CN103589294A - Acrylic acid finishing paint and preparation method thereof - Google Patents
Acrylic acid finishing paint and preparation method thereof Download PDFInfo
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- CN103589294A CN103589294A CN201310466224.7A CN201310466224A CN103589294A CN 103589294 A CN103589294 A CN 103589294A CN 201310466224 A CN201310466224 A CN 201310466224A CN 103589294 A CN103589294 A CN 103589294A
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- acrylic acid
- hour
- paint
- finishing paint
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003973 paint Substances 0.000 title abstract description 14
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910017083 AlN Inorganic materials 0.000 claims abstract description 7
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002367 Polyisobutene Polymers 0.000 claims abstract description 7
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 7
- -1 isopropoxy aluminate Chemical class 0.000 claims abstract description 7
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- APZPSKFMSWZPKL-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)(CO)CO APZPSKFMSWZPKL-UHFFFAOYSA-N 0.000 claims description 6
- 150000004645 aluminates Chemical class 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000010977 jade Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000002105 nanoparticle Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- QCCDLTOVEPVEJK-UHFFFAOYSA-N phenylacetone Chemical compound CC(=O)CC1=CC=CC=C1 QCCDLTOVEPVEJK-UHFFFAOYSA-N 0.000 claims description 6
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical compound [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 claims description 3
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 3
- 229940037003 alum Drugs 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 229960000306 zinc gluconate Drugs 0.000 claims description 3
- 235000011478 zinc gluconate Nutrition 0.000 claims description 3
- 239000011670 zinc gluconate Substances 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000010959 steel Substances 0.000 abstract description 3
- 230000003287 optical effect Effects 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract 2
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 239000002585 base Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000032683 aging Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses an acrylic acid finishing paint. The acrylic acid finishing paint is prepared from the following raw materials in parts by weight: 50-55 parts of epoxy acrylate, 10-12 parts of trimethylolpropane triacrylate, 8-10 parts of dipentaerythritol hexaacrylate, 10-15 parts of aluminium nitride, 3-4 parts of distearoyl isopropoxy aluminate, 6-8 parts of polyisobutylene, 9-12 parts of butyl acetate, 4-5 parts of 2-hydroxy-2methyl-1phenylacetone, 3-5 parts of zinc borate and 3-4 parts of dispersing aid. The dispersing aid can be used for improving the optical property, enabling the oil paint to be uniformly dispersed and maintaining the stability of the oil paint. The acrylic acid finishing paint has very good flexibility, rust resisting property, saline-alkaline tolerance, high hardness and scratch resistance and the characteristics of high gloss, good adhesive force, excellent water resistance and the like. The acrylic acid finishing paint has good protective color and workability, is simple in preparation technology and provides protective and decorating effects for outdoor walls, steel structures, mechanical equipment, motors and the like.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of acrylic acid top-coat and preparation method thereof.
Background technology
Finish paint is the final coating of application, therefore material therefor is had to higher requirement, not only to there be good colourity and brightness, more require to have good anti-pollution, ageing-resistant, protection against the tide, mildew resistance is good, also to have free from environmental pollution, safety non-toxic, fast without fire hazard, easy construction, dried coating film, protect light and protect the features such as look good, good permeability.Have and decorate and defencive function, as color, gloss, texture etc., also need the resistivity in the face of severe environment.
The single-component quick-drying finish paint that acrylic acid top-coat is comprised of thermoplastic acrylic resin, pigment, auxiliary agent, solvent etc.This paint has good tint retention and workability.For the effect that outdoor wall, steel construction, mechanical means, motor etc. provide protection and decorate, also can be used as the finish paint of embossment figure layer system.
Summary of the invention
The object of this invention is to provide the acrylic acid top-coat that a kind of sticking power is good, water tolerance is excellent.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
, by the raw material of following weight part, made: epoxy acrylate 50-55, Viscoat 295 10-12, double pentaerythritol methacrylate 8-10, aluminium nitride 10-15, sec.-propyl distearyl acyl-oxygen base Aluminate 3-4, polyisobutene 6-8, N-BUTYL ACETATE 9-12, methyl-1,2-hydroxyl-2 phenyl-acetone 4-5, zinc borate 3-5, dispersing auxiliary 3-4.
Described dispersing auxiliary makes by the following method: the weight part of its each feed composition is: diatomite 200-210, nano-sized carbon 4-5, jade powder 12-13, Zinc Gluconate 2-3, xitix 1-2, pentaerythritol triacrylate 1-2, Zirconium tetrafluoride 1-2, alum 3-4, polyoxyethylene octylphenol ether 1-2, Silane coupling agent KH550 1-2; Preparation method adds diatomite in 12-15% hydrochloric acid soln and soaks 3-4 hour, takes out, and with clear water, cleans, and calcines 3-4 hour with sending in calcining furnace at 530-550 ℃, cooling, merges and grinds to form 300-400 order powder with jade; Add Zirconium tetrafluoride, nano-sized carbon, polyoxyethylene octylphenol ether to continue grinding distribution 2-3 hour, then add other remaining component to be ground to fully to disperse to obtain 300-400 order powder, obtain.
Acrylic acid top-coat of the present invention, by following concrete steps, made:
(1) epoxy acrylate, Viscoat 295, double pentaerythritol methacrylate, aluminium nitride are added in reactor and stirred, temperature of reaction is controlled at below 40-60 ℃, stirs 1-1.5 hour;
(2) in reactor, add sec.-propyl distearyl acyl-oxygen base Aluminate, polyisobutene, N-BUTYL ACETATE, methyl-1,2-hydroxyl-2 phenyl-acetone again, temperature of reaction is controlled at below 70-80 ℃, stirs 1 hour;
(3) finally add all the other remaining components, mix, stir, grind, obtain the slurry of 20-40 μ m, filter and get final product.
Dispersing auxiliary of the present invention has improved optical property, and paint is uniformly dispersed, and has maintained the stability of paint; The present invention has fabulous snappiness, rust-resisting property, salt tolerant alkalescence; and hardness is high, scratch resistance; there is the features such as high gloss, sticking power is good, water tolerance is excellent; the present invention has good sematic color and workability; preparation technology is simple, for outdoor wall, steel construction, mechanical means, motor etc. provide the effect of protecting and decorating.
Specific embodiments
Below by specific examples, the present invention is described in detail.
, by following weight part (kilogram) raw material make: epoxy acrylate 50, Viscoat 295 10, double pentaerythritol methacrylate 8, aluminium nitride 10, sec.-propyl distearyl acyl-oxygen base Aluminate 3, polyisobutene 6, N-BUTYL ACETATE 9, methyl-1,2-hydroxyl-2 phenyl-acetone 4, zinc borate 3, dispersing auxiliary 3.
Described dispersing auxiliary makes by the following method: the weight part of its each feed composition (kilogram) be: diatomite 200, nano-sized carbon 4, jade powder 12, Zinc Gluconate 2, xitix 1, pentaerythritol triacrylate 1, Zirconium tetrafluoride 1, alum 3, polyoxyethylene octylphenol ether 1, Silane coupling agent KH550 1; Preparation method adds diatomite in 12-15% hydrochloric acid soln and soaks 3-4 hour, takes out, and with clear water, cleans, and calcines 3-4 hour with sending in calcining furnace at 530-550 ℃, cooling, merges and grinds to form 300-400 order powder with jade; Add Zirconium tetrafluoride, nano-sized carbon, polyoxyethylene octylphenol ether to continue grinding distribution 2-3 hour, then add other remaining component to be ground to fully to disperse to obtain 300-400 order powder, obtain.
Acrylic acid top-coat of the present invention, by following concrete steps, made:
(1) epoxy acrylate, Viscoat 295, double pentaerythritol methacrylate, aluminium nitride are added in reactor and stirred, temperature of reaction is controlled at below 40-60 ℃, stirs 1-1.5 hour;
(2) in reactor, add sec.-propyl distearyl acyl-oxygen base Aluminate, polyisobutene, N-BUTYL ACETATE, methyl-1,2-hydroxyl-2 phenyl-acetone again, temperature of reaction is controlled at below 70-80 ℃, stirs 1 hour;
(3) finally add all the other remaining components, mix, stir, grind, obtain the slurry of 20-40 μ m, filter and get final product.
Product performance index of the present invention:
1, time of drying (25 ℃): surface drying 28min, does solid work 42h
2, snappiness mm≤1
3, hardness >=2H
4, high temperature resistant (130 ℃) >=490h
5, shock-resistance 50
6, salt spray resistance (120h level) >=3
7, water tolerance (29 ± 1 ℃ of 240h): non-foaming, do not come off
8, oil resistant (90# gasoline, 56h): non-foaming, do not come off
9, alkali resistance (GB/T9755-2001): by 48 hours
10, artificial weathering ageing resistance (GB/T9755-2001): by 1200 hours.
Claims (2)
1. an acrylic acid top-coat, it is characterized in that, by the raw material of following weight part, made: epoxy acrylate 50-55, Viscoat 295 10-12, double pentaerythritol methacrylate 8-10, aluminium nitride 10-15, sec.-propyl distearyl acyl-oxygen base Aluminate 3-4, polyisobutene 6-8, N-BUTYL ACETATE 9-12, methyl-1,2-hydroxyl-2 phenyl-acetone 4-5, zinc borate 3-5, dispersing auxiliary 3-4;
Described dispersing auxiliary makes by the following method: the weight part of its each feed composition is: diatomite 200-210, nano-sized carbon 4-5, jade powder 12-13, Zinc Gluconate 2-3, xitix 1-2, pentaerythritol triacrylate 1-2, Zirconium tetrafluoride 1-2, alum 3-4, polyoxyethylene octylphenol ether 1-2, Silane coupling agent KH550 1-2; Preparation method adds diatomite in 12-15% hydrochloric acid soln and soaks 3-4 hour, takes out, and with clear water, cleans, and calcines 3-4 hour with sending in calcining furnace at 530-550 ℃, cooling, merges and grinds to form 300-400 order powder with jade; Add Zirconium tetrafluoride, nano-sized carbon, polyoxyethylene octylphenol ether to continue grinding distribution 2-3 hour, then add other remaining component to be ground to fully to disperse to obtain 300-400 order powder, obtain.
2. acrylic acid top-coat according to claim 1, is characterized in that, by following concrete steps, is made:
(1) epoxy acrylate, Viscoat 295, double pentaerythritol methacrylate, aluminium nitride are added in reactor and stirred, temperature of reaction is controlled at below 40-60 ℃, stirs 1-1.5 hour;
(2) in reactor, add sec.-propyl distearyl acyl-oxygen base Aluminate, polyisobutene, N-BUTYL ACETATE, methyl-1,2-hydroxyl-2 phenyl-acetone again, temperature of reaction is controlled at below 70-80 ℃, stirs 1 hour;
(3) finally add all the other remaining components, mix, stir, grind, obtain the slurry of 20-40 μ m, filter and get final product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310466224.7A CN103589294A (en) | 2013-10-09 | 2013-10-09 | Acrylic acid finishing paint and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310466224.7A CN103589294A (en) | 2013-10-09 | 2013-10-09 | Acrylic acid finishing paint and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
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CN103589294A true CN103589294A (en) | 2014-02-19 |
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Application Number | Title | Priority Date | Filing Date |
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CN201310466224.7A Pending CN103589294A (en) | 2013-10-09 | 2013-10-09 | Acrylic acid finishing paint and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104046212A (en) * | 2014-05-14 | 2014-09-17 | 阜阳市美叶家具有限公司 | Acid and alkali resistant heat dissipation coating |
CN106676901A (en) * | 2016-08-27 | 2017-05-17 | 无锡凤凰画材有限公司 | High-gloss inkjet canvas and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101412887A (en) * | 2008-11-10 | 2009-04-22 | 嘉丰木业(苏州)有限公司 | Floor paint |
CN101935496A (en) * | 2010-09-17 | 2011-01-05 | 江苏海田技术有限公司 | UV (Ultraviolet)-scratch-resistant finish paint |
CN103305117A (en) * | 2013-06-28 | 2013-09-18 | 江苏海田技术有限公司 | Ultraviolet(UV)-scratch-resistant matte finishing paint specially used for polyvinyl chloride (PVC) |
-
2013
- 2013-10-09 CN CN201310466224.7A patent/CN103589294A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101412887A (en) * | 2008-11-10 | 2009-04-22 | 嘉丰木业(苏州)有限公司 | Floor paint |
CN101935496A (en) * | 2010-09-17 | 2011-01-05 | 江苏海田技术有限公司 | UV (Ultraviolet)-scratch-resistant finish paint |
CN103305117A (en) * | 2013-06-28 | 2013-09-18 | 江苏海田技术有限公司 | Ultraviolet(UV)-scratch-resistant matte finishing paint specially used for polyvinyl chloride (PVC) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104046212A (en) * | 2014-05-14 | 2014-09-17 | 阜阳市美叶家具有限公司 | Acid and alkali resistant heat dissipation coating |
CN106676901A (en) * | 2016-08-27 | 2017-05-17 | 无锡凤凰画材有限公司 | High-gloss inkjet canvas and preparation method thereof |
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Application publication date: 20140219 |
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