CN103467792B - A kind of meteorological balloon and preparation method thereof and the built-up type balloon containing this meteorological balloon - Google Patents

A kind of meteorological balloon and preparation method thereof and the built-up type balloon containing this meteorological balloon Download PDF

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CN103467792B
CN103467792B CN201310433943.9A CN201310433943A CN103467792B CN 103467792 B CN103467792 B CN 103467792B CN 201310433943 A CN201310433943 A CN 201310433943A CN 103467792 B CN103467792 B CN 103467792B
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balloon
meteorological balloon
centimetres
meteorological
phenyl
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CN103467792A (en
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肖迪娥
黄炯
潘显智
张雅妮
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Rubber Studying And Designing Institute China Chemical Industry Zhuzhou Co Ltd
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Rubber Studying And Designing Institute China Chemical Industry Zhuzhou Co Ltd
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Abstract

The invention provides a kind of meteorological balloon, meteorological balloon comprises following component and weight part: centrifugal concentrating natural rubber latex 100 parts, 0 ~ 0.30 part, potassium hydroxide, casein 0 ~ 0.2 part, paregal O 0 ~ 0.15 part, 1 ~ 2 part, sulphur, N-phenyl-2-naphthylamine 1 ~ 2 part, Ethyl-phenyl-zinc dithiocarbamate 1 ~ 2 part, N-phenyl-N '-sec.-propyl-Ursol D 1 ~ 2 part, 0.5 ~ 3 part, zinc oxide, 3 ~ 5 parts, machinery oil, emulsified olefin 3 ~ 7 parts.Present invention also offers preparation method and the built-up type meteorological balloon of this meteorological balloon.750 grams of specification meteorological balloons provided by the invention on average go up to the air and highly reach 30450 meters, lift-off highly reach 26000 meters efficient be 88.2%, 1600 grams of specification meteorological balloon rainy days on average go up to the air and highly reach 33481 meters, lift-off highly reach 30000 meters efficient be 91.7%, all reach the requirement at present to meteorological balloon.

Description

A kind of meteorological balloon and preparation method thereof and the built-up type balloon containing this meteorological balloon
Technical field
The invention belongs to aerological sounding field, particularly relate to a kind of meteorological balloon and preparation method thereof and the built-up type meteorological balloon containing this meteorological balloon.
Background technology
Meteorological balloon is research air, development meteorology, aviation, space technology and carries out the important and indispensable launch vehicle of space science research.
At present, the average lift-off height under the average lift-off aspect ratio fair weather condition of conventional meteorological balloon under the adverse weather conditions such as sleet, freezing, strong wind is much lower, causes the disappearance of station high-altitude data.If more under the atrocious weather such as sleet, freezing, strong wind high lower atmosphere layer can be understood influence each other and disturbance transmitting procedure; observe the processes such as the transmission of solar ultraviolet radiation in stratosphere and microwave scmiddle atmosphere, absorption and photochmeical reaction; by the research of change be conducive to the overall physical process of air and stratospheric circulation; thus improve detection height and detection level further; for weather warning forecast provides service accurately and timely; improve the capability and qualification of whole society's defence Disaster Event, farthest protect people life property safety.This just needs the aerological balloon that can use under adverse weather condition.
Although meteorological balloon of the prior art can reach the height of about 30000 meters under general weather condition, but at sleet, freezing, under the adverse weather conditions such as strong wind, the lift-off of balloon highly significantly reduces, and it is unstable, the such as balloon of 750 grams, average detection height is about 18000 meters, minimum detection is highly about 12000 meters, even if increase the quality of balloon, also be difficult to effectively solve lift-off height problem, 26000 meters that require with detection specifications detect and highly have a long way to go, 26000 meters highly efficient less than 50%, cause the disappearance of station high-altitude data, affect accuracy rate and the Meteorological Science research of weather-forecast.
Its reason is that the covering of above-mentioned balloon does not have hydrophobic performance, and when sleet sky discharges, rainwater can be condensed in balloon covering surface, in cold zone, water build-ups ice, and the ice sheet on covering surface has a strong impact on extension rate and the rebound performance of balloon, and balloon anti-crystallization can be poor, burst in advance, impact lift-off height.
The Chinese patent being CN102352060A as publication number discloses a kind of meteorological balloon and preparation method thereof, this meteorological balloon is made up of the material of following weight part: natural centrifugal concentrating latex 100, casein 0.10-0.25, potassium hydroxide 0.15-0.40, dispersion agent NF0.05-0.10, sodium tetraborate 0.01-0.05, Nekal BX 0.5-1.0, paregal O 0.05-0.15, sulphur 1.5-2.5, promotor PX0.7-3.0, protective agent 1.5-2.5, 4010NA 1.5-3.1, zinc oxide 0.1-2.5, cold-resistance agent 3.0-5.0 and neoprene latex and isoprene copolymer 3-8.The meteorological balloon stating method obtained by upper art does not have hydrophobic performance, cannot meet highly efficient service requirements under inclement weather conditions.
Summary of the invention
The present invention is the technical problem solving above-mentioned existence, provides a kind of and can adapt to meteorological balloon of severe weather use and preparation method thereof and the built-up type meteorological balloon containing this meteorological balloon.
The invention provides a kind of meteorological balloon, described meteorological balloon comprises following component and weight part:
Centrifugal concentrating natural rubber latex 100 parts
0 ~ 0.30 part, potassium hydroxide
Casein 0 ~ 0.2 part
Paregal O 0 ~ 0.15 part
1 ~ 2 part, sulphur
Antioxidant D (N-phenyl-2-naphthylamine) 1 ~ 2 part
PX(Ethyl-phenyl-zinc dithiocarbamate) 1 ~ 2 part
4010NA(N-phenyl-N '-sec.-propyl-Ursol D) 1 ~ 2 part
0.5 ~ 3 part, zinc oxide
3 ~ 5 parts, machinery oil
Emulsified olefin 3 ~ 7 parts.
Present invention also offers a kind of built-up type meteorological balloon, described built-up type meteorological balloon comprises ectosphere and position interior ball in the inner, and described ectosphere is meteorological balloon of the present invention.
Present invention also offers the preparation method of described meteorological balloon, the method comprises the steps:
S1, sulphur, N-phenyl-2-naphthylamine, N-phenyl-N '-sec.-propyl-Ursol D, Ethyl-phenyl-zinc dithiocarbamate and zinc oxide are made water dispersion;
S2, potassium hydroxide, casein and paregal O are mixed with solution;
S3, machinery oil and emulsified olefin are mixed with milk sap;
S4, water dispersion and solution to be added in concentrated natural latex, and then add milk sap, mixing and stirring, obtain composition;
S5, composition is prepared meteorological balloon.
The present invention makes full use of paraffin and has hydrophobic feature, emulsified olefin is added in balloon raw materials for production, it is made to be uniformly distributed in covering glued membrane, because the solubleness of paraffin in cross-linked rubber is than much smaller before sulfuration, therefore, in balloon sulfidation, crystallization change is there is and forms wax crystal body in the undissolved paraffin of part in cross-linked rubber, these wax crystal bodies are subject to the pressure of sizing material around and produce stress to its inside, should exist with partial balancing with between the wax crystal body of internal stress with the sizing material around directly contacted, and in contrast, the sizing material being in surface but keeps balancing with the paraffin of unstress state.Therefore, after balloon has been produced in parking period, will produce and make newly to be dissolved in sizing material with internal stress wax crystal body weight to become the reactive force that unstressed paraffin separates out surface.Under the effect of this reactive force, there is paraffin in sizing material to the phenomenon of surface transport.Namely paraffin progressively moves to balloon surface, therefore, after balloon has been produced, parks certain hour, and these paraffin waxes moving to balloon surface define the interlayer of one deck waterproof.This interlayer can expand or resilience in company with covering.
Therefore, even if under adverse weather condition, in lift-off process, the sleet adhesion amount of balloon surface is fewer, so after entering cold zone, also just tail off in the amount of balloon surface layers of ice, and then balloon extension rate under cryogenic and rebound performance can be improved, make balloon under inclement weather conditions, the height of needs can be reached.
Accompanying drawing explanation
Fig. 1 is the structural representation of built-up type meteorological balloon of the present invention.
In figure: ball in 1-ectosphere, 2-.
Embodiment
In order to make technical problem solved by the invention, technical scheme and beneficial effect clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
The invention provides a kind of meteorological balloon, described meteorological balloon comprises following component and weight part:
Centrifugal concentrating natural rubber latex 100 parts
0 ~ 0.30 part, potassium hydroxide
Casein 0 ~ 0.2 part
Paregal O 0 ~ 0.15 part
1 ~ 2 part, sulphur
Anti-aging agent N-phenyl-2-naphthylamine 1 ~ 2 part
Ethyl-phenyl-zinc dithiocarbamate 1 ~ 2 part
N-phenyl-N '-sec.-propyl-Ursol D 1 ~ 2 part
0.5 ~ 3 part, zinc oxide
3 ~ 5 parts, machinery oil
Emulsified olefin 3 ~ 7 parts.
In the present invention; meteorological balloon has been produced in rear parking period; emulsified olefin can move; sealing coat is formed at balloon surface; effectively can isolate moisture; this sealing coat can expand or resilience in company with covering, uses under being adapted to severe weather, and the ectosphere of built-up type meteorological balloon can ball in available protecting in rainy day lift-off process.
In order to strengthen the performance of balloon further, preferably, the content of described emulsified olefin is 4 ~ 5 weight parts.Its content is very few, does not reach desirable effect, crosses the film forming properties that can affect at most in balloon processing.
In order to strengthen the anti-old performance of balloon further, preferably, 5 ~ 15 weight part polychloroprene latexs are also comprised in described ectosphere.
Preferably, the quality of described meteorological balloon 700 ~ 800 grams, ball handle length is 13 ~ 16 centimetres, ball handle width 8 ~ 10 centimetres, and spheroid length is 210 ~ 250 centimetres.
Preferably, the quality of described meteorological balloon 1550 ~ 1650 grams, ball handle length is 12 ~ 16 centimetres, ball handle width 9 ~ 13 centimetres, and spheroid length is 305 ~ 355 centimetres.
Present invention also offers a kind of built-up type meteorological balloon, as shown in Figure 1, comprise ectosphere 1 and the ball 2 being positioned at ectosphere 1 inside.Described ectosphere 1 is meteorological balloon of the present invention.
Preferably, the quality of described ectosphere 1 is 85 ~ 115 grams, and ball handle length is 8 ~ 11 centimetres, ball handle width 8 ~ 10 centimetres, and spheroid length is 57 ~ 69 centimetres, and the quality of described interior ball is 700 ~ 800 grams.
Preferably, the quality of described ectosphere 1 is 270 ~ 330 grams, and ball handle length is 8 ~ 11 centimetres, ball handle width 9 ~ 11 centimetres, and spheroid length is 130 ~ 150 centimetres, and the quality of described interior ball is 1550 ~ 1650 grams.
In the present invention, built-up type meteorological balloon the present inventor is by the long-term observation to sounding data, find that the atrocious weather such as sleet is with in the section of fine day meteorologicelements difference mainly below ten thousand metres, more than ten thousand metres meteorologicelements highly and weather good time almost indifference.For this characteristic, inventor has devised a kind of integrated mode, utilize the principle of the multistage lift-off of similar rocket to discharge.The i.e. ectosphere of an outer surface cover special facture of ball in inflation is normal, namely above-mentioned meteorological balloon, allows ectosphere contact rainwater layer, to overcome the larger unfavorable meteorologicelements of humidity; After built-up type meteorological balloon have passed the terrible weather key element layer of ten thousand metres height, ectosphere is fried fall off from, interior ball continues lift-off, continues to carry instrument and to go up to the air desired height, detection climate factors.
When ectosphere quality is 85 ~ 115 grams, preferably, the quality of described interior ball is 700 ~ 800 grams.Preferably, the lifting force of described interior ball is 1.5 ~ 2.6 kilograms, and total lifting force of described meteorological balloon is 2.2 ~ 3.1 kilograms.Be well positioned to meet ectosphere like this to explode about ten thousand metres, interior ball continues lift-off, reaches the requirement of more than 26000 meters.
When ectosphere quality is 270 ~ 330 grams, preferably, the quality of described interior ball is 1550 ~ 1650 grams.Preferably, the lifting force of described interior ball is 2.0 ~ 2.4 kilograms, and total lifting force of described meteorological balloon is 2.9 ~ 3.4 kilograms.Be well positioned to meet ectosphere like this to explode about ten thousand metres, interior ball continues lift-off, reaches the requirement of more than 30000 meters.
Present invention also offers the preparation method of meteorological balloon of the present invention, the method comprises the steps:
S1, sulphur, N-phenyl-2-naphthylamine, N-phenyl-N '-sec.-propyl-Ursol D, Ethyl-phenyl-zinc dithiocarbamate and zinc oxide are made water dispersion;
S2, potassium hydroxide, casein and paregal O are mixed with solution;
S3, machinery oil and emulsified olefin are mixed with milk sap;
S4, water dispersion and solution to be added in concentrated natural latex, and then add milk sap, mixing and stirring, obtain composition;
S5, composition is prepared meteorological balloon.
Preferably, the method adds polychloroprene latex before being also included in step S5 in the composition.
The concrete steps of step S5 are:
1, mould dipping: balloon mould is flooded in peptizer;
2, pad pasting: mould surface being stained with peptizer soaks in the composition of configuration, makes composition stick uniformly on balloon mould;
3, solidify the demoulding: the balloon mould surface drying being stained with composition is placed in hot water and soaks the demoulding, and the balloon blank after the demoulding to be placed in water temperature be that the tank of 20-30 DEG C soaks 40-50 minute;
4, aeration settling: balloon blank is inflated and shapes, after venting, also sulfuration forms meteorological balloon, and this meteorological balloon parks more than one month;
5, form meteorological balloon: adopt existing meteorological balloon as interior ball, and place it in the ectosphere interior formation built-up type meteorological balloon obtained in step 4.
Below by specific embodiment, the present invention is described in detail.
Embodiment 1
1, the composition of meteorological balloon
Centrifugal concentrating natural rubber latex 100 parts, 0.15 part, potassium hydroxide, casein 0.2 part, paregal O (alkylpolyoxyethylene) 0.1 part, 1 part, sulphur, antioxidant D (N-phenyl-2-naphthylamine) 1.5 parts, PX(Ethyl-phenyl-zinc dithiocarbamate) 1 part, 4010NA(N-phenyl-N '-sec.-propyl-Ursol D) 2 parts, 1.5 parts, zinc oxide, machinery oil weight ratio is 3.00 parts, emulsified olefin 5 parts;
2, preparation method
(1) composition is prepared
S1, sulphur, antioxidant D, 4010NA, PX and zinc oxide are made water dispersion;
S2, potassium hydroxide, casein and paregal O are mixed with solution;
S3, machinery oil and emulsified olefin are mixed with milk sap;
S4, water dispersion and solution to be added in concentrated natural latex, and then add milk sap, mixing and stirring, obtain composition;
(2) meteorological balloon is prepared
1, mould dipping: balloon mould is flooded in peptizer;
2, pad pasting: mould surface being stained with peptizer soaks in the composition of configuration, makes composition stick uniformly on balloon mould;
3, solidify the demoulding: the balloon mould surface drying being stained with balloon composition is placed in hot water and soaks the demoulding, and the balloon blank after the demoulding to be placed in water temperature be that the tank of 20-30 DEG C soaks 40-50 minute;
4, aeration settling: balloon blank is inflated and shapes, after venting, also sulfuration forms the ectosphere of meteorological balloon, and this ectosphere parks more than one month;
5, form meteorological balloon: adopt existing meteorological balloon as interior ball, and place it in the ectosphere interior formation built-up type meteorological balloon A1 obtained in step 4.
The quality of ectosphere 100 grams, ball handle length 8 centimetres, ball handle width 8 centimetres, spheroid length 63 centimetres; The quality of interior ball 750 grams.
Embodiment 2
1, the composition of meteorological balloon
Centrifugal concentrating natural rubber latex 100 parts, 0.30 part, potassium hydroxide, casein 0.1 part, paregal O (alkylpolyoxyethylene) 0.15 part, 2 parts, sulphur, antioxidant D (N-phenyl-2-naphthylamine) 1 part, PX(Ethyl-phenyl-zinc dithiocarbamate) 1.5 parts, 4010NA(N-phenyl-N '-sec.-propyl-Ursol D) 1 part, 3 parts, zinc oxide, machinery oil weight ratio is 5.0 parts, polychloroprene latex 5 parts, emulsified olefin 7 parts;
2, preparation method
(1) composition is prepared
S1, sulphur, antioxidant D, 4010NA, PX and zinc oxide are made water dispersion;
S2, potassium hydroxide, casein and paregal O are mixed with solution;
S3, machinery oil and emulsified olefin are mixed with milk sap;
S4, water dispersion and solution to be added in concentrated natural latex, and then add milk sap and polychloroprene latex, mixing and stirring obtains composition.
(2) meteorological balloon is prepared
1, mould dipping: balloon mould is flooded in peptizer;
2, pad pasting: mould surface being stained with peptizer soaks in the composition of configuration, makes composition stick uniformly on balloon mould;
3, solidify the demoulding: the balloon mould surface drying being stained with composition is placed in hot water and soaks the demoulding, and the balloon blank after the demoulding to be placed in water temperature be that the tank of 20-30 DEG C soaks 40-50 minute;
4, aeration settling: balloon blank is inflated and shapes, after venting, also sulfuration forms the ectosphere of meteorological balloon, and this ectosphere parks more than one month;
5, form meteorological balloon: adopt existing meteorological balloon as interior ball, and place it in the ectosphere interior formation built-up type meteorological balloon A2 obtained in step 4.
The quality of ectosphere 115 grams, ball handle length 11 centimetres, ball handle width 10 centimetres, spheroid length 69 centimetres; The quality of interior ball 800 grams.
Embodiment 3
1, the composition of meteorological balloon
Centrifugal concentrating natural rubber latex 100 parts, 0.1 part, potassium hydroxide, casein 0.15 part, paregal O (alkylpolyoxyethylene) 0.1 part, 1.5 parts, sulphur, antioxidant D (N-phenyl-2-naphthylamine) 2 parts, PX(Ethyl-phenyl-zinc dithiocarbamate) 2 parts, 4010NA(N-phenyl-N '-sec.-propyl-Ursol D) 1.5 parts, 0.5 part, zinc oxide, machinery oil weight ratio is 4 parts, polychloroprene latex 15 parts, emulsified olefin 3 parts;
2, preparation method
(1) composition is prepared
S1, sulphur, antioxidant D, 4010NA, PX and zinc oxide are made water dispersion;
S2, potassium hydroxide, casein and paregal O are mixed with solution;
S3, machinery oil and emulsified olefin are mixed with milk sap;
S4, water dispersion and solution to be added in concentrated natural latex, and then add milk sap and polychloroprene latex, mixing and stirring obtains composition.
(2) meteorological balloon is prepared
1, mould dipping: balloon mould is flooded in peptizer;
2, pad pasting: mould surface being stained with peptizer soaks in the composition of configuration, makes composition stick uniformly on balloon mould;
3, solidify the demoulding: the balloon mould surface drying being stained with composition is placed in hot water and soaks the demoulding, and the balloon blank after the demoulding to be placed in water temperature be that the tank of 20-30 DEG C soaks 40-50 minute;
4, aeration settling: balloon blank is inflated and shapes, after venting, also sulfuration forms the ectosphere of meteorological balloon, and this ectosphere parks more than one month;
5, form meteorological balloon: adopt existing meteorological balloon as interior ball, and place it in the ectosphere interior formation built-up type meteorological balloon A3 obtained in step 4.
The quality of ectosphere 85 grams, ball handle length 10 centimetres, ball handle width 9 centimetres, spheroid length 57 centimetres; The quality of interior ball 700 grams.
Embodiment 4
1, the composition of meteorological balloon
Centrifugal concentrating natural rubber latex 100 parts, 0.15 part, potassium hydroxide, casein 0.2 part, paregal O (alkylpolyoxyethylene) 0.1 part, 1 part, sulphur, antioxidant D (N-phenyl-2-naphthylamine) 1.5 parts, PX(Ethyl-phenyl-zinc dithiocarbamate) 1 part, 4010NA(N-phenyl-N '-sec.-propyl-Ursol D) 2 parts, 1.5 parts, zinc oxide, machinery oil weight ratio is 3.00 parts, polychloroprene latex 5 parts, emulsified olefin 5 parts.
2, preparation method
(1) composition is prepared
S1, sulphur, antioxidant D, 4010NA, PX and zinc oxide are made water dispersion;
S2, potassium hydroxide, casein and paregal O are mixed with solution;
S3, machinery oil and emulsified olefin are mixed with milk sap;
S4, water dispersion and solution to be added in concentrated natural latex, and then add milk sap and polychloroprene latex, mixing and stirring, obtain composition;
(2) meteorological balloon is prepared
1, mould dipping: balloon mould is flooded in peptizer;
2, pad pasting: mould surface being stained with peptizer soaks in the composition of configuration, makes composition stick uniformly on balloon mould;
3, solidify the demoulding: the balloon mould surface drying being stained with balloon composition is placed in hot water and soaks the demoulding, and the balloon blank after the demoulding to be placed in water temperature be that the tank of 20-30 DEG C soaks 40-50 minute;
4, aeration settling: balloon blank is inflated and shapes, after venting, also sulfuration forms the ectosphere of meteorological balloon, and this ectosphere parks more than one month;
5, form meteorological balloon: adopt existing meteorological balloon as interior ball, and place it in the ectosphere interior formation built-up type meteorological balloon A4 obtained in step 4.
The quality of ectosphere 300 grams, ball handle length 11 centimetres, ball handle width 11 centimetres, spheroid length 150 centimetres; The quality of interior ball 1600 grams.
Embodiment 5
1, the composition of meteorological balloon
Centrifugal concentrating natural rubber latex 100 parts, 0.1 part, potassium hydroxide, casein 0.15 part, paregal O (alkylpolyoxyethylene) 0.1 part, 1.5 parts, sulphur, antioxidant D (N-phenyl-2-naphthylamine) 2 parts, PX(Ethyl-phenyl-zinc dithiocarbamate) 2 parts, 4010NA(N-phenyl-N '-sec.-propyl-Ursol D) 1.5 parts, 0.5 part, zinc oxide, machinery oil weight ratio is 4 parts, polychloroprene latex 15 parts, emulsified olefin 3 parts;
2, preparation method
(1) composition is prepared
S1, sulphur, antioxidant D, 4010NA, PX and zinc oxide are made water dispersion;
S2, potassium hydroxide, casein and paregal O are mixed with solution;
S3, machinery oil and emulsified olefin are mixed with milk sap;
S4, water dispersion and solution to be added in concentrated natural latex, and then add milk sap and polychloroprene latex, mixing and stirring obtains composition.
(2) meteorological balloon is prepared
1, mould dipping: balloon mould is flooded in peptizer;
2, pad pasting: mould surface being stained with peptizer soaks in the composition of configuration, makes composition stick uniformly on balloon mould;
3, solidify the demoulding: the balloon mould surface drying being stained with composition is placed in hot water and soaks the demoulding, and the balloon blank after the demoulding to be placed in water temperature be that the tank of 20-30 DEG C soaks 40-50 minute;
4, aeration settling: balloon blank is inflated and shapes, after venting, also sulfuration forms the ectosphere of meteorological balloon, and this ectosphere parks more than one month;
5, form meteorological balloon: adopt existing meteorological balloon as interior ball, and place it in the ectosphere interior formation meteorological balloon built-up type A5 obtained in step 4.
The quality of ectosphere 270 grams, ball handle length 8 centimetres, ball handle width 9 centimetres, spheroid length 130 centimetres; The quality of interior ball 1550 grams.
Embodiment 6
1, the composition of meteorological balloon
Centrifugal concentrating natural rubber latex 100 parts, 0.30 part, potassium hydroxide, casein 0.1 part, paregal O (alkylpolyoxyethylene) 0.15 part, 2 parts, sulphur, antioxidant D (N-phenyl-2-naphthylamine) 1 part, PX(Ethyl-phenyl-zinc dithiocarbamate) 1.5 parts, 4010NA(N-phenyl-N '-sec.-propyl-Ursol D) 1 part, 3 parts, zinc oxide, machinery oil weight ratio is 5.0 parts, emulsified olefin 7 parts;
2, preparation method
(1) composition is prepared
S1, sulphur, antioxidant D, 4010NA, PX and zinc oxide are made water dispersion;
S2, potassium hydroxide, casein and paregal O are mixed with solution;
S3, machinery oil and emulsified olefin are mixed with milk sap;
S4, water dispersion and solution to be added in concentrated natural latex, and then add milk sap, mixing and stirring obtains composition.
(2) meteorological balloon is prepared
1, mould dipping: balloon mould is flooded in peptizer;
2, pad pasting: mould surface being stained with peptizer soaks in the composition of configuration, makes composition stick uniformly on balloon mould;
3, solidify the demoulding: the balloon mould surface drying being stained with composition is placed in hot water and soaks the demoulding, and the balloon blank after the demoulding to be placed in water temperature be that the tank of 20-30 DEG C soaks 40-50 minute;
4, aeration settling: balloon blank is inflated and shapes, after venting, also sulfuration forms the ectosphere of meteorological balloon, and this ectosphere parks more than one month;
5, form meteorological balloon: adopt existing meteorological balloon as interior ball, and place it in the ectosphere interior formation built-up type meteorological balloon A6 obtained in step 4.
The quality of ectosphere 330 grams, ball handle length 10 centimetres, ball handle width 10 centimetres, spheroid length 140 centimetres; The quality of interior ball 1650 grams.
Comparative example 1
Be that method in CN102352060A prepares meteorological balloon CA1 with publication number.
Testing method and data
1, meteorological balloon A1-A3 and CA1 is discharged in the Changsha of 2013.2.28.19 rainy weather simultaneously, test the wicking height that it is final, the results are shown in Table 1.
2, interior ball discharges separately and discharges with combined spheres A1-A6 contrast by the rainy day, tests its lift-off height, the results are shown in Table 2.
3, weather station discharges situation
Meteorological balloon: A1 ball
Time: 2013.2-2013.4;
Place: Changsha
Weather conditions: meteorological conditions is relatively more severe, and rainwater, strong wind weather are many.
Specifically discharge data in table 3.
4, weather station discharges situation
Meteorological balloon: A4 ball
Time: 2013.2-2013.3;
Place: Changsha
Weather conditions: meteorological conditions is relatively more severe, and rainwater, strong wind weather are many.
Specifically discharge data in table 4.
Table 1
Final height (m)
A1 33587
A2 31845
A3 30984
CA1 18996
Table 2
Combined spheres Final height (rice) Dan Fangqiu Final height (rice)
A1 30505 Ball in A1 28323
A2 31230 Ball in A2 18560
A3 29879 Ball in A3 20430
A4 34976 Ball in A4 23750
A5 33875 Ball in A5 20165
A6 33795 Ball in A6 28450
Table 3
Time Weather conditions Interior ball lifting force Total lifting force Ectosphere height of burst degree Final height
2013.2.28.19 Rain 1.65 2.21 14500 33587
2013.3.1.07 Rain 2.38 3.15 13000 31506
2013.3.1.19 Rain 2.02 2.83 10000 31307
2013.3.17.19 Rain 1.72 2.85 10500 32230
2013.3.19.12 Rain 1.50 2.93 12000 34100
2013.3.22.19 Rain 1.60 2.85 11000 31915
2013.3.23.07 Rain 1.68 2.94 6000 31171
2013.3.23.19 Rain 1.72 2.97 10500 24315
2013.3.26.01 Rain 1.81 2.89 9000 30848
2013.3.26.19 Rain 2.30 2.72 9500 29908
2013.3.29.19 Rain 2.26 3.05 9000 32432
2013.3.31.19 Rain 2.60 3.03 10500 30506
2013.3.23 Rain / / 11000 34804
2013.3.23 Rain / / / 32692
2013.4.19 Rain 2.60 3.0 11000 29538
2013.2.19 Rain 2.6 3.05 8000 17895
2013.4.21 Rain 2.35 2.75 9000 28912
Table 4
Time Weather conditions Interior ball lifting force Total lifting force Ectosphere height of burst degree Final height
2013.2.28.19 Rain 2.10 2.92 12000 36500
2013.3.1.07 Rain 2.08 3.15 9500 35120
2013.3.1.19 Rain 2.02 3.15 10000 33489
2013.3.17.19 Rain 2.40 3.25 11000 35189
2013.3.19.12 Rain 2.00 2.93 10500 35975
2013.3.22.19 Rain 2.15 3.06 10000 24023
2013.3.23.07 Rain 2.10 2.94 8700 34870
2013.3.23.19 Rain 2.30 2.97 9000 36070
2013.3.26.01 Rain 2.28 3.40 9500 34496
2013.3.26.19 Rain 2.16 3.35 10500 32678
2013.3.29.19 Rain 2.26 3.05 9500 33109
2013.3.31.19 Rain 2.35 3.03 11500 30257
As can be seen from Table 1, in the present invention, the wicking height of the built-up type meteorological balloon of specification 750 grams reaches more than 26000 meters, and the height of the meteorological balloon of comparative example only has 18996 meters.
As can be seen from Table 2, ectosphere internal ball when the rainy day discharges of combined spheres has significant protective effect, effectively can improve its height.
As can be seen from Table 3, what the built-up type meteorological balloon of interior gauge ball lattice 750 grams carried out under the adverse weather condition of Changsha discharges experiment, average lift-off highly reaches 30450 meters, lift-off highly reaches 26000 meters efficient, and (it is highly 26000 meters that 750 grams of billiard table stations require that the rainy days discharge, more than 26000 meters efficient divided by being of obtaining of sum) be 88.2%, reach the requirement at present to meteorological balloon.
As can be seen from Table 4, what the built-up type meteorological balloon of interior gauge ball lattice 1600 grams carried out under the adverse weather condition of Changsha discharges experiment, average lift-off highly reaches 33481 meters, lift-off highly reaches 30000 meters efficient, and (it is highly 30000 meters that 1600 grams of billiard table stations require that the rainy days discharge, more than 30000 meters efficient divided by being of obtaining of sum) be 91.7%, reach the requirement at present to meteorological balloon.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.

Claims (7)

1. a meteorological balloon, is characterized in that, described meteorological balloon comprises following component and weight part:
Centrifugal concentrating natural rubber latex 100 parts
0 ~ 0.30 part, potassium hydroxide
Casein 0 ~ 0.2 part
Paregal O 0 ~ 0.15 part
1 ~ 2 part, sulphur
N-phenyl-2-naphthylamine 1 ~ 2 part
Ethyl-phenyl-zinc dithiocarbamate 1 ~ 2 part
N-phenyl-N '-sec.-propyl-Ursol D 1 ~ 2 part
0.5 ~ 3 part, zinc oxide
3 ~ 5 parts, machinery oil
Emulsified olefin 3 ~ 7 parts
Polychloroprene latex 5 ~ 15 parts
The preparation method of described meteorological balloon comprises the steps:
S1, sulphur, N-phenyl-2-naphthylamine, N-phenyl-N '-sec.-propyl-Ursol D, Ethyl-phenyl-zinc dithiocarbamate and zinc oxide are made water dispersion;
S2, potassium hydroxide, casein and paregal O are mixed with solution;
S3, machinery oil and emulsified olefin are mixed with milk sap;
S4, water dispersion and solution to be added in concentrated natural latex, and then add milk sap, mixing and stirring, obtain composition; Add polychloroprene latex in the composition;
S5, composition is prepared meteorological balloon, described meteorological balloon parks more than one month.
2. meteorological balloon as claimed in claim 1, it is characterized in that, the content of described emulsified olefin is 4 ~ 5 weight parts.
3. meteorological balloon as claimed in claim 1, it is characterized in that, the quality of described meteorological balloon 700 ~ 800 grams, ball handle length is 13 ~ 16 centimetres, ball handle width 8 ~ 10 centimetres, and spheroid length is 210 ~ 250 centimetres.
4. meteorological balloon as claimed in claim 1, it is characterized in that, the quality of described meteorological balloon 1550 ~ 1650 grams, ball handle length is 12 ~ 16 centimetres, ball handle width 9 ~ 13 centimetres, and spheroid length is 305 ~ 355 centimetres.
5. a built-up type meteorological balloon, is characterized in that, described built-up type meteorological balloon comprises ectosphere and position interior ball in the inner, and described ectosphere is the meteorological balloon described in claim 1-3 any one.
6. built-up type meteorological balloon as claimed in claim 5, it is characterized in that, the quality of described ectosphere is 85 ~ 115 grams, and ball handle length is 8 ~ 11 centimetres, ball handle width 8 ~ 10 centimetres, and spheroid length is 57 ~ 69 centimetres, and the quality of described interior ball is 700 ~ 800 grams.
7. built-up type meteorological balloon as claimed in claim 5, it is characterized in that, the quality of described ectosphere is 270 ~ 330 grams, and ball handle length is 8 ~ 11 centimetres, ball handle width 9 ~ 11 centimetres, and spheroid length is 130 ~ 150 centimetres, and the quality of described interior ball is 1550 ~ 1650 grams.
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