Summary of the invention
In order to solve above-mentioned technical matters of the prior art, the object of the present invention is to provide a kind of heat-resisting and plastic garbage bin fire-proof function that has.
There is heat-resisting and plastic garbage bin fire-proof function, comprise the cylindrical plastic staving with open topped, and be fastened on the plastic cover on described plastics staving top; Described plastic cover comprises roof and cylindrical sleeve tubular sidewall, and described sidewall is from roof to downward-extension, at described sidewall, near the place of roof, offers at least one window; It is characterized in that: on the outer wall of described plastics staving, be provided with groove, in described groove, be provided with the snap ring extending to described plastic cover sidewall, in the sidewall of described plastic cover, be formed with jut, described jut is supported on described snap ring and makes plastic cover remain on use location, opens thus through window to the passage of plastics staving open topped; When described snap ring is made by heat-sensitive resin material and temperature reaches setting value in plastics staving, described snap ring shrinks and/or melts, make described plastic cover under Action of Gravity Field along the downward landing of outer wall of described plastics staving and the roof of described plastic cover is contacted with the open topped of plastics staving, thereby make to close to the passage of plastics staving open topped via window.
Wherein, in order to be 160 ℃ of left and right by Temperature Setting, be chosen in 160 ℃ of above modified alkyd resins that significantly softening contraction (>70%) can occur as heat-sensitive resin material; The manufacturing process of described modified alkyd resin is as follows: the rosin of the maleic anhydride of the dimethylbenzene of the phthalate anhydride of the polytetramethylene glycol of the end hydroxy butadiene of the methylsuccinic acid of the soy(a)-bean oil fatty acid of 18.2wt%, 4.8wt%, 8.8wt%, 5.1wt%, 10.8wt%, 3.08wt%, 0.35wt% and surplus is added in esterifying kettle, be warming up to 150 ℃, start to stir, while being warmed up to 180 ℃, constant temperature refluxes 1 hour; Continue to be warmed up to 225 ~ 230 ℃, backflow esterification, remains to acid number and is less than 10mgKOH/g, in suction reactor, and cooling curing.
Compared with prior art, plastic garbage bin of the present invention has following beneficial effect:
The plastic garbage bin of heat-resisting and fire-proof function of the present invention, by stoping and/or significantly reducing the necessary oxygen of burning, enter in the plastics staving of the sewage disposer under case of fire, thereby can suffocate, started the fire lighted, realized and stop spreading of naked light and anneal.Plastic garbage bin of the present invention, as long as when temperature reaches the softening and/or fusion temperature of resin sensitive to heat, softening and/or the fusing of resin sensitive to heat can make described plastic cover under Action of Gravity Field along the downward landing of outer wall of described plastics staving and the roof of described plastic cover is contacted with the open topped of plastics staving, thereby substantially stoped the required oxygen that burns to enter in described plastics staving, this has improved the fire savety of sewage disposer to a great extent, and makes fire spreading become more difficult to sewage disposer outside.
The specific embodiment
Below with reference to specific embodiment and Figure of description, heat-resisting and plastic garbage bin fire-proof function of the present invention is described further, to help those skilled in the art to have more complete, accurate and deep understanding to inventive concept of the present invention, technical scheme.
As Figure 1-3, of the present invention have heat-resisting and plastic garbage bin fire-proof function, comprises the cylindrical plastic staving 10 with open topped 12, and be fastened on the plastic cover 20 on described plastics staving 10 tops; Described plastic cover 20 comprises roof 21 and cylindrical sleeve tubular sidewall 22, and described sidewall 22 is from roof to downward-extension, at described sidewall 22, near the place of roof, offers at least one window 23; On the outer wall 14 of described plastics staving 10, be provided with groove 18, in described groove 18, be provided with the snap ring 30 extending to described plastic cover sidewall, in the sidewall of described plastic cover 20, be formed with jut 24, described jut 24 is supported on described snap ring 30 and makes plastic cover 20 remain on use location, opens thus as shown in Figure 1 through window to the passage of plastics staving open topped; When described snap ring is made by heat-sensitive resin material and temperature reaches setting value in plastics staving, described snap ring shrinks and/or melts, make described plastic cover under Action of Gravity Field along the downward landing of outer wall of described plastics staving and the roof of described plastic cover is contacted with the open topped of plastics staving, thereby make as shown in Figure 3 to close to the passage of plastics staving open topped via window.
Wherein, in order to be 160 ℃ of left and right by Temperature Setting, be chosen in 160 ℃ of above modified alkyd resins that significantly softening contraction (>70%) can occur as heat-sensitive resin material; The manufacturing process of described modified alkyd resin is as follows: the rosin of the maleic anhydride of the dimethylbenzene of the phthalate anhydride of the polytetramethylene glycol of the end hydroxy butadiene of the methylsuccinic acid of the soy(a)-bean oil fatty acid of 18.2wt%, 4.8wt%, 8.8wt%, 5.1wt%, 10.8wt%, 3.08wt%, 0.35wt% and surplus is added in esterifying kettle, be warming up to 150 ℃, start to stir, while being warmed up to 180 ℃, constant temperature refluxes 1 hour; Continue to be warmed up to 225 ~ 230 ℃, backflow esterification, remains to acid number and is less than 10mgKOH/g, in suction reactor, and cooling curing.
Wherein, in order to guarantee that snap ring shrinks and/or melts, make described plastic cover can, along the outer wall landing smoothly downwards of described plastics staving, as preferably, on the outer wall of described plastics staving, also be provided with smooth refractory coating 16 under Action of Gravity Field.The thickness of described smooth refractory coating is 100-500 μ m.Described smooth refractory coating is by 2 of spraying 18wt%, 2'-dihydroxyl-5, the polyaryletherketone of the chloro-diphenylsulfide of 5'-bis-, the melamine formaldehyde resin of 12wt%, the dimethyl siloxane of the polytetrafluoroethylene of 8wt%, 5wt%, the calcium fluoride of the hydroxyethyliminodiacetic acid of 5wt%, 5wt%, the alkylether sulfonate of 2wt% and surplus forms.Described smooth refractory coating still can keep good not viscosity and slickness under the condition up to 250 ℃, can guarantee the smooth landing of plastic cover.
Wherein, described plastics staving and plastic cover are prepared by heat resisting flame retardant resin composition.Described heat resisting flame retardant resin composition be the ekonol of 12 ~ 15wt%, the methacrylate of the polyacrylinitrile of 5 ~ 8wt%, 5 ~ 8wt%, the triethyl phosphate of the PTT of 2 ~ 3wt%, 1.5 ~ 2wt%, the compound of the magnesium hydroxide of the aluminium hydroxide of 1.2 ~ 1.5wt%, 1.8 ~ 2.0wt% and the polyimide of surplus.
The plastic garbage bin of described heat-resisting and fire-proof function, by stoping and/or significantly reducing the necessary oxygen of burning, enter in the plastics staving of the sewage disposer under case of fire, thereby can suffocate, started the fire lighted, realized and stop spreading of naked light and anneal.Plastic garbage bin of the present invention, as long as when temperature reaches the softening and/or fusion temperature of resin sensitive to heat, softening and/or the fusing of resin sensitive to heat can make described plastic cover under Action of Gravity Field along the downward landing of outer wall of described plastics staving and the roof of described plastic cover is contacted with the open topped of plastics staving, thereby substantially stoped the required oxygen that burns to enter in described plastics staving, this has improved the fire savety of sewage disposer to a great extent, and makes fire spreading become more difficult to sewage disposer outside.
embodiment 1
Plastics staving described in the present embodiment and plastic cover are used heat resisting flame retardant resin composition die casting to form, the compound of the ekonol that described heat resisting flame retardant resin composition is 15wt%, the polyacrylinitrile of 5wt%, the methacrylate of 5wt%, the triethyl phosphate of the PTT of 2 ~ 3wt%, 2wt%, the magnesium hydroxide of the aluminium hydroxide of 1.2wt%, 2.0wt% and the polyimide of surplus.
embodiment 2
Plastics staving described in the present embodiment and plastic cover are used heat resisting flame retardant resin composition die casting to form, the compound of the ekonol that described heat resisting flame retardant resin composition is 12wt%, the polyacrylinitrile of 8wt%, the methacrylate of 8wt%, the triethyl phosphate of the PTT of 2wt%, 1.5wt%, the magnesium hydroxide of the aluminium hydroxide of 1.5wt%, 1.8wt% and the polyimide of surplus.
comparative example 1
Plastics staving described in the present embodiment and plastic cover are used heat resisting flame retardant resin composition die casting to form, the ekonol that described heat resisting flame retardant resin composition is 15wt%, the polyacrylinitrile of 5wt%, the methacrylate of 5wt%, the aluminium hydroxide of the triethyl phosphate of 1.5wt%, 1.2wt%, the compound of the polyimide of the magnesium hydroxide of 2.0wt% and surplus.
comparative example 2
Plastics staving described in the present embodiment and plastic cover are used heat resisting flame retardant resin composition die casting to form, the ekonol that described heat resisting flame retardant resin composition is 12wt%, the polyacrylinitrile of 8wt%, the methacrylate of 8wt%, the aluminium hydroxide of the triethyl phosphate of 1.5wt%, 1.5wt%, the compound of the polyimide of the magnesium hydroxide of 1.8wt% and surplus.
By conventional double screw extrusion machine (L/D=35, Φ=45mm), the resin combination described in embodiment 1-2 and comparative example 1-2 is extruded into pellet.Utilize 10oz injection (mo(u)lding) machine, at 310 ℃, each resin granular material is shaped to specimen.Under 23 ℃ and 50% RH, expose after 48 hours, according to ASTM D648, under the pressure of 0.45MPa, measure heat modification temperature.Resin combination heat modification temperature described in embodiment 1-2 can reach 280 ~ 300 ℃, and resin combination heat modification temperature described in comparative example 1-2 is only 220 ~ 230 ℃.
In the present invention; for the ordinary skill in the art described; specific embodiment is just exemplarily described the present invention; obviously specific implementation of the present invention is not subject to the restrictions described above; as long as adopted the improvement of the various unsubstantialities that method of the present invention design and technical scheme carry out; or without improving, design of the present invention and technical scheme are directly applied to other occasion, all within protection scope of the present invention.