CN103556788A - Self-adhesive waterproof roll and manufacturing and using method thereof - Google Patents
Self-adhesive waterproof roll and manufacturing and using method thereof Download PDFInfo
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- CN103556788A CN103556788A CN201310345279.2A CN201310345279A CN103556788A CN 103556788 A CN103556788 A CN 103556788A CN 201310345279 A CN201310345279 A CN 201310345279A CN 103556788 A CN103556788 A CN 103556788A
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Abstract
Disclosed are a self-adhesive waterproof roll and a manufacturing and using method thereof. The invention discloses a self-adhesive waterproof roll. The self-adhesive waterproof roll is composed of a first insulating layer, a first adhesive sealing layer, a nonwoven layer, a waterproof layer, a polyurethane fabric base layer, a waterproof layer, a nonwoven fabric layer, a second adhesive sealing layer, and a second insulating layer which are sequentially arranged in the thickness direction of the self-adhesive waterproof roll in a combination mode. The self-adhesive waterproof roll which is composed of the first adhesive sealing layer, the second adhesive sealing layer, the first insulating layer, the second insulating layer, the nonwoven layers, the waterproof layers and the polyurethane fabric base layer in a combination mode can be used at the construction site without the base first coat, heated baked coating or adhesive bonding; has high strength, large elongation, aging resistance, corrosion resistance, puncture resistance, cold construction available, no solvent evaporation, safety, environment friendliness, no fire hazard and convenient construction, can be bonded in moisture environment or in water, saves the construction period, is further improved in waterproof effects as well as is applicable to double-sided waterproofing.
Description
Technical field
The present invention relates to civil works field, be specifically related to a kind of adhesive waterproof coil and its preparation method and using method.
Background technology
Adhesive waterproof coil has been widely used in the waterproofings such as industry and the roofing of civil building, basement, indoor, municipal engineering and reservoir, swimming pool and subway tunnel.It is that the self-adhesive rubber asphalt that the synthetic rubber such as a kind of SBS of take, tackifier and high-quality pavement petroleum asphalt etc. are mixed with is base-material, tough density polyethylene film with high or aluminium foil are as top surface, and strippable painting silicon barrier film or painting silicon barrier paper are the waterproofing materials that the antiseized isolated material of soffit is made.Be a kind of waterproof material that has development prospect, have the advantages that low temperature flexibility, self-healing property and adhesive property are good, can normal temperature construction, speed of application fast, meet environmental requirement.
At present, the adhesive waterproof coil manufacturing of a great variety, the Chinese patent literature that is called " wet coating self-adhering waterproof coiled material and production method thereof and job practices " (publication number CN1788350A) as name is recorded the following technical scheme in road: a kind of wet coating self-adhering waterproof coiled material and production method thereof and job practices, by butyl rubber, High Quality Oxidized Asphalt is through high-temperature mixing, add acrylic absorbent resin, process oil, filler, stop-off gent, through high speed dispersion, make self bonding waterproof sealing material, dip-coating is on macromolecule water-proof sheet material carrier one side, through calendering, extrude, paving separation layer is as adherent layer, and flexible protective layer is pasted to macromolecule water-proof sheet material carrier another side, putting on suspender belt makes again.Although the disclosed adhesive waterproof coil of this patent documentation is at the construction field (site) without basic unit's primary coat, do not need to heat roasting painting, also without binding agent, bond, and intensity is high, elongation per unit length is large, ageing-resistant, corrosion-resistant, anti-puncture, cold construction, solvent-free volatilization, safety and environmental protection, without hidden fire-fighting danger, construct convenient, can wet environment or water in bond, save the duration.But its waterproof effect also needs further to promote, to obtain better waterproof effect and construction quality.In addition, in above-mentioned patent documentation, provide adhesive waterproof coil to be also only applicable to one side and paste waterproof.
Summary of the invention
It has better waterproof effect and ageing-resistant, corrosion-resistant, anti-puncture, cold construction, safety and environmental protection to the object of the present invention is to provide a kind of adhesive waterproof coil, applicable to double faced adhesive waterproof.
For achieving the above object, the present invention is by the following technical solutions: a kind of adhesive waterproof coil, it is characterized in that: the thickness direction along adhesive waterproof coil is followed successively by the first separation layer, first layer that is bonded and sealed, nonwoven layer, waterproofing course, polyurethane-base layer of cloth, waterproofing course, nonwoven layer, second layer that is bonded and sealed, the second separation layer, wherein first be bonded and sealed layer by the oxidized asphalts of 30～35 weight portions, the butyl rubber of 16～17 weight portions, the ethylene-vinyl acetate copolymer of 1.5～2.0 weight portions, the tackifier of 17～19 weight portions, the age resistor of 0.5～0.6 weight portion, the coupling agent of 0.2～0.4 weight portion, the carbon black of 14～15 weight portions forms, second be bonded and sealed layer by the oxidized asphalt of 25～40 weight portions, the butadiene-styrene rubber of the butyl rubber of 1～5 weight portion, 8～10 weight portions, the vulcanizing agent of the polyisobutene of 5～8 weight portions, 0.5～0.6 weight portion, the inorganic additives of the initator of 0.2～0.4 weight portion, 1～1.5 weight portion form, waterproofing course 14 is polyvinyl chloride, vinyl acetate, oxidized asphalt mixing formation.
Further scheme is: tackifier are that terpene resin, age resistor are that N-phenyl-α-aniline, coupling agent are that titanate esters, vulcanizing agent are that urethanes, initator are that sulfonic acid, inorganic additives are zinc chloride.
First and second separation layer is respectively silicone oil paper or polyester insulating film.
By repetition test and continuing to optimize, preferably according to following two kinds of concrete operations, as preferred version, implement realizing the present invention on the basis of the object of the invention:
The first prioritization scheme is: in adhesive waterproof coil first be bonded and sealed layer by the oxidized asphalt of 30 weight portions, the ethylene-vinyl acetate copolymer of the butyl rubber of 17 weight portions, 2.0 weight portions, the N-phenyl-α-aniline of the terpene resin of 19 weight portions, 0.6 weight portion, the carbon black of the titanate esters of 0.2 weight portion, 15 weight portions form; Second be bonded and sealed layer by the oxidized asphalt of 25 weight portions, the butadiene-styrene rubber of the butyl rubber of 1 weight portion, 10 weight portions, the urethanes of the polyisobutene of 8 weight portions, 0.6 weight portion, the zinc chloride of the sulfonic acid of 0.2 weight portion, 1 weight portion form.
The second prioritization scheme is: in adhesive waterproof coil wherein first be bonded and sealed layer by the oxidized asphalt of 35 weight portions, the ethylene-vinyl acetate copolymer of the butyl rubber of 16 weight portions, 1.5 weight portions, the N-phenyl-α-aniline of the terpene resin of 17 weight portions, 0.5 weight portion, the carbon black of the titanate esters of 0.4 weight portion, 14 weight portions form; Second be bonded and sealed layer by the oxidized asphalt of 40 weight portions, the butadiene-styrene rubber of the butyl rubber of 5 weight portions, 8 weight portions, the urethanes of the polyisobutene of 5 weight portions, 0.5 weight portion, the zinc chloride of the sulfonic acid of 0.4 weight portion, 1.5 weight portions form.
Preparation method of the present invention is: lay polyurethane-base layer of cloth, the material that forms waterproofing course is mixed in polyurethane-base layer of cloth one side and lays waterproofing course, after laying waterproofing course, on waterproofing course, lay again nonwoven layer, and lay first layer that is bonded and sealed in nonwoven layer, first is bonded and sealed lays first separation layer after layer is laid, after the first separation layer is laid, by laying be successively bonded and sealed layer, the first separation layer of waterproofing course, nonwoven layer, second at polyurethane-base layer of cloth opposite side again after the upset of polyurethane-base layer of cloth, can make this adhesive waterproof coil.
Production method of the present invention is: one or two in first and second separation layer thrown off, then the adhesive waterproof coil of throwing off separation layer is pasted.
First and second formation by above-mentioned particular components adhesive waterproof coil that layer and first and second separation layer, nonwoven layer, waterproofing course, polyurethane-base layer of cloth constitute that is bonded and sealed, it can be at the construction field (site) without basic unit's primary coat, do not need to heat roasting painting, also without binding agent, bond, and intensity is high, elongation per unit length is large, ageing-resistant, corrosion-resistant, anti-puncture, cold construction, solvent-free volatilization, safety and environmental protection, without hidden fire-fighting danger, construct convenient, can wet environment or water in bond, save the duration.And waterproof effect is further promoted, and can be used for double-faced waterproofing engineering.
accompanying drawing explanation
Fig. 1 is adhesive waterproof coil structural representation.
the specific embodiment
By specific embodiment, come below that the present invention is further illustrated, but it should not be construed as limitation of the present invention.Wherein in embodiment 1～3, waterproofing course can be called according to name the macromolecule water-proof sheet material scheme of recording in the patent documentation of " wet coating self-adhering waterproof coiled material and production method thereof and job practices " publication number CN1788350A and implements, that is waterproofing course is that polyvinyl chloride, vinyl acetate, oxidized asphalt mix and form.
Embodiment 1
Lay polyurethane-base layer of cloth 15, the material that forms waterproofing course 14 is mixed in polyurethane-base layer of cloth 15 1 sides and lays waterproofing course 14, after laying waterproofing course 14, on waterproofing course 14, lay again nonwoven layer 13, and in nonwoven layer 13, lay first be bonded and sealed layer 12 oxidized asphalt by 30 weight portions, the butyl rubber of 17 weight portions, the terpene resin of the ethylene-vinyl acetate copolymer of 2.0 weight portions, 19 weight portions, the titanate esters of the N-phenyl-α-aniline of 0.6 weight portion, 0.2 weight portion, the carbon black of 15 weight portions of layer 12, the first that are bonded and sealed and form; First is bonded and sealed lays a silicone oil paper after layer 12 is laid, after silicone oil paper is laid, by laying be successively bonded and sealed layer 16, polyester insulating film of waterproofing course 14, nonwoven layer 13, second at polyurethane-base layer of cloth 15 opposite sides again after 15 upsets of polyurethane-base layer of cloth, can make this adhesive waterproof coil.Wherein, second be bonded and sealed layer 16 oxidized asphalts by 25 weight portions, the butyl rubber of 1 weight portion, the polyisobutene of the butadiene-styrene rubber of 10 weight portions, 8 weight portions, the sulfonic acid of the urethanes of 0.6 weight portion, 0.2 weight portion, the zinc chloride of 1 weight portion form.
During operation, one or two in first and second separation layer 11,17 thrown off, then the adhesive waterproof coil of throwing off separation layer is pasted.
Embodiment 2
Lay polyurethane-base layer of cloth 15, the material that forms waterproofing course 14 is mixed in polyurethane-base layer of cloth 15 1 sides and lays waterproofing course 14, after laying waterproofing course 14, on waterproofing course 14, lay again nonwoven layer 13, and lay first layer 12 that is bonded and sealed in nonwoven layer 13, wherein, first be bonded and sealed layer 12 oxidized asphalts by 35 weight portions, the butyl rubber of 16 weight portions, the terpene resin of the ethylene-vinyl acetate copolymer of 1.5 weight portions, 17 weight portions, the titanate esters of the N-phenyl-α-aniline of 0.5 weight portion, 0.4 weight portion, the carbon black of 14 weight portions form; First is bonded and sealed lays a silicone oil paper after layer 12 is laid, after silicone oil paper is laid, by laying be successively bonded and sealed layer 16, polyester insulating film of waterproofing course 14, nonwoven layer 13, second at polyurethane-base layer of cloth 15 opposite sides again after 15 upsets of polyurethane-base layer of cloth, can make this adhesive waterproof coil.Wherein, second be bonded and sealed layer 16 oxidized asphalts by 40 weight portions, the butyl rubber of 5 weight portions, the polyisobutene of the butadiene-styrene rubber of 8 weight portions, 5 weight portions, the sulfonic acid of the urethanes of 0.5 weight portion, 0.4 weight portion, the zinc chloride of 1.5 weight portions form.
During operation, one or two in first and second separation layer 11,17 thrown off, then the adhesive waterproof coil of throwing off separation layer is pasted.
Embodiment 3
Lay polyurethane-base layer of cloth 15, the material that forms waterproofing course 14 is mixed in polyurethane-base layer of cloth 15 1 sides and lays waterproofing course 14, after laying waterproofing course 14, on waterproofing course 14, lay again nonwoven layer 13, and lay first layer 12 that is bonded and sealed in nonwoven layer 13, wherein, first be bonded and sealed layer 12 oxidized asphalts by 32 weight portions, the butyl rubber of 16 weight portions, the terpene resin of the ethylene-vinyl acetate copolymer of 1.8 weight portions, 17 weight portions, the titanate esters of the N-phenyl-α-aniline of 0.5 weight portion, 0.3 weight portion, the carbon black of 15 weight portions form; First is bonded and sealed lays a polyester insulating film after layer 12 is laid, after polyester insulating film is laid, by laying be successively bonded and sealed layer 16, polyester insulating film of waterproofing course 14, nonwoven layer 13, second at polyurethane-base layer of cloth 15 opposite sides again after 15 upsets of polyurethane-base layer of cloth, can make this adhesive waterproof coil.Wherein, second be bonded and sealed layer 16 oxidized asphalts by 30 weight portions, the butyl rubber of 3 weight portions, the polyisobutene of the butadiene-styrene rubber of 9 weight portions, 7 weight portions, the sulfonic acid of the urethanes of 0.5 weight portion, 0.3 weight portion, the zinc chloride of 1.2 weight portions form.
During operation, one or two in first and second separation layer 11,17 thrown off, then the adhesive waterproof coil of throwing off separation layer is pasted.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (7)
1. an adhesive waterproof coil, it is characterized in that: the thickness direction along adhesive waterproof coil is followed successively by the first separation layer (11), first be bonded and sealed layer (12), nonwoven layer (13), waterproofing course (14), polyurethane-base layer of cloth (15), waterproofing course (14), nonwoven layer (13), second be bonded and sealed layer (16), the second separation layer (17), wherein first be bonded and sealed layer (12) by oxidized asphalts of 30～35 weight portions, the butyl rubber of 16～17 weight portions, the ethylene-vinyl acetate copolymer of 1.5～2.0 weight portions, the tackifier of 17～19 weight portions, the age resistor of 0.5～0.6 weight portion, the coupling agent of 0.2～0.4 weight portion, the carbon black of 14～15 weight portions forms, second be bonded and sealed layer (16) by the oxidized asphalt of 25～40 weight portions, the butadiene-styrene rubber of the butyl rubber of 1～5 weight portion, 8～10 weight portions, the vulcanizing agent of the polyisobutene of 5～8 weight portions, 0.5～0.6 weight portion, the inorganic additives of the initator of 0.2～0.4 weight portion, 1～1.5 weight portion form, waterproofing course (14) is polyvinyl chloride, vinyl acetate, oxidized asphalt mixing formation.
2. adhesive waterproof coil as claimed in claim 1, is characterized in that: tackifier are that terpene resin, age resistor are that N-phenyl-α-aniline, coupling agent are that titanate esters, vulcanizing agent are that urethanes, initator are that sulfonic acid, inorganic additives are zinc chloride.
3. adhesive waterproof coil as claimed in claim 2, is characterized in that: first and second separation layer is respectively silicone oil paper or polyester insulating film.
4. adhesive waterproof coil as claimed in claim 2, is characterized in that: wherein first be bonded and sealed layer (12) by the oxidized asphalt of 30 weight portions, the ethylene-vinyl acetate copolymer of the butyl rubber of 17 weight portions, 2.0 weight portions, the N-phenyl-α-aniline of the terpene resin of 19 weight portions, 0.6 weight portion, the carbon black of the titanate esters of 0.2 weight portion, 15 weight portions form; Second be bonded and sealed layer (16) by the oxidized asphalt of 25 weight portions, the butadiene-styrene rubber of the butyl rubber of 1 weight portion, 10 weight portions, the urethanes of the polyisobutene of 8 weight portions, 0.6 weight portion, the zinc chloride of the sulfonic acid of 0.2 weight portion, 1 weight portion form.
5. adhesive waterproof coil as claimed in claim 2, is characterized in that: wherein first be bonded and sealed layer (12) by the oxidized asphalt of 35 weight portions, the ethylene-vinyl acetate copolymer of the butyl rubber of 16 weight portions, 1.5 weight portions, the N-phenyl-α-aniline of the terpene resin of 17 weight portions, 0.5 weight portion, the carbon black of the titanate esters of 0.4 weight portion, 14 weight portions form; Second be bonded and sealed layer (16) by the oxidized asphalt of 40 weight portions, the butadiene-styrene rubber of the butyl rubber of 5 weight portions, 8 weight portions, the urethanes of the polyisobutene of 5 weight portions, 0.5 weight portion, the zinc chloride of the sulfonic acid of 0.4 weight portion, 1.5 weight portions form.
6. the preparation method of an adhesive waterproof coil as claimed in claim 1, it is operating as: lay polyurethane-base layer of cloth (15), the material that forms waterproofing course (14) is mixed in polyurethane-base layer of cloth (15) one sides and lays waterproofing course (14), after laying waterproofing course (14), at waterproofing course (14), above lay nonwoven layer (13) again, and nonwoven layer (13) lay first be bonded and sealed layer (12), first is bonded and sealed lays first separation layer (11) after layer (12) is laid, after the first separation layer (11) is laid, to after polyurethane-base layer of cloth (15) upset, at polyurethane-base layer of cloth (15) opposite side, lay successively waterproofing course (14) again, nonwoven layer (13), second be bonded and sealed layer (16), the second separation layer (17) can make this adhesive waterproof coil.
7. a using method for adhesive waterproof coil as claimed in claim 1, it is operating as: one or two in first and second separation layer (11,17) thrown off, then the adhesive waterproof coil of throwing off separation layer is pasted.
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| CN201310345279.2A CN103556788B (en) | 2013-08-09 | 2013-08-09 | A kind of adhesive waterproof coil and its preparation method and using method |
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| CN201310345279.2A CN103556788B (en) | 2013-08-09 | 2013-08-09 | A kind of adhesive waterproof coil and its preparation method and using method |
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| CN103556788A true CN103556788A (en) | 2014-02-05 |
| CN103556788B CN103556788B (en) | 2016-05-11 |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104191754A (en) * | 2014-07-15 | 2014-12-10 | 王春义 | EVA coating root-resistant material |
| CN104354425A (en) * | 2014-11-14 | 2015-02-18 | 无锡英普林纳米科技有限公司 | High-strength nanometer press film |
| CN104987607A (en) * | 2015-06-30 | 2015-10-21 | 南阳理工学院 | Corrosion-resistant and waterproof material |
| CN105273224A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | Titanate waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
| CN105694491A (en) * | 2016-02-04 | 2016-06-22 | 广西青龙化学建材有限公司 | High-viscosity self-adhesion elastomer modified asphalt and waterproof roll |
| CN110804401A (en) * | 2019-11-14 | 2020-02-18 | 湖南古圣砖瓦科技有限公司 | Self-adhesive waterproof coiled material |
| CN111269668A (en) * | 2020-03-27 | 2020-06-12 | 山东双圆密封科技有限公司 | Exposed flexible flashing sealing repairing adhesive tape and preparation method thereof |
| CN113215833A (en) * | 2021-06-18 | 2021-08-06 | 汪晓东 | Moisture-keeping antirust oil sealing tape |
| CN114634774A (en) * | 2022-02-25 | 2022-06-17 | 湖北华宇防水材料科技股份有限公司 | Preparation method of butyl rubber polymer self-adhesive waterproof roll |
| CN116731626A (en) * | 2023-06-06 | 2023-09-12 | 河北宇阳泽丽防水材料有限公司 | High-strength stainless steel waterproof coiled material and preparation method thereof |
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Cited By (12)
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| CN105273224A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | Titanate waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
| CN104191754A (en) * | 2014-07-15 | 2014-12-10 | 王春义 | EVA coating root-resistant material |
| CN104354425A (en) * | 2014-11-14 | 2015-02-18 | 无锡英普林纳米科技有限公司 | High-strength nanometer press film |
| CN104987607A (en) * | 2015-06-30 | 2015-10-21 | 南阳理工学院 | Corrosion-resistant and waterproof material |
| CN105694491A (en) * | 2016-02-04 | 2016-06-22 | 广西青龙化学建材有限公司 | High-viscosity self-adhesion elastomer modified asphalt and waterproof roll |
| CN110804401A (en) * | 2019-11-14 | 2020-02-18 | 湖南古圣砖瓦科技有限公司 | Self-adhesive waterproof coiled material |
| CN111269668A (en) * | 2020-03-27 | 2020-06-12 | 山东双圆密封科技有限公司 | Exposed flexible flashing sealing repairing adhesive tape and preparation method thereof |
| CN111269668B (en) * | 2020-03-27 | 2021-01-26 | 山东双圆密封科技有限公司 | Exposed flexible flashing sealing repairing adhesive tape and preparation method thereof |
| CN113215833A (en) * | 2021-06-18 | 2021-08-06 | 汪晓东 | Moisture-keeping antirust oil sealing tape |
| CN114634774A (en) * | 2022-02-25 | 2022-06-17 | 湖北华宇防水材料科技股份有限公司 | Preparation method of butyl rubber polymer self-adhesive waterproof roll |
| CN116731626A (en) * | 2023-06-06 | 2023-09-12 | 河北宇阳泽丽防水材料有限公司 | High-strength stainless steel waterproof coiled material and preparation method thereof |
| CN116731626B (en) * | 2023-06-06 | 2023-11-14 | 河北宇阳泽丽防水材料有限公司 | High-strength stainless steel waterproof coiled material and preparation method thereof |
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