CN103572597B - The antibacterial reinforcement means of a kind of poor rotten COTTON FABRIC historical relic - Google Patents
The antibacterial reinforcement means of a kind of poor rotten COTTON FABRIC historical relic Download PDFInfo
- Publication number
- CN103572597B CN103572597B CN201310509418.0A CN201310509418A CN103572597B CN 103572597 B CN103572597 B CN 103572597B CN 201310509418 A CN201310509418 A CN 201310509418A CN 103572597 B CN103572597 B CN 103572597B
- Authority
- CN
- China
- Prior art keywords
- cotton fabric
- historical relic
- rotten
- fabric
- acetum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 52
- 229920000742 Cotton Polymers 0.000 title claims abstract description 47
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 14
- 230000002787 reinforcement Effects 0.000 title claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 238000005728 strengthening Methods 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229960000583 acetic acid Drugs 0.000 claims abstract description 7
- 239000005357 flat glass Substances 0.000 claims abstract description 7
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 7
- 230000003014 reinforcing effect Effects 0.000 claims description 8
- 230000006196 deacetylation Effects 0.000 claims description 6
- 238000003381 deacetylation reaction Methods 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 208000027418 Wounds and injury Diseases 0.000 abstract description 2
- 230000006378 damage Effects 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 208000014674 injury Diseases 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000003643 water by type Substances 0.000 abstract 1
- 229920001661 Chitosan Polymers 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 108010054033 Chitin deacetylase Proteins 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to the antibacterial reinforcement means of a kind of poor rotten COTTON FABRIC historical relic, get 1 part of glacial acetic acid by mass fraction, 100 parts of deionized waters are mixed to get acetum; Get 0.25 part of shitosan to add in described acetum, be stirred to and dissolve completely; Gained thick liquid is put in biochemical cultivation case, keeps solution temperature 20 ~ 25 DEG C, after ripe one day, obtain strengthening agent; Rotten for grain COTTON FABRIC is put into strengthening agent, takes out after flooding 0.5-2h at 20 ~ 35 DEG C, roll its surface 30 ~ 100min with smooth sheet glass, repeat the process of padding twice, at 60 ~ 80 DEG C, dry 5 ~ 10min, use washed with de-ionized water fabric face, air dry.The beneficial effect of the invention: 1) improve COTTON FABRIC historical relic intensity, increase the antimildew and antibacterial of historical relic.2) little to fabric injury.3) method is easy, cost is low, effective.4) nontoxic, harmless, pollution-free, meet the trend of environmental protection development.
Description
Technical field
The present invention relates to Techniques of Relics Protection field, the antibacterial reinforcement means of especially a kind of poor rotten COTTON FABRIC historical relic.
Background technology
Cotton is as far back as ground plantations such as Xinjiang, Yunnan, Hainan, and to first bright epoch, cotton gradually part replaces silk fiber crops, becomes the natural fabric crop that China is important.The COTTON FABRIC historical relic be unearthed so far is from the pre-Qin days to clearly bright, and the historical relic in each age has, and mainly exists with the first-class form of cloth, clothing, cotton blanket and cotton.Therefore COTTON FABRIC is part important in China's culture treasure-house, and carrying out reinforcing to the rotten COTTON FABRIC historical relic of grain be unearthed and be significant, is also always lacked research field.In order to the requirement that satisfied collection is studied and displayed, need to carry out necessary reinforcing to increase its intensity to COTTON FABRIC.
COTTON FABRIC is reinforced follow following basic principle: (1) keeps original appearance principle, and (2) ageing-resistant principle, (3) intervene principle less, (4) invertibity principle.
Summary of the invention
The present invention will solve the shortcoming of above-mentioned prior art, provides a kind of poor rotten COTTON FABRIC historical relic antibacterial reinforcement means.The present invention take chitosan solution as strengthening agent, adopts the processing method of " soak-roll-dry " to reinforce COTTON FABRIC historical relic, while improving COTTON FABRIC historical relic intensity, does not affect outward appearance and the feel of historical relic, increases the antimildew and antibacterial of historical relic.
The present invention solves the technical scheme that its technical problem adopts: adopt following steps:
1) get the glacial acetic acid of 1 part by mass fraction, join in the deionized water of 100 parts and make acetum;
2) shitosan getting 0.25 part of deacetylation >=90% by mass fraction joins in the obtained acetum of step 1), is stirred to and dissolves completely;
3) by step 2) obtained solution puts in biochemical cultivation case, and keep solution temperature 20 ~ 25 DEG C, after ripe one day, obtain poor rotten COTTON FABRIC historical relic strengthening agent;
4) rotten for grain COTTON FABRIC is put into strengthening agent, flood at 20 ~ 35 DEG C after 0.5-2 hour and take out, its surface 30 ~ 100min is rolled with smooth sheet glass, repeat the process of padding twice (process of padding performs three times altogether) again, then at 60 ~ 80 DEG C, 5 ~ 10min is dried, and use washed with de-ionized water fabric face, the COTTON FABRIC after must reinforcing after air dry.
Inventing useful effect is: 1) main body of cotton is cellulose, shitosan is the derivative of chitin deacetylase base, the cellulose of molecular structure and natural cotton is quite similar, and containing free amino and hydroxyl, there is reactivity, shitosan can form Hydrogenbond with the cellulose in COTTON FABRIC under certain condition, and chemical crosslinking to a certain degree occurs; Meanwhile, shitosan is the natural material of a kind of high absorbent ventilate and antimildew and antibacterial, to the effect of human non-toxic's evil, safe and reliable, has good biocompatibility, therefore uses chitosan solution reparation to be the perfect optimal path of poor rotten COTTON FABRIC teaching display stand.The present invention take chitosan solution as strengthening agent, adopts the processing method of " soak-roll-dry " to reinforce COTTON FABRIC historical relic, effectively can improve COTTON FABRIC historical relic intensity, increase the antimildew and antibacterial of historical relic.2) use chemicals less, chitosan molecule structure is similar to cotton-textile fibres element, little to the injury of fabric itself.3) method is easy, cost is low, effective.4) nontoxic, harmless, pollution-free, meet the trend of environmental protection development.
Detailed description of the invention
The invention will be further described below:
Embodiment 1: the antibacterial reinforcement means of a kind of poor rotten COTTON FABRIC historical relic, comprises the following steps:
First, get the glacial acetic acid of 1 part by mass fraction, join in the deionized water of 100 parts and make acetum; Secondly, the shitosan getting 0.25 part of deacetylation >=90% by mass fraction joins in the obtained acetum of abovementioned steps, is stirred to and dissolves completely; Again, the solution that previous step is obtained is put in biochemical cultivation case, keeps solution temperature 20 DEG C, after ripe one day, obtains poor rotten COTTON FABRIC historical relic strengthening agent; Finally, rotten for grain COTTON FABRIC is put into described strengthening agent, flood at 20 DEG C after 0.5 hour and take out, its surperficial 30min is rolled with smooth sheet glass, repeat the process of padding twice (process of padding performs three times altogether) again, at 60 DEG C, dry 5min again, and use washed with de-ionized water fabric face, the COTTON FABRIC after must reinforcing after air dry.
Embodiment 2: the antibacterial reinforcement means of a kind of poor rotten COTTON FABRIC historical relic, comprises the following steps:
First, get the glacial acetic acid of 1 part by mass fraction, join in the deionized water of 100 parts and make acetum; Secondly, the shitosan getting 0.25 part of deacetylation >=90% by mass fraction joins in the obtained acetum of abovementioned steps, is stirred to and dissolves completely; Again, the solution that previous step is obtained is put in biochemical cultivation case, keeps solution temperature 25 DEG C, after ripe one day, obtains poor rotten COTTON FABRIC historical relic strengthening agent; Finally, rotten for grain COTTON FABRIC is put into described strengthening agent, flood at 35 DEG C after 2 hours and take out, its surperficial 100min is rolled with smooth sheet glass, repeat the process of padding twice (process of padding performs three times altogether) again, at 80 DEG C, dry 10min again, and use washed with de-ionized water fabric face, the COTTON FABRIC after must reinforcing after air dry.
Embodiment 3: the antibacterial reinforcement means of a kind of poor rotten COTTON FABRIC historical relic, comprises the following steps:
First, get the glacial acetic acid of 1 part by mass fraction, join in the deionized water of 100 parts and make acetum; Secondly, the shitosan getting 0.25 part of deacetylation >=90% by mass fraction joins in the obtained acetum of abovementioned steps, is stirred to and dissolves completely; Again, the solution that previous step is obtained is put in biochemical cultivation case, keeps solution temperature 23 DEG C, after ripe one day, obtains poor rotten COTTON FABRIC historical relic strengthening agent; Finally, rotten for grain COTTON FABRIC is put into described strengthening agent, flood at 30 DEG C after 1 hour and take out, its surperficial 60min is rolled with smooth sheet glass, repeat the process of padding twice (process of padding performs three times altogether) again, at 70 DEG C, dry 8min again, and use washed with de-ionized water fabric face, the COTTON FABRIC after must reinforcing after air dry.
Embodiment 4: the antibacterial reinforcement means of a kind of poor rotten COTTON FABRIC historical relic, comprises the following steps:
First, get the glacial acetic acid of 1 part by mass fraction, join in the deionized water of 100 parts and make acetum; Secondly, the shitosan getting 0.25 part of deacetylation >=90% by mass fraction joins in the obtained acetum of abovementioned steps, is stirred to and dissolves completely; Again, the solution that previous step is obtained is put in biochemical cultivation case, keeps solution temperature 21 DEG C, after ripe one day, obtains poor rotten COTTON FABRIC historical relic strengthening agent; Finally, rotten for grain COTTON FABRIC is put into described strengthening agent, flood at 25 DEG C after 1.5 hours and take out, its surperficial 80min is rolled with smooth sheet glass, repeat the process of padding twice (process of padding performs three times altogether) again, at 65 DEG C, dry 7min again, and use washed with de-ionized water fabric face, the COTTON FABRIC after must reinforcing after air dry.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of application claims.
Claims (1)
1. the antibacterial reinforcement means of grain rotten COTTON FABRIC historical relic, is characterized in that adopting following steps:
1) get the glacial acetic acid of 1 part by mass fraction, join in the deionized water of 100 parts and make acetum;
2) shitosan getting 0.25 part of deacetylation >=90% by mass fraction joins in the obtained acetum of step 1), is stirred to and dissolves completely;
3) by step 2) obtained solution puts in biochemical cultivation case, and keep solution temperature 20 ~ 25 DEG C, after ripe one day, obtain poor rotten COTTON FABRIC historical relic strengthening agent;
4) rotten for grain COTTON FABRIC is put into the strengthening agent that step 3) obtains, flood at 20 ~ 35 DEG C after 0.5-2 hour and take out, its surface 30 ~ 100min is rolled with smooth sheet glass, repeat the process of padding twice again, then at 60 ~ 80 DEG C, 5 ~ 10min is dried, and use washed with de-ionized water fabric face, the COTTON FABRIC after must reinforcing after air dry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310509418.0A CN103572597B (en) | 2013-10-24 | 2013-10-24 | The antibacterial reinforcement means of a kind of poor rotten COTTON FABRIC historical relic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310509418.0A CN103572597B (en) | 2013-10-24 | 2013-10-24 | The antibacterial reinforcement means of a kind of poor rotten COTTON FABRIC historical relic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103572597A CN103572597A (en) | 2014-02-12 |
| CN103572597B true CN103572597B (en) | 2015-11-18 |
Family
ID=50045259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310509418.0A Expired - Fee Related CN103572597B (en) | 2013-10-24 | 2013-10-24 | The antibacterial reinforcement means of a kind of poor rotten COTTON FABRIC historical relic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103572597B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103999930B (en) * | 2014-06-04 | 2016-01-20 | 山西农业大学 | The biological composite mildewproof antistaling agent of a kind of oranges and tangerines and preparation and application |
| CN106174723A (en) * | 2016-08-31 | 2016-12-07 | 浙江棉田针织有限公司 | A kind of intelligent antibacterial motion bra |
| CN107447521B (en) * | 2017-08-18 | 2018-11-09 | 上海咏姿时装有限公司 | A kind of regeneration method of waste and old linen-cotton cloth |
| CN108914564B (en) * | 2018-07-29 | 2021-05-04 | 山东旭辉无纺布制品有限公司 | Preparation method of moisture-absorbing, breathable and antibacterial spunlace non-woven fabric for polyurethane synthetic leather |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0931847A (en) * | 1995-07-21 | 1997-02-04 | Seiren Co Ltd | Functional textile product and its production |
| JPH11100713A (en) * | 1997-09-24 | 1999-04-13 | Mitsubishi Rayon Co Ltd | Antimicrobial cellulose acetate fiber containing chitosan and its production |
| CN1391002A (en) * | 2002-06-21 | 2003-01-15 | 江志昕 | Process for removing acetylchitin size from fabric and its fabric |
| CN1626727A (en) * | 2003-12-08 | 2005-06-15 | 张宗泽 | Finishing process for face fabric of antibacterial knitted underwear |
| CN101074541A (en) * | 2007-06-18 | 2007-11-21 | 大连利健生物技术开发股份有限公司 | Antibacterial fabric finishing agent containing chitose its production and usage |
| KR100789462B1 (en) * | 2006-08-23 | 2008-01-02 | (주)청우섬유 | The preparation method of chitosan crosslinked cellulose fabrics |
| CN101392454A (en) * | 2008-11-07 | 2009-03-25 | 中国人民武装警察部队医学院 | Antibacterial cotton cloth and preparation method |
| CN102159765A (en) * | 2008-09-22 | 2011-08-17 | 连津格股份公司 | Method for treating cellulose moldings |
-
2013
- 2013-10-24 CN CN201310509418.0A patent/CN103572597B/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0931847A (en) * | 1995-07-21 | 1997-02-04 | Seiren Co Ltd | Functional textile product and its production |
| JPH11100713A (en) * | 1997-09-24 | 1999-04-13 | Mitsubishi Rayon Co Ltd | Antimicrobial cellulose acetate fiber containing chitosan and its production |
| CN1391002A (en) * | 2002-06-21 | 2003-01-15 | 江志昕 | Process for removing acetylchitin size from fabric and its fabric |
| CN1626727A (en) * | 2003-12-08 | 2005-06-15 | 张宗泽 | Finishing process for face fabric of antibacterial knitted underwear |
| KR100789462B1 (en) * | 2006-08-23 | 2008-01-02 | (주)청우섬유 | The preparation method of chitosan crosslinked cellulose fabrics |
| CN101074541A (en) * | 2007-06-18 | 2007-11-21 | 大连利健生物技术开发股份有限公司 | Antibacterial fabric finishing agent containing chitose its production and usage |
| CN102159765A (en) * | 2008-09-22 | 2011-08-17 | 连津格股份公司 | Method for treating cellulose moldings |
| CN101392454A (en) * | 2008-11-07 | 2009-03-25 | 中国人民武装警察部队医学院 | Antibacterial cotton cloth and preparation method |
Non-Patent Citations (4)
| Title |
|---|
| 壳聚糖与纤维素的结合及其抗菌性能的研究;许莹等;《印染》;20020220(第2期);第1-3页 * |
| 壳聚糖抗菌整理棉织物的研究;邓炳耀等;《纺织学报》;20060215;第27卷(第2期);第45-48页 * |
| 壳聚糖整理棉针织物的抗菌性能;许云辉等;《印染》;20040930(第18期);第1-3页 * |
| 用壳聚糖对织物进行改性的探讨;黄玉丽;《北京联合大学学报》;19981230;第12卷(第增1期);第206-210页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103572597A (en) | 2014-02-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103572597B (en) | The antibacterial reinforcement means of a kind of poor rotten COTTON FABRIC historical relic | |
| CN104436285B (en) | A kind of regenerated silk fibroin gel mould and preparation method thereof | |
| CN104017236B (en) | A kind of preparation method of hybrid inorganic-organic modifying super hydrophobicity bacteria cellulose aeroge oil absorption material | |
| CN104189944B (en) | High-purity natural collagenous fiber and preparation method thereof | |
| CN105088359B (en) | A kind of brief immersion flax degumming technique | |
| CN103981701B (en) | A kind of shitosan/Ag+Composite antibacterial dressing liquid and its preparation method and application | |
| CN107982089A (en) | A kind of preparation method of the bacterial cellulose facial mask with bacteriostasis efficacy | |
| CN105126159A (en) | Biomedical polysaccharide colloidal solution and preparation method thereof | |
| CN103572589A (en) | Amino acid-transglutaminase (TG) reinforcement method of fragile wool fabrics | |
| CN104160803A (en) | Method for improving watermelon seed germination rate | |
| CN106245357A (en) | A kind of method that pigment in leaves be transfer will be made directly on fabric | |
| CN107164828B (en) | Preparation method of cereal protein modified functional fiber | |
| CN102732977A (en) | Method for degumming silk cotton | |
| CN104233756A (en) | Sand washing technology of silk fabric | |
| CN101338515B (en) | Method for preparing fibroin strengthening agent | |
| CN105297429A (en) | No-ironing clothes with lasting shape memory and preparation method thereof | |
| CN110314125B (en) | Environment-friendly wet tissue for infants and preparation method thereof | |
| CN105239167B (en) | A kind of high intensity is modified mulberry fibre | |
| CN109487550B (en) | High-efficiency cool mildew-proof herbal cotton and preparation method thereof | |
| CN104928920A (en) | Antibacterial afterfinish process of printed cotton fabric | |
| CN109338724A (en) | The preparation method of chitin modified carboxylated cotton fabric in a kind of ion liquid medium | |
| CN104313871A (en) | Preparation method of lyophobic nano fiber fabric | |
| CN103103749A (en) | Application of plant stemona mothproofing agent on wool products | |
| CN110258108B (en) | Crease-resistant finishing method for cotton fabric | |
| CN103103751A (en) | Method for resisting bacteria, preventing crease and finishing silk fabric in biological enzymatic way |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Peng Zhiqin Inventor after: Peng Zhiqin Yao Qingqing Inventor before: Yao Qingqing Inventor before: Yao Qingqing Peng Zhiqin |
|
| COR | Change of bibliographic data | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151118 Termination date: 20181024 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |