CN103570878A - High-strength ethylene propylene diene monomer and preparation method thereof - Google Patents
High-strength ethylene propylene diene monomer and preparation method thereof Download PDFInfo
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- CN103570878A CN103570878A CN201310596018.8A CN201310596018A CN103570878A CN 103570878 A CN103570878 A CN 103570878A CN 201310596018 A CN201310596018 A CN 201310596018A CN 103570878 A CN103570878 A CN 103570878A
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Abstract
The invention discloses a high-strength ethylene propylene diene monomer and a preparation method thereof. The ethylene propylene diene monomer is characterized by being prepared by the following components in parts by weight: 90-110 parts of ethylene propylene diene monomer, 2-8 parts of acrylic acid, 0.4-1 part of initiator and 1-5 parts of sodium stearate. The high-strength ethylene propylene diene monomer has excellent mechanical property, and can be used for preparing medium-high-voltage power cables, motor lead wires, marine cables and the like.
Description
Technical field
The invention belongs to chemical technology field, be specifically related to a kind of high-strength ternary ethylene-propylene rubber(EPR) and preparation method thereof.
Background technology
Terpolymer EP rubber (EPDM) is the rubber being formed through solution copolymerization by ethene, propylene, then introduces the 3rd monomer (ENB).Terpolymer EP rubber is a kind of saturated superpolymer substantially, is the synthetic rubber of high comprehensive performance, has fabulous electrical property, aging resistance.But owing to not containing xln, so intensity is very low, the scope of application is very restricted.
Summary of the invention
The object of the invention is to overcome above-mentioned weak point a kind of high-strength ternary ethylene-propylene rubber(EPR) is provided.
Another object of the present invention is to provide the preparation method of above-mentioned high-strength ternary ethylene-propylene rubber(EPR).
The object of the invention is to realize in the following manner:
An ethylene-propylene rubber(EPR) is to be made by the component of following weight part:
90～110 parts of terpolymer EP rubbers, 2～8 parts, vinylformic acid, 0.4～1 part of initiator, 1～5 part of sodium stearate.
Above-mentioned terpolymer EP rubber is preferably made by the component of following weight part: 100 parts of terpolymer EP rubbers, 4～6 parts, vinylformic acid, 0.4～0.6 part of initiator, 2～3 parts of sodium stearate.
Described initiator is peroxide initiator.Described peroxide initiator is preferably dicumyl peroxide (DCP).
The preparation method of above-mentioned high-strength ternary ethylene-propylene rubber(EPR) comprises the following steps: terpolymer EP rubber, vinylformic acid, initiator, sodium stearate are added to extruding pelletization in twin screw extruder, and the screw speed adopting during extruding pelletization is 40-50 rev/min; Twin screw extruder temperature arranges as shown in the table:
Beneficial effect of the present invention compared with the prior art: the present invention is by being cross-linked into as from aggressiveness using stearate to make it to form physics after terpolymer EP rubber carboxyl grafting monomer, having improved the intensity of virgin rubber.Meanwhile, by increasing suitable subsidiary material, guarantee that other over-all propertieies of material that obtain are all stable again, to meet the demand of market diversification.
Embodiment
Below in conjunction with specific embodiment, describe the present invention in detail, in this illustrative examples of the present invention and explanation, be used for explaining the present invention, but not as a limitation of the invention.
Embodiment 1
Test recipe:
| Formula materials | Dosage (weight part) |
| Terpolymer EP rubber | 100 |
| Vinylformic acid | 6 |
| Initiator DCP | 0.6 |
| Sodium stearate | 2 |
Implementing process: terpolymer EP rubber, vinylformic acid, initiator, sodium stearate are added to extruding pelletization in twin screw extruder, and the screw speed adopting during extruding pelletization is 40-50 rev/min; Twin screw extruder temperature arranges as shown in the table:
The EPDM below preparing for the embodiment of the present invention 1 and common EPDM performance comparison table, from table, correlation data can find out that EPDM tensile strength of the present invention and elongation at break all have excellent performance.
Embodiment 2
Test recipe:
| Formula materials | Dosage (weight part) |
| Terpolymer EP rubber | 95 |
| Vinylformic acid | 4 |
| Initiator DCP | 0.4 |
| Sodium stearate | 3 |
Implementing process: terpolymer EP rubber, vinylformic acid, initiator, sodium stearate are added to extruding pelletization in twin screw extruder, and the screw speed adopting during extruding pelletization is 40-50 Zhuan ∕ minute; Twin screw extruder temperature arranges as shown in the table:
The EPDM below preparing for the embodiment of the present invention 2 and common EPDM performance comparison table, from table, correlation data can find out that EPDM tensile strength of the present invention and elongation at break all have excellent performance.
Claims (5)
1. a high-strength ternary ethylene-propylene rubber(EPR), is characterized in that this terpolymer EP rubber is to be made by the component of following weight part:
90～110 parts of terpolymer EP rubbers, 2～8 parts, vinylformic acid, 0.4～1 part of initiator, 1～5 part of sodium stearate.
2. high-strength ternary ethylene-propylene rubber(EPR) according to claim 1, is characterized in that this terpolymer EP rubber is to be made by the component of following weight part:
100 parts of terpolymer EP rubbers, 4～6 parts, vinylformic acid, 0.4～0.6 part of initiator, 2～3 parts of sodium stearate.
3. high-strength ternary ethylene-propylene rubber(EPR) according to claim 1 and 2, is characterized in that described initiator is peroxide initiator.
4. high-strength ternary ethylene-propylene rubber(EPR) according to claim 3, is characterized in that described peroxide initiator is dicumyl peroxide.
5. the preparation method of the high-strength ternary ethylene-propylene rubber(EPR) described in a claim 1 or 2, it is characterized in that described method comprises the following steps: terpolymer EP rubber, vinylformic acid, initiator, sodium stearate are added to extruding pelletization in twin screw extruder, and the screw speed adopting during extruding pelletization is 40-50 rev/min; Twin screw extruder temperature arranges as shown in the table:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310596018.8A CN103570878B (en) | 2013-11-22 | 2013-11-22 | A kind of High-strength ethylene propylene diene monomer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310596018.8A CN103570878B (en) | 2013-11-22 | 2013-11-22 | A kind of High-strength ethylene propylene diene monomer and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103570878A true CN103570878A (en) | 2014-02-12 |
| CN103570878B CN103570878B (en) | 2016-01-06 |
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| CN201310596018.8A Active CN103570878B (en) | 2013-11-22 | 2013-11-22 | A kind of High-strength ethylene propylene diene monomer and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104448664A (en) * | 2014-03-26 | 2015-03-25 | 江苏荣宜电缆有限公司 | Ethylene-propylene-diene monomer material used for electric wire and preparation method of ethylene-propylene-diene monomer material |
| CN105038082A (en) * | 2015-08-15 | 2015-11-11 | 无锡市群星线缆有限公司 | High-strength cold-resistant ethylene propylene diene monomer rubber and preparation method thereof |
| CN105086325A (en) * | 2015-08-15 | 2015-11-25 | 无锡市群星线缆有限公司 | Cold-resistant ethylene-propylene rubber insulation material for cables |
| CN107312250A (en) * | 2017-07-04 | 2017-11-03 | 合肥择浚电气设备有限公司 | A kind of excavator mechanical rubber crawler belt and preparation method thereof |
| US10680256B2 (en) | 2016-03-31 | 2020-06-09 | Sumitomo Riko Company Limited | Sealing member for a fuel cell |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1421465A (en) * | 2002-12-12 | 2003-06-04 | 上海交通大学 | Prepn process of high-hydroscopicity rubber |
| CN102532770A (en) * | 2011-12-29 | 2012-07-04 | 福建师范大学 | Ionic crosslinking thermoplastic elastic body and preparation method thereof |
-
2013
- 2013-11-22 CN CN201310596018.8A patent/CN103570878B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1421465A (en) * | 2002-12-12 | 2003-06-04 | 上海交通大学 | Prepn process of high-hydroscopicity rubber |
| CN102532770A (en) * | 2011-12-29 | 2012-07-04 | 福建师范大学 | Ionic crosslinking thermoplastic elastic body and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104448664A (en) * | 2014-03-26 | 2015-03-25 | 江苏荣宜电缆有限公司 | Ethylene-propylene-diene monomer material used for electric wire and preparation method of ethylene-propylene-diene monomer material |
| CN104448664B (en) * | 2014-03-26 | 2015-11-18 | 江苏荣宜电缆有限公司 | A kind of electric wire ethylene-propylene-diene monomer sizing material and preparation method thereof |
| CN105038082A (en) * | 2015-08-15 | 2015-11-11 | 无锡市群星线缆有限公司 | High-strength cold-resistant ethylene propylene diene monomer rubber and preparation method thereof |
| CN105086325A (en) * | 2015-08-15 | 2015-11-25 | 无锡市群星线缆有限公司 | Cold-resistant ethylene-propylene rubber insulation material for cables |
| CN105086325B (en) * | 2015-08-15 | 2019-01-11 | 上海玖开电线电缆有限公司 | A kind of cold resistant cable ethylene propylene rubber insulation material |
| US10680256B2 (en) | 2016-03-31 | 2020-06-09 | Sumitomo Riko Company Limited | Sealing member for a fuel cell |
| DE102016012405B4 (en) | 2016-03-31 | 2023-04-06 | Sumitomo Riko Company Limited | Sealing element for a fuel cell |
| CN107312250A (en) * | 2017-07-04 | 2017-11-03 | 合肥择浚电气设备有限公司 | A kind of excavator mechanical rubber crawler belt and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103570878B (en) | 2016-01-06 |
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