CN103555155A - High-performance high-decoration environment-friendly automobile baking finish coat and preparation method thereof - Google Patents
High-performance high-decoration environment-friendly automobile baking finish coat and preparation method thereof Download PDFInfo
- Publication number
- CN103555155A CN103555155A CN201310539130.8A CN201310539130A CN103555155A CN 103555155 A CN103555155 A CN 103555155A CN 201310539130 A CN201310539130 A CN 201310539130A CN 103555155 A CN103555155 A CN 103555155A
- Authority
- CN
- China
- Prior art keywords
- resin
- parts
- agent
- solvent
- decoration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention provides a high-performance high-decoration environment-friendly automobile baking finish coat which is prepared by mixing 55-60 parts of LH-09 resin, 13-15 parts of HMMM resin, 3-5 parts of closed polyisocyanate, 7-9 parts of titanium white R215, 1-3 parts of nano anticorrosive anti-wear agent, 0.2-5.0 parts of pigment, 0.4-0.6 part of accelerator, 0.4-1.5 parts of assistant, 5-6 parts of filler and 6-9 parts of solvent. Compared with the traditional paint, the finish coat provided by the invention has higher coating property, weather resistance, shield property and stability, prolongs the service life of the automobile, is environment-friendly, and belongs to an environment-friendly product.
Description
Technical field:
The present invention relates to paint field, be specifically related to a kind of high-performance high-decoration environmentally friendly vehicle and dry finish paint and preparation method thereof.
Background technology:
Development along with automotive industry; requirement to the application of automobile is more and more higher; not only require good decorative property; but also require weathering resistance good; meet environmental protection requirement; the vehicle furnace drying finish paint of all kinds that my company develops is to take the vibrin of tertiary carbonic acid glycidyl ester modification and the high solid finish paint that linking agent is made as main film forming substance, has good decorative property, weathering resistance is good and the advantage such as environmental protection.This vibrin resin with tertiary carbonic acid glycidyl ester modification does not at room temperature react with linking agent, film forming when being warming up to 135-140 ℃ and after linking agent reaction, this formula adopts crosslinker compounding technology, make the cross-linking density of coating higher, film level and smooth as mirror, fullness ratio is good, weathering resistance is good (ability with good resistance to solar exposure and the sleet of resistance to dust storm erosion), shock-resistant, damage resistant, low VOC, in filmogen, resin lower molecular weight, height contain admittedly, linking agent adopts compounded technology, is the innovation point of this kind coating.
Goal of the invention:
The invention provides a kind of high-performance high-decoration environmentally friendly vehicle and dry finish paint preparation method.Paint of the present invention is compared with tradition paint, has improved film performance, weathering resistance, protective, stability, has extended the work-ing life of automobile, and environmental protection belongs to environmentally friendly product.
The technical solution used in the present invention is as follows for achieving the above object:
High-decoration environmentally friendly vehicle is dried a finish paint, it is characterized in that, its component by following weight part is made:
Polymeric polyisocyanate 3-5, the titanium dioxide R2157-9 of LH-09 resin 55-60, HMMM resin 13-15, sealing, nano anti-corrosive anti-wear agent 1-3, pigment 0.2-5.0, Vulcanization accelerator TMTD 0.4-0.6, auxiliary agent 0.4-1.5, solvent 6-9, modified filler 5-6,
The preparation method of described LH-09 resin is:
(1) take by weight following component:
Tetra hydro Phthalic anhydride 16-20, oxalic acid 13-15, m-phthalic acid 2-4, TriMethylolPropane(TMP) 10-13, new pentane diacid alcohol 17-22, tertiary carbonic acid glycidyl ester 4-6, solvent 20-24, composite antioxidant 0.3-0.5, molecular weight regulator 0.2-0.4;
(2) by load weighted Tetra hydro Phthalic anhydride, oxalic acid, m-phthalic acid, TriMethylolPropane(TMP), new pentane diacid alcohol, tertiary carbonic acid glycidyl ester drops in reactor, to the dimethylbenzene that adds above-mentioned raw materials gross weight 6% in reactor, composite antioxidant is dissolved in to the solution that becomes concentration 20% in dimethylbenzene, by PPR pipe, join reactor, body CO2 ventilates simultaneously, slowly be warming up to 120 ℃, after dissolving, solid material starts stirring, at 140-160 ℃ of insulation esterification 2-3h, add the molecular weight regulator of formula ratio, continue to be warming up to 200-210 ℃ of insulation reaction, when being reacted to resinous acid value≤12mgKOH/g, viscosity is at 200-400(S) be coated with at-4 o'clock, be cooled to again below 150 ℃, add solvent latting drown, cooling, filter, discharging, obtain LH-09 resin finished product, wherein composite antioxidant is the equal proportion mixture of antioxidant 1010 and irgasfos 168, molecular weight regulator is lauryl mercaptan.
Described modified filler is to be prepared and obtained by following method: a. takes off the raw material of row weight part: kaolin 100-150, calcium carbonate 120-130, zeolite 10-12, nano-sized carbon 1-2, tungstic oxide 1-2, lanthanum trioxide 2-3, peppermint essential oil 2-3, Sodium peroxoborate 1-2, aluminum oxide 2-3, precipitator method barium sulfate 30-34, tea-polyphenol 3-4, triethyl citrate 1-2, titanate coupling agent TMC-TTS4-6, jade powder 1-2;
B, kaolin, calcium carbonate, zeolite are calcined to 4-5h at 450-480 ℃, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, the hydrochloric acid soln that adds 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, and it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filter, dry and obtain filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 8000-10000 rev/min, obtain.
Described high-performance high-decoration environmentally friendly vehicle is dried finish paint, it is characterized in that: described pigment is selected from one or more in ultramarine, organic yellow pigment, chrome yellow, molybdenum red, ferric oxide series, phthalein mountain valley with clumps of trees and bamboo series, toluidine maroon, talcum powder, calcium carbonate, barium sulfate, silicon-dioxide; Described nano anti-corrosive anti-wear agent is nano aluminium oxide.
Described high-performance high-decoration environmentally friendly vehicle is dried finish paint, it is characterized in that: described auxiliary agent is selected from one or more in wetting dispersing agent, flow agent, defoamer, siccative; Described solvent is one or more mixing in dimethylbenzene, N-BUTYL ACETATE, propandiol butyl ether acetic ester.
Described high-performance high-decoration environmentally friendly vehicle is dried the production method of finish paint, it is characterized in that, comprises the following steps:
(1) press formula rate by LH-09 resin, dispersion agent, pigment, filler, with 2000～2600r/min rotating speed high speed dispersion after 1-1.5 hour, then filter with 80 eye mesh screens;
(2) material filtering enters sand mill and is ground to fineness≤15u discharging, requires outlet material temperature≤60 ℃;
(3) material that mesh-of-grind is qualified adds to adjust to be converted in still, and adds the rest materials in formula, with the middling speed of 100～200r/min, stirs evenly;
(4), after stirring evenly, with solvent, adjust viscosity to 60-80(S)/be coated with-4, with 200 order vibratory screening apparatuss, filter, pack.
Technical scheme deterministic process of the present invention:
1, definite (hereinafter to be referred as the LH-09 resin) of tertiary carbonic acid glycidyl ester modified polyester resin
The chemical structure of tertiary carbonic acid glycidyl ester and reaction:
Above formula is the molecular structural formula of tertiary carbonic acid glycidyl ester.R1 wherein, R2, R3 is saturated alkane, total carbon number of its three alkyl is 8.
Tertiary carbonic acid glycidyl ester has epoxy-functional end group, be widely used in solvent-borne formulation that automobile packaged paint and retouching paint use, the major advantage of introducing tertiary carbonic acid glycidyl ester is to reduce the viscosity of the resin of synthesized, the fullness ratio, weathering resistance (having the ability that good resistance to solar exposure and the sleet of resistance to dust storm corrode) and the sticking power that improve resin, be specially adapted to acrylic resin modified and vibrin.
Glycidyl group in tertiary carbonic acid glycidyl ester and the reaction of the carboxyl functional group in resin can produce a new oh group, in the solidification process of baking finish system, can be cross-linked.
Tertiary carbonic acid glycidyl ester, by the glycidyl group in its molecule and the reaction of the free carboxy acid functional group in acrylic resin and polyester, can be easy to introduce in aforesaid propylene acid resin and vibrin.In tertiary carbonic acid glycidyl ester, tertiary monocarboxylic acid branched structure has increased the stability to hydrolysis of ester group, and good water-resistant stability and fatty long-chain make to adopt prepared by this material filming to have good water tolerance, resistance to acids and bases and weathering resistance.The side group of tertiary monocarboxylic acid; can reduce resin viscosity; the wettability of increase to pigment; epoxy group(ing) in its structure is very active; can make it participate in reaction and be incorporated in vibrin, due to its single functionality, can reduce the average functionality of reaction system; also be chain terminator simultaneously, can regulate the relative molecular weight and its distribution degree of resin.Tertiary monocarboxylic acid glyceryl ester is introduced to the viscosity that vibrin can reduce resin, improve solid part of resin.
2, the technical measures of synthetic water white resin
By choose reasonable composite antioxidant, to stop resin oxidation to heighten the color, make the color of filming made more bright-coloured; By CO2 gas, protect to reach the separated of resin-phase and air phase, thus synthetic water white resin.
Introducing due to tertiary carbonic acid glycidyl ester, make resin-phase to molecular weight, after being reacted with linking agent, it forms macromole converging network, just can obtain good filming, therefore adopting the HMMM of part methyl-etherified is main linking agent, dead front type aliphatic isocyanate is time linking agent, in being cross-linked into membrane process, mainly contain methoxyl group on vibrin hydroxyl and HMMM molecular resin and the crosslinking reaction of methylol, also may there is carboxymethyl simultaneously, the hydroxyl reaction of alkoxy methyl and vibrin, and methylol, self-condensation reaction between imino-and alkoxy methyl.It is residual that isocyanic ester is eliminated hydroxyl, improves cross-linking density, and increased the snappiness of filming by the flexible carbochain of aliphatic isocyanates.
In antifouling paste production technique of the present invention, LH-09 resin is the critical material of painting, the synthetic temperature of resin is controlled, the reinforced at the uniform velocity control of property is the key point of resin property quality, and effectively control can make the molecular weight distribution of synthetic resins narrower, thereby obtains desirable paint film; In sand milling operation, high-performance sand grinder grinds 2-3 road, and fineness can reach below 15 μ; Filter progress is that product is carried out to last purification, so that gratifying visual appearance to be provided.
Advantage of the present invention:
1, with tertiary carbonic acid glycidyl ester synthesizing polyester resin; can obviously reduce the synthetic viscosity of resin, thereby make high solid resin, reduce the discharge of organic volatile (VOC); than traditional paint, reduce VOC discharge more than 25%, be conducive to environment protection and reduce user's painting cost.
2, the fullness ratio of filming making with modified resin is high, and level and smooth as mirror, weathering resistance, water tolerance are all significantly improved than traditional paint, and artificial accelerated aging test reaches 1000 hours.
3, by composite crosslinking technology (HMMM of part methyl-etherified and case type aliphatic isocyanates), further improve the cross-linking density of coating, improved hardness and the scratch resistance of coating.
4, adopt various New-type adjuvants, increased the smoothness of coating; Adopt various weather-proof pigment further to improve the weathering resistance of coating; Adopt the agent of novel nano wear-and corrosion-resistant further to improve wear resistance and the preservative property of coating.
5, through national coating inspection center, detect resistance to artificial accelerated aging test and reach 1000 hours, surpass the technical requirements of 800 hours of GB/T13493-92 automobile finish artificial accelerated aging of all kinds, protect light tint retention more excellent.
6, the paint of producing with this technical formula, for Yangze river and Huai river, heavily block, gently block paint line high comprehensive performance in enormous quantities, reduced the expense of scratch maintenance, the vehicle of outdoor storage 2 years, the color of coating and velocity of variation≤3% of gloss, meet the technical requirements of car load application.
Embodiment
One, the synthetic LH-09 resin of embodiment 1
Main raw material(s)
1.1 materials form
Tetra hydro Phthalic anhydride, oxalic acid, m-phthalic acid, neopentyl glycol, TriMethylolPropane(TMP), tertiary carbonic acid glycidyl ester, composite antioxidant, dimethylbenzene, N-BUTYL ACETATE, propandiol butyl ether acetic ester.
Each constituent mass per-cent of 1.2 resins
1.3 synthesis technique
By synthetic resins with raw material 1.-6. drop in the enamel reaction still with condenser, agitator, water trap, add material quantity 6%(massfraction) dimethylbenzene, antioxidant 1010 and irgasfos 168 are dissolved in to the solution that becomes 20% in dimethylbenzene, by PPR pipe, add reactor, while adding this material, forbid contacting with the friction of iron medium logical CO
2slowly heat up 120 ℃, after solid material dissolves, start stirring, at 140-160 ℃ of insulation esterification 2-3h, add the molecular weight regulator of formula ratio, continue to be warming up to 200-210 ℃ of insulation reaction, when being reacted to resinous acid value≤12mgKOH/g, viscosity is at 200-400(S) be coated with at-4 o'clock, be cooled to below 150 ℃, add solvent latting drown, cooling, filtration, discharging.
The detection index of 1.4LH-09 resin
| Project | Index |
| Color (number, Fe-Co method)≤ | 1 |
| Solids content % | 80±2 |
| Viscosity (being coated with-4), s | 200-400 |
| Acid value mgKOH/g≤ | 12 |
Embodiment 2, lacquering are prepared main raw material(s)
2.1 materials form
Tertiary carbonic acid glycidyl ester modified polyester resin (the resulting resin that obtains of embodiment 1 preparation), part methyl-etherified HMMM aminoresin, dead front type aliphatic isocyanates, R type titanium dioxide, modified filler, nano aluminium oxide, BGS phthalocyanine blue, weathering resistance lemon yellow, various auxiliary agent, solvent etc.
2.2 lacquerings form (with Yangze river and Huai river orchid, being prepared as example) (weight part)
2.3 lacquering production technique
(1) LH-09 resin, wetting dispersing agent, pigment, filler high speed dispersion (2000-2600r/min), after 1 hour, are filtered with 80 eye mesh screens;
(2) material filtering enters sand mill circular grinding, outlet material temperature≤60 ℃, fineness control≤15u;
(3) material that mesh-of-grind is qualified adds to adjust to be converted in still, and with color paste toning to after meeting the requirements, add flow agent, defoamer, high boiling solvent, siccative, middling speed (100-200r/min) stirs evenly;
(4), after stirring evenly, with mixed solvent, adjust viscosity to 60-80(S)/be coated with-4, with 200 order vibratory screening apparatuss filtrations,
Packing,
Wherein, modified filler is to be prepared and obtained by following method: a. takes off the raw material of row weight part: kaolin 140, calcium carbonate 125, zeolite 11, nano-sized carbon 2, tungstic oxide 1, lanthanum trioxide 2, peppermint essential oil 2, Sodium peroxoborate 2, aluminum oxide 2, precipitator method barium sulfate 32, tea-polyphenol 4, triethyl citrate 2, titanate coupling agent TMC-TTS5, jade powder 2;
B, kaolin, calcium carbonate, zeolite are calcined to 4-5h at 450-480 ℃, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, the hydrochloric acid soln that adds 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, and it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filter, dry and obtain filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 8000-10000 rev/min, obtain.
2.4 lacquering assays
| Test item | Index | Assay |
| Paint film color and outward appearance | Meet aberration scope, smooth | Meet |
| Viscosity (being coated with-4), S >= | 60 | 87 |
| Fineness, μ m≤ | 15 | 15 |
| Opacifying power, g/m2≤ | Blue 80, light 200 | 80 |
| Time of drying (140 ℃), min | 30 | 30 |
| Hardness (pencil) >= | H | H |
| Sticking power (cross-hatching), level | 1 | 1 |
| Pliability test, mm≤ | 2 | 2 |
| Water tolerance (48h) | Without considerable change | Without considerable change |
| Oil-proofness (48h) | Without considerable change | Without considerable change |
| Gloss, 60 >= | 90 | 93 |
| Artificial accelerated aging test 1000h | By | Meet |
。
Claims (4)
1. high-performance high-decoration environmentally friendly vehicle is dried a finish paint, it is characterized in that, its component by following weight part is made:
The polymeric polyisocyanate 3-5 of LH-09 resin 55-60, HMMM resin 13-15, sealing, titanium dioxide R215 7-9, nano anti-corrosive anti-wear agent 1-3, pigment 0.2-5.0, Vulcanization accelerator TMTD 1-2 0.4-0.6, auxiliary agent 0.4-1.5, solvent 6-9, modified filler 5-6
The preparation method of described LH-09 resin is:
(1) take by weight following component:
Tetra hydro Phthalic anhydride 16-20, oxalic acid 13-15, m-phthalic acid 2-4, TriMethylolPropane(TMP) 10-13, new pentane diacid alcohol 17-22, tertiary carbonic acid glycidyl ester 4-6, solvent 20-24, composite antioxidant 0.3-0.5, molecular weight regulator 0.2-0.4;
(2) by load weighted Tetra hydro Phthalic anhydride, oxalic acid, m-phthalic acid, TriMethylolPropane(TMP), new pentane diacid alcohol, tertiary carbonic acid glycidyl ester drops in reactor, to the dimethylbenzene that adds above-mentioned raw materials gross weight 6% in reactor, composite antioxidant is dissolved in to the solution that becomes concentration 20% in dimethylbenzene, by PPR pipe, join reactor, body CO2 ventilates simultaneously, slowly be warming up to 120 ℃, after dissolving, solid material starts stirring, at 140-160 ℃ of insulation esterification 2-3h, add the molecular weight regulator of formula ratio, continue to be warming up to 200-210 ℃ of insulation reaction, when being reacted to resinous acid value≤12mgKOH/g, viscosity is at 200-400(S) be coated with at-4 o'clock, be cooled to again below 150 ℃, add solvent latting drown, cooling, filter, discharging, obtain LH-09 resin finished product, wherein composite antioxidant is the equal proportion mixture of antioxidant 1010 and irgasfos 168, molecular weight regulator is lauryl mercaptan,
Described modified filler is to be prepared and obtained by following method: a. takes off the raw material of row weight part: kaolin 100-150, calcium carbonate 120-130, zeolite 10-12, nano-sized carbon 1-2, tungstic oxide 1-2, lanthanum trioxide 2-3, peppermint essential oil 2-3, Sodium peroxoborate 1-2, aluminum oxide 2-3, precipitator method barium sulfate 30-34, tea-polyphenol 3-4, triethyl citrate 1-2, titanate coupling agent TMC-TTS 4-6, jade powder 1-2;
B, kaolin, calcium carbonate, zeolite are calcined to 4-5h at 450-480 ℃, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, the hydrochloric acid soln that adds 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, and it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filter, dry and obtain filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 8000-10000 rev/min, obtain.
2. high-performance high-decoration environmentally friendly vehicle according to claim 1 is dried finish paint, it is characterized in that: described pigment is selected from one or more in ultramarine, organic yellow pigment, chrome yellow, molybdenum red, ferric oxide series, phthalein mountain valley with clumps of trees and bamboo series, toluidine maroon, talcum powder, calcium carbonate, barium sulfate, silicon-dioxide; Described nano anti-corrosive anti-wear agent is nano aluminium oxide.
3. high-performance high-decoration environmentally friendly vehicle according to claim 1 is dried finish paint, it is characterized in that: described auxiliary agent is selected from one or more in wetting dispersing agent, flow agent, defoamer, siccative; Described solvent is one or more mixing in dimethylbenzene, N-BUTYL ACETATE, propandiol butyl ether acetic ester.
4. high-performance high-decoration environmentally friendly vehicle according to claim 1 is dried the production method of finish paint, it is characterized in that, comprises the following steps:
(1) press formula rate by LH-09 resin, dispersion agent, pigment, filler, with 2000～2600r/min rotating speed high speed dispersion after 1-1.5 hour, then filter with 80 eye mesh screens;
(2) material filtering enters sand mill and is ground to fineness≤15u discharging, requires outlet material temperature≤60 ℃;
(3) material that mesh-of-grind is qualified adds to adjust to be converted in still, and adds the rest materials in formula, with the middling speed of 100～200 r/min, stirs evenly;
(4), after stirring evenly, with solvent, adjust viscosity to 60-80(S)/be coated with-4, with 200 order vibratory screening apparatuss, filter, pack.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310539130.8A CN103555155A (en) | 2013-11-04 | 2013-11-04 | High-performance high-decoration environment-friendly automobile baking finish coat and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310539130.8A CN103555155A (en) | 2013-11-04 | 2013-11-04 | High-performance high-decoration environment-friendly automobile baking finish coat and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103555155A true CN103555155A (en) | 2014-02-05 |
Family
ID=50009529
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310539130.8A Pending CN103555155A (en) | 2013-11-04 | 2013-11-04 | High-performance high-decoration environment-friendly automobile baking finish coat and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103555155A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105885688A (en) * | 2016-07-05 | 2016-08-24 | 李康 | Preparation method of weather-resistance modified silicon resin exterior wall coating material |
| CN107722165A (en) * | 2017-11-13 | 2018-02-23 | 中国海洋石油集团有限公司 | Compound modified aqueous acrylic acid epoxy ester resin of versatic acid and preparation method thereof |
| CN108864750A (en) * | 2018-07-03 | 2018-11-23 | 俞华 | A kind of environmental protection color preserving agent |
| CN110105551A (en) * | 2019-05-20 | 2019-08-09 | 江苏柏鹤涂料有限公司 | High rigidity end-sealed type one-component baking-type top-coat resin and its preparation method and application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1710000A (en) * | 2005-07-01 | 2005-12-21 | 刘才方 | Low-temperature solidified polyester surface paint for procoating metal coiled material and its preparing method |
| JP2007119599A (en) * | 2005-10-28 | 2007-05-17 | Toyo Ink Mfg Co Ltd | Urethane adhesive |
| JP2007186682A (en) * | 2005-12-12 | 2007-07-26 | Dainippon Ink & Chem Inc | Water-based coating composition, organic-inorganic composite coating film and method for producing the same |
| EP2390290A1 (en) * | 2010-05-28 | 2011-11-30 | Seiko Epson Corporation | Ink jet recording ink composition |
| CN103305042A (en) * | 2013-06-17 | 2013-09-18 | 丹阳市佳美化工有限公司 | Thermosetting acrylic metallic paint |
-
2013
- 2013-11-04 CN CN201310539130.8A patent/CN103555155A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1710000A (en) * | 2005-07-01 | 2005-12-21 | 刘才方 | Low-temperature solidified polyester surface paint for procoating metal coiled material and its preparing method |
| JP2007119599A (en) * | 2005-10-28 | 2007-05-17 | Toyo Ink Mfg Co Ltd | Urethane adhesive |
| JP2007186682A (en) * | 2005-12-12 | 2007-07-26 | Dainippon Ink & Chem Inc | Water-based coating composition, organic-inorganic composite coating film and method for producing the same |
| EP2390290A1 (en) * | 2010-05-28 | 2011-11-30 | Seiko Epson Corporation | Ink jet recording ink composition |
| CN103305042A (en) * | 2013-06-17 | 2013-09-18 | 丹阳市佳美化工有限公司 | Thermosetting acrylic metallic paint |
Non-Patent Citations (1)
| Title |
|---|
| 傅绍燕: "《涂装工艺及车间设计手册》", 31 January 2013 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105885688A (en) * | 2016-07-05 | 2016-08-24 | 李康 | Preparation method of weather-resistance modified silicon resin exterior wall coating material |
| CN107722165A (en) * | 2017-11-13 | 2018-02-23 | 中国海洋石油集团有限公司 | Compound modified aqueous acrylic acid epoxy ester resin of versatic acid and preparation method thereof |
| CN107722165B (en) * | 2017-11-13 | 2020-12-04 | 中国海洋石油集团有限公司 | Tertiary carboxylic acid compound modified waterborne acrylic acid-epoxy ester resin and preparation method thereof |
| CN108864750A (en) * | 2018-07-03 | 2018-11-23 | 俞华 | A kind of environmental protection color preserving agent |
| CN110105551A (en) * | 2019-05-20 | 2019-08-09 | 江苏柏鹤涂料有限公司 | High rigidity end-sealed type one-component baking-type top-coat resin and its preparation method and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102010648B (en) | Floating coat-free shining base coat used for metal pieces and preparation method thereof | |
| CN105860722B (en) | A kind of one pack system, large arch dam, low VOC, environmentally friendly clear coat composition, preparation method and its usage | |
| CN103555191B (en) | A kind of two component farm machinery corrosion-resistanting decoration finish paint and preparation method thereof | |
| CN101550311B (en) | Aqueous finish paint used for coiled material | |
| CN109054519A (en) | A kind of water soluble acrylic acid anticorrosive paint and preparation method thereof containing pitch | |
| CN103555155A (en) | High-performance high-decoration environment-friendly automobile baking finish coat and preparation method thereof | |
| CN103555115B (en) | A kind of galvanized sheet coating and preparation method thereof | |
| CN103555121B (en) | A kind of aqueous automobile chassis corrosion resistant coating and preparation method thereof | |
| CN1687271A (en) | Primer of modified polyester coiled material | |
| CN105131227B (en) | A kind of use for synthetic leather UV cured flame-retardant polyurethane and preparation method thereof | |
| CN102504675B (en) | Weather-resistant hydrogenated bisphenol A-type epoxy powder coating and preparation method and application thereof | |
| CN103555176B (en) | A kind of two component engineering machinery corrosion-resistanting decoration finish paint and preparation method thereof | |
| CN103146292A (en) | Boil-resistant polyester powder coating, and preparation method and application thereof | |
| CN104449273A (en) | Ultraviolet-resistant water-based paint capable of reducing brightness of coating and applied to glass door and preparation method of ultraviolet-resistant water-based paint | |
| CN104449282A (en) | Antibacterial and antifouling waterborne coating for glass doors and preparation method thereof | |
| CN103013253A (en) | Nano aircraft coating and preparation method and using method thereof | |
| CN100410340C (en) | Aircraft skin coating | |
| CN101659822A (en) | Water-based water transfer varnish paint and preparation method thereof | |
| CN101121839A (en) | Nanometer composite exterior wall coating and preparation method thereof | |
| CN109354955A (en) | A kind of scratch-resistant paint of timber Environment-friendlywear-resistant wear-resistant | |
| CN111410907B (en) | Self-repairing type temperature-resistant wear-resistant polyaspartic acid ester coating and preparation method thereof | |
| CN104449278A (en) | Acid and alkali corrosion resistant glass door water-based paint with good smoothness and preparation method thereof | |
| CN105001427A (en) | Amine modified hyper-branched hydroxyl polymer and applications of amine modified hyper-branched hydroxyl polymer in rapid dry and pigment dispersion system | |
| CN103740241A (en) | Automobile plate spring anticorrosive priming paint and preparation method thereof | |
| CN112708333A (en) | Boiling-resistant powder coating composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 246000 Jixian Industrial Park, Daguan Economic Development Zone, Anhui, Anqing Applicant after: Anhui Ling Huqi limited-liability company Address before: 246000 Jixian Industrial Park, Daguan Economic Development Zone, Anhui, Anqing Applicant before: Anqing Linghu Paint Co.,Ltd. |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: ANQING LINGHU PAINT CO., LTD. TO: ANHUI LINGHU PAINT CO., LTD. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140205 |