CN103555996B - A kind of method preparing Copper Alloy Valve - Google Patents

A kind of method preparing Copper Alloy Valve Download PDF

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CN103555996B
CN103555996B CN201310536953.5A CN201310536953A CN103555996B CN 103555996 B CN103555996 B CN 103555996B CN 201310536953 A CN201310536953 A CN 201310536953A CN 103555996 B CN103555996 B CN 103555996B
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copper alloy
temperature
valve
copper
rate
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CN103555996A (en
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李茜
王文姣
邢桂生
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Haining Economic Development Industrial Park Development and Construction Co., Ltd
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XINCHANG COUNTY DONGMING TOWNSHIP DECHUANG MACHINERY PLANT
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Abstract

The invention discloses a kind of method preparing Copper Alloy Valve, it is characterized in that, the weight percent of alloy composition is: Ni18-20%, Zn3-4%, Mg8-9%, Sn0.03-0.04%, Sb0.07-0.08%, Ca0.05-0.06%, Bi0.03-0.04%, Ti0.01-0.02%, Mn0.03-0.04%, Y0.02-0.03%, Mo0.05-0.06%, surplus is copper and inevitable nonmetal inclusion, by adopting precision casting and blasting technology, improve the compactness of valve body, simplify technique, improve production efficiency, reduce production cost.

Description

A kind of method preparing Copper Alloy Valve
Technical field
The present invention relates to a kind of method preparing Copper Alloy Valve, belong to copper base alloy and manufacture field.
Background technology
Corronel is owing to having good mechanical property, wear resistance, solidity to corrosion etc., thus obtain in valve body manufacture field and use widely, but in view of the hot workability that corronel is poor, the forming mode of corronel bar is mainly cast, but it is many to there is subsurface defect in the corronel of casting, compactness is poor, and life-time service easily occurs the problems such as seepage, and this makes the reliability, yield rate, work-ing life, material use efficiency etc. of casting corronel all be restricted; And prior art prepare corronel need through press working repeatedly, homogenizing annealing, and its complete processing is complicated, causes existing corronel cost higher.
Summary of the invention
The object of this invention is to provide a kind ofly solve that prior art casting corronel valve inner defect is many, the poor problem of compactness, Simplified flowsheet, production cost of enhancing productivity, reduce the production technique of making Copper Alloy Valve.
The invention discloses a kind of preparation method of precision casting Copper Alloy Valve for achieving the above object, it is characterized in that, the weight percent of alloy composition is: Ni18-20%, Zn3-4%, Mg8-9%, Sn0.03-0.04%, Sb0.07-0.08%, Ca0.05-0.06%, Bi0.03-0.04%, Ti0.01-0.02%, Mn0.03-0.04%, Y0.02-0.03%, Mo0.05-0.06%, surplus is copper and inevitable nonmetal inclusion
The preparation method of institute's Copper Alloy Valve, comprises the following steps: require to prepare burden according to above-mentioned copper alloy chemical composition; First add fine copper ingot, nickel zinc alloy is added after the fusing of fine copper ingot, add magnesium again, finally add containing other alloying elements, smelting temperature is 1380-1390 DEG C, cast: pouring temperature is 1360-1370 DEG C, after carry out the demoulding, the Copper Alloy Valve obtained is incubated 120-150 minute at 860-880 DEG C, then carries out quench treatment in this temperature; Rate of cooling is for being greater than 30 DEG C/sec; Afterwards Copper Alloy Valve is heated to 360-380 DEG C of insulation 12-14 hour; Drop to 310-330 DEG C with 2 DEG C/min of rate of temperature fall afterwards, insulation 8-9 hour, after drop to 270-280 DEG C with 1 DEG C/min of rate of temperature fall, insulation 4-6 hour, after drop to 210-230 DEG C with 1 DEG C/min of rate of temperature fall again, insulation 5-6 hour, air cooling to room temperature,
The loading stage after thermal treatment, described valve body being placed on blaster carries out shot peening; Loading stage at the uniform velocity rotates with the rotating speed of 6rad/min; The jet angle of shot-peening constantly changes between 40-70 °; Spraying pressure is 0.2MPa; The particle diameter of aluminium alloy bullet is 0.1mm; The shot-peening time is 90 minutes, obtains final valve body, and described aluminium alloy bullet alloying element consists of: Zn12-13%, Cu5-6%, Ti4-5%, Mg1-2%, Mn0.01-0.02%, and surplus is aluminium and inevitable nonmetal inclusion.
As preferably, chemical component weight per-cent is: Ni19%, Zn3.5%, Mg8.5%, Sn0.035%, Sb0.075%, Ca0.055%, Bi0.035%, Ti0.015%, Mn0.035%, Y0.025%, Mo0.055%, and surplus is copper and inevitable nonmetal inclusion.
As preferably, chemical component weight per-cent is: Ni18%, Zn3%, Mg8%, Sn0.03%, Sb0.07%, Ca0.05%, Bi0.03%, Ti0.01%, Mn0.03%, Y0.02%, Mo0.05%, and surplus is copper and inevitable nonmetal inclusion.
As preferably, chemical component weight per-cent is: Ni20%, Zn4%, Mg9%, Sn0.04%, Sb0.08%, Ca0.06%, Bi0.04%, Ti0.02%, Mn0.04%, Y0.03%, Mo0.06%, and surplus is copper and inevitable nonmetal inclusion.
As preferably, smelting temperature is 1385 DEG C, and pouring temperature is 1365 DEG C.
As preferably, chemical component weight per-cent is: Copper Alloy Valve was 370 DEG C of insulations 13 hours; After drop to 320 DEG C with 2 DEG C/min of rate of temperature fall, be incubated 8 hours, after drop to 275 DEG C with 1 DEG C/min of rate of temperature fall, be incubated 5 hours, after drop to 220 DEG C with 1 DEG C/min of rate of temperature fall again, be incubated 5 hours, air cooling is to room temperature.
As preferably, described aluminium alloy bullet alloying element consists of: Zn12.5%, Cu5.5%, Ti4.5%, Mg1.5%, Mn0.015%, and surplus is aluminium and inevitable nonmetal inclusion.
The invention has the beneficial effects as follows:
Precision casting Copper Alloy Valve of the present invention requires mould and the technique of design according to finished product, refinement crystal grain, decrease corronel subsurface defect, improve the ductility of corronel, improve the compactness of Copper Alloy Valve, simplify technique, improve production efficiency, reduce production cost.
Embodiment
Embodiment 1:
A kind of preparation method of precision casting Copper Alloy Valve is provided, it is characterized in that, the weight percent of alloy composition is: Ni18%, Zn3%, Mg8%, Sn0.03%, Sb0.07%, Ca0.05%, Bi0.03%, Ti0.01%, Mn0.03%, Y0.02%, Mo0.05%, surplus is copper and inevitable nonmetal inclusion
The preparation method of institute's Copper Alloy Valve, comprises the following steps: require to prepare burden according to above-mentioned copper alloy chemical composition; First add fine copper ingot, nickel zinc alloy is added after the fusing of fine copper ingot, add magnesium again, finally add containing other alloying elements, smelting temperature is 1380 DEG C, cast: pouring temperature is 1360 DEG C, after carry out the demoulding, the Copper Alloy Valve obtained is incubated 120 minutes at 860 DEG C, then carries out quench treatment in this temperature; Rate of cooling is for being greater than 30 DEG C/sec; Afterwards Copper Alloy Valve is heated to 360 DEG C of insulations 12 hours; Drop to 310 DEG C with 2 DEG C/min of rate of temperature fall afterwards, be incubated 8 hours, after drop to 270 DEG C with 1 DEG C/min of rate of temperature fall, be incubated 4 hours, after drop to 210 DEG C with 1 DEG C/min of rate of temperature fall again, be incubated 5 hours, air cooling to room temperature,
The loading stage after thermal treatment, described valve body being placed on blaster carries out shot peening; Loading stage at the uniform velocity rotates with the rotating speed of 6rad/min; The jet angle of shot-peening constantly changes between 40-70 °; Spraying pressure is 0.2MPa; The particle diameter of aluminium alloy bullet is 0.1mm; The shot-peening time is 90 minutes, obtains final valve body, and described aluminium alloy bullet alloying element consists of: Zn12%, Cu5%, Ti4%, Mg1%, Mn0.01%, and surplus is aluminium and inevitable nonmetal inclusion.
Embodiment 2:
A kind of preparation method of precision casting Copper Alloy Valve is provided, it is characterized in that, the weight percent of alloy composition is: Ni20%, Zn4%, Mg9%, Sn0.04%, Sb0.08%, Ca0.06%, Bi0.04%, Ti0.02%, Mn0.04%, Y0.03%, Mo0.06%, surplus is copper and inevitable nonmetal inclusion
The preparation method of institute's Copper Alloy Valve, comprises the following steps: require to prepare burden according to above-mentioned copper alloy chemical composition; First add fine copper ingot, nickel zinc alloy is added after the fusing of fine copper ingot, add magnesium again, finally add containing other alloying elements, smelting temperature is 1390 DEG C, cast: pouring temperature is 1370 DEG C, after carry out the demoulding, the Copper Alloy Valve obtained is incubated 150 minutes at 880 DEG C, then carries out quench treatment in this temperature; Rate of cooling is for being greater than 30 DEG C/sec; Afterwards Copper Alloy Valve is heated to 380 DEG C of insulations 14 hours; Drop to 330 DEG C with 2 DEG C/min of rate of temperature fall afterwards, be incubated 9 hours, after drop to 280 DEG C with 1 DEG C/min of rate of temperature fall, be incubated 6 hours, after drop to 230 DEG C with 1 DEG C/min of rate of temperature fall again, be incubated 6 hours, air cooling to room temperature,
The loading stage after thermal treatment, described valve body being placed on blaster carries out shot peening; Loading stage at the uniform velocity rotates with the rotating speed of 6rad/min; The jet angle of shot-peening constantly changes between 40-70 °; Spraying pressure is 0.2MPa; The particle diameter of aluminium alloy bullet is 0.1mm; The shot-peening time is 90 minutes, obtains final valve body, and described aluminium alloy bullet alloying element consists of: Zn13%, Cu6%, Ti5%, Mg2%, Mn0.02%, and surplus is aluminium and inevitable nonmetal inclusion.
Embodiment 3:
A kind of preparation method of precision casting Copper Alloy Valve is provided, it is characterized in that, the weight percent of alloy composition is: Ni19%, Zn3.5%, Mg8.5%, Sn0.035%, Sb0.075%, Ca0.055%, Bi0.035%, Ti0.015%, Mn0.035%, Y0.025%, Mo0.055%, surplus is copper and inevitable nonmetal inclusion
The preparation method of institute's Copper Alloy Valve, comprises the following steps: require to prepare burden according to above-mentioned copper alloy chemical composition; First add fine copper ingot, nickel zinc alloy is added after the fusing of fine copper ingot, add magnesium again, finally add containing other alloying elements, smelting temperature is 1385 DEG C, cast: pouring temperature is 1365 DEG C, after carry out the demoulding, the Copper Alloy Valve obtained is incubated 130 minutes at 870 DEG C, then carries out quench treatment in this temperature; Rate of cooling is for being greater than 30 DEG C/sec; Afterwards Copper Alloy Valve is heated to 370 DEG C of insulations 13 hours; Drop to 320 DEG C with 2 DEG C/min of rate of temperature fall afterwards, be incubated 8.5 hours, after drop to 275 DEG C with 1 DEG C/min of rate of temperature fall, be incubated 5 hours, after drop to 220 DEG C with 1 DEG C/min of rate of temperature fall again, be incubated 5.5 hours, air cooling to room temperature,
The loading stage after thermal treatment, described valve body being placed on blaster carries out shot peening; Loading stage at the uniform velocity rotates with the rotating speed of 6rad/min; The jet angle of shot-peening constantly changes between 40-70 °; Spraying pressure is 0.2MPa; The particle diameter of aluminium alloy bullet is 0.1mm; The shot-peening time is 90 minutes, obtains final valve body, and described aluminium alloy bullet alloying element consists of: Zn12.5%, Cu5.5%, Ti4.5%, Mg1.5%, Mn0.015%, and surplus is aluminium and inevitable nonmetal inclusion.
Embodiment 4:
A kind of preparation method of precision casting Copper Alloy Valve is provided, it is characterized in that, the weight percent of alloy composition is: Ni18.5%, Zn3.2%, Mg8.2%, Sn0.032%, Sb0.072%, Ca0.052%, Bi0.032%, Ti0.012%, Mn0.032%, Y0.022%, Mo0.052%, surplus is copper and inevitable nonmetal inclusion
The preparation method of institute's Copper Alloy Valve, comprises the following steps: require to prepare burden according to above-mentioned copper alloy chemical composition; First add fine copper ingot, nickel zinc alloy is added after the fusing of fine copper ingot, add magnesium again, finally add containing other alloying elements, smelting temperature is 1382 DEG C, cast: pouring temperature is 1362 DEG C, after carry out the demoulding, the Copper Alloy Valve obtained is incubated 120 minutes at 860 DEG C, then carries out quench treatment in this temperature; Rate of cooling is for being greater than 30 DEG C/sec; Afterwards Copper Alloy Valve is heated to 360 DEG C of insulations 12 hours; Drop to 310 DEG C with 2 DEG C/min of rate of temperature fall afterwards, be incubated 8 hours, after drop to 270 DEG C with 1 DEG C/min of rate of temperature fall, be incubated 4 hours, after drop to 210 DEG C with 1 DEG C/min of rate of temperature fall again, be incubated 5 hours, air cooling to room temperature,
The loading stage after thermal treatment, described valve body being placed on blaster carries out shot peening; Loading stage at the uniform velocity rotates with the rotating speed of 6rad/min; The jet angle of shot-peening constantly changes between 40-70 °; Spraying pressure is 0.2MPa; The particle diameter of aluminium alloy bullet is 0.1mm; The shot-peening time is 90 minutes, obtains final valve body, and described aluminium alloy bullet alloying element consists of: Zn12.2%, Cu5.2%, Ti4.2%, Mg1.2%, Mn0.012%, and surplus is aluminium and inevitable nonmetal inclusion.
Embodiment 5:
A kind of preparation method of precision casting Copper Alloy Valve is provided, it is characterized in that, the weight percent of alloy composition is: Ni19.5%, Zn3.4%, Mg8.4%, Sn0.034%, Sb0.074%, Ca0.054%, Bi0.034%, Ti0.014%, Mn0.034%, Y0.024%, Mo0.054%, surplus is copper and inevitable nonmetal inclusion
The preparation method of institute's Copper Alloy Valve, comprises the following steps: require to prepare burden according to above-mentioned copper alloy chemical composition; First add fine copper ingot, nickel zinc alloy is added after the fusing of fine copper ingot, add magnesium again, finally add containing other alloying elements, smelting temperature is 1390 DEG C, cast: pouring temperature is 1370 DEG C, after carry out the demoulding, the Copper Alloy Valve obtained is incubated 150 minutes at 880 DEG C, then carries out quench treatment in this temperature; Rate of cooling is for being greater than 30 DEG C/sec; Afterwards Copper Alloy Valve is heated to 380 DEG C of insulations 14 hours; Drop to 330 DEG C with 2 DEG C/min of rate of temperature fall afterwards, be incubated 9 hours, after drop to 280 DEG C with 1 DEG C/min of rate of temperature fall, be incubated 6 hours, after drop to 230 DEG C with 1 DEG C/min of rate of temperature fall again, be incubated 6 hours, air cooling to room temperature,
The loading stage after thermal treatment, described valve body being placed on blaster carries out shot peening; Loading stage at the uniform velocity rotates with the rotating speed of 6rad/min; The jet angle of shot-peening constantly changes between 40-70 °; Spraying pressure is 0.2MPa; The particle diameter of aluminium alloy bullet is 0.1mm; The shot-peening time is 90 minutes, obtains final valve body, and described aluminium alloy bullet alloying element consists of: Zn12.4%, Cu5.4%, Ti4.4%, Mg1.4%, Mn0.014%, and surplus is aluminium and inevitable nonmetal inclusion.
Embodiment 6:
A kind of preparation method of precision casting Copper Alloy Valve is provided, it is characterized in that, the weight percent of alloy composition is: Ni18%, Zn3.6%, Mg8.6%, Sn0.036%, Sb0.076%, Ca0.056%, Bi0.036%, Ti0.016%, Mn0.036%, Y0.026%, Mo0.056%, surplus is copper and inevitable nonmetal inclusion
The preparation method of institute's Copper Alloy Valve, comprises the following steps: require to prepare burden according to above-mentioned copper alloy chemical composition; First add fine copper ingot, nickel zinc alloy is added after the fusing of fine copper ingot, add magnesium again, finally add containing other alloying elements, smelting temperature is 1380 DEG C, cast: pouring temperature is 1360 DEG C, after carry out the demoulding, the Copper Alloy Valve obtained is incubated 120 minutes at 860 DEG C, then carries out quench treatment in this temperature; Rate of cooling is for being greater than 30 DEG C/sec; Afterwards Copper Alloy Valve is heated to 360 DEG C of insulations 12 hours; Drop to 310 DEG C with 2 DEG C/min of rate of temperature fall afterwards, be incubated 8 hours, after drop to 270 DEG C with 1 DEG C/min of rate of temperature fall, be incubated 4 hours, after drop to 210 DEG C with 1 DEG C/min of rate of temperature fall again, be incubated 5 hours, air cooling to room temperature,
The loading stage after thermal treatment, described valve body being placed on blaster carries out shot peening; Loading stage at the uniform velocity rotates with the rotating speed of 6rad/min; The jet angle of shot-peening constantly changes between 40-70 °; Spraying pressure is 0.2MPa; The particle diameter of aluminium alloy bullet is 0.1mm; The shot-peening time is 90 minutes, obtains final valve body, and described aluminium alloy bullet alloying element consists of: Zn12.6%, Cu5.6%, Ti4.6%, Mg1.6%, Mn0.01-0.02%, and surplus is aluminium and inevitable nonmetal inclusion.

Claims (3)

1. prepare the method for Copper Alloy Valve for one kind, it is characterized in that, the weight percent of alloy composition is: Ni18-20%, Zn3-4%, Mg8-9%, Sn0.03-0.04%, Sb0.07-0.08%, Ca0.05-0.06%, Bi0.03-0.04%, Ti0.01-0.02%, Mn0.03-0.04%, Y0.02-0.03%, Mo0.05-0.06%, surplus is copper and inevitable nonmetal inclusion
The preparation method of described Copper Alloy Valve, comprises the following steps: require to prepare burden according to above-mentioned copper alloy chemical composition; First add fine copper ingot, nickel zinc alloy is added after the fusing of fine copper ingot, add magnesium again, finally add other alloying elements, smelting temperature is 1380-1390 DEG C, cast: pouring temperature is 1360-1370 DEG C, after carry out the demoulding, the Copper Alloy Valve obtained is incubated 120-150 minute at 860-880 DEG C, then carries out quench treatment in this temperature; Rate of cooling is for being greater than 30 DEG C/sec; Afterwards Copper Alloy Valve is heated to 360-380 DEG C of insulation 12-14 hour; Drop to 310-330 DEG C with 2 DEG C/min of rate of temperature fall afterwards, insulation 8-9 hour, after drop to 270-280 DEG C with 1 DEG C/min of rate of temperature fall, insulation 4-6 hour, after drop to 210-230 DEG C with 1 DEG C/min of rate of temperature fall again, insulation 5-6 hour, air cooling to room temperature,
The loading stage after thermal treatment, described valve body being placed on blaster carries out shot peening; Loading stage at the uniform velocity rotates with the rotating speed of 6rad/min; The jet angle of shot-peening constantly changes between 40-70 °; Spraying pressure is 0.2MPa; The particle diameter of aluminium alloy bullet is 0.1mm; The shot-peening time is 90 minutes, obtains final valve body, and described aluminium alloy bullet alloying element consists of: Zn12-13%, Cu5-6%, Ti4-5%, Mg1-2%, Mn0.01-0.02%, and surplus is aluminium and inevitable nonmetal inclusion.
2. prepare the method for Copper Alloy Valve as claimed in claim 1, smelting temperature is 1385 DEG C, and pouring temperature is 1365 DEG C.
3. prepare the method for Copper Alloy Valve as claimed in claim 1, described aluminium alloy bullet alloying element consists of: Zn12.5%, Cu5.5%, Ti4.5%, Mg1.5%, Mn0.015%, and surplus is aluminium and inevitable nonmetal inclusion.
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CN104846239A (en) * 2015-04-08 2015-08-19 盐城赛普金属制品有限公司 Aluminum alloy abrasive and processing technology thereof
CN107263029A (en) * 2017-06-23 2017-10-20 扬中市第蝶阀厂有限公司 A kind of Albrac valve body manufacturing process
CN113278845A (en) * 2021-05-04 2021-08-20 宁波华成阀门有限公司 Copper alloy for valve and valve manufacturing method

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