to more than 1000 meters, can greatly be enhanced productivity and reduce production costs.
Brief description of the drawings
Fig. 1 is the single-coated foam structural representation of colding pressing provided by the invention.
Embodiment
Preparation technology of the present invention is the routine techniques of the art, does not elaborate at this.
Below in conjunction with drawings and Examples, the present invention will be described in detail.
embodiment 1
As shown in Figure 1, the single-coated foam of colding pressing described in provided by the invention, is followed successively by PET rete 1, acrylic pressure sensitive glue-line 2, cotton paper layer 3, genuine milk glue-line 4 from top to bottom.The formula of described acrylic pressure sensitive glue-line is: 30 parts of butyl acrylates; 130 parts of Isooctyl acrylate monomers; 20 parts of vinyl acetate between to for plastics; 6 parts of methacrylic acids; 5 parts of Rocryl 410s; 3 parts of glycidyl methacrylate; 1 part of acrylamide; 0.16 part of Diisopropyl azodicarboxylate; 0.35 part of dibenzoyl peroxide; 80 parts of toluene; 120 parts of ethyl acetate; 3 parts of isocyanic ester.Described natural emulsion layer formula is 100 parts of natural emulsions; 30 parts of rosin milks; 1 part of p-cresol and dicyclopentadiene copolymer.Finally obtain by rolling technology the single-coated foam of colding pressing.Described PET thicknesses of layers is 25 μ m; Described acrylic pressure sensitive bondline thickness is 20 μ m; Described cotton paper layer thickness is 18 μ m; Described natural emulsion layer thickness is 17 μ m.
embodiment 2
As shown in Figure 1, the single-coated foam of colding pressing described in provided by the invention, is followed successively by PET rete 1, acrylic pressure sensitive glue-line 2, cotton paper layer 3, genuine milk glue-line 4 from top to bottom.The formula of described acrylic pressure sensitive glue-line is: 25 parts of butyl acrylates; 121 parts of Isooctyl acrylate monomers; 23 parts of vinyl acetate between to for plastics; 4 parts of methacrylic acids; 7 parts of Rocryl 410s; 4 parts of glycidyl methacrylate; 3 parts of acrylamides; 0.3 part of Diisopropyl azodicarboxylate; 0.5 part of dibenzoyl peroxide; 65 parts of toluene; 130 parts of ethyl acetate; 5 parts of isocyanic ester.Described natural emulsion layer formula is 83 parts of natural emulsions; 40 parts of rosin milks; 2.5 parts of p-cresol and dicyclopentadiene copolymers.Finally obtain by rolling technology the single-coated foam of colding pressing.Described PET thicknesses of layers is 20 μ m; Described acrylic pressure sensitive bondline thickness is 25 μ m; Described cotton paper layer thickness is 15 μ m; Described natural emulsion layer thickness is 20 μ m.
embodiment 3
As shown in Figure 1, the single-coated foam of colding pressing described in provided by the invention, is followed successively by PET rete 1, acrylic pressure sensitive glue-line 2, cotton paper layer 3, genuine milk glue-line 4 from top to bottom.The formula of described acrylic pressure sensitive glue-line is: 32 parts of butyl acrylates; 135 parts of Isooctyl acrylate monomers; 18 parts of vinyl acetate between to for plastics; 5 parts of methacrylic acids; 6 parts of Rocryl 410s; 3 parts of glycidyl methacrylate; 2 parts of acrylamides; 0.2 part of Diisopropyl azodicarboxylate; 0.4 part of dibenzoyl peroxide; 85 parts of toluene; 105 parts of ethyl acetate; 3.5 parts of isocyanic ester.Described natural emulsion layer formula is 115 parts of natural emulsions; 25 parts of rosin milks; 2 parts of p-cresol and dicyclopentadiene copolymers.Finally obtain by rolling technology the single-coated foam of colding pressing.Described PET thicknesses of layers is 28 μ m; Described acrylic pressure sensitive bondline thickness is 22 μ m; Described cotton paper layer thickness is 20 μ m; Described natural emulsion layer thickness is 15 μ m.
embodiment 4
As shown in Figure 1, the single-coated foam of colding pressing described in provided by the invention, is connected and composed successively by PET rete 1, acrylic pressure sensitive glue-line 2, cotton paper layer 3, synthetic latex layer 4 from top to bottom.The formula of described acrylic pressure sensitive glue-line is: 30 parts of butyl acrylates; 122 parts of Isooctyl acrylate monomers; 21 parts of vinyl acetate between to for plastics; 6 parts of methacrylic acids; 5 parts of Rocryl 410s; 2.5 parts of glycidyl methacrylate; 1 part of acrylamide; 0.1 part of Diisopropyl azodicarboxylate; 0.45 part of dibenzoyl peroxide; 75 parts of toluene; 125 parts of ethyl acetate; 2 parts of isocyanic ester.Described synthetic latex layer formula is 90 parts of synthetic latexs; 35 parts of rosin milks; 1.5 parts of p-cresol and dicyclopentadiene copolymers.Finally obtain by rolling technology the single-coated foam of colding pressing.Described PET thicknesses of layers is 22 μ m; Described acrylic pressure sensitive bondline thickness is 24 μ m; Described cotton paper layer thickness is 19 μ m; Described natural emulsion layer thickness is 17 μ m.
The above embodiment has only expressed embodiments of the present invention; it describes comparatively concrete and detailed; but can not therefore be interpreted as the restriction to the scope of the claims of the present invention; in every case the technical scheme that adopts the form that is equal to replacement or equivalent transformation to obtain, within all should dropping on protection scope of the present invention.

Claims (1)

1. the single-coated foam of colding pressing, is characterized in that: be followed successively by from top to bottom PET rete, binder layer, cotton paper layer, emulsion layer; Described binder layer is acrylic pressure sensitive glue-line;
Described acrylic pressure sensitive glue-line is made up of the component of following parts by weight:
25 ~ 35 parts of butyl acrylates;
120 ~ 140 parts of Isooctyl acrylate monomers;
15 ~ 23 parts of vinyl acetate between to for plastics;
4 ~ 7 parts of methacrylic acids;
4 ~ 7 parts of Rocryl 410s;
2 ~ 4 parts of glycidyl methacrylate;
1 ~ 3 part of acrylamide;
0.1 ~ 0.3 part of Diisopropyl azodicarboxylate;
0.3 ~ 0.5 part of dibenzoyl peroxide;
65 ~ 90 parts of toluene;
100 ~ 130 parts of ethyl acetate;
1 ~ 5 part of isocyanic ester.
2. the one according to claim 1 single-coated foam of colding pressing, is characterized in that: described emulsion layer is genuine milk glue-line.
3. the one according to claim 2 single-coated foam of colding pressing, is characterized in that: described genuine milk glue-line is made up of the component of following parts by weight:
80 ~ 120 parts of natural emulsions;
20 ~ 40 parts of rosin milks;
1 ~ 3 part of p-cresol and dicyclopentadiene copolymer.
4. the one according to claim 1 single-coated foam of colding pressing, is characterized in that: described PET thicknesses of layers is 20 ~ 30 μ m.
5. the one according to claim 1 single-coated foam of colding pressing, is characterized in that: described binder layer thickness is 18 ~ 25 μ m.
6. the one according to claim 1 single-coated foam of colding pressing, is characterized in that: described cotton paper layer thickness is 15 ~ 20 μ m.
7. the one according to claim 1 single-coated foam of colding pressing, is characterized in that: described emulsion layer thickness is 15 ~ 20 μ m.
CN201310562154.5A 2013-11-13 2013-11-13 Cold-pressed self-adhesive tape Active CN103589363B (en)

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105619994A (en) * 2014-11-03 2016-06-01 上海夏荷印刷器材有限公司 Novel weldable sealing paper can not be tore, and preparation method thereof
CN104962043A (en) * 2015-05-29 2015-10-07 吉翔宝(太仓)离型材料科技发展有限公司 PET photodiffusion release film
CN107699150A (en) * 2016-08-08 2018-02-16 惠州瑞德新材料科技股份有限公司 A kind of environmentally friendly cold-pressed adhesive tape
CN107603508A (en) * 2017-08-30 2018-01-19 浙江欧丽数码喷绘材料有限公司 A kind of removable traffic allowance and its preparation method and application

Citations (4)

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Publication number Priority date Publication date Assignee Title
CN201347238Y (en) * 2008-11-10 2009-11-18 江苏九鼎新材料股份有限公司 Fiber band
CN101942279A (en) * 2010-09-03 2011-01-12 北京立高科技股份有限公司 Self-bonding layer strip material with environmental protection and wide temperature change
WO2013016605A2 (en) * 2011-07-28 2013-01-31 3M Innovative Properties Company Laminated sheet, part affixed with laminated sheet, and process for production thereof
CN203569019U (en) * 2013-11-13 2014-04-30 惠州市新豪源发展有限公司 Cold-press self-adhesive tape

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201347238Y (en) * 2008-11-10 2009-11-18 江苏九鼎新材料股份有限公司 Fiber band
CN101942279A (en) * 2010-09-03 2011-01-12 北京立高科技股份有限公司 Self-bonding layer strip material with environmental protection and wide temperature change
WO2013016605A2 (en) * 2011-07-28 2013-01-31 3M Innovative Properties Company Laminated sheet, part affixed with laminated sheet, and process for production thereof
CN203569019U (en) * 2013-11-13 2014-04-30 惠州市新豪源发展有限公司 Cold-press self-adhesive tape

Non-Patent Citations (1)

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Title
杨玉昆等.《压敏胶制品技术手册》.《压敏胶制品技术手册》.化学工业出版社,2004,(第1版),197,207. *

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Address after: 516227, Shun Town, Guangdong, Huizhou province Hui Hui Road, Gan village, Shun Yuen Industrial Park

Patentee after: Huizhou Reed new materials Polytron Technologies Inc

Address before: 516227, Shun Town, Guangdong, Huizhou province Hui Hui Road, Gan village, Shun Yuen Industrial Park

Patentee before: HUIZHOU XINHAOYUAN DEVELOPMENT CO., LTD.