CN103509499A - Polyisobutylene hot melt adhesive for adhesive tapes - Google Patents
Polyisobutylene hot melt adhesive for adhesive tapes Download PDFInfo
- Publication number
- CN103509499A CN103509499A CN201310401061.4A CN201310401061A CN103509499A CN 103509499 A CN103509499 A CN 103509499A CN 201310401061 A CN201310401061 A CN 201310401061A CN 103509499 A CN103509499 A CN 103509499A
- Authority
- CN
- China
- Prior art keywords
- parts
- hot melt
- melt adhesive
- resin
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002367 Polyisobutene Polymers 0.000 title claims abstract description 24
- 239000004831 Hot glue Substances 0.000 title claims abstract description 18
- 239000002390 adhesive tape Substances 0.000 title claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 22
- 229920005989 resin Polymers 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 229920001971 elastomer Polymers 0.000 claims abstract description 10
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 4
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 4
- FIBARIGPBPUBHC-UHFFFAOYSA-N octyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCOC(=O)CCCCCCCC1OC1CCCCCCCC FIBARIGPBPUBHC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 4
- 239000003549 soybean oil Substances 0.000 claims abstract description 4
- -1 [2.4-di-tert-butyl-phenyl] phosphorous acid ester Chemical class 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000003208 petroleum Substances 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229940043810 zinc pyrithione Drugs 0.000 claims description 6
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 claims description 6
- BJZYYSAMLOBSDY-QMMMGPOBSA-N (2s)-2-butoxybutan-1-ol Chemical compound CCCCO[C@@H](CC)CO BJZYYSAMLOBSDY-QMMMGPOBSA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- 229940024545 aluminum hydroxide Drugs 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 229950002083 octabenzone Drugs 0.000 claims description 3
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 238000007665 sagging Methods 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
A disclosed polyisobutylene hot melt adhesive for adhesive tapes is composed of the following raw materials in parts by weight: 80-90 parts of polyisobutylene rubber, 10-20 parts of hydrogenated rosin resin, 10-13 parts of chlorinated paraffin, 2-3 parts of octyl epoxy stearate, 1-2 parts of alkanolamide, 1-2 parts of aluminium hydroxide powder, 0.1-0.3 part of hydroquinone, 8-10 parts of epoxidized soybean oil, 0.2-0.3 part of tris(2,4-di-tert-butyl-phenyl) phosphite, 0.2-0.4 part of 2-hydroxy-4-n-octyloxybenzophenone and 10-20 parts of a tackifier. The prepared hot melt adhesive is used for the adhesive tapes and is capable of guaranteeing excellent sagging resistance and contact adhesion property of the adhesive tapes, is strong in high temperature resistance, low temperature resistance, durable, and long in effect lasting time.
Description
Technical field
The present invention relates generally to a kind of hot melt adhesive powder, relates in particular to a kind of adhesive tape polyisobutene hot melt adhesive.
Background technology
Hot melt adhesive is a kind of plastic tackiness agent, and in certain temperature range, its physical condition changes with temperature change, and chemical property is constant, and it is nonpoisonous and tasteless, belongs to environmental-protecting chemical product.
Summary of the invention
The object of the invention is just to provide a kind of adhesive tape polyisobutene hot melt adhesive.
The present invention is achieved by the following technical solutions:
Use a polyisobutene hot melt adhesive, it is comprised of the raw material of following weight parts:
Polyisobutylene rubber 80-90, staybelite resin 10-20, clorafin 10-13, octyl epoxy stearate 2-3, alkylol amide 1-2, aluminium-hydroxide powder 1-2, Resorcinol 0.1-0.3, epoxy soybean oil 8-10, three [2.4-di-tert-butyl-phenyl] phosphorous acid ester 0.2-0.3, Octabenzone 0.2-0.4, tackifier 10-20;
Described tackifier are comprised of the raw material of following weight parts:
Terpine resin 30-40, C5 petroleum resin 20-30, Sodium Silicofluoride 3-5, silane resin acceptor kh-550 1-2, Zinc Pyrithione 0.2-0.3, poly(lactic acid) 2-3, PTMG 1-2;
Above-mentioned terpine resin and C5 petroleum resin Hybrid Heating are arrived to 100-150 ℃, add Sodium Silicofluoride, insulated and stirred 10-15 minute, reduction temperature is 70-75 ℃, add Zinc Pyrithione, fully mix, reduction temperature is 60-65 ℃, adds silane resin acceptor kh-550,600-800 rev/min of dispersed with stirring 4-6 minute, add each raw material of residue, fully mix, obtain described tackifier.
A preparation method for polyisobutene hot melt adhesive for adhesive tape, comprises the following steps:
By above-mentioned each raw material Hybrid Heating melting except polyisobutylene rubber, add polyisobutylene rubber, insulation reaction 30-40 minute at 120-150 ℃, cooling after stirring, obtain described adhesive tape polyisobutene hot melt adhesive.
Advantage of the present invention is:
Hot melt adhesive prepared by the present invention has good sag resistance and tactile viscosity for guaranteeing adhesive tape on adhesive tape, and anti-high and low-temp performance is strong, durable in use, and the effect time length is of a specified duration.
Embodiment
Embodiment 1
Use a polyisobutene hot melt adhesive, it by following weight parts (kilogram) raw material form:
Polyisobutylene rubber 90, staybelite resin 20, clorafin 13, octyl epoxy stearate 3, alkylol amide 2, aluminium-hydroxide powder 1, Resorcinol 0.3, epoxy soybean oil 10, three [2.4-di-tert-butyl-phenyl] phosphorous acid ester 0.3, Octabenzone 0.4, tackifier 20;
Described tackifier are comprised of the raw material of following weight parts:
Terpine resin 40, C5 petroleum resin 30, Sodium Silicofluoride 3, silane resin acceptor kh-550 1, Zinc Pyrithione 0.3, poly(lactic acid) 3, PTMG 1;
By above-mentioned terpine resin and C5 petroleum resin Hybrid Heating to 150 ℃, add Sodium Silicofluoride, insulated and stirred 15 minutes, reducing temperature is 75 ℃, add Zinc Pyrithione, fully mix, reducing temperature is 65 ℃, adds silane resin acceptor kh-550,800 revs/min of dispersed with stirring 6 minutes, add each raw material of residue, fully mix, obtain described tackifier.
A preparation method for polyisobutene hot melt adhesive for adhesive tape, comprises the following steps:
By above-mentioned each raw material Hybrid Heating melting except polyisobutylene rubber, add polyisobutylene rubber, at 150 ℃, insulation reaction is 40 minutes, cooling after stirring, and obtains described adhesive tape polyisobutene hot melt adhesive.
Performance test
Shearing resistance: 4.6Mp.
Claims (2)
1. an adhesive tape polyisobutene hot melt adhesive, is characterized in that what it was comprised of the raw material of following weight parts:
Polyisobutylene rubber 80-90, staybelite resin 10-20, clorafin 10-13, octyl epoxy stearate 2-3, alkylol amide 1-2, aluminium-hydroxide powder 1-2, Resorcinol 0.1-0.3, epoxy soybean oil 8-10, three [2.4-di-tert-butyl-phenyl] phosphorous acid ester 0.2-0.3, Octabenzone 0.2-0.4, tackifier 10-20;
Described tackifier are comprised of the raw material of following weight parts:
Terpine resin 30-40, C5 petroleum resin 20-30, Sodium Silicofluoride 3-5, silane resin acceptor kh-550 1-2, Zinc Pyrithione 0.2-0.3, poly(lactic acid) 2-3, PTMG 1-2;
Above-mentioned terpine resin and C5 petroleum resin Hybrid Heating are arrived to 100-150 ℃, add Sodium Silicofluoride, insulated and stirred 10-15 minute, reduction temperature is 70-75 ℃, add Zinc Pyrithione, fully mix, reduction temperature is 60-65 ℃, adds silane resin acceptor kh-550,600-800 rev/min of dispersed with stirring 4-6 minute, add each raw material of residue, fully mix, obtain described tackifier.
2. a preparation method for polyisobutene hot melt adhesive for adhesive tape as claimed in claim 1, is characterized in that comprising the following steps:
By above-mentioned each raw material Hybrid Heating melting except polyisobutylene rubber, add polyisobutylene rubber, insulation reaction 30-40 minute at 120-150 ℃, cooling after stirring, obtain described adhesive tape polyisobutene hot melt adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310401061.4A CN103509499B (en) | 2013-09-06 | 2013-09-06 | A kind of adhesive tape polyisobutene PUR |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310401061.4A CN103509499B (en) | 2013-09-06 | 2013-09-06 | A kind of adhesive tape polyisobutene PUR |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103509499A true CN103509499A (en) | 2014-01-15 |
| CN103509499B CN103509499B (en) | 2016-05-18 |
Family
ID=49892938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310401061.4A Expired - Fee Related CN103509499B (en) | 2013-09-06 | 2013-09-06 | A kind of adhesive tape polyisobutene PUR |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103509499B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111454494A (en) * | 2020-03-19 | 2020-07-28 | 深圳市天宁达胶粘技术有限公司 | Sealing grease for sealing protection of cylindrical battery gasket and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6008148A (en) * | 1996-04-15 | 1999-12-28 | Ato Findley, Inc. | Oil resistant polybutylene based hot melt adhesive |
| CN101186794A (en) * | 2007-12-03 | 2008-05-28 | 周飞鹏 | Adhesive tape for mosquito eradication lamp, hot-melt adhesive of the adhesive tap and preparation method of the hot-melt adhesive |
| CN101805569A (en) * | 2009-10-23 | 2010-08-18 | 郑州中原应用技术研究开发有限公司 | Transparent butyl hot-melt sealant and preparation method thereof |
-
2013
- 2013-09-06 CN CN201310401061.4A patent/CN103509499B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6008148A (en) * | 1996-04-15 | 1999-12-28 | Ato Findley, Inc. | Oil resistant polybutylene based hot melt adhesive |
| CN101186794A (en) * | 2007-12-03 | 2008-05-28 | 周飞鹏 | Adhesive tape for mosquito eradication lamp, hot-melt adhesive of the adhesive tap and preparation method of the hot-melt adhesive |
| CN101805569A (en) * | 2009-10-23 | 2010-08-18 | 郑州中原应用技术研究开发有限公司 | Transparent butyl hot-melt sealant and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 纪楠 等: "中空玻璃用丁基热熔密封胶的研究", 《沈阳化工大学学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111454494A (en) * | 2020-03-19 | 2020-07-28 | 深圳市天宁达胶粘技术有限公司 | Sealing grease for sealing protection of cylindrical battery gasket and preparation method thereof |
| CN111454494B (en) * | 2020-03-19 | 2021-12-28 | 深圳市天宁达胶粘技术有限公司 | Sealing grease for sealing protection of cylindrical battery gasket and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103509499B (en) | 2016-05-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| GR01 | Patent grant | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160426 Address after: 241200 Anhui city of Wuhu province Fanchang County Economic and Technological Development Zone Beisi entrepreneurial Science Park Applicant after: Fanchang Beisi Productivity Promotion Center Co., Ltd. Address before: 241200 Anhui city of Wuhu province Fanchang County Economic Development Zone Science and technology park business times thinking Applicant before: Wuhu City Zheng Tong Electric Appliance Equipment Co., Ltd |
|
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Liao Gunren Inventor before: Wu Shunbao |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170407 Address after: No. 11 Heshan Yayao town of Chaoyang Road 529724 Guangdong city of Jiangmen Province Patentee after: Heshan Hongming adhesive product industry Co., Ltd. Address before: 241200 Anhui city of Wuhu province Fanchang County Economic and Technological Development Zone Beisi entrepreneurial Science Park Patentee before: Fanchang Beisi Productivity Promotion Center Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170522 Address after: The town of Nanhai District, Guangdong city of Foshan province 528222 Luocun Lo Sanya two team Lutang Industrial Zone Patentee after: Nanhai District of Foshan city Harong packing material Co. Ltd Address before: No. 11 Heshan Yayao town of Chaoyang Road 529724 Guangdong city of Jiangmen Province Patentee before: Heshan Hongming adhesive product industry Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160518 Termination date: 20180906 |