CN103450749A - Hydrocarbon-resistant indoor ultrathin fireproofing coating for steel structures - Google Patents
Hydrocarbon-resistant indoor ultrathin fireproofing coating for steel structures Download PDFInfo
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- CN103450749A CN103450749A CN2013100160699A CN201310016069A CN103450749A CN 103450749 A CN103450749 A CN 103450749A CN 2013100160699 A CN2013100160699 A CN 2013100160699A CN 201310016069 A CN201310016069 A CN 201310016069A CN 103450749 A CN103450749 A CN 103450749A
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Abstract
The invention provides a hydrocarbon-resistant indoor ultrathin fireproofing coating for steel structures. The fireproofing coating consists a component A and a component B, wherein the component A is composed of highly chlorinated polyethylene, TBBP, ammonium polyphosphate, melamine, pentaerythritol, antimonous oxide, chlorinated paraffin, titanium dioxide and a mixed solvent, and the component B is polyamide 300#, and the components A and B are mixed at 1.5:(9-10) in percentage by mass. The fireproofing coating has characteristics of strong adhesion force, good film forming performance, excellent combustion and expansion, high hardness of carbon layer, being anti-corrosive and anti-rust, hydrocarbon fire resistance and the like, and the fireproofing coating is free from toxicity, smell and release of harmful gas.
Description
Technical field
The present invention relates to the metal coating material technical field, be specifically related to the indoor ultrathin steel structure of anti-hydro carbons frie retardant coating.
Background technology
The framework of modernization high level and heavy construction adopts steel construction mostly, but steel exist as material of construction the defect that is difficult to avoid aspect fire prevention, as yield-point, stretch-proof and Young's modulus etc. all can sharply descend because of the rising of temperature, thereby lose supporting capacity, very easily cause collapsing of buildings.Therefore, usually need to coat frie retardant coating to structural steel, guarantee construction quality and wearing quality.
Existing steel structure fire-proof paint kind is more, mainly by coat-thickness, is divided into thick type, slim and ultrathin three classes, and wherein slim and ultra-thin fire-resistant coating, because fire resistance and decorate properties are preferably arranged, becomes the developing direction of frie retardant coating.
Hydrocarbon fire and general building fire have very large difference, have the advantages that propagation of flame and heat-up rate are exceedingly fast, and fire scene temperature can rise to rapidly more than 1000 ℃.And the frie retardant coating of selling on market can not reach the requirement of anti-hydrocarbon fire usually.
At present, the batching of the super-thin steel structure fire-proof paint of China mainly comprises ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane and mineral filler, and filmogen mainly comprises aqueous polymer emulsion, water-soluble polymeric resin and solvent based polymer resin.Although its good combination property, exist and waste resource, contaminate environment, infringement health of human body, have the shortcomings such as potential safety hazard, range of application is subject to certain limitation; And when hydrocarbon fire occurs, the filmogen of these frie retardant coatings can not bear the temperature sharply raise and be burnt very soon, and can not play the effect of anti-hydrocarbon fire.
Summary of the invention
The objective of the invention is for a kind of indoor super-thin steel structure fire-proof paint with high cohesive strength, high adhesive force, weathering resistance, anticorrosion, antirust, fire of anti-the hydro carbons is provided.
The present invention realizes that the technical scheme that goal of the invention adopts is: the indoor ultrathin steel structure of anti-hydro carbons frie retardant coating, raw material forms and comprises A component and B component, wherein the A component comprises highly-chlorinated polyethylene, tetrabromobisphenol, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane, antimonous oxide, clorafin, titanium dioxide, mixed solvent, and the B component is kymene 00#; A, B two components are by 1.5: (9~10) mass ratio mixes;
In the A component by mass percentage each component content be constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: (0.5~0.8): (0.5~0.8): (1~1.2).
The invention has the beneficial effects as follows:
(1) coating adhesion is strong, film forming properties good, burning expansion is excellent, carbon-coating hardness is high, antiseptic and rustproof, the fire of anti-the hydro carbons;
(2) environmental protection: nontoxic, tasteless, discharge without obnoxious flavour.
Embodiment
The indoor ultrathin steel structure of anti-hydro carbons frie retardant coating, raw material forms and comprises A component and B component, wherein the A component comprises highly-chlorinated polyethylene, tetrabromobisphenol, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane, antimonous oxide, clorafin, titanium dioxide, mixed solvent, and the B component is kymene 00#; A, B two components are by 1.5: (9.0~10.0) mass ratio mixes;
In the A component by mass percentage each component content be constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: (0.5~0.8): (0.5~0.8): (1~1.2).
Embodiment 1
The indoor ultrathin steel structure of anti-hydro carbons frie retardant coating, raw material forms and comprises A component and B component, wherein the A component comprises highly-chlorinated polyethylene, tetrabromobisphenol, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane, antimonous oxide, clorafin, titanium dioxide, mixed solvent, and the B component is kymene 00#; A, B two components mix by 1.5: 9.2 mass ratioes;
In the A component by mass percentage each component content be constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: 0.6: 0.5: 1.
Embodiment 2
The indoor ultrathin steel structure of anti-hydro carbons frie retardant coating, raw material forms and comprises A component and B component, wherein the A component comprises highly-chlorinated polyethylene, tetrabromobisphenol, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane, antimonous oxide, clorafin, titanium dioxide, mixed solvent, and the B component is kymene 00#; A, B two components mix by 1.5: 9.4 mass ratioes;
In the A component by mass percentage each component content be constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: 0.5: 0.7: 1.2.
Embodiment 3
The indoor ultrathin steel structure of anti-hydro carbons frie retardant coating, raw material forms and comprises A component and B component, wherein the A component comprises highly-chlorinated polyethylene, tetrabromobisphenol, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane, antimonous oxide, clorafin, titanium dioxide, mixed solvent, and the B component is kymene 00#; A, B two components mix by 1.5: 9.8 mass ratioes;
In the A component by mass percentage each component content be constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: (0.5~0.8): (0.5~0.8): (1~1.2).
Embodiment 4
The indoor ultrathin steel structure of anti-hydro carbons frie retardant coating, raw material forms and comprises A component and B component, wherein the A component comprises highly-chlorinated polyethylene, tetrabromobisphenol, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane, antimonous oxide, clorafin, titanium dioxide, mixed solvent, and the B component is kymene 00#; A, B two components mix by 1.5: 10.0 mass ratioes;
In the A component by mass percentage each component content be constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: 0.7: 0.8: 1.2.
Embodiment 5
The indoor ultrathin steel structure of anti-hydro carbons frie retardant coating, raw material forms and comprises A component and B component, wherein the A component comprises highly-chlorinated polyethylene, tetrabromobisphenol, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane, antimonous oxide, clorafin, titanium dioxide, mixed solvent, and the B component is kymene 00#;
A, B two components mix by 1.5: 9.6 mass ratioes;
In the A component by mass percentage each component content be constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: 0.6: 0.6: 1.1.
After testing, salient features is as follows in the present invention:
By GB14907-2002 " steel structure fire-proof paint ", test, the performance index of the water-based indoor ultrathin steel structure of anti-hydro carbons frie retardant coating of development see the following form:
Claims (6)
1. the indoor ultrathin steel structure of anti-hydro carbons frie retardant coating, it is characterized in that: raw material forms and comprises A component and B component, wherein the A component comprises highly-chlorinated polyethylene, tetrabromobisphenol, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane, antimonous oxide, clorafin, titanium dioxide, mixed solvent, and the B component is kymene 00#; A, B two components are by 1.5: (9.0~10.0) mass ratio mixes;
In the A component by mass percentage each component content be constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: (0.5~0.8): (0.5~0.8): (1~1.2).
2. the indoor ultrathin steel structure of anti-hydro carbons frie retardant coating according to claim 1 is characterized in that: during described raw material forms, A, B two components mix in the A component each component content by mass percentage by 1.5: 9.6 mass ratioes and are constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: 0.6: 0.6: 1.1.
3. the indoor ultrathin steel structure of anti-hydro carbons frie retardant coating according to claim 1 is characterized in that: during described raw material forms, A, B two components mix by 1.5: 9.2 mass ratioes;
In the A component by mass percentage each component content be constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: 0.6: 0.5: 1.
4. the indoor ultrathin steel structure of anti-hydro carbons frie retardant coating according to claim 1 is characterized in that: during described raw material forms, A, B two components mix by 1.5: 9.4 mass ratioes;
In the A component by mass percentage each component content be constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: 0.5: 0.7: 1.2.
5. the indoor ultrathin steel structure of anti-hydro carbons frie retardant coating according to claim 1 is characterized in that: during described raw material forms, A, B two components mix by 1.5: 9.8 mass ratioes;
In the A component by mass percentage each component content be constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: (0.5~0.8): (0.5~0.8): (1~1.2).
6. the indoor ultrathin steel structure of anti-hydro carbons frie retardant coating according to claim 1 is characterized in that: during described raw material forms, A, B two components mix by 1.5: 10.0 mass ratioes;
In the A component by mass percentage each component content be constructed as follows:
Wherein mixed solvent comprises: pimelinketone: butanols: N-BUTYL ACETATE: vinyl acetic monomer, mass ratio is: 1: 0.7: 0.8: 1.2.
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Cited By (1)
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CN107216811A (en) * | 2017-07-25 | 2017-09-29 | 苏州文仓乐器有限公司 | A kind of wood furniture seal coat |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1927960A (en) * | 2005-09-05 | 2007-03-14 | 同济大学 | Decorative ultra-thin expansion steel structure fireproof anticorrosion paint and preparation method thereof |
CN101058693A (en) * | 2007-04-13 | 2007-10-24 | 兰州理工大学 | Fireproof paint for super-thin steel structure and preparation method thereof |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1927960A (en) * | 2005-09-05 | 2007-03-14 | 同济大学 | Decorative ultra-thin expansion steel structure fireproof anticorrosion paint and preparation method thereof |
CN101058693A (en) * | 2007-04-13 | 2007-10-24 | 兰州理工大学 | Fireproof paint for super-thin steel structure and preparation method thereof |
Non-Patent Citations (2)
Title |
---|
刘登良: "《涂料工艺 第四版 下册》", 31 January 2010, 化学工业出版社 * |
黄玉媛等: "《涂料配方》", 31 January 2008, 中国纺织出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107216811A (en) * | 2017-07-25 | 2017-09-29 | 苏州文仓乐器有限公司 | A kind of wood furniture seal coat |
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Effective date of registration: 20180731 Address after: 050800 Dong Po Tang Village, Zhengding County, Shijiazhuang, Hebei Patentee after: Shijiazhuang grace Chemical Co., Ltd. Address before: 050800 Dong Po Tang Village, Zhengding County, Shijiazhuang, Hebei Patentee before: Wang Haihui |