CN103588439A - Novel polymer cement waterproof paint and preparation method thereof - Google Patents
Novel polymer cement waterproof paint and preparation method thereof Download PDFInfo
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- CN103588439A CN103588439A CN201310430865.7A CN201310430865A CN103588439A CN 103588439 A CN103588439 A CN 103588439A CN 201310430865 A CN201310430865 A CN 201310430865A CN 103588439 A CN103588439 A CN 103588439A
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Abstract
The invention relates to novel polymer cement waterproof paint. The novel polymer cement waterproof paint comprises a liquid component A and a powder component B at a weight ratio of 1:(1.0-2), wherein the liquid component A comprises one or two of acrylic esters and VAE (Vinyl Acetateethylene Emulsion), a defoaming agent, a stabilizer, a water reducer, water and an adhesive; the powder component B comprises one of 325 cement and 425 cement. The waterproof paint provided by the invention has firm cementation, high tensile strength and good anti-seepage effect, is not easy to crack and convenient to transport, and can be used for omitting production of the powder material of enterprises and greatly reducing the investment on powder production and dust treatment of enterprises.
Description
Technical field
The present invention relates to water-proof material, a kind of new polymers cement waterproof paint and preparation method thereof.
Background technology
Polymer cement waterproof paint (being called for short JS) is a kind of cement group water-proofing material, and it has good basic unit cohesive strength and water tolerance, so be widely used in balcony, kitchen, toilet, vault, roof, pond.JS waterproof paint in the market is all comprised of liquid material part A and inorganic powder part B, and after A, B component mix, brushing is used.According to the difference of physicals, be divided into I type, II type, III type, wherein I type is used in and exposes in engineering, and II type is used in the non-engineerings that expose such as kitchen, toilet, balcony, vault, and III type is used in the long-term engineerings that contact with water such as pond.The JS waterproof paint of each model has corresponding formula liquid powder ratio corresponding thereto, and in use, corresponding model is selected in the requirement of waterproof as required.There are roof, kitchen, toilet, balcony, vault, basement roof in the position that buildings need to be done waterproof, need to select the JS waterproof paint without model, and the JS of different model has different packaged liquid material and powder, material is numerous like this, is not easy to use and manage.Country more and more payes attention to energy-conserving and environment-protective at present, the inorganic powder B component of JS waterproof paint, in water-proof material manufacturer, press powder formulation processing, mix, pack, need corresponding personnel, equipment and wrapping material, in powder production process, can produce a large amount of dust simultaneously, can pollute production surrounding environment, need enterprise's infusion of financial resources with processing dust.In powder formulation, containing cement, is a repeated transportation, production process.Like this environment, producers' health, the reasonable utilization of social resources are had to disadvantageous effect.Concerning the workmen with product carrys out final user, due to transportation, if manufacturer can provide a kind of JS product that does not use specific powder, will be conducive to reduce product construction cost and construction costs.
Summary of the invention
The deficiency existing in order to solve current polymer cement waterproof paint, the invention provides a kind of new polymers cement waterproof paint and preparation method thereof.The single kind of cement that this new polymers cement waterproof paint enough liquid material of energy and building site can be found directly matches, the waterproof paint performance of being mixed and stirred can reach GB/T23445-2009 < < polymer cement waterproof paint > > I type, II type, III type standard, workability is the same with traditional JS waterproof paint, has effectively solved the problem of currently available products on processing, construction, cost.
A kind of new polymers cement waterproof paint provided by the invention, comprises liquid material component A and powder B component, and both ratios of weight ratio of take are 1:1.0～2.0,
Wherein liquid material part A comprises by weight percentage:
Acrylic emulsion 69%～85%
VAE emulsion 0%～16%
Defoamer 1%
Water reducer 0.2%
Water 12.3%
Stablizer 1%
Caking agent 0.5%
Wherein wt per-cent meter liquid material B component comprises:
A kind of in 32.5 slag cement, 42.5 ordinary Portland cements, 32.5 complex cements, 32.5 silicate white cements
The present invention also provides a kind of technique of preparing new polymers cement waterproof paint, and step is as follows:
1) configuration liquid material component A:
1. weigh by weight acrylic emulsion 69%～85%, VAE emulsion 0%～16%, defoamer 1%, water reducer 0.2%, stablizer 1%;
2. water and Natvosol mix and blend 5 minutes are static 30 minutes.
3. in mixed solution, add acrylic emulsion, stir 10 minutes, then add VAE emulsion, stir 10 minutes, finally add defoamer, water reducer, water, continue to stir to till mixing.
4. discharging, packs;
2) powder B component:
Select a kind of in 32.5 slag cement, 42.5 ordinary Portland cements, 32.5 complex cements, 32.5 silicate white cements.
3) new polymers cement waterproof paint preparation:
By gained liquid material component A with gained powder, combine B, in weight ratio 1:1.0～2.0, first liquid material is added in agitator, start whipping device, progressively add corresponding powder, after treating that whole powders add, continue to stir and can use for 10 minutes～20 minutes.
Adopt new polymers cement waterproof paint provided by the invention, after directly becoming coating by liquid material with cement mixing, use, the physicals of brushing after solid can reach GB/T23445-2009 < < polymer cement waterproof paint > > I type, II type, III type standard, it is the same with traditional polymer cement waterproof paint (JS) that water-repellancy can keep, construction quality reaches the requirement of national buildings waterproof II level, can reach and save the production cost of enterprise and the object that facilitates client to use.
Embodiment
The concrete weight proportion of example one each component of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 85%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.3%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 slag cement: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.2
The waterproof paint brushing of preparing according to component described in the present embodiment and proportioning thereof is solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > I type
The concrete weight proportion of example two each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 85%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.3%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 slag cement: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.5
The waterproof paint brushing of preparing according to component described in the present embodiment and proportioning thereof is solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > II type
The concrete weight proportion of example three each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 85%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.3%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 slag cement: 100%
3) weight proportion of each component:
Liquid material: powder=1:2
The waterproof paint brushing of preparing according to component described in the present embodiment and proportioning thereof is solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > III type
The concrete weight proportion of example four each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 69%;
VAE emulsion: 16%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 slag cement: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.2
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > I type standard
The concrete weight proportion of example five each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 69%;
VAE emulsion: 16%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 slag cement: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.5
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > II type standard
The concrete weight proportion of example six each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 69%;
VAE emulsion: 16%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 slag cement: 100%
3) weight proportion of each component:
Liquid material: powder=1:2
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > III type standard
The concrete weight proportion of example seven each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 85%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 complex cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.2
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > I type standard
The concrete weight proportion of example eight each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 85%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 complex cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.5
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > II type standard
The concrete weight proportion of example nine each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 85%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 complex cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:2
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > III type standard
The concrete weight proportion of example ten each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 69%;
VAE emulsion: 16%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 complex cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.2
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > I type standard
The concrete weight proportion of example 11 each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 69%;
VAE emulsion: 16%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 complex cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.5
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > II type standard
The concrete weight proportion of example 12 each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 69%;
VAE emulsion: 16%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 complex cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:2
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > III type standard
The concrete weight proportion of example 13 each components of the present invention is as follows:
ACRYLIC EMULSION: 85%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
42.5 ordinary Portland cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.2
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > I type standard
The concrete weight proportion of example 14 each components of the present invention is as follows:
ACRYLIC EMULSION: 85%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
42.5 ordinary Portland cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.5
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > II type standard
The concrete weight proportion of example 15 each components of the present invention is as follows:
ACRYLIC EMULSION: 85%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
42.5 ordinary Portland cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.8
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > III type standard
The concrete weight proportion of example 16 each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 69%;
VAE emulsion: 16%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
42.5 ordinary Portland cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.2
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > I type standard
The concrete weight proportion of example 17 each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 69%;
VAE emulsion: 16%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
42.5 ordinary Portland cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.5
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > II type standard
The concrete weight proportion of example 18 each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 69%;
VAE emulsion: 16%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
42.5 ordinary Portland cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.8
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > III type standard
The concrete weight proportion of example 19 each components of the present invention is as follows:
ACRYLIC EMULSION: 85%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 normal silicate white cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.2
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > I type standard
The concrete weight proportion of example 20 each components of the present invention is as follows:
ACRYLIC EMULSION: 85%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 normal silicate white cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.5
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > II type standard
The concrete weight proportion of example 21 each components of the present invention is as follows:
ACRYLIC EMULSION: 85%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 normal silicate white cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.8
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > III type standard
The concrete weight proportion of example 22 each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 69%;
VAE emulsion: 16%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 normal silicate white cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.2
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > I type standard
The concrete weight proportion of example 23 each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 69%;
VAE emulsion: 16%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 normal silicate white cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.5
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > II type standard
The concrete weight proportion of example 24 each components of the present invention is as follows:
1) liquid material part
ACRYLIC EMULSION: 69%;
VAE emulsion: 16%;
Silicon oil foam killer: 1%;
Polycarboxylate dehydragent: 0.2%;
Hydroxyethyl cellulose aqueous solution: 1%;
Water: 12.8%;
Polyvinyl alcohol rubber powder: 0.5%;
2) powder part
32.5 normal silicate white cements: 100%
3) weight proportion of each component:
Liquid material: powder=1:1.8
The waterproof paint of preparing according to component described in the present embodiment and proportioning thereof is brushed solid by test, and its relevant technologies index can reach GB/T23445-2009 < < polymer cement waterproof paint > > III type standard
The above-mentioned new polymers cement waterproof paint that the present invention provides, example detection result is as follows:
Table 1(example one, two, three detected results)
Table 2(example four, five, six detected results)
Table 3(example seven, eight, nine detected results)
Table 4(example ten, 11,12 detected results)
Table 5(example 13,14,15 detected results)
Table 6(example 16,17,18 detected results)
Table 7(example 19,20,21 detected results)
Table 8(example 22,23,24 detected results)
Claims (11)
1. a new polymers cement waterproof paint, comprises liquid material component A and powder B component, and both ratios of weight ratio of take are 1:1.0～2.0,
Wherein wt per-cent meter liquid material component A comprises:
Acrylic emulsion 69%～85%
VAE emulsion 0%～16%
Defoamer 1%
Water reducer 0.2%
Water 12.3%
Stablizer 1%
Caking agent 0.5%
Each constituent mass per-cent summation is 100 above.
2. wherein wt per-cent meter liquid material B component comprises: a kind of in 32.5 slag cement, 42.5 ordinary Portland cements, 32.5 complex cements, 32.5 silicate white cements.
3. a kind of new polymers cement waterproof paint according to claim 1, is characterized in that: described defoamer is mineral oil defoaming agent.
4. a kind of new polymers cement waterproof paint according to claim 1, is characterized in that: described water reducer is water soluble polycarboxylic acid salt water reducer.
5. a kind of new polymers cement waterproof paint according to claim 1, is characterized in that: described stablizer is hydroxyethyl cellulose aqueous solution.
6. a kind of new polymers cement waterproof paint according to claim 1, is characterized in that: described acrylic emulsion is benzene emulsion or pure-acrylic emulsion.
7. a kind of new polymers cement waterproof paint according to claim 1, is characterized in that: described caking agent is polyvinyl alcohol rubber powder.
8. a new polymers method for preparing cement waterproof paint as claimed in claim 1, is characterized in that
Configuration liquid material component A:
Weigh by weight acrylic emulsion 69%～85%, VAE emulsion 0%～16%, defoamer 1%, water reducer 0.2%, stablizer 1%, caking agent 0.5%;
Water and Natvosol mix and blend 5 minutes are static 10 minutes.
9. in mixed solution, add acrylic emulsion, stir 10 minutes, then add VAE emulsion, stir 10 minutes, finally add defoamer, water reducer, water, caking agent, continues to stir to till mixing.
10. discharging, packs;
Powder B component:
Select a kind of in 32.5 slag cement, 42.5 ordinary Portland cements, 32.5 complex cements, 32.5 silicate white cements.
11. new polymers cement waterproof paint preparations:
By liquid material component A and powder B component, in weight ratio 1:1.0～2, they are put into agitation vat, then mixed, if viscosity is too high, cannot stir, can add and be no more than liquid powder than the water of total amount 6%, stir.
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Cited By (11)
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| CN105385279A (en) * | 2015-12-24 | 2016-03-09 | 桂林市和鑫防水装饰材料有限公司 | Polymer cement waterproof paint and preparing method thereof |
| CN106116352A (en) * | 2016-06-24 | 2016-11-16 | 广德县中威新型材料有限公司 | A kind of low temperature resistant water-repellent paint |
| CN106116382A (en) * | 2016-06-21 | 2016-11-16 | 山东宏艺科技股份有限公司 | A kind of inorganic leak-stopping material |
| CN107573771A (en) * | 2017-08-31 | 2018-01-12 | 天津市禹红建筑防水材料有限公司 | A kind of coating for waterproof layer protection and preparation method thereof |
| CN108610800A (en) * | 2016-12-21 | 2018-10-02 | 中国石化集团四川维尼纶厂 | A kind of modified JS waterproofing paint and preparation method thereof |
| CN109231909A (en) * | 2018-07-19 | 2019-01-18 | 山东天汇防水股份有限公司 | A kind of waterproof heat resistant coating and its manufacturing method applied to roof |
| CN109369094A (en) * | 2018-10-12 | 2019-02-22 | 德州科顺建筑材料有限公司 | Polymer cement waterproof paint and its application method and preparation method thereof |
| CN111500224A (en) * | 2020-04-28 | 2020-08-07 | 华北理工大学 | Organic-inorganic hybrid modified cement-based sealant and preparation method and application thereof |
| CN111592325A (en) * | 2020-05-25 | 2020-08-28 | 黄永华 | Concrete sealing curing agent and preparation method and construction method thereof |
| CN112694773A (en) * | 2020-12-21 | 2021-04-23 | 杭州东方雨虹建筑材料有限公司 | Environment-friendly polymer cement waterproof coating with low construction coating rate and preparation method thereof |
| CN113321351A (en) * | 2021-08-02 | 2021-08-31 | 清大国华环境集团股份有限公司 | Method for treating cadmium wastewater and solidifying cadmium slag |
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