CN103483915B - Preparation method of pigment yellow 17 emulsion - Google Patents
Preparation method of pigment yellow 17 emulsion Download PDFInfo
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- CN103483915B CN103483915B CN201310411001.0A CN201310411001A CN103483915B CN 103483915 B CN103483915 B CN 103483915B CN 201310411001 A CN201310411001 A CN 201310411001A CN 103483915 B CN103483915 B CN 103483915B
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- 239000000049 pigment Substances 0.000 title claims abstract description 39
- 239000000839 emulsion Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 32
- 238000010008 shearing Methods 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 6
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003208 petroleum Substances 0.000 claims abstract description 6
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 6
- 239000011734 sodium Substances 0.000 claims abstract description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 5
- -1 polyoxyethylene Polymers 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 claims 1
- 229960002446 octanoic acid Drugs 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 4
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000004530 micro-emulsion Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- SQABAALQCGKFFO-UHFFFAOYSA-N octanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCC(O)=O SQABAALQCGKFFO-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
技术领域 technical field
本发明涉及一种乳液的制备方法，特别是涉及一种颜料黄17乳液的制备方法。 The invention relates to a method for preparing an emulsion, in particular to a method for preparing a Pigment Yellow 17 emulsion.
背景技术 Background technique
颜料黄17为一种偶氮颜料，具有不溶于水的特点。由于其不溶于水，在一些水体系下，就会制约了颜料黄17的用途和空间。为了拓展颜料黄17的应用领域，很多人尝试将颜料黄17作为微乳液或者乳液，目前将其做成为微乳液的没有，因为其结构所决定做成为微乳液难度较大。作为乳液，目前的研究也较少，而且取得的效果不甚显著，依然存在很多的缺点，制约了其的大规模应用。 Pigment Yellow 17 is an azo pigment that is insoluble in water. Because it is insoluble in water, in some water systems, the use and space of Pigment Yellow 17 will be restricted. In order to expand the application field of Pigment Yellow 17, many people try to use Pigment Yellow 17 as a microemulsion or emulsion. At present, there is no such thing as a microemulsion, because its structure determines that it is difficult to make a microemulsion. As an emulsion, the current research is less, and the effect obtained is not very significant, and there are still many shortcomings, which restrict its large-scale application.
发明内容 Contents of the invention
要解决的技术问题：常规颜料黄17乳液粒径大、稳定性差的问题。 The technical problem to be solved: the problem of large particle size and poor stability of conventional pigment yellow 17 emulsion.
技术方案：本发明公开了一种颜料黄17乳液的制备方法，制备方法包括以下步骤：（1）取目数为400～500目的颜料黄17粉末为10～12份，将颜料黄17放入容器中；（2）向容器中加入辛癸酸甘油酯为5～9份，将颜料黄17与辛癸酸甘油酯混合均匀，为A混合体；（3）另取一容器，向容器中加入松香酸聚氧乙烯酯为20～24份，再加入石油磺酸钠为18～25份，再加入水为160至170份，混合均匀为B液；（4）将A混合体与B液混合，使用剪切机剪切10～20min，转速为6000rpm至8000rpm；（5）剪切结束后保藏。颜料黄17粉末目数优选为500目。颜料黄17粉末优选为12份。辛癸酸甘油酯优选为5份。剪切机剪切时间优选为20min。 Technical solution: The invention discloses a preparation method of Pigment Yellow 17 emulsion. The preparation method includes the following steps: (1) Take 10-12 parts of Pigment Yellow 17 powder with a mesh number of 400-500 mesh, put Pigment Yellow 17 into (2) Add 5-9 parts of caprylic acid glycerin to the container, mix Pigment Yellow 17 and caprylic capric acid glycerin evenly, and form A mixture; Add 20-24 parts of polyoxyethylene rosin acid, then add 18-25 parts of sodium petroleum sulfonate, and then add 160-170 parts of water, mix well to form B liquid; (4) Mix A mixture with B liquid Mix and shear with a shear for 10 to 20 minutes at a speed of 6,000 to 8,000 rpm; (5) Store after shearing. The mesh number of Pigment Yellow 17 powder is preferably 500 mesh. Pigment Yellow 17 powder is preferably 12 parts . Caprylic capric acid glyceride is preferably 5 parts. Shear shearing time is preferably 20min.
有益效果：本制备方法制备得到颜料黄17乳液粒径非常小，为10um～16um。同时具有良好热稳定性和离心稳定性。乳液在50℃下加热5～10h没有发生分层现象。另外在转速为4000rpm下离心30min～60min也未有分层和破乳现象产生。 Beneficial effects: the particle size of the pigment yellow 17 emulsion prepared by the preparation method is very small, ranging from 10um to 16um. At the same time, it has good thermal stability and centrifugal stability. The emulsion did not delaminate when heated at 50°C for 5-10 hours. In addition, there was no delamination and demulsification when centrifuged at 4000rpm for 30min to 60min.
具体实施方式 Detailed ways
实施例1 Example 1
（1）取目数为400目的颜料黄17粉末为10kg，将颜料黄17放入容器中；（2）向容器中加入辛癸酸甘油酯为9kg，将颜料黄17与辛癸酸甘油酯混合均匀，为A混合体；（3）另取一容器，向容器中加入松香酸聚氧乙烯酯为24kg，再加入石油磺酸钠为25kg，再加入水为160kg，混合均匀为B液；（4）将A混合体与B液混合，使用剪切机剪切10min，转速为6000rpm；（5）剪切结束后保藏。 (1) Take 10kg of Pigment Yellow 17 powder with a mesh number of 400, and put Pigment Yellow 17 into the container; (2) Add caprylic capric acid glyceride to the container to make 9kg, mix Pigment Yellow 17 and caprylic capric glyceride Mix well, it is A mixture; (3) Take another container, add polyoxyethylene rosin acid to the container to make 24kg, add petroleum sodium sulfonate to make 25kg, add water to make 160kg, mix evenly to make B liquid; (4) Mix A mixture with B liquid, and use a shearing machine to shear for 10 minutes at a speed of 6000 rpm; (5) Store after shearing.
实施例2 Example 2
（1）取目数为500目的颜料黄17粉末为11kg，将颜料黄17放入容器中；（2）向容器中加入辛癸酸甘油酯为5kg，将颜料黄17与辛癸酸甘油酯混合均匀，为A混合体；（3）另取一容器，向容器中加入松香酸聚氧乙烯酯为20kg，再加入石油磺酸钠为23kg，再加入水为170kg，混合均匀为B液；（4）将A混合体与B液混合，使用剪切机剪切20min，转速为7000rpm；（5）剪切结束后保藏。 (1) Take 11kg of Pigment Yellow 17 powder with a mesh number of 500, and put Pigment Yellow 17 into the container; (2) Add caprylic capric acid glyceride to the container to make 5kg, mix Pigment Yellow 17 and caprylic capric glycerin Mix evenly, it is A mixture; (3) Take another container, add polyoxyethylene rosin acid to the container to make 20kg, then add petroleum sodium sulfonate to make 23kg, then add water to make 170kg, mix evenly to make B liquid; (4) Mix A mixture with B liquid, and use a shearing machine to shear for 20 minutes at a speed of 7000 rpm; (5) Store after shearing.
实施例3 Example 3
（1）取目数为450目的颜料黄17粉末为12kg，将颜料黄17放入容器中；（2）向容器中加入辛癸酸甘油酯为7kg，将颜料黄17与辛癸酸甘油酯混合均匀，为A混合体；（3）另取一容器，向容器中加入松香酸聚氧乙烯酯为22kg，再加入石油磺酸钠为18kg，再加入水为165kg，混合均匀为B液；（4）将A混合体与B液混合，使用剪切机剪切15min，转速为8000rpm；（5）剪切结束后保藏。 (1) Take 12kg of Pigment Yellow 17 powder with a mesh number of 450, put Pigment Yellow 17 into the container; (2) add caprylic capric acid glyceride to the container to make 7kg, mix Pigment Yellow 17 and caprylic capric glycerin Mix well, it is A mixture; (3) Take another container, add polyoxyethylene rosin acid to the container to make 22kg, then add petroleum sodium sulfonate to make 18kg, then add water to make 165kg, mix evenly to make B liquid; (4) Mix A mixture with B liquid, and use a shearing machine to shear for 15 minutes at a speed of 8000 rpm; (5) Store after shearing.
对实施例1、实施例2、实施例3的产品进行了粒径、热稳定性、离心稳定性测定。结果如下表。 The products of embodiment 1, embodiment 2 and embodiment 3 have carried out particle diameter, thermal stability, centrifugal stability measurement. The results are shown in the table below.
制备得到的产品具备了良好的热稳定性和离心稳定性。 The prepared product has good thermal stability and centrifugal stability.
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| CN201310411001.0A CN103483915B (en) | 2013-09-11 | 2013-09-11 | Preparation method of pigment yellow 17 emulsion |
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| CN103483915A CN103483915A (en) | 2014-01-01 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2048206A1 (en) * | 2006-07-31 | 2009-04-15 | DIC Corporation | Process for producing aqueous pigment dispersion and ink for ink-jet recording |
| CN101469155A (en) * | 2007-12-24 | 2009-07-01 | 深圳市海川实业股份有限公司 | Environment friendly transparent iron oxide yellow superfine aqueous color sizing dispersion and preparation thereof |
| CN101597446A (en) * | 2008-12-25 | 2009-12-09 | 天津兆阳纳米科技有限公司 | A kind of stable-type yellow nanometer water-type pigment dispersion |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101597443A (en) * | 2008-12-25 | 2009-12-09 | 天津兆阳纳米科技有限公司 | A kind of Yellow nanometer water-type pigment dispersion |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2048206A1 (en) * | 2006-07-31 | 2009-04-15 | DIC Corporation | Process for producing aqueous pigment dispersion and ink for ink-jet recording |
| CN101469155A (en) * | 2007-12-24 | 2009-07-01 | 深圳市海川实业股份有限公司 | Environment friendly transparent iron oxide yellow superfine aqueous color sizing dispersion and preparation thereof |
| CN101597446A (en) * | 2008-12-25 | 2009-12-09 | 天津兆阳纳米科技有限公司 | A kind of stable-type yellow nanometer water-type pigment dispersion |
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