CN103568466A - Flame-retardant acid-alkali-resistant adhesive tape and manufacturing method thereof - Google Patents

Flame-retardant acid-alkali-resistant adhesive tape and manufacturing method thereof Download PDF

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Publication number
CN103568466A
CN103568466A CN201210272472.3A CN201210272472A CN103568466A CN 103568466 A CN103568466 A CN 103568466A CN 201210272472 A CN201210272472 A CN 201210272472A CN 103568466 A CN103568466 A CN 103568466A
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resistance
antiacid alkali
combustion
adhesive plaster
weight portions
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CN201210272472.3A
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Chinese (zh)
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宋国辉
徐正己
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FORMOSAN RUBBER GROUP INCORPORATE
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FORMOSAN RUBBER GROUP INCORPORATE
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Abstract

The fire-retardant acid-alkali resistant adhesive tape and the manufacturing method thereof comprise the following steps: firstly, providing a base cloth with two opposite surfaces, then forming a W paste layer on the two opposite surfaces of the base cloth, then attaching a flame-retardant acid-alkali-resistant mixed adhesive material to the W paste layer, and finally carrying out vulcanization treatment, wherein the flame-retardant acid-alkali-resistant mixed adhesive material comprises chloroprene rubber, ethylene propylene rubber, inorganic flame-retardant filler and inorganic filler, and can achieve the best physical properties and flame-retardant effect.

Description

The antiacid alkali adhesive plaster of resistance to combustion and manufacture method thereof
Technical field
The present invention relates to the antiacid alkali adhesive plaster of a kind of resistance to combustion and manufacture method, and particularly relate to the antiacid alkali adhesive plaster of a kind of resistance to combustion of using epoxy glue material and flame retardant to make and manufacture method.
Background technology
For a long time, macromolecular material is widely used in the people's livelihood, national defence and industrial, can say closely bound up, but macromolecule has a deadly defect, has exactly flammable or inflammability, so flame-retarded technology becomes an important topic in daily life with it.
The general easy material that causes fire, cloth products such as curtain, tablecloth, adhesive plaster or clothes must add some flame retardants, conventionally to reduce fire Probability in these cloth products.
In addition, industrial for chemical protection, be still an important problem, and acid, aqueous slkali account for great ratio for raw material synthetic, user is also usually to contact to this chemical raw material, but commercially available vest is mostly cloth material, and durable number of times is limited, and protection effect fails to bring into play maximum effect, if can use non-cloth material to replace, must promote chemical protection effect, increase durable number of times.
But this type of special clothing product not can take into account user's comfortableness mostly, and the weight of this type of special clothing product is extremely heavy, not only handicapped and consume one's strength after user dress.Moreover this type of clothing material does not have the feature of resistance to combustion, and not scratch resistance conventionally.
In view of this, inventor is according to being engaged in for many years manufacturing development and the design experiences of Related product, for above-mentioned target design in detail with discretion assessment after, finally obtain the present invention of a kind of true tool practicality.
Summary of the invention
Main purpose of the present invention be to provide a kind of can resistance to combustion and the adhesive plaster of antiacid alkali and preparation method thereof, contribute to promote the protection effect of vest.
According to a particular embodiment of the invention, first the manufacture method of the antiacid alkali adhesive plaster of described resistance to combustion comprises the following steps:, a base cloth is provided; Then, form a W and stick with paste layer on two relative surfaces of this base cloth; Subsequently, the epoxy glue material of the antiacid alkali of a resistance to combustion being fitted in to this W sticks with paste on layer; Finally, carry out vulcanizing treatment, wherein, the epoxy glue material of the antiacid alkali of this resistance to combustion includes neoprene, ethylene-propylene rubber, the inorganic filler of resistance to combustion and inorganic filler.
According to above-mentioned manufacture method, the antiacid alkali adhesive plaster of described resistance to combustion comprises that a base cloth, a W stick with paste the epoxy glue material of layer and the antiacid alkali of a resistance to combustion.Wherein, this W sticks with paste layer and is arranged on two relative surfaces of this base cloth, the epoxy glue material of the antiacid alkali of this resistance to combustion includes neoprene, ethylene-propylene rubber, the inorganic filler of resistance to combustion and inorganic filler, and the epoxy glue material of the antiacid alkali of this resistance to combustion is arranged on this W paste layer.
Through the above, the antiacid alkali adhesive plaster of resistance to combustion of the present invention is arranged in pairs or groups mutually with inorganic filler by adding the moderate inorganic filler of resistance to combustion, can reach preferably resistance to fuel efficiency fruit.Moreover the epoxy glue material of the antiacid alkali of described resistance to combustion is selected from the common mixing former of neoprene and EP rubbers institute as main glue kind, therefore the antiacid alkali adhesive plaster of described resistance to combustion has preferably anti-chemistry.In addition, the two-sided epoxy glue material that is all the antiacid alkali of resistance to combustion of base cloth, and thickness 0.3mm approximately only, the clothes of therefore making, except possessing above-mentioned advantage, also has portability, can not cause user's burden.
By specific embodiment, illustrate in detail below, enable the effect that is easier to understand object of the present invention, technology contents and wants to reach.
Accompanying drawing explanation
Fig. 1 is the process step figure of the manufacture method of the antiacid alkali adhesive plaster of resistance to combustion of the present invention; And
Fig. 2 is the cross sectional view of the antiacid alkali adhesive plaster of resistance to combustion of the present invention.
[main element symbol description]
The antiacid alkali adhesive plaster of 1 resistance to combustion
10 base cloths
20W sticks with paste layer
The epoxy glue material of the antiacid alkali of 30 resistance to combustion
The specific embodiment
Refer to Fig. 1 and 2, it shows the manufacture method of the antiacid alkali adhesive plaster 1 of resistance to combustion of the present invention, and first it comprise the following steps:, performs step S12, and a base cloth 10 is provided, and it has two relative surfaces.In this specific embodiment, described base cloth 10 is nylon base cloth (Nylon), yet according to different user demands, base cloth 10 also can select mylar, cotton, polyester/nylon spinning cloth or other different mixed yarns that form fiber to weave cotton cloth.
Then, execution step S14, forms a W and sticks with paste layer 20 on the surface of base cloth 10.Particularly, first base cloth 10 being sent into impregnation machine paper expects on two relative surfaces of base cloth 10, because sticking with paste layer 20, W is dissolved in the made thickener of toluene for neoprene, therefore needing afterwards the base cloth 10 that surface is formed with to W paste layer 20 inserts in baking oven, at the temperature between between 150 to 160 degree Celsius, the time of use between 90 to 160 seconds toasts, and the solvent that W is stuck with paste in layer 20 volatilizees completely.
In this specific embodiment, the constituent that W sticks with paste layer 20 comprises 80 to 100 weight portions (Parts per hundreds of rubber; The curing agent of the promoter of neoprene PHR), 5 to 16 weight portions and 3 to 10 weight portions, supplement mention be, PHR unit represents the percentage composition of additive in every hundred parts of rubber contents, and for example 20PHR represents the additive that adds 20gHuo kg unit in the rubber of every 100g Huokg unit.
Subsequently, execution step S16, fits in this W by the epoxy glue material 30 of the antiacid alkali of a resistance to combustion and sticks with paste on layer 20.Particularly, the constituent of the epoxy glue material 30 of the antiacid alkali of resistance to combustion comprises the neoprene of 40 to 60 weight portions, the ethylene-propylene rubber of 20 to 40 weight portions, the inorganic filler of resistance to combustion of 100 to 200 weight portions and the inorganic filler of 50 to 100 weight portions, and inorganic filler is aluminium hydroxide or antimony oxide.
Moreover, after the epoxy glue material 30 of the antiacid alkali of resistance to combustion is first mixing via 10,000 horsepowers of mixing rolls, at the temperature between 50 to 95 degree Celsius, with two rollers (a thick wheel and is wheel carefully), fully mix again, with conveyer belt, send into calendering make-up machine afterwards and be calendered to a fixed thickness and formed, wherein said fixed thickness is between 0.1 to 2.0 centimetre.And described in there is fixed thickness the epoxy glue material 30 of the antiacid alkali of combustion when doing two-sided laminating with base cloth 10, its temperature of crossing light laminating wheel is controlled between 60 to 95 degree Celsius.
Finally, execution step S18, the unvulcanized base cloth 10 that is fitted with the epoxy glue material 30 of the antiacid alkali of resistance to combustion is inserted to tank to be added in sulphur baking oven, at the temperature between between 140 to 150 degree Celsius, the time of use between 60 to 90 minutes has been heated sulfuration program rolling, finally in becoming inspection machine check outward appearance to be finished product.Sulfuration (Vulcanization) program refers to that rubber size passes through intermolecular cross-linking, generates the process of the vulcanizate with three-dimensional net structure, can make rubber size possess high strength, high resiliency, high abrasion, the good characteristic such as anticorrosive.
According to above-mentioned manufacture method, the present invention separately provides a kind of resistance to combustion antiacid alkali adhesive plaster 1, and it comprises that a base cloth 10, a W stick with paste the epoxy glue material 30 of the antiacid alkali of layer 20 and one resistance to combustion.Wherein, base cloth 10 has two relative surfaces, and W sticks with paste layer 20 and is arranged on two relative surfaces of base cloth 10, and the epoxy glue material 30 of the antiacid alkali of resistance to combustion is arranged on W paste layer 20.In addition, the antiacid alkali adhesive plaster 1 of described resistance to combustion after testing rear resistance to fuel efficiency fruit can pass through UL94V-0, and process experiment showed, that the immersion physical property of 72 hours, as following table 1, can promote the protection effect of vest on anti-chemical raw material.
Table 1
Figure BDA00001962656600051
In sum, the antiacid alkali adhesive plaster of resistance to combustion of the present invention is arranged in pairs or groups mutually with inorganic filler by adding the moderate inorganic filler of resistance to combustion, can reach preferably resistance to fuel efficiency fruit.Moreover the epoxy glue material of the antiacid alkali of described resistance to combustion is selected from the common mixing former of neoprene and EP rubbers institute as main glue kind, therefore the antiacid alkali adhesive plaster of described resistance to combustion has preferably anti-chemistry.In addition, the two-sided epoxy glue material that is all the antiacid alkali of resistance to combustion of base cloth, and thickness 0.3mm approximately only, the clothes of therefore making, except possessing above-mentioned advantage, also has portability, can not cause user's burden.

Claims (16)

1. the antiacid alkali adhesive plaster of resistance to combustion, is characterized in that, comprising:
One base cloth, it has two relative surfaces;
One W sticks with paste layer, and it is arranged on relative described two surfaces of described base cloth; And
The antiacid alkali epoxy glue of one resistance to combustion material, it includes neoprene and ethylene-propylene rubber, and the antiacid alkali epoxy glue of described resistance to combustion material is arranged on described W paste layer.
2. the antiacid alkali adhesive plaster of resistance to combustion according to claim 1, is characterized in that, the constituent that described W sticks with paste layer comprises:
(A) neoprene of 80 to 100 weight portions;
(B) promoter of 5 to 16 weight portions; And
(C) curing agent of 3 to 10 weight portions.
3. the antiacid alkali adhesive plaster of resistance to combustion according to claim 1, is characterized in that, the constituent of the antiacid alkali epoxy glue of described resistance to combustion material comprises:
(A) neoprene of 40 to 60 weight portions;
(B) ethylene-propylene rubber of 20 to 40 weight portions;
(C) the inorganic filler of resistance to combustion of 100 to 200 weight portions; And
(D) inorganic filler of 50 to 100 weight portions.
4. the antiacid alkali adhesive plaster of resistance to combustion according to claim 3, is characterized in that, described inorganic filler is aluminium hydroxide or antimony oxide.
5. the antiacid alkali adhesive plaster of resistance to combustion according to claim 1, is characterized in that, described base cloth is nylon base cloth.
6. a manufacture method for the antiacid alkali adhesive plaster of resistance to combustion, is characterized in that, comprises the following steps:
(A) provide a base cloth, it has two relative surfaces;
(B) on relative described two surfaces of described base cloth, form a W and stick with paste layer; And
(C) the antiacid alkali epoxy glue of resistance to combustion material is fitted in to described W and stick with paste layer above, wherein, the antiacid alkali epoxy glue of described resistance to combustion material includes neoprene and ethylene-propylene rubber.
7. the manufacture method of the antiacid alkali adhesive plaster of resistance to combustion according to claim 6, it is characterized in that, further comprising the steps of between described step (B) and described step (C): the described base cloth that is formed with described W paste layer on surface is inserted in baking oven, and the time between 90 to 160 seconds of using at the temperature between between 150 to 160 degree Celsius toasts.
8. the manufacture method of the antiacid alkali adhesive plaster of resistance to combustion according to claim 6, it is characterized in that, in described step (C), utilize a calendering make-up machine to fit at the temperature between between 60 to 95 degree Celsius described base cloth and the antiacid alkali epoxy glue of described resistance to combustion material.
9. the manufacture method of the antiacid alkali adhesive plaster of resistance to combustion according to claim 6, is characterized in that, the constituent that described W sticks with paste layer comprises:
(A) neoprene of 80 to 100 weight portions;
(B) promoter of 5 to 16 weight portions; And
(C) curing agent of 3 to 10 weight portions.
10. the manufacture method of the antiacid alkali adhesive plaster of resistance to combustion according to claim 6, is characterized in that, the constituent of the antiacid alkali epoxy glue of described resistance to combustion material comprises:
(A) neoprene of 40 to 60 weight portions;
(B) ethylene-propylene rubber of 20 to 40 weight portions;
(C) the inorganic filler of resistance to combustion of 100 to 200 weight portions; And
(D) inorganic filler of 50 to 100 weight portions.
The manufacture method of the antiacid alkali adhesive plaster of 11. resistance to combustion according to claim 10, is characterized in that, described inorganic filler is aluminium hydroxide or antimony oxide.
The manufacture method of the antiacid alkali adhesive plaster of 12. resistance to combustion according to claim 6, is characterized in that, described base cloth is nylon base cloth.
The manufacture method of the antiacid alkali adhesive plaster of 13. resistance to combustion according to claim 6, it is characterized in that, the antiacid alkali epoxy glue of described resistance to combustion material has a fixed thickness, and after the antiacid alkali epoxy glue of described resistance to combustion material first mixes by two rollers via ten thousand horsepowers of mixing rolls and at the temperature between 50 to 95 degree Celsius, then send into a calendering make-up machine and form.
The manufacture method of the antiacid alkali adhesive plaster of 14. resistance to combustion according to claim 13, is characterized in that, described fixed thickness is between 0.1 centimetre to 2.0 centimetres.
The manufacture method of the antiacid alkali adhesive plaster of 15. resistance to combustion according to claim 13, is characterized in that, described two rollers include carefully wheel of a thick wheel and.
The manufacture method of the antiacid alkali adhesive plaster of 16. resistance to combustion according to claim 6, it is characterized in that, in described step (C), also comprise afterwards a step (D): the described base cloth that is fitted with the antiacid alkali epoxy glue of described resistance to combustion material is inserted to tank and add in sulphur baking oven, the time between 60 to 90 minutes of using has been heated sulfuration at the temperature between between 140 to 150 degree Celsius.
CN201210272472.3A 2012-07-20 2012-08-01 Flame-retardant acid-alkali-resistant adhesive tape and manufacturing method thereof Pending CN103568466A (en)

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TW101126228A TW201404871A (en) 2012-07-20 2012-07-20 Flam and chemical-resistance rubber fabric and the manufacturing method thereof
TW101126228 2012-07-20

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59176351A (en) * 1983-03-25 1984-10-05 Sumitomo Chem Co Ltd Flame-retardant material
CN2576668Y (en) * 2002-10-28 2003-10-01 兖矿集团有限公司 Fire-retardant transport bent
JP2011197660A (en) * 2010-02-24 2011-10-06 Tokai Rubber Ind Ltd Endless belt for electrophotographic equipment
CN102275712A (en) * 2011-05-23 2011-12-14 兖矿集团有限公司 High-temperature resistant conveyer belt
CN102582169A (en) * 2011-12-14 2012-07-18 中国航空工业集团公司北京航空材料研究院 Preparation method for inflaming retarding ethylene propylene rubber tent cloth

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59176351A (en) * 1983-03-25 1984-10-05 Sumitomo Chem Co Ltd Flame-retardant material
CN2576668Y (en) * 2002-10-28 2003-10-01 兖矿集团有限公司 Fire-retardant transport bent
JP2011197660A (en) * 2010-02-24 2011-10-06 Tokai Rubber Ind Ltd Endless belt for electrophotographic equipment
CN102275712A (en) * 2011-05-23 2011-12-14 兖矿集团有限公司 High-temperature resistant conveyer belt
CN102582169A (en) * 2011-12-14 2012-07-18 中国航空工业集团公司北京航空材料研究院 Preparation method for inflaming retarding ethylene propylene rubber tent cloth

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Application publication date: 20140212