CN103579653A - System for real-time hydrogen production and power generation system by methanol water and control method of system - Google Patents
System for real-time hydrogen production and power generation system by methanol water and control method of system Download PDFInfo
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- CN103579653A CN103579653A CN201310520515.XA CN201310520515A CN103579653A CN 103579653 A CN103579653 A CN 103579653A CN 201310520515 A CN201310520515 A CN 201310520515A CN 103579653 A CN103579653 A CN 103579653A
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- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
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- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
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- H01M8/04104—Regulation of differential pressures
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Abstract
The invention discloses a system for real-time hydrogen production and power generation by using methanol water and a control method of the system. The hydrogen production power generation system is not provided with a display screen, and comprises a hydrogen production subsystem, a power generation subsystem and a control subsystem, wherein the hydrogen production subsystem is used for producing hydrogen, and used for conveying the produced hydrogen to the power generation subsystem; the power generation subsystem is used for generating power by using the hydrogen which is conveyed from the hydrogen production subsystem at real time; the control subsystem comprises a microprocessor, a first wireless communication module and a mobile terminal; the mobile terminal is provided with a second wireless communication module; the mobile terminal is used for transmitting control instructions to the microprocessor through the second wireless communication module; the microprocessor is used for controlling the operation of the hydrogen production subsystem and the power generation subsystem according to the received instructions. According to the system for real-time hydrogen production and power generation system by using the methanol water and the control method of the system disclosed by the invention, information of the hydrogen production subsystem and the power generation subsystem is obtained through the mobile terminal, and the operation of the hydrogen production subsystem and the power generation subsystem is controlled; no display screen is needed to be arranged, so that raw materials are saved.
Description
Technical field
The invention belongs to hydrogen gas generation technical field, relate to a kind of electricity generation system, relate in particular to the instant hydrogen manufacturing electricity generation system of a kind of methanol-water; Meanwhile, the invention still further relates to the control method of the instant hydrogen manufacturing electricity generation system of a kind of methanol-water.
Background technology
In numerous new forms of energy, Hydrogen Energy will become the optimal energy of 21 century.This is because in the situation that coal, gasoline and the hydrogen of burning identical weight, the energy that hydrogen produces is maximum, and the product of its burning is water, there is no lime-ash and waste gas, does not pollute the environment; And coal and oil combustion generate, be carbon dioxide and sulfur dioxide, can produce respectively greenhouse effect and acid rain.Coal and reserves are limited, and hydrogen is mainly stored in water, and after burning, unique product is also water, can produce continuously hydrogen, is finished never.
Hydrogen is a kind of colourless gas.The one gram of Hydrogen Energy of burning discharges your heat of 142 kilojoules, is 3 times of gasoline caloric value.The weight of hydrogen is light especially, and it is all gently more than gasoline, natural gas, kerosene, thereby carries, transports conveniently, is the most suitable fuel of the high-speed flight vehicles such as space flight, aviation.Hydrogen can burn in oxygen, and the temperature of hydrogen flame can be up to 2500 ℃, thereby the conventional hydrogen cutting of people or weldable steel iron material.
In the Nature, the distribution of hydrogen is very extensive.Water is exactly large " warehouse " of hydrogen, wherein contains 11% hydrogen.There is 1.5% hydrogen earth Rio; All contain hydrogen in oil, coal, natural gas, animal and plant body etc.The main body of hydrogen is that the form with compound water exists, and earth surface approximately 70% is covered by water, and moisture storage capacity is very large, therefore can say, hydrogen is the energy of " inexhaustible, nexhaustible ".If can be with suitable method preparing hydrogen from water, hydrogen also will be the energy that a kind of price is quite cheap so.
Having many uses of hydrogen, applicability is strong.It can not only be used as fuel, and metal hydride has the function that chemical energy, heat energy and mechanical energy are changed mutually.For example, hydrogen storage metal has the ability of inhaling hydrogen heat release and absorbing heat and putting hydrogen, heat can be stored, and as heating and air-conditioning in room, uses.
Hydrogen, as gaseous fuel, is first used on automobile.In May, 1976, the U.S. develops a kind of automobile of making fuel with hydrogen; Afterwards, Japan also succeeded in developing a kind of automobile that liquified hydrogen is fuel of take; In the latter stage seventies, the Mercedes of front Germany tests hydrogen, and they have only used five kg of hydrogen, has just made running car 110 kilometers.
As motor vehicle fuel, not only clean with hydrogen, easily start at low temperatures, and little to the corrosiveness of engine, can extend the useful life of engine.Because hydrogen can evenly mix with air, can save vaporizer used on general automobile completely, thereby can simplify the structure of existing automobile.More interestingly, need only the hydrogen that adds 4% in gasoline.Use it as automobile engine fuel, just can fuel-economizing 40%, and without petrol engine being done to great improvement.
Hydrogen is easy to become liquid at certain pressure and temperature, thereby it is all very convenient by iron flask car, on-highway tractor or ship transportation.Liquid hydrogen both can be used as the fuel of automobile, aircraft, also can be used as the fuel of rocket, guided missile.The fly to Apollo Personnel investigation Program of the moon of the U.S. " Long March carrier rocket that number spaceship and China launch a man-made satellite., all with liquified hydrogen, make fuel.
In addition, use hydrogen-hydrogen fuel cell Hydrogen Energy directly can also be changed into electric energy, make utilizing of Hydrogen Energy more convenient.At present, this fuel cell is used on spaceship and submarine, and effect is pretty good.Certainly, because cost is higher, be also difficult to generally use for the moment.
The annual production of hydrogen is about 3,600 ten thousand tons in the world now, and wherein the overwhelming majority is produced from oil, coal and natural gas, and this must consume original just fossil fuel very in short supply; Separately having 4% hydrogen is to produce by the method for brine electrolysis, but the electric energy consuming is too many, very calculates, and therefore, people are trying to explore to study hydrogen manufacturing new method.And can reduce the energy consumption in Chemical Manufacture and reduce costs with methyl alcohol, water reformation hydrogen production, be expected to substitute the technique of " water electrolysis hydrogen production " be called as electricity-eating tiger, utilize advanced methanol vapor to reform--pressure swing adsorption making pure hydrogen and be rich in CO
2mist, through further reprocessing, can obtain hydrogen and carbon dioxide gas simultaneously.
Methyl alcohol and steam pass through catalyst under certain temperature, pressure condition, under the effect of catalyst, the transformationreation of methanol decomposition reaction and carbon monoxide occurs, generate hydrogen and carbon dioxide, this is the gas solid catalytic reaction system of component more than, many reactions.Reactional equation is as follows:
CH
3OH→CO+2H
2 (1)
H
2O+CO→CO
2+H
2 (2)
CH
3OH+H
2O→CO
2+3H
2 (3)
The H that reforming reaction generates
2and CO
2, then pass through the separation of palladium film by H
2and CO
2separation, obtains high-purity hydrogen.The power consumption of pressure swing adsorption method is high, equipment is large, and is not suitable for small-scale hydrogen preparation.
Existing hydrogen gas generating system, normally utilizes the hydrogen gas generation having prepared, and preparing hydrogen is separated with hydrogen gas generation.First utilize hydrogen producer to prepare hydrogen, hydrogen is positioned in hydrogen gas buffer, then by the hydrogen gas generation in hydrogen gas buffer.The volume of hydrogen gas buffer is comparatively huge, Portable belt not, and mobility is poor, thereby has restricted the portability of hydrogen preparation and generating equipment.
In addition, existing hydrogen producer, generating equipment in order to obtain the information of equipment, conventionally need to arrange display screen, thereby increase equipment cost on equipment.
In view of this, nowadays in the urgent need to designing a kind of new hydrogen gas generating system, to overcome the above-mentioned defect of existing hydrogen gas generating system.
Summary of the invention
Technical problem to be solved by this invention is: provide a kind of methanol-water instant hydrogen manufacturing electricity generation system, can move by Mobile terminal control system, without display screen is set, save system production cost.
In addition, the present invention also provides the control method of the instant hydrogen manufacturing electricity generation system of a kind of methanol-water, can move by Mobile terminal control system, without display screen is set, saves system production cost.
For solving the problems of the technologies described above, the present invention adopts following technical scheme:
An instant hydrogen manufacturing electricity generation system, described preparing hydrogen, generating power system is not established display screen, and described preparing hydrogen, generating power system comprises: hydrogen manufacturing subsystem, air pressure adjustment subsystem, power generation sub-system, control subsystem; Hydrogen manufacturing subsystem, air pressure adjustment subsystem, power generation sub-system connect successively, and control subsystem is connected with hydrogen manufacturing subsystem, air pressure adjustment subsystem, power generation sub-system respectively;
Described hydrogen manufacturing subsystem, in order to prepare hydrogen, is delivered to power generation sub-system by the hydrogen making, the hydrogen gas generation that power generation sub-system utilizes described hydrogen manufacturing subsystem to transmit in real time;
Described control subsystem comprises microprocessor, the first wireless communication module, mobile terminal, and mobile terminal is provided with the second wireless communication module; Described mobile terminal utilizes the second wireless communication module that control command is sent to microprocessor, and microprocessor is controlled the operation of described hydrogen manufacturing subsystem, power generation sub-system according to the order receiving;
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem comprises solid hydrogen reservoir vessel, liquid container, raw material conveying device, hydrogen producer, membrane separation device;
Described hydrogen producer comprises heat exchanger, vaporizer, reformer chamber; Membrane separation device is arranged at the top that Nei， separation chamber, separation chamber is arranged at reformer chamber;
Described solid hydrogen reservoir vessel, liquid container are connected with hydrogen producer respectively; In liquid container, store liquid first alcohol and water;
In described solid hydrogen reservoir vessel, store solid hydrogen, when hydrogen generating system starts, by gasification module, solid hydrogen is converted to gaseous hydrogen, gaseous hydrogen is by burning heat release, for hydrogen producer provides startup heat energy, as the startup energy of hydrogen producer;
First alcohol and water in described liquid container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange;
Methanol vapor and steam after gasification enter reformer chamber, and reformer chamber is provided with catalyst, and reformer chamber bottom and middle part temperature are 350 ℃～409 ℃;
The temperature on described reformer chamber top is 400 ℃～570 ℃; Reformer chamber is connected by connecting line with separation chamber, and heating can be continued from the gas of reformer chamber output in all or part of top that is arranged at reformer chamber of connecting line by the high temperature on reformer chamber top; Described connecting line, as the buffering between reformer chamber and separation chamber, makes from the temperature of gas of reformer chamber output identical with the temperature of separation chamber or approaching;
Temperature Setting in described separation chamber is 400 ℃～570 ℃; In separation chamber, be provided with membrane separator, from the aerogenesis end of membrane separator, obtain hydrogen;
Described raw material conveying device provides power, and the raw material in liquid container is delivered to hydrogen producer; Described raw material conveying device provides the pressure of 1.1～5M Pa to raw material, make the hydrogen that hydrogen producer makes have enough pressure;
Described hydrogen producer starts after hydrogen manufacturing, and the hydrogen partial that hydrogen producer makes is or/and residual air maintains hydrogen producer by burning moves;
The hydrogen that described hydrogen producer makes is delivered to membrane separation device and carries out separation, for separating of the difference of the inside and outside pressure of the membrane separation device of hydrogen, is more than or equal to 1.1M Pa;
Described membrane separation device is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, and silver accounts for 22%～25%;
Described hydrogen manufacturing subsystem passes through transfer conduit real-time Transmission to power generation sub-system by the hydrogen making; In described transfer conduit, be provided with air pressure adjustment subsystem, for adjusting the air pressure of transfer conduit; The hydrogen gas generation that described power generation sub-system utilizes hydrogen manufacturing subsystem to make;
Described air pressure adjustment subsystem comprises the second microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe; Described gas pressure sensor is arranged in transfer conduit, in order to respond to the barometric information in transfer conduit, and the barometric information of induction is sent to the second microprocessor; Described the second microprocessor is compared this barometric information receiving from gas pressure sensor and setting threshold interval; When the maximum of the pressure data receiving higher than setting threshold interval, the second microprocessor by-pass valve control controller opens air outlet valve setting-up time, make in transfer conduit air pressure in setting range, one end of outlet pipe connects air outlet valve simultaneously, the other end connects described hydrogen manufacturing subsystem, and the firing equipment that needs that is hydrogen manufacturing subsystem by burning heats; When the minimum value of the pressure data receiving lower than setting threshold interval, the second microprocessor is controlled the transporting velocity that described hydrogen manufacturing subsystem is accelerated raw material.
An instant hydrogen manufacturing electricity generation system, described preparing hydrogen, generating power system is not established display screen, and described preparing hydrogen, generating power system comprises hydrogen manufacturing subsystem, power generation sub-system, control subsystem;
Described hydrogen manufacturing subsystem, in order to prepare hydrogen, is delivered to power generation sub-system by the hydrogen making, the hydrogen gas generation that power generation sub-system utilizes described hydrogen manufacturing subsystem to transmit in real time;
Described control subsystem comprises microprocessor, the first wireless communication module, mobile terminal, and mobile terminal is provided with the second wireless communication module; Described mobile terminal utilizes the second wireless communication module that control command is sent to microprocessor, and microprocessor is controlled the operation of described hydrogen manufacturing subsystem, power generation sub-system according to the order receiving.
As a preferred embodiment of the present invention, described hydrogen manufacturing subsystem passes through transfer conduit real-time Transmission to power generation sub-system by the hydrogen making; In described transfer conduit, be provided with air pressure adjustment subsystem, for adjusting the air pressure of transfer conduit; The hydrogen gas generation that described power generation sub-system utilizes hydrogen manufacturing subsystem to make;
Described air pressure adjustment subsystem comprises the second microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe; Described gas pressure sensor is arranged in transfer conduit, in order to respond to the barometric information in transfer conduit, and the barometric information of induction is sent to the second microprocessor; Described the second microprocessor is compared this barometric information receiving from gas pressure sensor and setting threshold interval; When the maximum of the pressure data receiving higher than setting threshold interval, the second microprocessor by-pass valve control controller opens air outlet valve setting-up time, make in transfer conduit air pressure in setting range, one end of outlet pipe connects air outlet valve simultaneously, the other end connects described hydrogen manufacturing subsystem, and the firing equipment that needs that is hydrogen manufacturing subsystem by burning heats; When the minimum value of the pressure data receiving lower than setting threshold interval, the second microprocessor is controlled the transporting velocity that described hydrogen manufacturing subsystem is accelerated raw material.
As a preferred embodiment of the present invention, described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem comprises solid hydrogen reservoir vessel, liquid container, raw material conveying device, hydrogen producer, membrane separation device.
As a preferred embodiment of the present invention, described system is also provided with remote server, mobile terminal connects hydrogen manufacturing subsystem, power generation sub-system and remote server by the second wireless communication module, the information of hydrogen manufacturing subsystem, power generation sub-system is sent to remote server, and can obtains from server the set information of any hydrogen manufacturing subsystem, power generation sub-system.
The control method of the instant hydrogen manufacturing electricity generation system of a kind of above-mentioned methanol-water, described control method comprises: mobile terminal utilizes the second wireless communication module that control command is sent to microprocessor, and microprocessor is controlled the operation of described hydrogen manufacturing subsystem, power generation sub-system according to the order receiving.
As a preferred embodiment of the present invention, described method also comprises: mobile terminal connects hydrogen manufacturing subsystem, power generation sub-system and remote server by the second wireless communication module, the information of hydrogen manufacturing subsystem, power generation sub-system is sent to remote server, and can obtains from server the set information of any hydrogen manufacturing subsystem, power generation sub-system.
Beneficial effect of the present invention is: the instant hydrogen manufacturing electricity generation system of methanol-water and control method thereof that the present invention proposes, by the information of acquisition for mobile terminal hydrogen manufacturing subsystem, power generation sub-system, and control the operation of hydrogen manufacturing subsystem, power generation sub-system; Without display screen is set, and from conservation.In addition, the present invention also can utilize the standby hydrogen gas generation of immediate system, without hydrogen gas buffer, by air pressure adjustment subsystem, adjusts the hydrogen gas pressure in transfer conduit; Because the volume of air pressure adjustment subsystem is very little, thereby can further improve portability, the mobility of preparing hydrogen, generating power system.
Accompanying drawing explanation
Fig. 1 is the composition schematic diagram of the instant hydrogen manufacturing electricity generation system of methanol-water of the present invention.
Fig. 2 is the composition schematic diagram of hydrogen manufacturing subsystem.
Embodiment
Below in conjunction with accompanying drawing, describe the preferred embodiments of the present invention in detail.
Embodiment mono-
Refer to Fig. 1, the present invention has disclosed the instant hydrogen manufacturing electricity generation system of a kind of methanol-water, and described preparing hydrogen, generating power system is not established display screen, and described preparing hydrogen, generating power system comprises hydrogen manufacturing subsystem 100, power generation sub-system 300, control subsystem 200.Described hydrogen manufacturing subsystem 100, in order to prepare hydrogen, is delivered to power generation sub-system 300 by the hydrogen making, the hydrogen gas generation that power generation sub-system 300 utilizes described hydrogen manufacturing subsystem 100 to transmit in real time.
Described control subsystem 200 comprises microprocessor 201, the first wireless communication module 202, mobile terminal 203, and mobile terminal 203 is provided with the second wireless communication module; Described mobile terminal 203 utilizes the second wireless communication module that control command is sent to microprocessor 201, and microprocessor 201 is controlled the operation of described hydrogen manufacturing subsystem 100, power generation sub-system 300 according to the order receiving.
Utilize the present invention can pass through mobile terminal (as mobile phone) control system, and by mobile terminal, from remote server, obtain the set information of system, without display screen, thereby reduce manufacturing cost.
The present invention also discloses the control method of the instant hydrogen manufacturing electricity generation system of a kind of above-mentioned methanol-water, described control method comprises: hydrogen manufacturing subsystem is prepared hydrogen, the hydrogen making is delivered to power generation sub-system, the hydrogen gas generation that power generation sub-system utilizes described hydrogen manufacturing subsystem to transmit in real time; Mobile terminal utilizes the second wireless communication module that control command is sent to microprocessor, and microprocessor is controlled the operation of described hydrogen manufacturing subsystem, power generation sub-system according to the order receiving.
Described method also comprises: mobile terminal connects hydrogen manufacturing subsystem, power generation sub-system and remote server by the second wireless communication module, the information of hydrogen manufacturing subsystem, power generation sub-system is sent to remote server, and can obtains from server the set information of any hydrogen manufacturing subsystem, power generation sub-system.
Embodiment bis-
The difference of the present embodiment and embodiment mono-is, in the present embodiment, described hydrogen manufacturing subsystem by the hydrogen making by transfer conduit real-time Transmission to power generation sub-system; In described transfer conduit, be provided with air pressure adjustment subsystem, for adjusting the air pressure of transfer conduit; The hydrogen gas generation that described power generation sub-system utilizes hydrogen manufacturing subsystem to make.
Described air pressure adjustment subsystem comprises the second microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe; Described gas pressure sensor is arranged in transfer conduit, in order to respond to the barometric information in transfer conduit, and the barometric information of induction is sent to the second microprocessor; Described the second microprocessor is compared this barometric information receiving from gas pressure sensor and setting threshold interval; When the maximum of the pressure data receiving higher than setting threshold interval, the second microprocessor by-pass valve control controller opens air outlet valve setting-up time, make in transfer conduit air pressure in setting range, one end of outlet pipe connects air outlet valve simultaneously, the other end connects described hydrogen manufacturing subsystem, and the firing equipment that needs that is hydrogen manufacturing subsystem by burning heats; When the minimum value of the pressure data receiving lower than setting threshold interval, the second microprocessor is controlled the transporting velocity that described hydrogen manufacturing subsystem is accelerated raw material.
Embodiment tri-
The difference of the present embodiment and embodiment mono-, embodiment bis-is, in the present embodiment, refer to Fig. 2, described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem comprises solid hydrogen reservoir vessel 40, liquid container 10, raw material conveying device 50, hydrogen producer 20, membrane separation device 30.
Described solid hydrogen reservoir vessel 40, liquid container 10 are connected with hydrogen producer 20 respectively; In liquid container 10, store liquid first alcohol and water, in described solid hydrogen reservoir vessel 40, store solid hydrogen.
When hydrogen generating system starts, by gasification module, the solid hydrogen in solid hydrogen reservoir vessel 40 is converted to gaseous hydrogen, gaseous hydrogen is by burning heat release, for hydrogen producer 20 provides startup heat energy, as the startup energy of hydrogen producer 20.Certainly, solid hydrogen reservoir vessel 40 is not necessaries of the present invention, can start hydrogen producer 20 by other energy.
Described raw material conveying device 50 provides power, and the raw material in liquid container 10 is delivered to hydrogen producer 20; The pressure (as provide 1.1M Pa or 1.2M Pa or 1.5M Pa or 5M Pa pressure) of 1.1～5M Pa is provided to raw material described raw material conveying device 50, and the hydrogen that hydrogen producer 20 is made has enough pressure.Described hydrogen producer 20 starts after hydrogen manufacturing, and the hydrogen partial that hydrogen producer 20 makes is or/and residual air maintains hydrogen producer 20 operations (certainly, the operation of hydrogen producer 20 can also be passed through other energy) by burning.
The hydrogen that described hydrogen producer 20 makes is delivered to membrane separation device 30 and carries out separation, for separating of the difference of the inside and outside pressure of the membrane separation device 30 of hydrogen be more than or equal to 1.1M Pa(as the inside and outside pressure of membrane separation device 30 be 1.1M Pa or 1.2M Pa or 1.5M Pa or 5M Pa).
In the present embodiment, described membrane separation device 30 is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, and silver accounts for 22%～25%.The preparation technology of described membrane separation device 30 comprises the steps:
Step 1, porous ceramic is arranged in the vacuum chamber of magnetic control sputtering device;
Step 2, utilize the magnetic field of magnetic control sputtering device to produce mechanism to produce magnetic field, make metallic target produce deviation electric current, metallic target is as negative pole, thereby makes porous ceramic surface with magnetosphere body; The material of described metallic target is sputter precious metal, and described precious metal is palladium-silver, and mass percent palladium accounts for 75%～78%, and silver accounts for 22%～25%;
Step 3, when metallic target produces deviation electric current, the vacuum chamber of magnetic control sputtering device is heated, temperature is controlled at 350 ℃～800 ℃;
Gas in step 4, extraction vacuum chamber, the vacuum degree indoor when vacuum is less than 10
-2during Pa, in vacuum chamber, be filled with the argon gas of setting concentration;
Step 5, to metallic target, pass into electric current, carry out sputter coating; The ion that metallic target produces accelerates to fly in the process of porous ceramic surface and bumps with ar atmo under the effect of electric field, ionizes out a large amount of argon ions and electronics, and electronics flies to porous ceramic surface; Argon ion accelerates bombardment metallic target under the effect of electric field, sputters a large amount of metallic target target atom or molecule, is neutral target atom or molecule deposition on porous ceramic surface, forms the precious metal film of 1～15 μ m;
Wherein, in the process of sputter coating, also comprise argon concentration detecting step; Detect the argon concentration in vacuum chamber in real time or with setting-up time interval, when argon concentration, automatically open argon gas charging valve during lower than setting threshold, in vacuum chamber, be filled with argon gas, until the argon concentration in vacuum chamber meets setting threshold scope;
In the process of sputter coating, also comprise air pressure detecting step; Detect the air pressure in vacuum chamber in real time or with setting-up time interval, not interval at setting threshold when the air pressure that vacuum is indoor, the air pressure of adjusting in vacuum chamber is interval to setting threshold;
Step 6, in vacuum chamber, pass into atmosphere, take out workpiece.
Preferably, described hydrogen producer comprises heat exchanger, vaporizer, reformer chamber; Membrane separation device is arranged at the top that Nei， separation chamber, separation chamber is arranged at reformer chamber.
First alcohol and water in described liquid container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange; Methanol vapor and steam after gasification enter reformer chamber, and reformer chamber is provided with catalyst, and reformer chamber bottom and middle part temperature are 350 ℃～409 ℃; The temperature on described reformer chamber top is 400 ℃～570 ℃; Reformer chamber is connected by connecting line with separation chamber, and heating can be continued from the gas of reformer chamber output in all or part of top that is arranged at reformer chamber of connecting line by the high temperature on reformer chamber top; Described connecting line, as the buffering between reformer chamber and separation chamber, makes from the temperature of gas of reformer chamber output identical with the temperature of separation chamber or approaching; Temperature Setting in described separation chamber is 400 ℃～570 ℃; In separation chamber, be provided with membrane separator, from the aerogenesis end of membrane separator, obtain hydrogen.
More than introduced the composition of methanol-water hydrogen manufacturing subsystem, the present invention also discloses a kind of hydrogen production process that utilizes above-mentioned methanol-water hydrogen manufacturing subsystem, and described hydrogen production process comprises:
In [step 0] described solid hydrogen reservoir vessel, store solid hydrogen, when hydrogen generating system starts, by gasification module, solid hydrogen is converted to gaseous hydrogen, gaseous hydrogen is by burning heat release, for hydrogen producer provides startup heat energy, as the startup energy of hydrogen producer;
[step 1] described raw material conveying device provides power, and the raw material in liquid container is delivered to hydrogen producer; Described raw material conveying device provides the pressure of 1.1～5M Pa to raw material, make the hydrogen that hydrogen producer makes have enough pressure;
[step 2] hydrogen producer is prepared hydrogen; Specifically comprise:
First alcohol and water in described liquid container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange;
Methanol vapor and steam after gasification enter reformer chamber, and reformer chamber is provided with catalyst, and reformer chamber bottom and middle part temperature are 350 ℃～409 ℃;
The temperature on described reformer chamber top is 400 ℃～570 ℃; Reformer chamber is connected by connecting line with separation chamber, and heating can be continued from the gas of reformer chamber output in all or part of top that is arranged at reformer chamber of connecting line by the high temperature on reformer chamber top; Described connecting line, as the buffering between reformer chamber and separation chamber, makes from the temperature of gas of reformer chamber output identical with the temperature of separation chamber or approaching;
Temperature Setting in described separation chamber is 400 ℃～570 ℃; In separation chamber, be provided with membrane separator, from the aerogenesis end of membrane separator, obtain hydrogen.
The hydrogen that [step 3] described hydrogen producer makes is delivered to membrane separation device and carries out separation, for separating of the difference of the inside and outside pressure of the membrane separation device of hydrogen, is more than or equal to 1.1M Pa;
In the present embodiment, hydrogen manufacturing subsystem is arranged at separation chamber on the top of reformer chamber, the temperature that middle part and bottom are compared in reformer chamber top is higher, by connecting line, connect reformer chamber and separation chamber, the gas that connecting line can utilize the high-temperature heating on reformer chamber top to carry in the process of carrying, play pre-heat effect, mode of heating is very convenient simultaneously.Pipeline between reformer chamber and separation chamber, as preheating temperature control mechanism, can, to heating from the gas of reformer chamber output, make from the temperature of gas of reformer chamber output identical with the temperature of separation chamber or approaching; Thereby can guarantee respectively the low temperature requirement of reformer chamber catalyst, and the high temperature requirement of separation chamber, and then improve hydrogen preparation efficiency.
In sum, the instant hydrogen manufacturing electricity generation system of methanol-water and control method thereof that the present invention proposes, by the information of acquisition for mobile terminal hydrogen manufacturing subsystem, power generation sub-system, and control the operation of hydrogen manufacturing subsystem, power generation sub-system; Without display screen is set, and from conservation.In addition, the present invention also can utilize the standby hydrogen gas generation of immediate system, without hydrogen gas buffer, by air pressure adjustment subsystem, adjusts the hydrogen gas pressure in transfer conduit; Because the volume of air pressure adjustment subsystem is very little, thereby can further improve portability, the mobility of preparing hydrogen, generating power system.
Here description of the invention and application is illustrative, not wants by scope restriction of the present invention in the above-described embodiments.Here the distortion of disclosed embodiment and change is possible, and for those those of ordinary skill in the art, the various parts of the replacement of embodiment and equivalence are known.Those skilled in the art are noted that in the situation that not departing from spirit of the present invention or substantive characteristics, and the present invention can be with other form, structure, layout, ratio, and realizes with other assembly, material and parts.In the situation that not departing from the scope of the invention and spirit, can carry out other distortion and change to disclosed embodiment here.
Claims (7)
1. the instant hydrogen manufacturing electricity generation system of methanol-water, is characterized in that, described preparing hydrogen, generating power system is not established display screen, and described preparing hydrogen, generating power system comprises: hydrogen manufacturing subsystem, air pressure adjustment subsystem, power generation sub-system, control subsystem; Hydrogen manufacturing subsystem, air pressure adjustment subsystem, power generation sub-system connect successively, and control subsystem is connected with hydrogen manufacturing subsystem, air pressure adjustment subsystem, power generation sub-system respectively;
Described hydrogen manufacturing subsystem, in order to prepare hydrogen, is delivered to power generation sub-system by the hydrogen making, the hydrogen gas generation that power generation sub-system utilizes described hydrogen manufacturing subsystem to transmit in real time;
Described control subsystem comprises microprocessor, the first wireless communication module, mobile terminal, and mobile terminal is provided with the second wireless communication module; Described mobile terminal utilizes the second wireless communication module that control command is sent to microprocessor, and microprocessor is controlled the operation of described hydrogen manufacturing subsystem, power generation sub-system according to the order receiving;
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem comprises solid hydrogen reservoir vessel, liquid container, raw material conveying device, hydrogen producer, membrane separation device;
Described hydrogen producer comprises heat exchanger, vaporizer, reformer chamber; Membrane separation device is arranged at the top that Nei， separation chamber, separation chamber is arranged at reformer chamber;
Described solid hydrogen reservoir vessel, liquid container are connected with hydrogen producer respectively; In liquid container, store liquid first alcohol and water;
In described solid hydrogen reservoir vessel, store solid hydrogen, when hydrogen generating system starts, by gasification module, solid hydrogen is converted to gaseous hydrogen, gaseous hydrogen is by burning heat release, for hydrogen producer provides startup heat energy, as the startup energy of hydrogen producer;
First alcohol and water in described liquid container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange;
Methanol vapor and steam after gasification enter reformer chamber, and reformer chamber is provided with catalyst, and reformer chamber bottom and middle part temperature are 350 ℃～409 ℃;
The temperature on described reformer chamber top is 400 ℃～570 ℃; Reformer chamber is connected by connecting line with separation chamber, and heating can be continued from the gas of reformer chamber output in all or part of top that is arranged at reformer chamber of connecting line by the high temperature on reformer chamber top; Described connecting line, as the buffering between reformer chamber and separation chamber, makes from the temperature of gas of reformer chamber output identical with the temperature of separation chamber or approaching;
Temperature Setting in described separation chamber is 400 ℃～570 ℃; In separation chamber, be provided with membrane separator, from the aerogenesis end of membrane separator, obtain hydrogen;
Described raw material conveying device provides power, and the raw material in liquid container is delivered to hydrogen producer; Described raw material conveying device provides the pressure of 1.1～5M Pa to raw material, make the hydrogen that hydrogen producer makes have enough pressure;
Described hydrogen producer starts after hydrogen manufacturing, and the hydrogen partial that hydrogen producer makes is or/and residual air maintains hydrogen producer by burning moves;
The hydrogen that described hydrogen producer makes is delivered to membrane separation device and carries out separation, for separating of the difference of the inside and outside pressure of the membrane separation device of hydrogen, is more than or equal to 1.1M Pa;
Described membrane separation device is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, and silver accounts for 22%～25%;
Described hydrogen manufacturing subsystem passes through transfer conduit real-time Transmission to power generation sub-system by the hydrogen making; In described transfer conduit, be provided with air pressure adjustment subsystem, for adjusting the air pressure of transfer conduit; The hydrogen gas generation that described power generation sub-system utilizes hydrogen manufacturing subsystem to make;
Described air pressure adjustment subsystem comprises the second microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe; Described gas pressure sensor is arranged in transfer conduit, in order to respond to the barometric information in transfer conduit, and the barometric information of induction is sent to the second microprocessor; Described the second microprocessor is compared this barometric information receiving from gas pressure sensor and setting threshold interval; When the maximum of the pressure data receiving higher than setting threshold interval, the second microprocessor by-pass valve control controller opens air outlet valve setting-up time, make in transfer conduit air pressure in setting range, one end of outlet pipe connects air outlet valve simultaneously, the other end connects described hydrogen manufacturing subsystem, and the firing equipment that needs that is hydrogen manufacturing subsystem by burning heats; When the minimum value of the pressure data receiving lower than setting threshold interval, the second microprocessor is controlled the transporting velocity that described hydrogen manufacturing subsystem is accelerated raw material.
2. the instant hydrogen manufacturing electricity generation system of methanol-water, is characterized in that, described preparing hydrogen, generating power system is not established display screen, and described preparing hydrogen, generating power system comprises hydrogen manufacturing subsystem, power generation sub-system, control subsystem;
Described hydrogen manufacturing subsystem, in order to prepare hydrogen, is delivered to power generation sub-system by the hydrogen making, the hydrogen gas generation that power generation sub-system utilizes described hydrogen manufacturing subsystem to transmit in real time;
Described control subsystem comprises microprocessor, the first wireless communication module, mobile terminal, and mobile terminal is provided with the second wireless communication module; Described mobile terminal utilizes the second wireless communication module that control command is sent to microprocessor, and microprocessor is controlled the operation of described hydrogen manufacturing subsystem, power generation sub-system according to the order receiving.
3. the instant hydrogen manufacturing electricity generation system of methanol-water according to claim 2, is characterized in that:
Described hydrogen manufacturing subsystem passes through transfer conduit real-time Transmission to power generation sub-system by the hydrogen making; In described transfer conduit, be provided with air pressure adjustment subsystem, for adjusting the air pressure of transfer conduit; The hydrogen gas generation that described power generation sub-system utilizes hydrogen manufacturing subsystem to make;
Described air pressure adjustment subsystem comprises the second microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe; Described gas pressure sensor is arranged in transfer conduit, in order to respond to the barometric information in transfer conduit, and the barometric information of induction is sent to the second microprocessor; Described the second microprocessor is compared this barometric information receiving from gas pressure sensor and setting threshold interval; When the maximum of the pressure data receiving higher than setting threshold interval, the second microprocessor by-pass valve control controller opens air outlet valve setting-up time, make in transfer conduit air pressure in setting range, one end of outlet pipe connects air outlet valve simultaneously, the other end connects described hydrogen manufacturing subsystem, and the firing equipment that needs that is hydrogen manufacturing subsystem by burning heats; When the minimum value of the pressure data receiving lower than setting threshold interval, the second microprocessor is controlled the transporting velocity that described hydrogen manufacturing subsystem is accelerated raw material.
4. the instant hydrogen manufacturing electricity generation system of methanol-water according to claim 2, is characterized in that:
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem comprises solid hydrogen reservoir vessel, liquid container, raw material conveying device, hydrogen producer, membrane separation device.
5. the instant hydrogen manufacturing electricity generation system of methanol-water according to claim 2, is characterized in that:
Described system is also provided with remote server, mobile terminal connects hydrogen manufacturing subsystem, power generation sub-system and remote server by the second wireless communication module, the information of hydrogen manufacturing subsystem, power generation sub-system is sent to remote server, and can obtains from server the set information of any hydrogen manufacturing subsystem, power generation sub-system.
6. a control method for the instant hydrogen manufacturing electricity generation system of the described methanol-water of one of claim 1 to 5, is characterized in that, described control method comprises:
Mobile terminal utilizes the second wireless communication module that control command is sent to microprocessor, and microprocessor is controlled the operation of described hydrogen manufacturing subsystem, power generation sub-system according to the order receiving.
7. control method according to claim 6, is characterized in that:
Described method also comprises: mobile terminal connects hydrogen manufacturing subsystem, power generation sub-system and remote server by the second wireless communication module, the information of hydrogen manufacturing subsystem, power generation sub-system is sent to remote server, and can obtains from server the set information of any hydrogen manufacturing subsystem, power generation sub-system.
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| CN105193236A (en) * | 2015-10-12 | 2015-12-30 | 上海合既得动氢机器有限公司 | Portable alcohol-hydrogen electric cooker |
| CN105194779A (en) * | 2015-10-12 | 2015-12-30 | 上海合既得动氢机器有限公司 | Water hydrogen breathing machine |
| CN105207299A (en) * | 2015-10-12 | 2015-12-30 | 上海合既得动氢机器有限公司 | Water and hydrogen blood analyzer |
| CN105206853A (en) * | 2015-10-12 | 2015-12-30 | 上海合既得动氢机器有限公司 | Water-hydrogen medical device |
| CN105232030A (en) * | 2015-10-12 | 2016-01-13 | 上海合既得动氢机器有限公司 | Water-hydrogen electrocardiogram machine |
| CN105362008A (en) * | 2015-10-12 | 2016-03-02 | 上海合既得动氢机器有限公司 | ICU (intensive care unit) electric hospital bed driven by hydrogen produced from methanol-water |
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