CN103451973B - The Health shoulder pad of far infrared fabric, its preparation method and preparation thereof - Google Patents

The Health shoulder pad of far infrared fabric, its preparation method and preparation thereof Download PDF

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Publication number
CN103451973B
CN103451973B CN201310395532.5A CN201310395532A CN103451973B CN 103451973 B CN103451973 B CN 103451973B CN 201310395532 A CN201310395532 A CN 201310395532A CN 103451973 B CN103451973 B CN 103451973B
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China
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far infrared
infrared fabric
fabric
aqueous white
shoulder pad
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Expired - Fee Related
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CN201310395532.5A
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CN103451973A (en
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洪一清
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SHANGHAI BOSHUN APPAREL Co Ltd
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SHANGHAI BOSHUN APPAREL Co Ltd
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Abstract

The invention discloses a kind of far infrared fabric, comprise the component of following weight parts: 0-55 part aqueous white rubber cement, 20-40 part aqueous white foaming slurry, 0-10 part aqueous color paste, 15-50 part far infrared solid magnetic.Present invention also offers the preparation method of described far infrared fabric, and the Health shoulder pad be made up of described far infrared fabric.Far infrared fabric of the present invention, can activate the activity of large biological molecule, promotes and improves blood circulation, increases metabolism, improves immune function of human body, possesses good health care.Health shoulder pad of the present invention, aims at shoulder heating design, is applicable to working clan, pregnant woman, sportsman and omarthritis patient.

Description

The Health shoulder pad of far infrared fabric, its preparation method and preparation thereof
Technical field
The present invention relates to a kind of far infrared fabric, its preparation method and Health shoulder pad thereof.
Background technology
At present, the cotton that the shoulder protector that market exists is normally simple or terylene quality, its technique is simple, but style is old.In addition, only there is ornamental and effect that is warmth retention property, and do not possess health care in existing shoulder protector.
This year studies discovery, the fuel factor of far infrared technology and non-thermal effect can treat the various diseases such as rheumatic Bi syndrome, ischemic disease, chronic inflammation, and also have positive effect in prevention diabetic complication, preventing cold, anti-ageing, dispelling fatigue, beauty and skin care, Weight-reducing and lipid-lowering etc.Famous ZhouLin frequency spectrum instrument and Kang Yi health-care bedding also utilize the far-infrared therapeutic disease of 8-15 μm just to have had ten hundreds of consumers to prove, achieve good result for the treatment of.
But far infrared technology is applied to textiles, and application is unsatisfactory at present, and a part of reason is that the emissivity of the far infrared of 8-15 μm is lower, does not reach desirable health care or result for the treatment of; A part reason be textiles after the processes such as washing, the particle with emitting far-infrared effect comes off, and reduces service life.
Summary of the invention
For solving the problem, one of technical problem solved by the invention is to provide a kind of far infrared fabric.
This goal of the invention is achieved by the following technical solution:
A kind of far infrared fabric, comprises the component of following weight parts: 0-55 part aqueous white rubber cement, 20-40 part aqueous white foaming slurry, 0-10 part aqueous color paste, 15-50 part far infrared solid magnetic.
Preferably, described far infrared fabric, comprises the component of following weight parts: 30-50 part aqueous white rubber cement, 20-40 part aqueous white foaming slurry, 2-8 part aqueous color paste, 15-30 part far infrared solid magnetic.
Preferably, described far infrared solid magnetic, is selected from the one in medical stone, germanite, limonite and potassic feldspar or its mixture.
Preferred again, described far infrared solid magnetic, is made up of by weight following component: medical stone 60-80 part, germanite 10-20 part, limonite 10-25 part, potassic feldspar 1-8 part.
After medical stone, germanite, limonite, potassic feldspar are pulverized respectively, cross 200-2000 mesh sieve, mix, obtain far infrared solid magnetic.
Two of this technical problem solved by the invention is to provide the preparation method of described far infrared fabric, and it comprises the steps:
(1) by aqueous white rubber cement, aqueous white foaming slurry, aqueous color paste, far infrared solid magnetic mixes, and stirs;
(2) by mixed for step (1) slurries stamp on base cloth, circulation dry 0.5-3 hour;
(3) at 140-170 DEG C, hot pressure 5-8 second.
Wherein step (2) described drying mode is preferably and adopts mobile drying machine to move left and right oven dry.
In the present invention,
Described aqueous white rubber cement, can by buying or preparing acquisition.Its composition can comprise resin, filler, dispersant, thickener, aqueous solvent etc.Wherein a kind of formula is: 40-70 parts by weight resin, 10-30 parts by weight of filler, 1-5 parts per weight dispersing agent, 1-5 parts by weight of thickening agent, 10-40 weight parts water.Described resin can comprise polyethylene (PE) resin, polyvinyl chloride (PVC) resin, styrene resin, vinyl acetate (EVA) resin, water-based PU resin, waterborne polyurethane resin etc.; Described filler comprises silica flour, titanium dioxide etc.; Described dispersant comprises fatty acid, aliphatic amide type and ester class, atoleine class etc., is specifically as follows ethylene group bis-stearamides (EBS), glyceryl monostearate (GMS), glyceryl tristearate (HTG) etc.; Described thickener comprises polyacrylic, cellulose ethers, alkali-soluble acrylic, non-ionic associative type polyurethane class, be specifically as follows ASE-60, TT-935, RM-2020NPR, Carboxymethyl Cellulose, hydroxyethylcellulose, hydroxypropyl cellulose, cetyl hydroxyethyl cellulose (HMHEC) etc.
Described aqueous white foaming slurry, can by buying or preparing acquisition.Its composition can comprise resin, blowing agent, titanium dioxide and aqueous solvent etc.Wherein a kind of formula can be: 50-80 parts by weight resin, 1-8 weight portion titanium dioxide, 5-15 parts by weight of blowing agent, 10-40 weight parts water.Described resin can for comprising polyethylene (PE) resin, polyvinyl chloride (PVC) resin, styrene resin, vinyl acetate (EVA) resin, water-based PU resin, waterborne polyurethane resin etc.; Described blowing agent comprises dodecyl sodium sulfate (K12), sodium sulfate of polyethenoxy ether of fatty alcohol (AES), magnesium carbonate, calcium carbonate, sodium bicarbonate, sodium metasilicate, lauric acid diethyl amide, ethoxylated dodecyl alcohol etc.
Described aqueous color paste take water as the paint filler slurry that medium adds surfactant-dispersed.Can by buying or preparing acquisition.Wherein, surfactant can be dodecyl sodium sulfate, two sodium isobutyl naphthalene sulfonate, dispersing agent MF, sodium methylene bis-naphthalene sulfonate, ethoxylated dodecyl alcohol, fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether etc.Pigment is a kind of coloring matter of fine powder, generally water insoluble, oily and solvent, but can be dispersed in wherein uniformly, can carry out the selection of color as required.
Described medical stone, another name: long-lived stone, health-care stone, refining mountain stone, gingival cyst of mucous gland in the newborn sand, bean dregs stone.Medical stone is a kind of to biological nontoxic, harmless and have certain bioactive complex mineral or medicinal rock.It is the granitic rock of class half weathering.The main chemical compositions of medical stone is inorganic alumino-silicate.Comprising SiO 2, Al 2o 3, Fe 2o 3, FeO, MgO, CaO, K 2o, Na 2o, TiO 2, P 2o 5, MnO etc., also containing the whole macroelements needed for animal, as the trace element such as K, Na, Ca, Mg, Cu, Mo and rare earth element, about 58 kinds more than.
Described germanite is the class ore containing Ge element.Germanium is greyish-silver crystals, fusing point 937.4 DEG C, boiling point 2830 DEG C, density 5.35 gram per centimeter 3, hardness 6 ~ 6.5 is a kind of rare metals, important semi-conducting material, and under room temperature, crystal germanium matter is crisp; There is obvious nonmetal character.Germanium, atomic number 32, atomic weight 72.61.
Described limonite, limonite is a kind of very rare hollow stone, and formal name used at school " too a surplus grain ", " aetite ", " in stone yellow son ", be commonly called as " stone of reviving after death ", " phoenix egg ".Limonite originates in steamed bun mountain, Changqing District, Jinan, Shandong Province city, and be a kind of stone of hollow, its shape differs in size, and comes in every shape, and generally has cavity, and what in chamber, thing had is egg nucleus shape, and what have is powder or liquid, and hand or striking energy sends the interesting to listen to sound.Shell quality is hard, fine and smooth, usually in beans shape, also has stalactitic, bulk etc.; Surface is drabon look, orange-yellow, aubergine or black; Semimetallic lustre, fresh section is shell shape; Mohs hardness about 5.5, proportion 3.6.The mineral composition of limonite is limonite, and from 20% to 78% not etc., other impurity is often phosphate, also has a small amount of metasilicate, Yi Jisi, molybdenum, lithium, zinc, selenium and other trace elements for the content of Fe2O3.
Described potassic feldspar, is the aluminium silicate mineral of the alkali metal such as a class potassium, sodium, calcium or alkaline-earth metal, is also feldspar race mineral, usually also claims orthoclase, belongs to monoclinic system, is flesh pink usually, is white or grey.Density 2.54-2.57g/cm 3, proportion 2.56 ~ 2.59g/cm 3, hardness 6, its theoretical composition is SiO 264.7%, Al 2o 318.4%, K 2o16.9%.
Far infrared fabric of the present invention, can activate the activity of large biological molecule, promotes and improves blood circulation, increases metabolism, improves immune function of human body, possesses good health care.
Wherein, aqueous white rubber cement makes printing technology have elasticity and can increase the fastness of stamp; Aqueous white foaming slurry has foaming effect after passing through oven dry, press process after stamp, has obvious stereoeffect; Aqueous color paste has toning effect; Far infrared solid magnetic has negative CATION, heat accumulation thermal, promotes blood circulation of human body, has health care.
Three of technical problem solved by the invention is to provide a kind of Health shoulder pad be made up of described far infrared fabric, and it comprises blend fibre surface layer and polyester fiber nexine, and described blend fibre surface layer and described polyester fiber nexine are weaved and formed;
The surface of described blend fibre surface layer is sewed with warming portion, described warming portion is four-layer structure, and the spring Asia being followed successively by the hot air cotton of contiguous described blend fibre surface layer, the gum sprayed cotton of contiguous described hot air cotton, the spun-bonded non-woven fabrics of contiguous described gum sprayed cotton and contiguous described spun-bonded non-woven fabrics is spun;
The surface of described polyester fiber nexine is sewed with described far infrared fabric.
Preferably, described blend fibre surface layer is formed by modified polyester fiber and regenerated celulose fibre blending.
Preferably, described polyester fiber nexine is coral fleece structure.
Preferably, described gum sprayed cotton is formed by wool and polyester fiber blending.
Preferably, the weight of described spun-bonded non-woven fabrics is 10-11 gram every square metre.
Preferably, described hot air cotton is polyester fiber, and weight is 23-25 gram every square metre.
Health shoulder pad of the present invention, the surface of blend fibre surface layer is made warming portion, improves the integral heat insulation performance of far infrared health care shoulder protector.Far infrared fabric is made on the surface of polyester fiber nexine, the activity of large biological molecule can be activated, promote and improve blood circulation, increase metabolism, improve immune function of human body, possess good health care.
Health shoulder pad of the present invention, aims at shoulder heating design, is applicable to working clan, pregnant woman, sportsman and omarthritis patient.
Accompanying drawing explanation
Fig. 1 is the structural representation of the utility model far infrared health care shoulder protector;
Fig. 2 is that the A-A of Fig. 1 is to sectional view;
Fig. 3 is the partial enlarged drawing of part B in Fig. 2.
Detailed description of the invention
Embodiment 1 far infrared solid magnetic
Take each raw material according to embodiment 1 data corresponding in table 1, raw material is pulverized respectively, after crossing 1250 mesh sieves, mix, obtain the far infrared solid magnetic of embodiment 1.
Table 1: far infrared solid magnetic formula table unit: kilogram
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Medical stone 70 / 70 70
Germanite 15 15 / 15
Limonite 20 20 20 /
Potassic feldspar 5 5 5 5
Embodiment 2 far infrared solid magnetic
Take each raw material according to embodiment 2 data corresponding in table 1, according to method described in embodiment 1, obtain the far infrared solid magnetic of embodiment 2.
Embodiment 3 far infrared solid magnetic
Take each raw material according to embodiment 3 data corresponding in table 1, according to method described in embodiment 1, obtain the far infrared solid magnetic of embodiment 3.
Embodiment 4 far infrared solid magnetic
Take each raw material according to embodiment 4 data corresponding in table 1, according to method described in embodiment 1, obtain the far infrared solid magnetic of embodiment 4.
Embodiment 5 far infrared fabric
By 45 kilograms of water-based white size slurries, 30 kilograms of aqueous white foaming slurries, 5 kilograms of aqueous color pastes, the far infrared solid magnetic mixing of 20 kilograms of embodiments 1, stirs; Mixed slurries stamp, on base cloth, mobile drying machine moves left and right circulation oven dry 1 hour; At 150 DEG C, hot pressure 8 seconds, obtains the far infrared fabric of embodiment 5.
Embodiment 6 far infrared fabric
By 45 kilograms of water-based white size slurries, 30 kilograms of aqueous white foaming slurries, 5 kilograms of aqueous color pastes, the far infrared solid magnetic mixing of 20 kilograms of embodiments 2, stirs; Mixed slurries stamp, on base cloth, mobile drying machine moves left and right circulation oven dry 1 hour; At 150 DEG C, hot pressure 8 seconds, obtains the far infrared fabric of embodiment 6.
Embodiment 7 far infrared fabric
By 45 kilograms of water-based white size slurries, 30 kilograms of aqueous white foaming slurries, 5 kilograms of aqueous color pastes, the far infrared solid magnetic mixing of 20 kilograms of embodiments 3, stirs; Mixed slurries stamp, on base cloth, mobile drying machine moves left and right circulation oven dry 1 hour; At 150 DEG C, hot pressure 8 seconds, obtains the far infrared fabric of embodiment 7.
Embodiment 8 far infrared fabric
By 45 kilograms of water-based white size slurries, 30 kilograms of aqueous white foaming slurries, 5 kilograms of aqueous color pastes, the far infrared solid magnetic mixing of 20 kilograms of embodiments 4, stirs; Mixed slurries stamp, on base cloth, mobile drying machine moves left and right circulation oven dry 1 hour; At 150 DEG C, hot pressure 8 seconds, obtains the far infrared fabric of embodiment 8.
The PVA glue-2800 that the aqueous white rubber cement used in embodiment 5-8 is produced for science and technology Guan Lie Co., Ltd of Dongguan, Guangdong city three, aqueous white foaming slurry is the foaming slurry-8200 that Shanghai ink Si Lian Chemical Co., Ltd. produces, and aqueous color paste is the mill base-8205 that Shanghai ink Si Lian Chemical Co., Ltd. produces.
Embodiment 9 Health shoulder pad
As shown in Figures 1 to 3, far infrared health care shoulder protector of the present invention, comprises blend fibre surface layer 2 and polyester fiber nexine 1, and blend fibre surface layer 2 and polyester fiber nexine 1 are weaved and formed.Wherein, connecting line can be polyester fiber, also can be polyester fiber and spandex blending, and the latter makes far infrared health care shoulder protector entirety more comfortable, has more elasticity.Blend fibre surface layer 2 is preferably conventional modified polyester fiber and regenerated celulose fibre blending, and its concrete percentage by weight can be 30% modified polyester fiber and 70% regenerated celulose fibre.
For improving the warmth retention property of this far infrared health care shoulder protector, the surface of blend fibre surface layer 2 is sewed with warming portion 3, the area in warming portion 3 can be less than the area of blend fibre surface layer 2, it is made only to cover in part hybrid fibrous face layer 2, as shown in Figure 1, warming portion 3 is only arranged on the upside of Health shoulder pad, near the position of shoulder.This warming portion 3 is four-layer structure, and the spring Asia being followed successively by the hot air cotton 301 of contiguous blend fibre surface layer 2, the gum sprayed cotton 302 of contiguous hot air cotton 301, the spun-bonded non-woven fabrics 303 of contiguous gum sprayed cotton 302 and contiguous spun-bonded non-woven fabrics 303 spins 304.As shown in Figure 3, hot air cotton 301 is positioned at outside blend fibre surface layer 2, and gum sprayed cotton 302 is positioned at outside hot air cotton 301, and spun-bonded non-woven fabrics 303 is positioned at outside gum sprayed cotton 302, and spring Asia is spun 304 and is positioned at outside spun-bonded non-woven fabrics 303.
Described gum sprayed cotton, also known as spraying-bonded wadding, is the one of non-weaving cloth, namely usually said space wadding or vacuum cotton, and it is by natural cotton fiber, and artificial fibre or synthetic fiber are through drawing pine, combing, glue spraying, curedly processing.
Described spun-bonded non-woven fabrics is conventional material, that is: by polymer-extruded, stretching, after forming continuous filament yarn, long filament is laid to net, and fibre web through self bonding, heat bonding, chemical adhesion or mechanical consolidation method, makes fibre web become nonwoven fabric again.
Described spring Asia is spun and is commonly called as waterproof cloth, also can be coating nylon shioze.Its cloth cover is flat very smooth, light and strong wear-resisting, the elastic force of quality and glossiness good, do not contract, easily wash, quick-drying, good hand touch.
The surface of polyester fiber nexine 1 is sewed with the far infrared fabric 4 that embodiment 5 is obtained, far infrared fabric 4 can generate heat, and has good health-care effect to shoulder.From the preparation method of embodiment 5, far infrared fabric 4 comprises base cloth 401 and slurries 402.
As a kind of preferred embodiment, polyester fiber nexine 1 is coral fleece structure.Coral fleece is comfortable and easy to wear, and can improve the warmth retention property of far infrared health care shoulder protector.
For ensureing the warmth retention property of far infrared health care shoulder protector, gum sprayed cotton 302 is formed by wool and polyester fiber blending, can comprise a large amount of still air when wearing, and warmth retention property by force and easier moisture-inhibiting.Preferred as one, adopt the polyester fiber blending of the wool of 10% percentage by weight and 90% percentage by weight to form.
For reducing the overall weight of far infrared health care shoulder protector, the weight of spun-bonded non-woven fabrics 303 is 10-11 gram every square metre.
Preferred as one, the hot air cotton 301 in the present invention is polyester fiber, and its weight is 23-25 gram every square metre.
The detection of test case 1 far infrared transmissivity
The far infrared fabric of embodiment 5-8 is carried out to the test of far infrared transmissivity, use instrument is IR-1 emissivity measurement instrument, and measure 8-14 μm of spectral regions normal emittance, temperature during measurement is 25 DEG C.The results are shown in Table 2.
Table 2 far infrared fabric far infrared transmissivity
Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8
Emissivity/% 87.1 74.5 80.2 81.6
The detection of test case 2CLO value
The far infrared fabric of embodiment 5-8 is carried out to the test of CLO value, CLO value is commonly used to the thermal resistance value representing clothes, 1CLO value=0.155m 2dEG C/W.CLO value is larger, proves that this fabric thermal property is better.20 DEG C of temperature, in the environment of 60% relative humidity, use 100W light-illuminating 5min, measure the CLO value of far infrared fabric respectively, the results are shown in Table 3.
Table 3 far infrared fabric CLO value
Light application time/min Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8
0 0.98 0.60 0.78 0.82
1 1.76 1.38 1.59 1.66
2 3.02 2.50 2.67 2.88
3 4.20 3.86 3.88 4.03
4 8.32 6.11 7.16 7.29
5 12.95 10.55 11.23 11.08
From table 2, table 3 result, the far infrared fabric that the present invention uses has higher far infrared transmissivity, and higher CLO value, especially the far infrared fabric that the far infrared solid magnetic using medical stone, germanite, limonite and potassic feldspar to carry out proportioning is made, has higher far infrared transmissivity CLO value.
Far infrared fabric of the present invention, can activate the activity of large biological molecule, promotes and improves blood circulation, increases metabolism, improves immune function of human body, possesses good health care.The Health shoulder pad obtained by far infrared fabric of the present invention, aims at shoulder heating design, is applicable to working clan, pregnant woman, sportsman and omarthritis patient.
The above; be only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.

Claims (9)

1. a far infrared fabric, is characterized in that, comprises the component of following weight parts: 0-55 part aqueous white rubber cement, 20-40 part aqueous white foaming slurry, 0-10 part aqueous color paste, 15-50 part far infrared solid magnetic;
Described far infrared solid magnetic, is made up of by weight following component: medical stone 60-80 part, germanite 10-20 part, limonite 10-25 part, potassic feldspar 1-8 part.
2. far infrared fabric as claimed in claim 1, is characterized in that described far infrared fabric comprises the component of following weight parts: 30-50 part aqueous white rubber cement, 20-40 part aqueous white foaming slurry, 2-8 part aqueous color paste, 15-30 part far infrared solid magnetic.
3. far infrared fabric as claimed in claim 1, it is characterized in that, described aqueous white rubber cement comprises the component of following weight parts: 40-70 part resin, 10-30 part filler, 1-5 dispersant, 1-5 part thickener, 10-40 part water.
4. far infrared fabric as claimed in claim 1, is characterized in that, described aqueous white foaming slurry comprises the component of following weight parts: 50-80 part resin, 1-8 part titanium dioxide, 5-15 part blowing agent, 10-40 part water.
5. the preparation method of far infrared fabric according to any one of claim 1-4, it comprises the steps:
(1) by aqueous white rubber cement, aqueous white foaming slurry, aqueous color paste, far infrared solid magnetic mixes, and stirs;
(2) by mixed for step (1) slurries stamp on base cloth, circulation dry 0.5-3 hour;
(3) at 140-170 DEG C, hot pressure 5-8 second.
6. the Health shoulder pad that far infrared fabric is made according to any one of claim 1-4, it comprises blend fibre surface layer and polyester fiber nexine, and described blend fibre surface layer and described polyester fiber nexine are weaved and formed;
The surface of described blend fibre surface layer is sewed with warming portion, described warming portion is four-layer structure, and the spring Asia being followed successively by the hot air cotton of contiguous described blend fibre surface layer, the gum sprayed cotton of contiguous described hot air cotton, the spun-bonded non-woven fabrics of contiguous described gum sprayed cotton and contiguous described spun-bonded non-woven fabrics is spun;
The surface of described polyester fiber nexine is sewed with the far infrared fabric according to any one of claim 1-4.
7. Health shoulder pad as claimed in claim 6, is characterized in that: described polyester fiber nexine is coral fleece structure.
8. Health shoulder pad as claimed in claim 6, is characterized in that: described gum sprayed cotton is formed by wool and polyester fiber blending.
9. the Health shoulder pad according to any one of claim 6-8, is characterized in that: the weight of described spun-bonded non-woven fabrics is 10-11 gram every square metre.
CN201310395532.5A 2013-09-03 2013-09-03 The Health shoulder pad of far infrared fabric, its preparation method and preparation thereof Expired - Fee Related CN103451973B (en)

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CN106929941A (en) * 2015-12-31 2017-07-07 上海水星家用纺织品股份有限公司 The fabric that the preparation method and the fiber of stalactite Chinese medicine mineral fibres are prepared
CN106757480A (en) * 2016-12-15 2017-05-31 江苏易宅软装设计院有限公司 A kind of heat resistance fiber for wallpaper
CN108360276B (en) * 2018-02-06 2021-06-01 江苏明源纺织有限公司 Functional warp beam printing method
CN109463806A (en) * 2018-11-03 2019-03-15 青岛创恩康生物科技有限公司 A kind of Briefs that can be emitting far-infrared
CN113897803B (en) * 2021-11-03 2022-11-22 中国地质大学(北京) Illite mineral composite quick-heating warm-feeling textile and preparation method thereof
CN115976846A (en) * 2022-12-20 2023-04-18 深圳全棉时代科技有限公司 All-cotton double-layer quick-drying warm-keeping fabric and preparation method thereof

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CN2443616Y (en) * 2000-09-13 2001-08-22 上海依福瑞实业有限公司 Shoulder protector
CN102021841A (en) * 2009-09-15 2011-04-20 华懋(厦门)织造染整有限公司 Manufacture method of far infrared technological shell fabric
CN103239426A (en) * 2012-02-01 2013-08-14 上海慈济药业有限公司 Preparation method of far-infrared gel composition and preparation method of gel paste

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Publication number Priority date Publication date Assignee Title
CN2443616Y (en) * 2000-09-13 2001-08-22 上海依福瑞实业有限公司 Shoulder protector
CN102021841A (en) * 2009-09-15 2011-04-20 华懋(厦门)织造染整有限公司 Manufacture method of far infrared technological shell fabric
CN103239426A (en) * 2012-02-01 2013-08-14 上海慈济药业有限公司 Preparation method of far-infrared gel composition and preparation method of gel paste

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