CN103526376A - Anti-acarid polylactic acid fiber fabric - Google Patents
Anti-acarid polylactic acid fiber fabric Download PDFInfo
- Publication number
- CN103526376A CN103526376A CN201310533627.9A CN201310533627A CN103526376A CN 103526376 A CN103526376 A CN 103526376A CN 201310533627 A CN201310533627 A CN 201310533627A CN 103526376 A CN103526376 A CN 103526376A
- Authority
- CN
- China
- Prior art keywords
- mite
- fiber
- polylactic
- fabric
- terylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses an anti-acarid polylactic acid fiber fabric which is woven by blending the following raw materials by weight: 25-35 parts of polylactic acid fibers and 65-75 parts of anti-acarid fibers. The anti-acarid polylactic acid fiber fabric is good in anti-microbial, elasticity and friendliness to skin and comfortable to wear, and has good acarid prevention and driving effect.
Description
Technical field
The present invention relates to a kind of fabric, relate in particular to a kind of anti-mite acid fiber by polylactic fabric.
Background technology
Mite class is the monoid of most species in Arthropoda arachnid, and on the earth, existing mite class can have 500,000 kinds more than, and their form, habit and habitat are varied, can find Anywhere on earth the trace of mite class.The disease that medical domain causes the dirt mite being distributed in people's living environment is studied, research shows that it is a kind of strong sensibiligen, the people in the whole world nearly 1/10 suffers from anaphylactia, and wherein the morbidity of asthma, allergic rhinitis and atopical dermatitis etc. is all closely bound up with existing of house dust mite.
Along with the development of world architecture technology and enriching of people's material life, indoor living environment has a very large change, the improvement of house airtight performance, indoor pollution is assembled, simultaneously improper ventilation has increased the growth that indoor humidity is also conducive to mould and house dust mite, thereby make dirt mite become allergen the most general in living environment, the change of life style and working method makes people 80% time spend indoor.The change of environment has promoted dirt mite to grow, and people have also increased and the contacting of dust mite allergen in the prolongation of indoor residence time, and the incidence of disease of the diseases such as dust mite allergy asthma increases thereupon.Therefore, the control of dirt mite has been subject to countries in the world researchers' extensive concern.
Because the textiles in room is the raw main place of dirt mite evil, by adding in textiles, there is the chemical reagent that kills mite or drive mite effect and give the anti-mite of textiles and drive mite function, in the process of using textiles, realize anti-mite and drive mite, become a kind of new trend.
Summary of the invention
For the deficiencies in the prior art, technical problem to be solved by this invention is to provide a kind of anti-mite acid fiber by polylactic fabric.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A mite acid fiber by polylactic fabric, the raw material blending that adopts following weight portion to form is weaved and is formed: 25-35 part acid fiber by polylactic, the anti-mite fiber of 65-75 part.
Anti-mite acid fiber by polylactic fabric of the present invention can adopt industry universal method first acid fiber by polylactic and anti-mite fiber to be carried out to blending, makes blended yarn, then adopts industry universal method to be woven into anti-mite acid fiber by polylactic fabric this blended yarn.The preparation method of obvious described blended yarn woven fabric itself does not have originality, is only to adopt prior art, and innovation of the present invention is the difference of fabric blend fibre raw material and proportioning.
Described anti-mite fiber, material is terylene, also contains 0.05-0.15wt% and drives mite agent.Describedly drive mite agent and formed by 30-50 weight portion Fenamidone, 30-50 weight portion decis and 10-30 weight portion lauryl sodium carboxymethyl type imidazoline acetate.
Fenamidone, CAS:161326-34-7.Decis, CAS:52918-63-5.Lauryl sodium carboxymethyl type imidazoline acetate, CAS:64041-76-5.
Described anti-mite fiber, is prepared from by following step:
(1) by terylene with drive mite agent and mix, extrude, cut into slices, make and drive mite terylene chips, wherein terylene is 100:0.05-100:0.15 with the mass ratio that drives mite agent;
(2) described in general, drive mite terylene chips heating and melting, extruding, the moulding of spray silk.
Further, described anti-mite fiber also contains the coupling agent of 0.02-0.10wt%.
Described coupling agent is titanate coupling agent.
Described coupling agent is comprised of 60-80wt% isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters and 20-40wt% bis-(triethanolamine) metatitanic acid diisopropyl ester.
Isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, CAS:67691-13-8.Two (triethanolamine) metatitanic acid diisopropyl ester, CAS:36673-16-2.
Described anti-mite fiber, is prepared from by following step:
(1) coupling agent is mixed with terylene, obtain modified dacron, wherein the mass ratio of terylene and coupling agent is 100:0.02-100:0.10;
(2) by modified dacron with drive mite agent and mix, extrude, cut into slices, make and drive mite terylene chips, wherein terylene is 100:0.05-100:0.15 with the mass ratio that drives mite agent;
(3) described in general, drive mite terylene chips heating and melting, extruding, the moulding of spray silk.
Below main raw material fiber of the present invention is introduced:
Acid fiber by polylactic is a kind of synthetic fiber of fully biodegradable, and it can obtain from cereal.After its goods are discarded, in soil or seawater, through microbial action, can be decomposed into carbon dioxide and water, during burning, can not distribute poison gas, can not pollute.It is a kind of ecological fiber of sustainable development.
The raw materials for production lactic acid of acid fiber by polylactic (PLA) is to make from cornstarch, so also this fiber is called to zein fiber.It is common native compound in organism (comprising human body).By the chemical polymerization of lactic acid Cyclodimerization thing or the direct polymerization of lactic acid, can obtain the PLA of high molecular.Take PLA as the goods that raw material obtains, there is good biocompatibility and Bioabsorbable, and well biological degradability, water imbibition, biocidal property, anti-flammability, and in biodegradable thermoplastic polymer material, PLA has best heat resistance.
Concrete, as the acid fiber by polylactic of the productions such as the Changjiang river chemical fibre Co., Ltd, Jiangyin Gaoxin Chemical Fiber Co., Ltd..
Terylene is the trade name of the important kind ，Shi of in synthetic fiber China polyester fiber.It is to take fiber-forming polymer---the polyethylene terephthalate (PET) that p-phthalic acid (PTA) or dimethyl terephthalate (DMT) (DMT) and ethylene glycol (EG) make through esterification or ester exchange and polycondensation reaction as raw material, the fiber of making through spinning and post processing.
Anti-mite acid fiber by polylactic fabric of the present invention, mite-proof agent is embedded in fibrous inside, in the process that wears and wash textiles, surface one deck mite-proof agent is washed off, there is again new mite-proof agent to supplement from interior stripping, at fabric face, form again the anti-mite layer that one deck is new, bring into play anti-mite effect, thereby embody good washability.
Anti-mite acid fiber by polylactic fabric of the present invention, antibiotic, skin-friendly good, good springiness, comfortable and easy to wear, and there is good anti-mite and drive mite effect.
The specific embodiment
Embodiment 1:
(1) 0.06 weight portion coupling agent is mixed with 100 weight portion terylene, obtain modified dacron;
Described coupling agent is comprised of 70wt% isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters and 30wt% bis-(triethanolamine) metatitanic acid diisopropyl ester;
(2) above-mentioned modified dacron and 0.1 weight portion are driven to mite agent and mix, extrude, cut into slices, make and drive mite terylene chips;
Describedly drive mite agent and formed by 40wt% Fenamidone, 40wt% decis and 20wt% lauryl sodium carboxymethyl type imidazoline acetate;
(3) by the above-mentioned mite terylene chips heating and melting that drives, extruding, the moulding of spray silk, makes anti-mite fiber.Embodiment 2:
Adopt the essentially identical method of embodiment 1 to prepare anti-mite fiber, unique difference is: described coupling agent is two (triethanolamine) metatitanic acid diisopropyl ester, and addition is also 0.06 weight portion.
Embodiment 3:
Adopt the essentially identical method of embodiment 1 to prepare anti-mite fiber, unique difference is: described coupling agent is isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, and addition is also 0.06 weight portion.
Embodiment 4:
Adopt the essentially identical method of embodiment 1 to prepare anti-mite fiber, unique difference is: do not add any coupling agent.
Embodiment 5
The blending mass ratio of the anti-mite fiber of acid fiber by polylactic, embodiment 1 is 30:70.
By the anti-mite fiber of acid fiber by polylactic and embodiment 1, adopt artificial a small amount of mixed, opening picking machine made rolling, carding machine is made blended sliver;
By above-mentioned blended sliver, by pre-drawing machine, drawing frame, Speed frames, fine spining machine and bobbin winder, make described anti-mite acid fiber by polylactic fabric successively.Prepared blended yarn, number is 21S, the twist is 330.
By the above-mentioned anti-mite acid fiber by polylactic fabric making, adopt conventional woven method can make described anti-mite acid fiber by polylactic fabric again, plain cloth, fabric grammes per square metre is 180 grams/m.Embodiment 6
The blending mass ratio of the anti-mite fiber of acid fiber by polylactic, embodiment 2 is 30:70.Adopt the method for embodiment 5 to prepare anti-mite acid fiber by polylactic fabric.
Embodiment 7
The blending mass ratio of the anti-mite fiber of acid fiber by polylactic, embodiment 3 is 30:70.Adopt the method for embodiment 5 to prepare anti-mite acid fiber by polylactic fabric.
Embodiment 8
The blending mass ratio of the anti-mite fiber of acid fiber by polylactic, embodiment 4 is 30:70.Adopt the method for embodiment 5 to prepare anti-mite acid fiber by polylactic fabric.
Test case 1:
" the anti-mite bedding of the FZ/T62012-2009 " standard of employing, the anti-mite acid fiber by polylactic fabric to above-mentioned employing embodiment 5-8, carries out anti-mite performance test:
Table 1: anti-mite performance test table
Test case 2:
Embodiment 1 drives mite agent (40wt% Fenamidone, 40wt% decis and 20wt% lauryl sodium carboxymethyl type imidazoline acetate) toxicity test:
(1) drive mite agent aqueous solution per os acute toxicity; Get 1wt% and drive the Kunming kind standard small white mouse disposable per os gavage of the mite agent aqueous solution to 40 empty stomach 16h, drive mite agent aqueous solution dosage up to 20000mg/kg.Observe animal and poisoning manifestations every day, seven days finish experiment, and each organizes animal used as test in whole experimentation, and without any poisoning manifestations, diet and motion are all normal, none animal dead.
(2) to skin irritation: 10 large ear tag quasi-experiments of Japan are cut respectively with the backbone diamond wool of rabbit, will be flooded 1wt% and drive the gauze of the mite agent aqueous solution, apply ointment or plaster on the skin exposing on right side.After 24 hours, observe application site skin, all do not occur the irritations such as erythema and oedema, according to skin irritatin strength grading standard, this drives mite agent skin is belonged to non-stimulated material.
(3) to eye irritation: 1wt% is driven to the mite agent aqueous solution, directly splash into the right eye of rabbit for the large ear tag quasi-experiment of Japan, left eye compares, passive closed 5 seconds, then clean with normal saline flushing, after 24 hours, to observe, eyes are all without abnormal, according to eye irritation strength grading standard, this drives mite agent eyes is belonged to non-stimulated material.
Anti-mite acid fiber by polylactic fabric of the present invention, mite-proof agent is embedded in fibrous inside, in the process that wears and wash textiles, surface one deck mite-proof agent is washed off, there is again new mite-proof agent to supplement from interior stripping, at fabric face, form again the anti-mite layer that one deck is new, bring into play anti-mite effect, thereby embody good washability.
Claims (8)
1. an anti-mite acid fiber by polylactic fabric, is characterized in that, the raw material blending that adopts following weight portion to form is weaved and formed: 25-35 part acid fiber by polylactic, the anti-mite fiber of 65-75 part.
2. anti-mite acid fiber by polylactic fabric as claimed in claim 1, is characterized in that, described anti-mite fiber, and material is terylene, also contains 0.05-0.15wt% and drives mite agent.
3. anti-mite acid fiber by polylactic fabric as claimed in claim 2, is characterized in that, described anti-mite fiber also contains the coupling agent of 0.02-0.10wt%.
4. anti-mite acid fiber by polylactic fabric as claimed in claim 2 or claim 3, is characterized in that, described in drive mite agent and formed by 30-50 weight portion Fenamidone, 30-50 weight portion decis and 10-30 weight portion lauryl sodium carboxymethyl type imidazoline acetate.
5. anti-mite acid fiber by polylactic fabric as claimed in claim 3, is characterized in that, described coupling agent is titanate coupling agent.
6. anti-mite acid fiber by polylactic fabric as claimed in claim 5, is characterized in that, described coupling agent is comprised of 60-80wt% isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters and 20-40wt% bis-(triethanolamine) metatitanic acid diisopropyl ester.
7. anti-mite acid fiber by polylactic fabric as claimed in claim 2, is characterized in that, described anti-mite fiber, is prepared from by following step:
(1) by terylene with drive mite agent and mix, extrude, cut into slices, make and drive mite terylene chips, wherein terylene is 100:0.05-100:0.15 with the mass ratio that drives mite agent;
(2) described in general, drive mite terylene chips heating and melting, extruding, the moulding of spray silk.
8. anti-mite acid fiber by polylactic fabric as claimed in claim 3, is characterized in that, described anti-mite fiber, is prepared from by following step:
(1) coupling agent is mixed with terylene, obtain modified dacron, wherein the mass ratio of terylene and coupling agent is 100:0.02-100:0.10;
(2) by modified dacron with drive mite agent and mix, extrude, cut into slices, make and drive mite terylene chips, wherein terylene is 100:0.05-100:0.15 with the mass ratio that drives mite agent;
(3) described in general, drive mite terylene chips heating and melting, extruding, the moulding of spray silk.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310533627.9A CN103526376B (en) | 2013-10-31 | 2013-10-31 | Anti-mite polylactic acid fiber fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310533627.9A CN103526376B (en) | 2013-10-31 | 2013-10-31 | Anti-mite polylactic acid fiber fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103526376A true CN103526376A (en) | 2014-01-22 |
| CN103526376B CN103526376B (en) | 2015-08-05 |
Family
ID=49928701
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310533627.9A Active CN103526376B (en) | 2013-10-31 | 2013-10-31 | Anti-mite polylactic acid fiber fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103526376B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108991819A (en) * | 2018-08-08 | 2018-12-14 | 宁波华业纤维科技有限公司 | A kind of mattress convenient for the dehumidifying of voluntarily anti-mite |
| CN113279097A (en) * | 2021-06-07 | 2021-08-20 | 红豆集团无锡红豆童装有限公司 | Preparation method of chitin natural colored cotton blended yarn |
| CN114262976A (en) * | 2021-12-29 | 2022-04-01 | 骏隆翔(厦门)纤维科技有限公司 | Energy-saving environment-friendly regenerated knitted fabric and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106498531B (en) * | 2016-10-20 | 2019-06-21 | 华南理工大学 | A kind of antibiosis anti-acarien fiber and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1712595A (en) * | 2004-06-15 | 2005-12-28 | 上海市纺织科学研究院 | Shell fabric from corn fibre and bamboo fibre blend and production thereof |
| CN101168863A (en) * | 2007-11-28 | 2008-04-30 | 盛虹集团有限公司 | Highly effective acarid-proof terylene fibre |
| US20100029776A1 (en) * | 2006-12-22 | 2010-02-04 | Bayer Crop Science Ag | Pesticidal composition comprising fenamidone and an insecticide compound |
| CN102517796A (en) * | 2011-12-02 | 2012-06-27 | 江苏紫荆花纺织科技股份有限公司 | Healthcare environment-friendly mattress and preparation method thereof |
| CN103361997A (en) * | 2013-08-06 | 2013-10-23 | 上海婉静纺织科技有限公司 | Silkworm pupa protein, cotton and polyester blended fabric |
-
2013
- 2013-10-31 CN CN201310533627.9A patent/CN103526376B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1712595A (en) * | 2004-06-15 | 2005-12-28 | 上海市纺织科学研究院 | Shell fabric from corn fibre and bamboo fibre blend and production thereof |
| US20100029776A1 (en) * | 2006-12-22 | 2010-02-04 | Bayer Crop Science Ag | Pesticidal composition comprising fenamidone and an insecticide compound |
| CN101168863A (en) * | 2007-11-28 | 2008-04-30 | 盛虹集团有限公司 | Highly effective acarid-proof terylene fibre |
| CN102517796A (en) * | 2011-12-02 | 2012-06-27 | 江苏紫荆花纺织科技股份有限公司 | Healthcare environment-friendly mattress and preparation method thereof |
| CN103361997A (en) * | 2013-08-06 | 2013-10-23 | 上海婉静纺织科技有限公司 | Silkworm pupa protein, cotton and polyester blended fabric |
Non-Patent Citations (2)
| Title |
|---|
| 张丽等: "高性能医用纺织品的新发展", 《现代纺织技术》 * |
| 赵建华: "《材料科技与人类文明》", 31 August 2011, 华中科技大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108991819A (en) * | 2018-08-08 | 2018-12-14 | 宁波华业纤维科技有限公司 | A kind of mattress convenient for the dehumidifying of voluntarily anti-mite |
| CN113279097A (en) * | 2021-06-07 | 2021-08-20 | 红豆集团无锡红豆童装有限公司 | Preparation method of chitin natural colored cotton blended yarn |
| CN114262976A (en) * | 2021-12-29 | 2022-04-01 | 骏隆翔(厦门)纤维科技有限公司 | Energy-saving environment-friendly regenerated knitted fabric and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103526376B (en) | 2015-08-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103526376B (en) | Anti-mite polylactic acid fiber fabric | |
| CN1291645C (en) | Dermatophagoides culturing method | |
| CN101265621A (en) | Collagen protein-polyvinyl alcohol-chitosan blending medical fibre and method for making same | |
| CN101956244A (en) | Method for preparing anti-mosquito and ultraviolet-resistant polypropylene fiber | |
| CN105113075A (en) | Textile material | |
| CN103526384B (en) | Anti-mite chitin fabric | |
| JP2006225785A (en) | Blended yarn and antimicrobial woven or knitted fabric using the same | |
| CN104562281A (en) | Preparation method of nano silk protein bamboo pulp fibers | |
| CN105239234A (en) | Textile material and preparation method thereof | |
| CN105088460A (en) | Textile material and preparation method thereof | |
| CN103556332B (en) | Anti-mite man textile fabric | |
| CN202430389U (en) | Biomass fiber composite core-spun yarn structure | |
| CN103526424B (en) | Anti-mite milk protein fiber fabric | |
| CN103556358B (en) | Anti-mite sheet fabric | |
| CN106012092A (en) | Multifunctional protein fiber and preparation method thereof | |
| CN103526377B (en) | Anti-mite pina fibre fabric | |
| CN102851768A (en) | Production method of durable composite antibiotic fibers | |
| CN103526423B (en) | Anti-mite modal fiber fabric | |
| CN103556359B (en) | The beautiful match fabric of anti-mite | |
| CN107237017A (en) | A kind of textile material and preparation method thereof | |
| CN103526426B (en) | Anti-mite pillow case fabric | |
| CN103526425B (en) | Anti-mite Pai Site fabric lining | |
| CN103005978A (en) | Antibacterial table cloth and preparation method thereof | |
| Azam et al. | Sustainable Raw Materials | |
| CN100512723C (en) | An antibiotic superfine fibre straw mat |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhou Jing Inventor before: Yuan Juan |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170309 Address after: 528000 Guangdong Province, Foshan city Chancheng District xiacha Road No. 13 block ten room 314-315 Patentee after: Foshan source Shun Shun Ecological Textile Technology Co., Ltd. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T158 Patentee before: Shanghai Wanjing Textile Technology Co., Ltd. |