CN101047258A - Fuel cell type power generation device, electronic apparatus and treatment method of fuel - Google Patents
Fuel cell type power generation device, electronic apparatus and treatment method of fuel Download PDFInfo
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- CN101047258A CN101047258A CNA2007100884341A CN200710088434A CN101047258A CN 101047258 A CN101047258 A CN 101047258A CN A2007100884341 A CNA2007100884341 A CN A2007100884341A CN 200710088434 A CN200710088434 A CN 200710088434A CN 101047258 A CN101047258 A CN 101047258A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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Abstract
A fuel cell type power generation device including: a fuel cell extracting electric power by an electrochemical reaction of a fuel; a first combustor burning an unreacted fuel exhausted from the fuel cell; and a second combustor burning an unburned fuel exhausted from the first combustor.
Description
Technical field
The electronic equipment that the present invention relates to a kind of fuel cell-type power generation device and have this fuel cell-type power generation device, wherein said fuel cell-type power generation device adopts the modifier resulting modification gas generation of modified fuel electrochemical reaction to obtain electric power by making in generator unit (fuel battery main body); The processing method that relates to a kind of unreacted fuel of discharging from generator unit simultaneously.
Background technology
Fuel cell is to obtain electric power by the electrochemical reaction of fuel, is extensively carrying out the research and development of fuel cell at present.The employed fuel of fuel cell is hydrogen, generates above-mentioned hydrogen by adopting original fuels (raw fuel) such as modifier upgrading methyl alcohol.In addition, in order to improve energy utilization efficiency, at present ongoingly be: the unreacted hydrogen of discharging from generator unit (fuel battery main body) is burnt burners such as combustion furnace, and heat modifier by means of this combustion heat.In addition, make the fuel of discharging be sent to other burner along separate routes, be sent to the quantity delivered of the fuel of this other burner by control and control the quantity combusted of modifier heating, carry out the temperature control of modifier thus with burner from generator unit.
But,, also discharge unburned fuel with burner sometimes from this other burner or modifier heating even the quantity delivered that is sent to the fuel of other burner by generator unit (Power Generation Section main body) is controlled.
Summary of the invention
So the present invention carries out in view of the above-mentioned problems, its purpose is not make unburned fuel to discharge from burner.
According to the 1st scheme of the present invention, a kind of fuel cell-type power generation device is provided, it comprises: the generator unit that obtains electric power by the electrochemical reaction of fuel; Make the 1st burner that is burnt from the unreacted fuel of described generator unit discharge; And the 2nd burner that the unburned fuel of discharging from described the 1st burner is burnt.
According to the 2nd scheme of the present invention, a kind of electronic equipment is provided, it comprises: the generator unit that obtains electric power by the electrochemical reaction of fuel; Make the 1st burner that is burnt from the unreacted fuel of described generator unit discharge; Make the 2nd burner that is burnt from the unburned fuel of described the 1st burner discharge; And the electronic equipment main body of carrying out work by means of the electric power that obtains by described generator unit.
According to the 3rd scheme of the present invention, a kind of processing method of unreacted fuel of discharging from generator unit is provided, described generator unit obtains electric power by the electrochemical reaction of fuel, and wherein said processing method comprises: make the step of burning the 1st burner from the unreacted fuel of generator unit discharge; And the step that the unburned fuel of discharging from described the 1st burner is burnt the 2nd burner.
Description of drawings
The present invention above-mentioned and further purpose, feature and advantage will become clearer from the following detailed description of carrying out with reference to the accompanying drawings.This:
Fig. 1 is the block diagram by the electronic equipment of the electronic equipment main body of the fuel cell-type power generation device that comprises the 1st embodiment, load etc. and engaging body (cartridge) formation.
Fig. 2 is the schematic sectional view of the fuel cell-type power generation device of the 1st embodiment.
Fig. 3 is the block diagram by the electronic equipment main body of the fuel cell-type power generation device that comprises the 2nd embodiment, load etc. and the electronic equipment that constitutes of engaging body.
Fig. 4 is the block diagram by the electronic equipment main body of the fuel cell-type power generation device that comprises the 3rd embodiment, load etc. and the electronic equipment that constitutes of engaging body.
Fig. 5 is the schematic sectional view of the fuel cell-type power generation device of the 3rd embodiment.
Fig. 6 is the figure of the employed safety valve of fuel cell-type power generation device of expression the 3rd embodiment.
Fig. 7 is the block diagram by the electronic equipment main body of the fuel cell-type power generation device that comprises the 4th embodiment, load etc. and the electronic equipment that constitutes of engaging body.
Fig. 8 is the block diagram by the electronic equipment main body of the fuel cell-type power generation device that comprises the 5th embodiment, load etc. and the electronic equipment that constitutes of engaging body.
Fig. 9 is the block diagram by the electronic equipment main body of the fuel cell-type power generation device that comprises the 6th embodiment, load etc. and the electronic equipment that constitutes of engaging body.
Embodiment
Describe with regard to the preferred embodiment of the invention with reference to the accompanying drawings.Yet, in the embodiment of following narration, carried out all preferred restrictions for implementing the present invention at technical elements, but scope of the present invention is not limited to following embodiment and illustrated example.
[the 1st embodiment]
Fig. 1 is the block diagram of the electronic equipment 1010 that is made of electronic equipment main body 810 that comprises fuel cell-type power generation device 101, load 700 etc. and engaging body 2; Fig. 2 is the schematic sectional view of fuel cell-type power generation device 101.This fuel cell-type power generation device 101 comprises pump 3, gasifier 4, modifier 5, carbon monoxide removal device 6, generator unit (Power Generation Section main body) the 8, the 1st catalytic burner the 9, the 2nd catalytic burner 10, controller 30, air pump 31 and air pump 32.This fuel cell-type power generation device 101 is loaded on the electronic equipments 1000 such as notebook personal computer, PDA, electronic notebook, digital camera, mobile phone, wrist-watch, register and projector.Pump 3, gasifier 4, modifier 5, carbon monoxide removal device 6, generator unit the 8, the 1st catalytic burner the 9, the 2nd catalytic burner 10, controller the 30, the 1st air pump 31 and the 2nd air pump 32 contain in the inside of electronic equipment main body 810, engaging body 2 be designed to can dismounting with respect to electronic equipment main body 810 freely, when engaging body 2 was installed on the electronic equipment main body 810, engaging body 2 was connected with pump 3.In addition, load 700 also contains in the inside of electronic equipment main body 810.The details of load 700 holds the back narration.
In engaging body 2, liquid original fuel (for example methyl alcohol, ethanol, dimethyl ether) and state or the separate storage of water to mix.
In gasifier 4, be provided with the electric heater that constitutes by the thermo electric material temperature sensor 41 of holding concurrently.Hold concurrently with regard to the temperature sensor 41 with regard to electric heater, its resistance value exists with ... temperature, also plays a role as temperature sensor.The mixed liquor that is sent to gasifier 4 by pump 3 is by means of electric heater the hold concurrently heat of the heat of temperature sensor 41 and the 1st catalytic burner 9 and generating gasification.The mist of gasification is sent to modifier 5 in gasifier 4.
Be provided with in modifier 5 that resistance value exists with ... temperature and by the electric heater that thermo electric material the constitutes temperature sensor 51 of holding concurrently.Inside at modifier 5 is formed with stream, catalyst at the wall appendix of this stream.The mist that is sent to modifier 5 by gasifier 4 flows through the stream of modifier 5, is heated by hold concurrently temperature sensor 51 and the 1st catalytic burner 9 of electric heater, and reacts under the effect of catalyst.By the catalytic reaction of original fuel and water, generate the hydrogen, the carbon dioxide (and accessory substance described later is the carbon monoxide of trace etc.) that act as a fuel.In addition, be under the situation of methyl alcohol at original fuel, in modifier 5, mainly take place as shown in the formula the reaction shown in (1).
CH
3OH+H
2O→3H
2+CO
2 (1)
Carbon monoxide be according to chemical equation (1) take place successively afterwards all as shown in the formula the reaction equation of (2) and so on micro-by-product.
H
2+CO
2→H
2O+CO (2)
Be provided with in carbon monoxide removal device 6 that resistance value exists with ... temperature and by the electric heater that thermo electric material the constitutes temperature sensor 61 of holding concurrently.Inside at carbon monoxide removal device 6 is formed with stream, catalyst at the wall appendix of this stream.The modification gas that generates in modifier 5 is sent to carbon monoxide removal device 6.Moreover air outside also is sent to carbon monoxide removal device 6.Be sent to the modification gas of carbon monoxide removal device 6 and air mixed by modifier 5 and flow through the stream of carbon monoxide removal device 6, and be heated by hold concurrently temperature sensor 61 and the 1st catalytic burner 9 of electric heater.And in modification gas, carbon monoxide is under the effect of catalyst, and is preferentially oxidized like that as shown in the formula (3).Generate carbon dioxide thus, and carbon monoxide is removed from modification gas.For example, the concentration of the carbon monoxide in the modification gas reaches below the 10ppm.
2CO+O
2→2CO
2 (3)
Above-mentioned gasifier 4, modifier 5, carbon monoxide removal device 6 are accommodated in the insulation pack 20 of case shape.Air pressure in the insulation pack 20 remains under the vacuum pressure (for example 10Pa is following).
The modification gas of discharging from carbon monoxide removal device 6 is sent to the stream of the fuel electrodes dividing plate 85 of generator unit 8 by pipe arrangement 71, and air is sent to the stream of the opposing party's oxygen utmost point dividing plate 86.And the hydrogen in the modification gas that fuel electrodes film 81 is supplied with via oxygen utmost point film 83 with the airborne oxygen generation electrochemical reaction of supplying with to oxygen utmost point film 83, between fuel electrodes film 81 and oxygen utmost point film 83, produce electric power thus.In addition, under dielectric film 82 situation for dielectric film (for example solid polyelectrolyte membrane) with hydrogen ion permeability, on fuel electrodes film 81, take place as shown in the formula (4) such reaction, the hydrogen ion that generates on fuel electrodes film 81 sees through dielectric film 82, takes place as shown in the formula (5) such reaction on oxygen utmost point film 83.
H
2→2H
++2e
- (4)
2H
++1/2O
2+2e
-→H
2O (5)
Also comprise unreacted hydrogen in the modification gas of the stream by fuel electrodes dividing plate 85.In addition, the discharge modification gas of discharging by the stream of fuel electrodes dividing plate 85 is supplied to the 1st catalytic burner 9.Moreover air outside is subjected to the attraction of air pump 31 and is supplied to the 1st catalytic burner 9.As air pump 31, can use electric fan etc.
In the 1st catalytic burner 9, be provided with the electric heater that constitutes by the thermo electric material temperature sensor 91 of holding concurrently.The resistance value of temperature sensor 91 exists with ... temperature because electric heater is held concurrently, temperature sensor 91 also plays a role as the temperature sensor of the temperature of measuring the 1st catalytic burner 9 so this electric heater is held concurrently, and is input to controller 30 based on the hold concurrently mensuration temperature of temperature sensor 91 of this electric heater as the signal of telecommunication.
In addition, be formed with stream, catalyst at the wall appendix of this stream in the inside of the 1st catalytic burner 9.Be sent to the discharge modification gas of the 1st catalytic burner 9 and air mixed by fuel electrodes dividing plate 85 and flow through the stream of the 1st catalytic burner 9, and be heated by the electric heater temperature sensor 91 of holding concurrently.In the discharge modification gas of the stream that flows through the 1st catalytic burner 9, hydrogen produces the combustion heat under the effect of catalyst and burn thus.The 1st catalytic burner 9 is accommodated in the insulation pack 20, and the combustion heat that produces in the 1st catalytic burner 9 can be used for the selective oxidation reaction in gasification, the reaction of the upgrading in the modifier 5 and the carbon monoxide removal device 6 in the gasifier 4.In addition, gasifier 4, modifier 5, carbon monoxide removal device 6 and the 1st catalytic burner 9 are loaded in the insulation pack 20 in the mode that contacts with heat conducting material 21, and the combustion heat of the 1st catalytic burner 9 passes to gasifier 4, modifier 5 and carbon monoxide removal device 6 by heat conducting material 21.
Supply with the discharge modification gas by the 1st catalytic burner 9 to the 2nd catalytic burner 10, and then air outside is supplied to the 2nd catalytic burner 10 by air pump 32.As air pump 32, can use electric fan etc.Be provided with in the 2nd catalytic burner 10 that resistance value exists with ... temperature and by the electric heater that thermo electric material the constitutes temperature sensor 11 of holding concurrently, this electric heater temperature sensor 11 of holding concurrently also plays a role as temperature sensor.Inside at the 2nd catalytic burner 10 is formed with stream, catalyst at the wall appendix of this stream.In addition, the 2nd catalytic burner 10 is positioned at the outside of insulation pack 20.
Be sent to the discharge modification gas of the 2nd catalytic burner 10 and air mixed by the 1st catalytic burner 9 and flow through the stream of the 2nd catalytic burner 10, be heated by the electric heater temperature sensor 11 of holding concurrently.In the discharge modification gas of the stream that flows through the 2nd catalytic burner 10, hydrogen is under the effect of catalyst and burn.Like this, the hydrogen of the trace that contains in the discharge modification gas of being sent here by the 1st catalytic burner 9 is removed, and the discharge modification gas that flows through the stream of the 2nd catalytic burner 10 is discharged into the outside.
Work with regard to fuel cell-type power generation device 101 describes below, and just the processing method of the hydrogen from the discharge modification gas that the fuel electrodes of generator unit 8 is discharged describes simultaneously.
To electric heater temperature sensor 41, electric heater temperature sensor 51, electric heater temperature sensor 61, electric heater temperature sensor 91 and electric heater temperature sensor 11 supply capabilities of holding concurrently of holding concurrently of holding concurrently of holding concurrently of holding concurrently, make electric heater temperature sensor 41, electric heater temperature sensor 51, electric heater temperature sensor 61, electric heater temperature sensor 91 and electric heater temperature sensor 11 heatings of holding concurrently of holding concurrently of holding concurrently of holding concurrently of holding concurrently, under this state, pump 3 work, then air pump 32 is worked, and then makes air pump 31 work by controller 30.By the original fuel and the water of pump 3 delivering liquids, produce from gasifier 4 and reach flowing of the 2nd catalytic burner 10 via the fuel electrodes (fuel electrodes dividing plate 85) and the 1st catalytic burner 9 of modifier 5, carbon monoxide removal device 6, generator unit 8.In gasifier 4, original fuel and water generating gasification; In modifier 5, generate modification gas by original fuel and water; In carbon monoxide removal device 6, the carbon monoxide in the modification gas is removed; In generator unit 8, obtain electric power by the electrochemical reaction of the hydrogen in the modification gas; In the 1st catalytic burner 9, discharge and not used in the modification gas and residual hydrogen is burnt by generating; In the 2nd catalytic burner 10, unburned in the 1st catalytic burner 9 and the hydrogen of residual trace are burnt.
And the stable working state of gasifier 4, modifier 5, carbon monoxide removal device 6, generator unit the 8, the 1st catalytic burner 9 and the 2nd catalytic burner 10, flowing of modification gas etc. is also stable, and generator unit 8 is worked under stable generating state.Under this stable generating state, be used to make electric heater temperature sensor 41, electric heater temperature sensor 51, electric heater temperature sensor 61, electric heater temperature sensor 91 and the electric heater temperature sensor 11 of holding concurrently of holding concurrently of holding concurrently of holding concurrently of holding concurrently to supply with and to stop as the electric power of heater work.Under such stable state, the hold concurrently mensuration temperature of temperature sensor 91 of electric heater is predetermined value (design load), has imported this mensuration temperature controlling device 30 and has made the air quantity delivered of air pump 31 remain predetermined constant.This constant is redefined for the amount that is sent to the hydrogen completing combustion the discharge modification gas of the 1st catalytic burner 9 from generator unit 8 less than making.For this reason, even almost 100% burning that is used for hydrogen of the airborne oxygen of being supplied with by air pump 31 also has in the 1st catalytic burner 9 and discharges a part of hydrogen unburned in the modification gas and left behind.For example, when generator unit 8 was worked under a certain generating state, the consumption rate of supposing hydrogen was 80%, and then 20% unreacted hydrogen is sent to the 1st catalytic burner 9.In addition, 18% hydrogen burn in the 1st catalytic burner 9 to carry the air of constant for example to make, and 2% the hydrogen that then is left is sent to the 2nd catalytic burner 10.
As mentioned above, under the stable electric generation state, by controller 30 the air quantity delivered of air pump 31 is controlled to be constant, the quantity combusted of the hydrogen in the 1st catalytic burner 9 is controlled thus, thereby the control of the temperature in the insulation pack 20 can easily be carried out.In addition, under this stable state,, can supply with the air of sufficient quantity to the 2nd catalytic burner 10 by air pump 32 in order to make the hydrogen completing combustion in the discharge modification gas that is sent to the 2nd catalytic burner 10.Therefore, not hydrogeneous and become non-flammable compressive gas in the mist that discharge the outside.
In addition, when generator unit 8 was stablized with stable energy output work and system, if 700 the consumes power of loading reduces, then the energy output of generator unit 8 reduced, and the ratio (consumption rate) of the hydrogen that generator unit 8 consumes reduces.Therefore, the hydrogen concentration that is sent in the discharge modification gas of the 1st catalytic burner 9 by generator unit 8 raises.But, because only supply with constant (stable electric generation time-division) by the air that air pump 31 is supplied with to the 1st catalytic burner 9, so, raise even be sent to the hydrogen concentration of the 1st catalytic burner 9, the quantity combusted of this hydrogen can not change yet, thereby the 1st catalytic burner 9 can not heat up.In addition, raise by the hydrogen concentration of the 1st catalytic burner 9 in the discharge modification gas that the 2nd catalytic burner 10 is supplied with.For example, when the consumption rate of the hydrogen of generator unit 8 is reduced to 60% by 80%, 40% unreacted hydrogen is sent to the 1st catalytic burner 9,18% hydrogen burns in the 1st catalytic burner 9, remaining 22% hydrogen is sent to the 2nd catalytic burner 10, but, owing to air from sufficient quantity to the 2nd catalytic burner 10 that supply with, so hydrogen completing combustion in the 2nd catalytic burner 10.
Otherwise when generator unit 8 was stablized with a certain energy output work and system, if 700 the consumes power of loading increases, then the energy output of generator unit 8 increased, and the ratio (consumption rate) of the hydrogen that generator unit 8 consumes increases.Therefore, the hydrogen concentration that is sent in the discharge modification gas of the 1st catalytic burner 9 by generator unit 8 descends.But, as long as this hydrogen concentration (consuming by air pump 31 more than the air of the constant that the 1st catalytic burner 9 is supplied with) in permissible range then can make the quantity combusted of hydrogen remain unchanged, thereby can not change the temperature of the 1st catalytic burner 9.In addition, unburned in the 1st catalytic burner 9 and residual hydrogen is sent to the 2nd catalytic burner 10, owing to supply with the air of sufficient quantity to the 2nd catalytic burner 10, so hydrogen completing combustion in the 2nd catalytic burner 10.
As mentioned above, even being sent to the hydrogen concentration of the 1st catalytic burner 9 and the 2nd catalytic burner 10 changes, by controller 30 the air quantity delivered of air pump 31 is controlled to be constant, also can control the quantity combusted of the hydrogen in the 1st catalytic burner 9 thus, thereby the control of the temperature in the insulation pack 20 can be carried out easily.In addition, raise, also owing to air from sufficient quantity to the 2nd catalytic burner 10 that supply with, so hydrogen completing combustion in the 2nd catalytic burner 10 even be sent to the hydrogen concentration of the 1st catalytic burner 9 and the 2nd catalytic burner 10.At this moment, because the 2nd catalytic burner 10 is positioned at the outside of insulation pack 20, so the temperature control of the upgrading portion that comprises modifier is affected.
In addition, when generator unit 8 is stablized with a certain energy output work and system, if the situation that consideration reduces the liquid-conveying amount of pump 3, then because gasifier 4, modifier 5 and carbon monoxide removal device 6 all are the endothermic reaction, thereby the temperature in the insulation pack 20 rise.Its result, the hold concurrently mensuration temperature of temperature sensor 91 of electric heater is higher than predetermined value, has imported this mensuration temperature controlling device 30 and has made the air quantity delivered of air pump 31 be lower than constant.So, can reduce the heat that is produced by burning, thereby the temperature that can suppress in the insulation pack 20 rises.In addition, though the hydrogen amount of burning reduces in the 1st catalytic burner 9, the hydrogen concentration of being supplied with to the 2nd catalytic burner 10 by the 1st catalytic burner 9 raises, but, even being sent to the hydrogen concentration of the 2nd catalytic burner 10 raises, also owing to air from sufficient quantity to the 2nd catalytic burner 10 that supply with, so be sent to hydrogen completing combustion in the 2nd catalytic burner 10 of the 2nd catalytic burner 10.In addition, cause the temperature in the insulation pack 20 to rise even reduce the growing amount of hydrogen, also as described above, owing to by controller 30 the air quantity delivered of air pump 31 is controlled to be and is lower than constant, so the quantity combusted of the hydrogen in the 1st catalytic burner 9 is controlled, the temperature that can suppress in the insulation pack 20 rises, thereby can easily carry out temperature control.
Otherwise, when generator unit 8 is stablized with a certain energy output work and system, if the situation that consideration increases the liquid-conveying amount of pump 3, then because gasifier 4, modifier 5 and carbon monoxide removal device 6 all are the endothermic reaction, thereby the temperature in the insulation pack 20 descend.Its result, the hold concurrently mensuration temperature of temperature sensor 91 of electric heater is lower than predetermined value, has imported this mensuration temperature controlling device 30 and has made the air quantity delivered of air pump 31 be higher than constant.So, can increase the heat that is produced by burning, thereby the temperature that can suppress in the insulation pack 20 descends.In addition, unburned in the 1st catalytic burner 9 and residual hydrogen is sent to the 2nd catalytic burner 10, owing to supply with the air of sufficient quantity to the 2nd catalytic burner 10, so hydrogen completing combustion in the 2nd catalytic burner 10.
In the present embodiment, because unburned hydrogen completing combustion in the 2nd catalytic burner 10 in the 1st catalytic burner 9, so flammable exhaust can not discharged from the 2nd catalytic burner 10, thus fail safe is improved.In addition, because the 2nd catalytic burner 10 is positioned at the outside of insulation pack 20, thus the temperature control of the upgrading portion that comprises modifier is affected, thus can carry out stable generating.
In addition, do not control by generator unit 8 be sent to the 1st catalytic burner 9 the discharge modification gas flow and control the air quantity delivered of air pump 31, the quantity combusted of hydrogen in the 1st catalytic burner 9 is controlled, thereby controls with the temperature that simple structure just can be carried out in the insulation pack 20.
In addition, if adapt and change the liquid-conveying amount of pump 3 as required with the energy output of generator unit 8, then the growing amount of hydrogen changes, the hydrogen concentration that is sent to the 1st catalytic burner 9 by the fuel electrodes of generator unit 8 also changes, but, the variation of hydrogen concentration of being sent to the 1st catalytic burner 9 with fuel electrodes by generator unit 8 is irrelevant, the air quantity delivered of just controlling air pump 31 just can be controlled the quantity combusted of the hydrogen in the 1st catalytic burner 9, thereby the control of the temperature in the insulation pack 20 has good controlledly, can change the original fuel supplied with by pump 3 and the quantity delivered of water at short notice.
In addition, the present invention is not limited to above-mentioned embodiment, also can carry out the change of various improvement and design without departing from the spirit and scope of the present invention.
[the 2nd embodiment]
In above-mentioned the 1st embodiment, the situation that is 1 the 1st catalytic burners with the insulation pack 20 interior catalytic burners that are provided with is that example is illustrated, but, for example also can adopt following formation, promptly be respectively arranged with gasifier 4 usefulness, modifier 5 usefulness and carbon monoxide removal device 6 and use catalytic burner.
Fig. 3 represent to act as a fuel other configuration example of cell type Blast Furnace Top Gas Recovery Turbine Unit (TRT) 201.
The configuration example of Fig. 3 is that the catalytic burner of setting in the insulation pack 20 is 2 a situation.In addition, in Fig. 3,, simplify its explanation at this for the identical symbol of inscape mark common with Fig. 1.
The 1st catalytic burner is set at modifier 5,6 special uses of carbon monoxide removal device, and the catalytic burner 12 of another gasifier 4 special uses is arranged in the insulation pack 20, and their heat conducting material is respectively 21a, 21b.
, same at gasifier with other catalytic burner with in the catalytic burner 12, the electric heater that is made of the thermo electric material temperature sensor 13 of holding concurrently is set.The resistance value of temperature sensor 13 exists with ... temperature because electric heater is held concurrently, temperature sensor 13 also plays a role as measuring the temperature sensor of gasifier with the temperature of catalytic burner 12 so this electric heater is held concurrently, and is input to controller 33 based on the hold concurrently mensuration temperature of temperature sensor 13 of this electric heater as the signal of telecommunication.
The discharge modification gas of discharging by the stream of fuel electrodes dividing plate 85 is supplied to the 1st catalytic burner 9, but, in discharging modification gas, the hydrogen suitable with the heat of supplying with to modifier 5, carbon monoxide removal device 6 burns with an amount of air mixed in the 1st catalytic burner 9 under the control of controller 30.
And the discharge modification gas that comes from the 1st catalytic burner 9 is residual that unburned hydrogen arranged, and it is supplied to gasifier with catalytic burner 12.And then air outside is subjected to the attraction of air pump 34 and is supplied to gasifier catalytic burner 12.
The situation of controller 33 and the 1st catalytic burner is same, has by electric heater temperature sensor 13 input of holding concurrently to characterize electric heaters the hold concurrently function of the signal of telecommunication of mensuration temperature of temperature sensor 13 and the controlled function of controlling the air quantity delivered of air pump 34 according to the mensuration temperature of temperature sensor 13 inputs of being held concurrently by electric heater.The controlled function of controller 33 comprises: with electric heater hold concurrently the mensuration temperature of temperature sensor 13 and the comparing function that predetermined value compares; According to this result relatively, be lower than under the situation of predetermined value the function that the air quantity delivered of air pump 34 is increased to some extent than predetermined constant in the hold concurrently mensuration temperature of temperature sensor 13 of electric heater; And, be higher than under the situation of predetermined value the function that the air quantity delivered of air pump 34 is decreased than this constant according to relatively result in the hold concurrently mensuration temperature of temperature sensor 13 of electric heater.
, considerably under the control of controller 33, burn with in the catalytic burner 12 at gasifier by the residual discharge modification gas that unburned this situation of hydrogen arranged of being in of supplying with of the 1st catalytic burner and the heat of supplying with to gasifier 4 with an amount of air mixed.
In the 1st embodiment, by the heat of 1 the 1st catalytic burner 9 control gasifier, modifier and carbon monoxide removal devices; And in the 2nd embodiment, and row arrangement the 1st catalytic burner 9 and gasifier usefulness catalytic burner 12, can control respectively heat.
If adopt such formation, then can manage the temperature of gasifier 4 and the temperature of modifier 5 and carbon monoxide removal device 6 more accurately.
In addition, also unburned and the residual discharge modification gas that includes residual hydrogen is fed to the 2nd catalytic burner 10 that is located at insulation pack 20 outsides in above-mentioned 2 catalytic burners.
Because to the air of the 2nd catalytic burner 10 supply sufficient quantity, so hydrogen completing combustion in the 2nd catalytic burner 10.
Therefore, same with the 1st embodiment, flammable exhaust can not discharged from the 2nd catalytic burner 10, thereby fail safe is improved.
In addition, in above-mentioned each embodiment, for for simplicity, just be illustrated to the air fed situation of catalytic burner, but the present invention being not limited to air, can be the gas that contains oxidants such as aerobic.
Yet, under the situation that the electric weight that obtains from generator unit (fuel battery main body) is sharply descended by the stable electric generation state, owing to be subjected to the influence that the hydrogen use amount reduces in the generator unit, the pressure loss of stream increases in the generator unit, and the pressure loss that perhaps is positioned at the catalytic burner etc. in generator unit downstream increases.For this reason, the pressure that is arranged in the modifier of generator unit upstream sharply rises.Because the rapid rising of this pressure also can exist the adverse current of comprehensive generation gas, the following degradation phenomenon of gas flow, thereby make the work of whole device become unstable.
[the 3rd embodiment]
Fig. 4 is the block diagram of the electronic equipment 1030 that is made of the electronic equipment main body 830 of the fuel cell-type power generation device 301 that comprises the 3rd embodiment, load 700 etc. and engaging body 2, and Fig. 5 is the schematic sectional view of fuel cell-type power generation device 301.This fuel cell-type power generation device 301 comprises pump 3, gasifier 4, modifier 5, carbon monoxide removal device 6, safety valve 7, generator unit (fuel battery main body) the 8, the 1st catalytic burner the 9, the 2nd catalytic burner 10, controller 30, air pump 31 and air pump 32.
In the 3rd embodiment, the pipe arrangement 71 between the fuel electrodes of carbon monoxide removal device 6 and generator unit 8 is provided with safety valve 7.This safety valve 7 is opened valve when above when the pressure of pipe arrangement 71 to the modification gas of generator unit 8 of flowing through from carbon monoxide removal device 6 reaches predetermined value (for example 10kPa), with the modification gas in the discharging pipe arrangement 71.
Fig. 6 has represented an example of safety valve 7.As shown in Figure 6, on pipe arrangement 71, be formed with throttle orifice 72, around the outer peripheral face of pipe arrangement 71 and throttle orifice 72, be formed with valve seat 73.In addition, support (housing) 74 is arranged, and around throttle orifice 72, form space 75 by support 74 in the arranged outside of pipe arrangement 71.Support 74 is provided with rotating shaft 76, and rotating shaft 76 highlights in the inboard of support 74, and rotating shaft 76 is set to and can moves along its axis direction with respect to support 74.On the top of rotating shaft 76 valve body 77 is installed, package has spring 78 in rotating shaft 76.Under the effect of spring 78, valve body 77 is to valve seat 73 application of forces.The 2nd catalytic burner 10 is led to by pipe arrangement shown in Figure 4 79 in space 75.
In this mechanical passive safety valve 7, when the pressure of the modification gas that flows through pipe arrangement 71 is lower than predetermined value, then under the elastic force effect of spring 78, valve body 77 is shifted onto on the valve seat 73, thereby throttle orifice 72 is by 77 obturations of valve body.On the other hand, when the pressure of the modification gas that flows through pipe arrangement 71 reaches predetermined value when above, then under the effect of this pressure, the elastic force of valve body 77 antagonistic springs 78 and lift off a seat 73.For this reason, throttle orifice 72 is opened, the modification gas inflow space 75 in the pipe arrangement 71, and then flow into the 2nd catalytic burner 10 by pipe arrangement 79.In the 2nd catalytic burner 10, the hydrogen that flows through the next mist that comprises micro-hydrogen from safety valve 7 is burnt.
As mentioned above, if generator unit 8 sharply stops from the stable electric generation state, perhaps sharply descend,, can suppress to be arranged in the rapid rising of pressure of carbon monoxide removal device 6, modifier 5, the gasifier 4 of generator unit 8 upstreams then by opening the safety-valve 7 because of load change makes output.For this reason, the steady air current of fuel cell-type power generation device 301, whole device is working stability also.
In addition, the remainder of the modification gas of discharging from safety valve 7 is sent to the 2nd catalytic burner 10, because the hydrogen in the modification gas is burnt in the 2nd catalytic burner 10, so the gas of discharging from fuel cell-type power generation device 301 is non-flammable compressive gas from the gas that the 2nd catalytic burner 10 is discharged promptly.Therefore, can guarantee the fail safe of fuel cell-type power generation device 301.
[the 4th embodiment]
Fig. 7 is the block diagram of the electronic equipment 1040 that is made of the electronic equipment main body 840 of the fuel cell-type power generation device 401 that comprises the 4th embodiment, load 700 etc. and engaging body 2.This fuel cell-type power generation device 401 also has the 3rd catalytic burner 110 except each inscape of the fuel cell-type power generation device 301 of the 3rd embodiment.In the 3rd catalytic burner 110, be provided with resistance value and exist with ... temperature and, be formed with stream in the inside of the 3rd catalytic burner 110 by the electric heater 111 that thermo electric material constitutes, catalyst at the wall appendix of this stream.In addition, the 3rd catalytic burner 110 is positioned at the outside of insulation pack 20.
If adopt such formation,,, can suppress the pressure loss variation in the 2nd catalytic burner 10 so open and modification gas stream when coming when safety valve 7 then owing to be provided with the 3rd catalytic burner 110 in addition.
In addition, it is adjacent with the 2nd catalytic burner 10 that the 3rd catalytic burner 110 is set to, owing to carry out thermo-contact, thereby can utilize the heat of the electric heater 11 of the 2nd catalytic burner 10, can not waste and often maintenance can carry out the temperature of catalytic combustion.Therefore, open and the moment of modification gas stream, just can begin catalytic combustion at safety valve 7.In addition, in Fig. 7, electric heater 111 is designed to and electric heater 11 consubstantiality not, but also can be with 1 electric heater simultaneously as electric heater 111 and electric heater 11.
[the 5th embodiment]
Fig. 8 is the block diagram of the electronic equipment 1050 that is made of the electronic equipment main body 850 of the fuel cell-type power generation device 501 that comprises the 5th embodiment, load 700 etc. and engaging body 2.In this fuel cell-type power generation device 501, has each inscape of the fuel cell-type power generation device 301 of the 3rd embodiment.But pipe arrangement 79 is not to be connected with the 2nd catalytic burner 10, but is connected with the 1st catalytic burner 9.For this reason, when the pressure of the modification gas that flows in the pipe arrangement 71 reaches when making safety valve 7 drive valve more than the predetermined value, then the remainder of modification gas flows into the 1st catalytic burner 9 by safety valve 7.
[the 6th embodiment]
Fig. 9 is the block diagram of the electronic equipment 1060 that is made of the electronic equipment main body 860 of the fuel cell-type power generation device 601 that comprises the 6th embodiment, load 700 etc. and engaging body 2.This fuel cell-type power generation device 601 has and adopts electric-controlled type aggressive valve 570 that the signal of telecommunication opens and closes to replace mechanical type passive security valve 7.This valve 570 allows that by out valve modification gas flows to pipe arrangement 79 from pipe arrangement 71, stops modification gas to flow to pipe arrangement 79 from pipe arrangement 71 by closing valve.
Moreover this fuel cell-type power generation device 601 has pressure gauge 571 and controller 572.Pressure gauge 571 is measured the pressure of the modification gas that flow in the pipe arrangements 71, and will measure pressure and be converted to the signal of telecommunication.The mensuration pressure of pressure gauge 571 is sent to controller 572 as the signal of telecommunication.The function that controller 572 is had comprises: the function that the mensuration pressure and the predetermined value of pressure gauge 571 compared; According to result relatively, be the function that predetermined value is opened valve 570 when above at the mensuration pressure that transmits by pressure gauge 571; The function of shut off valve 570 when the mensuration pressure that is transmitted by pressure gauge 571 is lower than predetermined value.About other inscape of this fuel cell-type power generation device 601, then the inscape with the fuel cell-type power generation device 301 of the 3rd embodiment is identical.
When generator unit 8 is worked under stable generating state, because the mensuration pressure of pressure gauge 571 is lower than predetermined value, so controller 572 cuts out valve 570.On the other hand, if generator unit 8 sharply stops from the stable electric generation state, perhaps, load change sharply descends because of making output, then because the mensuration pressure of pressure gauge 571 is more than the predetermined value, thereby open valve 570 by controller 572, the remainder in the modification gas that flow in the pipe arrangement 71 flows into the 2nd catalytic burner 10.
By being designed to such formation, pressure threshold, switching degree that can make switching etc. freely changes.
In addition, about fuel cell-type power generation device shown in Figure 7 401, fuel cell-type power generation device 501 shown in Figure 8, also can be provided with the same electric-controlled type valve of valve 570 to replace safety valve 7, also can use with the same controller of controller 572 and control this electric-controlled type valve.
In addition, though safety valve 7, valve 570 be arranged between carbon monoxide removal device 6 and the generator unit 8, also can be between modifier 5 and generator unit 8.For example, also safety valve 7 and valve 570 can be set between modifier 5 and carbon monoxide removal device 6.
All disclosures of specification, claims, accompanying drawing and specification digest that the Japanese patent application that comprises Japanese patent application 2006-085579 number of application on March 27th, 2006 and applied on March 29th, 2006 is 2006-090941 number are incorporated among the present invention by quoting at this.
Illustrate and illustrated various typical embodiments above, but the present invention is not limited to these embodiments.Therefore, scope of the present invention is only limited by claims.
Claims (17)
1. fuel cell-type power generation device, it comprises:
Obtain the generator unit of electric power by the electrochemical reaction of fuel;
Make the 1st burner that is burnt from the unreacted fuel of described generator unit discharge; And
Make the 2nd burner that is burnt from the unburned fuel of described the 1st burner discharge.
2. fuel cell-type power generation device according to claim 1, it further has:
Modifier, it generates fuel by the upgrading original fuel, and the fuel that generates is sent to described generator unit;
Insulation pack: it is taking in described modifier and described the 1st burner;
Described the 2nd burner is arranged on the outside of described insulation pack.
3. fuel cell-type power generation device according to claim 2, it further has valve, its Jie is contained between described modifier and the described generator unit, when the pressure that is sent to the modification gas of described generator unit from described modifier reaches predetermined value when above, just this modification gas is discharged.
4. fuel cell-type power generation device according to claim 3, wherein, described valve is a safety valve, the pressure of the modification gas of this safety valve by being sent to described generator unit from described modifier and mechanically carry out work.
5. fuel cell-type power generation device according to claim 3, it further has:
Pressure gauge is used to measure the pressure that is sent to the modification gas of described generator unit from described modifier;
Controller, when the pressure of being measured by described pressure gauge reaches predetermined value when above, the modification gas that is sent to described generator unit from described modifier is discharged from described valve, when the pressure of being measured by described pressure gauge is lower than predetermined value, then stop the discharge of modification gas from described valve.
6. fuel cell-type power generation device according to claim 3, wherein, the modification gas of discharging from described valve is supplied to described the 2nd burner.
7. fuel cell-type power generation device according to claim 3, it further has the 3rd burner that is arranged on described insulation pack outside, and the modification gas of discharging from described valve is supplied to described the 3rd burner.
8. fuel cell-type power generation device according to claim 3, wherein, the modification gas of discharging from described valve is supplied to described the 1st burner.
9. fuel cell-type power generation device according to claim 1, it further has:
Pump, its gas that will contain oxidant is supplied to described the 1st burner;
Temperature sensor, it is used to measure the temperature of described the 1st burner;
Controller, it is according to the mensuration temperature of described temperature sensor, and control is by the quantity delivered of described pump gas that supply with and that contain oxidant.
10. fuel cell-type power generation device according to claim 9, wherein, described controller is lower than under the situation of predetermined value in described mensuration temperature, and the quantity delivered of the gas of being supplied with by described pump that contains oxidant is increased to some extent than predetermined amount; Be higher than under the situation of described predetermined value in described mensuration temperature, the quantity delivered of the gas of being supplied with by described pump that contains oxidant is decreased than described predetermined amount.
11. an electronic equipment, it comprises:
Obtain the generator unit of electric power by the electrochemical reaction of fuel;
Make the 1st burner that is burnt from the unreacted fuel of described generator unit discharge;
Make the 2nd burner that is burnt from the unburned fuel of described the 1st burner discharge; And
The electronic equipment main body of carrying out work by means of the electric power that obtains by described generator unit.
12. electronic equipment according to claim 11, it further has:
Modifier, it generates fuel by the upgrading original fuel, and the fuel that generates is sent to described generator unit;
Insulation pack: it is taking in described modifier and described the 1st burner;
Described the 2nd burner is arranged on the outside of described insulation pack.
13. electronic equipment according to claim 11, it further has:
Pump, its gas that will contain oxidant is supplied to described the 1st burner;
Temperature sensor, it is used to measure the temperature of described the 1st burner;
Controller, it is according to the mensuration temperature of described temperature sensor, and control is by the quantity delivered of described pump gas that supply with and that contain oxidant.
14. the processing method from the unreacted fuel of generator unit discharge, described generator unit obtains electric power by the electrochemical reaction of fuel, and wherein said processing method comprises:
Make the step of the 1st burner, burning from the unreacted fuel of described generator unit discharge; And
Make the step of the 2nd burner, burning from the unburned fuel of described the 1st burner discharge.
15. the processing method of fuel according to claim 14 wherein, is being taken in modifier and described the 1st burner in insulation pack, described modifier generates fuel by the upgrading original fuel, and the fuel that generates is sent to described generator unit;
Described the 2nd burner is arranged on the outside of described insulation pack.
16. the processing method of fuel according to claim 14, wherein, the gas that will contain oxidant is supplied to described the 1st burner, simultaneously according to the temperature of described the 1st burner, is controlled the quantity delivered of the gas of supplying with that contains oxidant by controller.
17. the processing method of fuel according to claim 16, wherein, described controller is lower than under the situation of predetermined value in the temperature of described the 1st burner, and the quantity delivered of the gas that contains oxidant is increased to some extent than predetermined amount; Temperature at described the 1st burner is higher than under the situation of described predetermined value, and the quantity delivered of the gas that contains oxidant is decreased than described predetermined amount.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006085579A JP5011775B2 (en) | 2006-03-27 | 2006-03-27 | Fuel cell power generator |
| JP085579/2006 | 2006-03-27 | ||
| JP2006090941A JP4872406B2 (en) | 2006-03-29 | 2006-03-29 | FUEL CELL TYPE POWER GENERATOR AND FUEL TREATMENT METHOD |
| JP090941/2006 | 2006-03-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101047258A true CN101047258A (en) | 2007-10-03 |
| CN101047258B CN101047258B (en) | 2011-03-30 |
Family
ID=38638451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100884341A Expired - Fee Related CN101047258B (en) | 2006-03-27 | 2007-03-27 | Fuel cell type power generation device, electronic apparatus and treatment method of fuel |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP5011775B2 (en) |
| CN (1) | CN101047258B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103579654A (en) * | 2013-10-29 | 2014-02-12 | 上海合既得动氢机器有限公司 | System and method for instant hydrogen production and power generation |
| CN103579653A (en) * | 2013-10-29 | 2014-02-12 | 上海合既得动氢机器有限公司 | System for real-time hydrogen production and power generation system by methanol water and control method of system |
| CN103618099A (en) * | 2013-11-18 | 2014-03-05 | 上海合既得动氢机器有限公司 | System and method forpower generation by using instantly prepared hydrogen |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008266118A (en) * | 2007-03-29 | 2008-11-06 | Aisin Seiki Co Ltd | Reformer system |
| EP2433904B1 (en) * | 2009-05-20 | 2019-11-20 | Panasonic Corporation | Method for operating a hydrogen generation device and fuel cell system |
| CN102052688B (en) * | 2010-12-31 | 2012-07-18 | 中国恩菲工程技术有限公司 | Method for controlling supply of fuel oil and air in heat insulation mode |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1011292B (en) * | 1987-06-10 | 1991-01-23 | 朱丽亚·帕夫罗夫娜·维伯 | Apparatus for puritying exhaust gas |
| JP2887346B2 (en) * | 1988-07-06 | 1999-04-26 | 富士電機 株式会社 | Fuel cell generator |
| JPH10106598A (en) * | 1996-09-25 | 1998-04-24 | Ishikawajima Harima Heavy Ind Co Ltd | Differential pressure control method for reformer of fuel cell |
| JP2000251911A (en) * | 1999-03-03 | 2000-09-14 | Nissan Motor Co Ltd | Fuel cell power generating system |
| JP2000344501A (en) * | 1999-06-02 | 2000-12-12 | Toyota Motor Corp | Operation control device for fuel reformer |
| JP2001052728A (en) * | 1999-08-10 | 2001-02-23 | Nissan Motor Co Ltd | Fuel cell system |
| JP3636068B2 (en) * | 2000-02-16 | 2005-04-06 | 日産自動車株式会社 | Fuel cell control device |
| JP2001254897A (en) * | 2000-03-10 | 2001-09-21 | Honda Motor Co Ltd | Hydrogen storage device |
| JP2002117874A (en) * | 2000-10-11 | 2002-04-19 | Nissan Motor Co Ltd | Reforming fuel cell system |
| JP3765989B2 (en) * | 2001-03-14 | 2006-04-12 | リンナイ株式会社 | Reformer heating method and heating apparatus |
| JP3454795B2 (en) * | 2001-03-28 | 2003-10-06 | 三洋電機株式会社 | Fuel cell system and start-up method thereof |
| JP3452051B2 (en) * | 2001-05-25 | 2003-09-29 | 日産自動車株式会社 | Fuel cell system |
| JP2003077517A (en) * | 2001-09-03 | 2003-03-14 | Toyota Motor Corp | Fuel cell system |
| JP3897682B2 (en) * | 2001-11-05 | 2007-03-28 | 大阪瓦斯株式会社 | Hydrogen-containing gas supply structure and fuel cell system including the same |
| US6926748B2 (en) * | 2001-11-19 | 2005-08-09 | General Motors Corporation | Staged lean combustion for rapid start of a fuel processor |
| JP3886789B2 (en) * | 2001-11-22 | 2007-02-28 | 東京瓦斯株式会社 | Reforming apparatus and operation method thereof |
| JP2003206104A (en) * | 2002-01-11 | 2003-07-22 | Nissan Motor Co Ltd | Membrane reactor system |
| JP4140253B2 (en) * | 2002-03-15 | 2008-08-27 | 日産自動車株式会社 | Fuel reforming system |
| JP2004152540A (en) * | 2002-10-29 | 2004-05-27 | Aisin Seiki Co Ltd | Method of stopping fuel cell system operation, and fuel cell system provided with same |
| JP4227062B2 (en) * | 2003-03-31 | 2009-02-18 | 株式会社東芝 | FUEL CELL SYSTEM, FUEL CELL SYSTEM FUEL AND FUEL CELL SYSTEM CLOSED CONTAINER |
| US20040247960A1 (en) * | 2003-03-31 | 2004-12-09 | Kabushiki Kaisha Toshiba | Fuel cell system |
| JP4098258B2 (en) * | 2004-02-25 | 2008-06-11 | アイシン精機株式会社 | Gas reforming system for fuel cell |
| JP4396467B2 (en) * | 2004-03-31 | 2010-01-13 | カシオ計算機株式会社 | Reactor |
| JP2006040597A (en) * | 2004-07-23 | 2006-02-09 | Mitsubishi Heavy Ind Ltd | Gas supply system, energy supply system and gas supply method |
| JP4388528B2 (en) * | 2006-03-24 | 2009-12-24 | アイシン精機株式会社 | Fuel reforming system |
| JP4724029B2 (en) * | 2006-03-27 | 2011-07-13 | アイシン精機株式会社 | Method for shutting down reformer |
-
2006
- 2006-03-27 JP JP2006085579A patent/JP5011775B2/en not_active Expired - Fee Related
-
2007
- 2007-03-27 CN CN2007100884341A patent/CN101047258B/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103579654A (en) * | 2013-10-29 | 2014-02-12 | 上海合既得动氢机器有限公司 | System and method for instant hydrogen production and power generation |
| CN103579653A (en) * | 2013-10-29 | 2014-02-12 | 上海合既得动氢机器有限公司 | System for real-time hydrogen production and power generation system by methanol water and control method of system |
| CN103579653B (en) * | 2013-10-29 | 2016-01-20 | 上海合既得动氢机器有限公司 | The instant hydrogen manufacturing electricity generation system of methanol-water and control method thereof |
| CN103618099A (en) * | 2013-11-18 | 2014-03-05 | 上海合既得动氢机器有限公司 | System and method forpower generation by using instantly prepared hydrogen |
| CN103618099B (en) * | 2013-11-18 | 2016-01-20 | 上海合既得动氢机器有限公司 | The hydrogen utilizing immediate system to obtain carries out the system and method generated electricity |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5011775B2 (en) | 2012-08-29 |
| CN101047258B (en) | 2011-03-30 |
| JP2007265651A (en) | 2007-10-11 |
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