CN103444722A - Sterilization composition containing quinoxyfen and triazole - Google Patents
Sterilization composition containing quinoxyfen and triazole Download PDFInfo
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- CN103444722A CN103444722A CN2012101763400A CN201210176340A CN103444722A CN 103444722 A CN103444722 A CN 103444722A CN 2012101763400 A CN2012101763400 A CN 2012101763400A CN 201210176340 A CN201210176340 A CN 201210176340A CN 103444722 A CN103444722 A CN 103444722A
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- Prior art keywords
- benzene oxygen
- oxygen quinoline
- active component
- triazole
- weight ratio
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 42
- 150000003852 triazoles Chemical class 0.000 title claims abstract description 19
- 230000001954 sterilising effect Effects 0.000 title abstract description 6
- 238000004659 sterilization and disinfection Methods 0.000 title abstract description 6
- 239000005831 Quinoxyfen Substances 0.000 title abstract description 4
- WRPIRSINYZBGPK-UHFFFAOYSA-N quinoxyfen Chemical compound C1=CC(F)=CC=C1OC1=CC=NC2=CC(Cl)=CC(Cl)=C12 WRPIRSINYZBGPK-UHFFFAOYSA-N 0.000 title abstract description 4
- 201000010099 disease Diseases 0.000 claims abstract description 38
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 38
- ZMYFCFLJBGAQRS-IRXDYDNUSA-N (2R,3S)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@@]1(CN2N=CN=C2)[C@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IRXDYDNUSA-N 0.000 claims abstract description 20
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000005767 Epoxiconazole Substances 0.000 claims abstract description 20
- 239000005787 Flutriafol Substances 0.000 claims abstract description 20
- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000005760 Difenoconazole Substances 0.000 claims abstract description 19
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- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims abstract description 19
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- 241000221785 Erysiphales Species 0.000 claims description 17
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 17
- 239000011737 fluorine Substances 0.000 claims description 17
- 229910052731 fluorine Inorganic materials 0.000 claims description 17
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- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 abstract description 2
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- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 abstract description 2
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- 229910021641 deionized water Inorganic materials 0.000 description 12
- 231100000820 toxicity test Toxicity 0.000 description 12
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- 206010067482 No adverse event Diseases 0.000 description 9
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- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
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- JSOJVSBOEOWZJX-UHFFFAOYSA-N [O].N1=CC=CC2=CC=CC=C21 Chemical compound [O].N1=CC=CC2=CC=CC=C21 JSOJVSBOEOWZJX-UHFFFAOYSA-N 0.000 description 4
- 230000009471 action Effects 0.000 description 4
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- 230000000855 fungicidal effect Effects 0.000 description 3
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- 238000010008 shearing Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 241000233866 Fungi Species 0.000 description 2
- 229930182558 Sterol Natural products 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
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- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
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- 206010059866 Drug resistance Diseases 0.000 description 1
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- BRYOVJAQXXCUCF-UHFFFAOYSA-N N1=CC=CC2=CC=CC=C12.[O].C1=CC=CC2=CC3=CC=C4C=C5C=CC=CC5=CC4=C3C=C12 Chemical compound N1=CC=CC2=CC=CC=C12.[O].C1=CC=CC2=CC3=CC=C4C=C5C=CC=CC5=CC4=C3C=C12 BRYOVJAQXXCUCF-UHFFFAOYSA-N 0.000 description 1
- 241000233654 Oomycetes Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
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- 235000013339 cereals Nutrition 0.000 description 1
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- -1 chloro-4-quinolyl Chemical group 0.000 description 1
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- 230000008595 infiltration Effects 0.000 description 1
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- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention discloses a sterilization composition containing quinoxyfen and triazole. The sterilization composition contains an active component A and an active component B. The active component A is qinoxyfen. The active component B is a triazole bactericide selected from tetraconazole, triflumizole, hexaconazole, difenoconazole, flutriafol, and epoxiconazole. A weight ratio of the active component A to the active component B is 1: 60 to 80: 1. The sterilization composition containing quinoxyfen and triazole has high activity of treating a plurality of diseases of a plurality of crops, produces obvious synergism, widens a sterilization spectrum, and has the characteristics of small drug dose, rainwater washing resistance and obvious synergism.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of application of bactericidal composition on crop pest containing benzene oxygen quinoline and triazole type.
Technical background
The chloro-4-quinolyl of benzene oxygen quinoline (Quinoxyfen) chemical name: 5,7-bis--4-fluorophenyl ether, molecular formula: C
15h
8cl
2fNO.Benzene oxygen quinoline is systemic fungicide, and has the vapor phase activity, contributes to like this reallocation of medicament whole plant.Benzene oxygen quinoline is the growth signals agent interfering.Research shows, it is not neither the sterol biosynthesis inhibitor is again dhodh inhibitors.This product is protective fungicide, and mobility is good, can suppress the appresorium growth, does not have eradicant action.
The triazole bactericidal agent sterilization wide spectrum-many kinds of disease funguses of sac fungi, basidiomycetes, imperfect fungus are had to very high activity, but to the oomycetes non-activity; Efficiently-drug effect is high, dosage reduces; Lasting period length-blade face 15-20 days, seed treatment is about 80 days, and soil treatment 100 days is all long than general bactericide, and extends with the increase of dosage; Interior suction transporting is good, and infiltration rate is fast, dispenser after 2 hours the absorbed amount of triazolone can suppress the growth of powdery mildew; There is strong preventive effect, therapeutic action preferably, stifling and eradicant action.The mechanism of action, for to affect the sterols biosynthesis, is damaged somatic cells film function.
In the real process of agricultural production, preventing and treating the problem that disease the most easily produces is the generation of disease drug resistance.The different cultivars composition carries out composite, is to prevent and treat the very common method of resistance disease.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, synergy ratio very high composite just still less.Through inventor's research, discovery is mutually composite by benzene oxygen quinoline and tetraconazole, fluorine bacterium azoles, own azoles alcohol, Difenoconazole, Flutriafol, epoxiconazole, good synergistic effect is arranged within the specific limits, and relevant composite about benzene oxygen quinoline and tetraconazole, fluorine bacterium azoles, own azoles alcohol, Difenoconazole, Flutriafol, epoxiconazole, there is not yet relevant report at present at home and abroad.
Summary of the invention
The objective of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good bactericidal composition containing benzene oxygen quinoline and triazole type.
The present invention is achieved through the following technical solutions:
A kind of bactericidal composition containing benzene oxygen quinoline and triazole type, it is characterized in that containing active components A and active component B, active components A and active component B weight ratio are 1 ︰ 60 ~ 80 ︰ 1, described active components A is selected from benzene oxygen quinoline, active component B is triazole bactericidal agent, and described triazole bactericidal agent is selected from following any one compound: a kind of in tetraconazole, fluorine bacterium azoles, own azoles alcohol, Difenoconazole, Flutriafol, epoxiconazole; The preferred weight ratio of active components A and active component B is 1 ︰ 40 ~ 60 ︰ 1; More preferably the weight ratio of benzene oxygen quinoline and tetraconazole is 1 ︰ 10 ~ 30 ︰ 1; The weight ratio of benzene oxygen quinoline and fluorine bacterium azoles or Flutriafol is 1 ︰ 10 ~ 20 ︰ 1; The weight ratio of benzene oxygen quinoline and own azoles alcohol is 1 ︰ 10 ~ 30 ︰ 1; The weight ratio of benzene oxygen quinoline and Difenoconazole or epoxiconazole is 1 ︰ 30 ~ 20 ︰ 1.
The disease of the described bactericidal composition containing benzene oxygen quinoline and triazole type for preventing and treating crop, described crop comprises cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flowers crop, medicinal crop, raw material crop, green manure pasture crop.
Described disease comprises powdery mildew, rust, smut, glume blight, moire disease, banded sclerotial blight, leaf spot, spot defoliation, scab, gray mold, leaf blight, early blight, anthrachose of grape, spot blight, black spot, anthracnose, shot hole.
Amount of application when in the present composition, the content of active component depends on independent use, also depend on mixed ratio and the synergistic effect degree of a kind of compound and another kind of compound, and the while is also relevant with the target disease.Usually in composition, the weight percentage of active component is gross weight 1%～90%, is preferably 5%～80%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1%～60% active substance by weight, is preferably 5%～50%; Solid pharmaceutical preparation contains 5%～80% active substance by weight, is preferably 10%～80%.
At least contain a kind of surfactant in bactericidal composition of the present invention, the dispersion of active component in water while being beneficial to use.Surface-active contents is 2%～30% of total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of bactericidal composition of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, thickener or defoamer.According to different dosage form, in preparation, can also contain stabilizing agent known in those skilled in the art, antifreeze etc.
Bactericidal composition of the present invention can be by the user before use through dilution or directly use.Its preparation can be by processing method known in those skilled in the art preparation, is about to active component and after liquid flux or solid carrier mix, then adds surfactant as one or more in dispersant, stabilizing agent, wetting agent, binding agent, defoamer etc.
Bactericidal composition of the present invention, can be processed into acceptable formulation on any agricultural chemicals on demand.Wherein preferred dosage form is wetting powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
When making wetting powder, composition comprises following component and content: active components A 1% ~ 80%, active component B 1% ~ 60%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, filler surplus.
When making water dispersible granules, composition comprises following component and content: active components A 1% ~ 80%, active component B 1% ~ 60%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, binding agent 0 ~ 8%, filler surplus.
Comprise following component and content when composition is made suspending agent: active components A 1% ~ 50%, active component B 1% ~ 50%, dispersant 1% ~ 10%, wetting agent 1% ~ 10%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
Comprise following component and content when composition is made suspension emulsion: active components A 1% ~ 50%, active component B 1% ~ 50%, emulsifier 1% ~ 10%, dispersant 1% ~ 10%, solvent 1% ~ 20%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
Comprise following component and content when composition is made microemulsion: active components A 1% ~ 50%, active component B1% ~ 50%, emulsifier 3% ~ 25%, solvent 1% ~ 10%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, deionized water add to 100%.
Comprise following component and content when composition is made aqueous emulsion: active components A 1% ~ 50%, active component B 1% ~ 50%, solvent 1% ~ 20%, emulsifier 1% ~ 12%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, deionized water add to 100%.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
The invention has the advantages that: (1) present composition has good synergy and lasting effect within the specific limits, and preventive effect is higher than single dose; (2) the agricultural chemicals dosage reduces, and reduces the residual quantity of agricultural chemicals on crop, alleviates environmental pollution; (3) enlarged fungicidal spectrum, multiple diseases has been had to greater activity as powdery mildew, rust, smut, glume blight, moire disease, banded sclerotial blight, leaf spot, spot defoliation, scab, gray mold, leaf blight, early blight, anthrachose of grape, spot blight, black spot, anthracnose, shot hole.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment all is weight percentage, but the present invention is not limited thereto.
Application Example one
Example 1 ~ 20 wetting powder
Benzene oxygen quinoline, active component B, dispersant, wetting agent, filler are mixed, mix in mixed cylinder, mix again after airslide disintegrating mill is pulverized, can be made into wetting powder product of the present invention.Specifically in Table 1,2.
Table 1 example 1 ~ 10 each component and content
Table 2 example 11 ~ 20 each component and content
Example 21 ~ 38 water dispersible granules
Benzene oxygen quinoline, active component B, dispersant, wetting agent, disintegrant, filler are obtained to the particle diameter needed through air-flow crushing together, then add other auxiliary agent such as binding agent (can add and can not add), obtain the materials of granulating.By item quantitatively send in the fluidized bed granulation dryer through granulation and drying after, make water dispersible granules product of the present invention.Specifically in Table 3.
Table 3 example 21 ~ 38 each component and content
Example 39 ~ 56 suspending agents
Dispersant, wetting agent, thickener (can add and can not add), defoamer, antifreeze (can add and can not add) are mixed through high speed shear, add benzene oxygen quinoline, active component B, supply surplus by deionized water, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make suspending agent product of the present invention.Specifically in Table 4.
Table 4 example 39 ~ 56 each component and content
Example 57 ~ 72 suspension emulsions
Dispersant, defoamer, thickener (can add and can not add), antifreeze (can add and can not add), deionized water are mixed through high speed shear, add benzene oxygen quinoline, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make benzene oxygen quinoline suspending agent, then by tetraconazole or fluorine bacterium azoles or own azoles alcohol or Difenoconazole, solvent, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.
Dispersant, defoamer, thickener (can add and can not add), antifreeze (can add and can not add), deionized water are mixed through high speed shear, add epoxiconazole or Flutriafol, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make epoxiconazole or Flutriafol suspending agent, then by benzene oxygen quinoline, solvent, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.Specifically in Table 5,6,7.
Table 5 example 57 ~ 62 each component and content
Table 6 example 63 ~ 67 each component and content
Table 7 example 68 ~ 72 each component and content
Example 73 ~ 87 aqueous emulsions
Benzene oxygen quinoline, active component B, solvent, emulsifier are added together, make to be dissolved into even oil phase; Deionized water, antifreeze (can add and can not add), thickener (can add and can not add), defoamer are mixed, become the homogeneous water.Under high-speed stirred, water is added to oil phase, make aqueous emulsion product of the present invention.Specifically in Table 8.
Table 8 example 73 ~ 87 each component and content
Table 1 to tetraconazole, fluorine bacterium azoles, own azoles alcohol, Difenoconazole, Flutriafol, epoxiconazole in table 8 exchanged, can make novel formulation.
Example 88 ~ 90 microemulsions
Benzene oxygen quinoline, active component B are dissolved in the homogenizer that solvent is housed, emulsifier, antifreeze (can add and can not add), defoamer are joined in the homogenizer that above-mentioned solution is housed, give strong the mixing and homogenize after supplying surplus by deionized water, finally obtain the as clear as crystal microemulsion product of the present invention of outward appearance.Specifically in Table 9.
Table 9 example 88 ~ 90 each component and content
Example 91 ~ 93 microcapsule suspending agents
By benzene oxygen quinoline, active component B, macromolecule cyst material, solvent, make to be dissolved into even oil phase, under shearing condition, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent, dispersant, defoamer, supply surplus by deionized water, bi-material reacts at oil-water interfaces, forms the macromolecule cyst wall, makes the finely disseminated microcapsule suspending agent product of the present composition.Specifically in Table 10.
Table 10 example 91 ~ 93 each component and content
Example 94 ~ 96 microcapsule suspensions-suspending agent
By tetraconazole or fluorine bacterium azoles or own azoles alcohol or Difenoconazole, macromolecule cyst material, solvent, make to be dissolved into even oil phase, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent under shearing condition, make finely disseminated microcapsule suspending agent.Dispersant, wetting agent, defoamer, thickener (can add and can not add) are mixed through high speed shear, add benzene oxygen quinoline, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make suspending agent, then suspending agent is joined in the aqueous phase solution of micro-capsule suspension, deionized water is supplied surplus, makes the finely disseminated microcapsule suspension of the present composition-suspending agent product.
By benzene oxygen quinoline, macromolecule cyst material, solvent, make to be dissolved into even oil phase, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent under shearing condition, make finely disseminated microcapsule suspending agent.Dispersant, wetting agent, defoamer, thickener (can add and can not add) are mixed through high speed shear, add Flutriafol or epoxiconazole, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make suspending agent, then suspending agent is joined in the aqueous phase solution of micro-capsule suspension, deionized water is supplied surplus, makes the finely disseminated microcapsule suspension of the present composition-suspending agent product.Specifically in Table 11.
Table 11 example 94 ~ 96 each component and content
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First by Toxicity Determination, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR<0.5 is antagonism, and 0.5≤SR≤1.5 are summation action, and SR>1.5 are synergistic effect, on this basis, then carry out field trial.
Test method: after the effective inhibition concentration scope of each medicament is determined in prerun, medicament is established respectively 5 dosage by active constituent content and is processed, and establishes the clear water contrast.Carry out with reference to " farm-chemical indoor determination test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament to the crop germ.Measure colony diameter by the right-angled intersection method after 72h, calculate and respectively process net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into to probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, with method of least squares, tries to achieve virulence regression equation (y=a+bx), and calculates thus the EC of every kind of medicament
50value.Calculate the different proportioning synergy ratio (SR) of two medicaments according to the Wadley method, SR<0.5 is antagonism simultaneously, and 0.5≤SR≤1.5 are summation action, and SR>1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively active components A and active component B shared ratio in combination;
A is benzene oxygen quinoline; B selects a kind of in tetraconazole, fluorine bacterium azoles, own azoles alcohol, Difenoconazole, Flutriafol, epoxiconazole.
Application Example two:
For trying disease: grape powdery mildew; Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd.; Experimental scheme: effective inhibition concentration scope of determining benzene oxygen quinoline and the former medicine of tetraconazole and the two different proportioning mixture through preliminary experiment.
The toxicity test result
The composite analysis of results table of the toxicity test to grape powdery mildew of table 12 benzene oxygen quinoline and tetraconazole
As shown in Table 12, the proportioning of the composite control grape powdery mildew of benzene oxygen quinoline and tetraconazole is when 1 ︰ 60 ~ 80 ︰ 1, synergy ratio SR all is greater than 1.5, illustrate that both are mixed and all show synergistic effect in 1 ︰ 60 ~ 80 ︰ 1 scopes, when the proportioning of benzene oxygen quinoline and tetraconazole during at 1 ︰ 10 ~ 30 ︰ 1, synergistic effect is more outstanding, and synergy ratio all is greater than 2.30.The optimum ratio of finding benzene oxygen quinoline and tetraconazole through test is 30:1,25:1,20:1,15:1,10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:10, especially synergy ratio maximum when benzene oxygen quinoline and tetraconazole weight ratio are 3:1, synergistic effect is the most obvious.
Application Example three:
For trying disease: pear scab; Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd.; Experimental scheme: effective inhibition concentration scope of determining benzene oxygen quinoline and the former medicine of fluorine bacterium azoles and the two different proportioning mixture through preliminary experiment.
The toxicity test result
The composite analysis of results table of the toxicity test to pear scab of table 13 benzene oxygen quinoline and fluorine bacterium azoles
As shown in Table 13, the proportioning of benzene oxygen quinoline and the composite control pear scab of fluorine bacterium azoles is when 1 ︰ 60 ~ 80 ︰ 1, synergy ratio SR all is greater than 1.5, illustrate that both are mixed and all show synergistic effect in 1 ︰ 60 ~ 80 ︰ 1 scopes, when the proportioning of benzene oxygen quinoline and fluorine bacterium azoles during at 1 ︰ 10 ~ 20 ︰ 1, synergistic effect is more outstanding, and synergy ratio all is greater than 2.30.The optimum ratio of finding benzene oxygen quinoline and fluorine bacterium azoles through test is 20:1,15:1,10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10, especially synergy ratio maximum when benzene oxygen quinoline and fluorine bacterium azoles weight ratio are 2:1, synergistic effect is the most obvious.
Application Example four:
For trying disease: rice sheath blight disease; Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd.; Experimental scheme: effective inhibition concentration scope of determining benzene oxygen quinoline and the pure former medicine of own azoles and the two different proportioning mixture through preliminary experiment.
The toxicity test result
Table 14 benzene oxygen quinoline and the composite analysis of results table of the toxicity test to rice sheath blight disease of own azoles alcohol
As shown in Table 14, benzene oxygen quinoline and the composite proportioning of rice sheath blight disease of preventing and treating of own azoles alcohol are when 1 ︰ 60 ~ 80 ︰ 1, synergy ratio SR all is greater than 1.5, illustrate that both are mixed and all show synergistic effect in 1 ︰ 60 ~ 80 ︰ 1 scopes, when the proportioning of benzene oxygen quinoline and own azoles alcohol during at 1 ︰ 10 ~ 30 ︰ 1, synergistic effect is more outstanding, and synergy ratio all is greater than 2.15.The optimum ratio of finding benzene oxygen quinoline and own azoles alcohol through test is 30:1,25:1,20:1,15:1,14:1,13:1,12:1,11:1,10:1,9:1,8:1,7:1,6:1,5:1,1:1,1:2,1:3,1:4,1:5,1:10, especially synergy ratio maximum when benzene oxygen quinoline and own azoles alcohol weight ratio is 6:1, synergistic effect is the most obvious.
Application Example five:
For trying disease: watermelon anthrax; Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd.; Experimental scheme: effective inhibition concentration scope of determining benzene oxygen quinoline and difenoconazole technical material and the two different proportioning mixture through preliminary experiment.
The toxicity test result
The composite analysis of results table of the toxicity test to watermelon anthrax of table 15 benzene oxygen quinoline and Difenoconazole
As shown in Table 15, the proportioning of the composite control watermelon anthrax of benzene oxygen quinoline and Difenoconazole is when 1 ︰ 60 ~ 80 ︰ 1, synergy ratio SR all is greater than 1.5, illustrate that both are mixed and all show synergistic effect in 1 ︰ 60 ~ 80 ︰ 1 scopes, when the proportioning of benzene oxygen quinoline and Difenoconazole during at 1 ︰ 30 ~ 20 ︰ 1, synergistic effect is more outstanding, and synergy ratio all is greater than 2.20.The optimum ratio of finding benzene oxygen quinoline and Difenoconazole through test is 20:1,15:1,10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,2:3,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:15,1:20,1:25,1:30, especially synergy ratio maximum when benzene oxygen quinoline and Difenoconazole weight ratio are 2:3, synergistic effect is the most obvious.
Application Example six:
For trying disease: wheat powdery mildew; Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd.; Experimental scheme: effective inhibition concentration scope of determining benzene oxygen quinoline and the former medicine of Flutriafol and the two different proportioning mixture through preliminary experiment.
The toxicity test result
The composite analysis of results table of the toxicity test to wheat powdery mildew of table 16 benzene oxygen quinoline and Flutriafol
As shown in Table 16, the proportioning of the composite control wheat powdery mildew of benzene oxygen quinoline and Flutriafol is when 1 ︰ 60 ~ 80 ︰ 1, synergy ratio SR all is greater than 1.5, illustrate that both are mixed and all show synergistic effect in 1 ︰ 60 ~ 80 ︰ 1 scopes, when the proportioning of benzene oxygen quinoline and Flutriafol during at 1 ︰ 10 ~ 20 ︰ 1, synergistic effect is more outstanding, and synergy ratio all is greater than 2.30.The optimum ratio of finding benzene oxygen quinoline and Flutriafol through test is 20:1,15:1,10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,2:3,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10, especially synergy ratio maximum when benzene oxygen quinoline and Flutriafol weight ratio are 2:1, synergistic effect is the most obvious.
Application Example seven:
For trying disease: sigatoka; Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd.; Experimental scheme: effective inhibition concentration scope of determining benzene oxygen quinoline and epoxiconazole raw drug and the two different proportioning mixture through preliminary experiment.
The toxicity test result
The composite analysis of results table of the toxicity test to sigatoka of table 17 benzene oxygen quinoline and epoxiconazole
As shown in Table 17, the composite proportioning of sigatoka of preventing and treating of benzene oxygen quinoline and epoxiconazole is when 1 ︰ 60 ~ 80 ︰ 1, synergy ratio SR all is greater than 1.5, illustrate that both are mixed and all show synergistic effect in 1 ︰ 60 ~ 80 ︰ 1 scopes, when the proportioning of benzene oxygen quinoline and epoxiconazole during at 1 ︰ 30 ~ 20 ︰ 1, synergistic effect is more outstanding, and synergy ratio all is greater than 2.30.The optimum ratio of finding benzene oxygen quinoline and epoxiconazole through test is 20:1,15:1,10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,2:3,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:15,1:20,1:25,1:30, especially synergy ratio maximum when benzene oxygen quinoline and epoxiconazole weight ratio are 2:3, synergistic effect is the most obvious.
Through test, find: the control to powdery mildew, rust, smut, glume blight, moire disease, banded sclerotial blight, leaf spot, spot defoliation, scab, gray mold, leaf blight, early blight, anthrachose of grape, spot blight, black spot, anthracnose, shot hole after benzene oxygen quinoline and active component B are composite has obvious synergistic effect, and synergy ratio is all more than 1.50.
Test of pesticide effectiveness part
Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd..Contrast medicament: 20% benzene oxygen quinoline missible oil (autogamy), 4% tetraconazole aqueous emulsion (commercial), 30% triflumizole wettable powder (commercial), 5% hexaconazole suspending agent (commercial), 10% difenoconazole water emulsion (commercial), 12.5% Flutriafol suspending agent (autogamy), 12.5% epoxiconazole suspension concentrate (commercial).
Application Example eight benzene oxygen quinoline and active component B and the composite control grape powdery mildew test of pesticide effectiveness thereof
This test arrangement, in Weinan City suburb, Shaanxi Province, is investigated the grape powdery mildew state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after the last dispenser 10 days, 30 days, 45 days, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 18 benzene oxygen quinoline and active component B and the composite control grape powdery mildew test of pesticide effectiveness thereof
As can be seen from Table 18, after benzene oxygen quinoline and active component B are composite, can effectively prevent and treat grape powdery mildew, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example nine benzene oxygen quinoline and active component B and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
This test arrangement, in the Xianyang, Shanxi province city, is investigated the alternaria leaf spot of apple state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after the last dispenser 10 days, 30 days, 45 days, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 19 benzene oxygen quinoline and active component B and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
As can be seen from Table 19, after benzene oxygen quinoline and active component B are composite, can effectively prevent and treat alternaria leaf spot of apple, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example ten benzene oxygen quinoline and active component B and the composite control pear scab test of pesticide effectiveness thereof
This test arrangement, in the Xianyang, Shanxi province city, is investigated the pear scab state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after the last dispenser 10 days, 30 days, 45 days, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 20 benzene oxygen quinoline and active component B and the composite control pear scab test of pesticide effectiveness thereof
As can be seen from Table 20, after benzene oxygen quinoline and active component B are composite, can effectively prevent and treat pear scab, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example 11 benzene oxygen quinoline and active component B and the composite sigatoka test of pesticide effectiveness of preventing and treating thereof
This test arrangement, at Nanning, is investigated the sigatoka state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after the last dispenser 10 days, 30 days, 45 days, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 21 benzene oxygen quinoline and active component B and the composite sigatoka test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 21, after benzene oxygen quinoline and active component B are composite, can effectively prevent and treat sigatoka, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example ten hexichol oxygen quinoline and active component B and the composite rice sheath blight disease test of pesticide effectiveness of preventing and treating thereof
This test arrangement, at Shaanxi Province's Hanzhong City, is investigated the rice sheath blight disease state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after the last dispenser 10 days, 30 days, 45 days, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 22 benzene oxygen quinoline and active component B and the composite rice sheath blight disease test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 22, after benzene oxygen quinoline and active component B are composite, can effectively prevent and treat rice sheath blight disease, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example ten triphen oxygen quinoline and active component B and the composite powdery mildew of cucumber test of pesticide effectiveness of preventing and treating thereof
This test arrangement, in the Jingyang County, Shaanxi Province, is investigated the powdery mildew of cucumber state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after the last dispenser 10 days, 30 days, 45 days, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 23 benzene oxygen quinoline and active component B and the composite powdery mildew of cucumber test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 23, after benzene oxygen quinoline and active component B are composite, can effectively prevent and treat powdery mildew of cucumber, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example 14 benzene oxygen quinoline and active component B and the composite control watermelon anthrax test of pesticide effectiveness thereof
This test arrangement, in Weinan City Dali County, Shaanxi Province, is investigated the watermelon anthrax state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after the last dispenser 10 days, 30 days, 45 days, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 24 benzene oxygen quinoline and active component B and the composite control watermelon anthrax test of pesticide effectiveness thereof
As can be seen from Table 24, after benzene oxygen quinoline and active component B are composite, can effectively prevent and treat watermelon anthrax, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example ten pentaphene oxygen quinoline and active component B and the composite wheat rust test of pesticide effectiveness of preventing and treating thereof
This test arrangement, at Shaanxi Province's Weinan City, is investigated the wheat rust state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after the last dispenser 10 days, 30 days, 45 days, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 25 benzene oxygen quinoline and active component B and the composite wheat rust test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 25, after benzene oxygen quinoline and active component B are composite, can effectively prevent and treat wheat rust, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example 16 benzene oxygen quinoline and active component B and the composite control flowers powdery mildew test of pesticide effectiveness thereof
This test arrangement, at Shaanxi Province's Weinan City, is investigated the flowers powdery mildew state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after the last dispenser 10 days, 30 days, 45 days, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 26 benzene oxygen quinoline and active component B and the composite control flowers powdery mildew test of pesticide effectiveness thereof
As can be seen from Table 26, after benzene oxygen quinoline and active component B are composite, can effectively prevent and treat the flowers powdery mildew, control efficiency all is better than the preventive effect of single dose, and the preventive effect phase is long.In the test scope of medication, the target crop is had no adverse effects.
After through different local throughout the country tests, draw, benzene oxygen quinoline and tetraconazole, fluorine bacterium azoles, own azoles alcohol, Difenoconazole, Flutriafol, the composite rear preventive effect to Common Diseases such as the powdery mildew on various crop, rust, smut, glume blight, moire disease, banded sclerotial blight, leaf spot, spot defoliation, scab, gray mold, leaf blight, early blight, anthrachose of grape, spot blight, black spot, anthracnose, shot holes of epoxiconazole are all more than 95%, be better than the single dose preventive effect, synergistic effect is obvious.
Claims (6)
1. the bactericidal composition containing benzene oxygen quinoline and triazole type, it is characterized in that containing active components A and active component B, active components A and active component B weight ratio are 1 ︰ 60 ~ 80 ︰ 1, described active components A is selected from benzene oxygen quinoline, active component B is triazole bactericidal agent, and described triazole bactericidal agent is selected from following any one compound: a kind of in tetraconazole, fluorine bacterium azoles, own azoles alcohol, Difenoconazole, Flutriafol, epoxiconazole.
2. the bactericidal composition containing benzene oxygen quinoline and triazole type according to claim 1, it is characterized in that: the weight ratio of active components A and active component B is 1 ︰ 40 ~ 60 ︰ 1.
3. the bactericidal composition containing benzene oxygen quinoline and triazole type according to claim 2 is characterized in that:
The weight ratio of benzene oxygen quinoline and tetraconazole is 1 ︰ 10 ~ 30 ︰ 1;
The weight ratio of benzene oxygen quinoline and fluorine bacterium azoles or Flutriafol is 1 ︰ 10 ~ 20 ︰ 1;
The weight ratio of benzene oxygen quinoline and own azoles alcohol is 1 ︰ 10 ~ 30 ︰ 1;
The weight ratio of benzene oxygen quinoline and Difenoconazole or epoxiconazole is 1 ︰ 30 ~ 20 ︰ 1.
4. according to the described bactericidal composition containing benzene oxygen quinoline and triazole type of any one in claim 1 ~ 3, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
5. the bactericidal composition containing benzene oxygen quinoline and triazole type according to claim 4, for preventing and treating the application of crop pest.
6. application according to claim 5 is characterized in that: described disease comprises powdery mildew, rust, smut, glume blight, moire disease, banded sclerotial blight, leaf spot, spot defoliation, scab, gray mold, leaf blight, early blight, anthrachose of grape, spot blight, black spot, anthracnose, shot hole.
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|---|---|---|---|---|
| WO1999048359A1 (en) * | 1998-03-20 | 1999-09-30 | Dow Agrosciences Llc | Pesticidal adjuvants |
| CN1255830A (en) * | 1997-05-15 | 2000-06-07 | 诺瓦提斯公司 | Fungicidal combinations comprising 4-phenoxyquinoline |
| US20020103224A1 (en) * | 1999-11-12 | 2002-08-01 | Gertrude Knauf-Beiter | Fungicidal combinations comprising a 4-phenoxyquinoline |
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| CN1255830A (en) * | 1997-05-15 | 2000-06-07 | 诺瓦提斯公司 | Fungicidal combinations comprising 4-phenoxyquinoline |
| WO1999048359A1 (en) * | 1998-03-20 | 1999-09-30 | Dow Agrosciences Llc | Pesticidal adjuvants |
| US20020103224A1 (en) * | 1999-11-12 | 2002-08-01 | Gertrude Knauf-Beiter | Fungicidal combinations comprising a 4-phenoxyquinoline |
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| CN106665595A (en) * | 2016-12-20 | 2017-05-17 | 东莞市瑞德丰生物科技有限公司 | Bactericidal composition containing flutianil and application of bactericidal composition |
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