CN103436140B - A kind of Anticorrosive paint for copper - Google Patents
A kind of Anticorrosive paint for copper Download PDFInfo
- Publication number
- CN103436140B CN103436140B CN201310372612.9A CN201310372612A CN103436140B CN 103436140 B CN103436140 B CN 103436140B CN 201310372612 A CN201310372612 A CN 201310372612A CN 103436140 B CN103436140 B CN 103436140B
- Authority
- CN
- China
- Prior art keywords
- present
- resin
- copper
- anticorrosive paint
- polybenzimidazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 10
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 10
- 239000010949 copper Substances 0.000 title claims abstract description 10
- 239000003973 paint Substances 0.000 title claims abstract description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 4
- 239000004693 Polybenzimidazole Substances 0.000 claims abstract description 4
- 229910000428 cobalt oxide Inorganic materials 0.000 claims abstract description 4
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000839 emulsion Substances 0.000 claims abstract description 4
- 239000003822 epoxy resin Substances 0.000 claims abstract description 4
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 claims abstract description 4
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 claims abstract description 4
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003208 petroleum Substances 0.000 claims abstract description 4
- 229920002480 polybenzimidazole Polymers 0.000 claims abstract description 4
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 4
- 229920005990 polystyrene resin Polymers 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 229920005989 resin Polymers 0.000 claims abstract description 4
- 239000011347 resin Substances 0.000 claims abstract description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 4
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 4
- 229960001866 silicon dioxide Drugs 0.000 claims abstract description 4
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 4
- 239000011734 sodium Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 4
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011248 coating agent Substances 0.000 abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 8
- 238000005260 corrosion Methods 0.000 abstract description 6
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052804 chromium Inorganic materials 0.000 abstract description 2
- 239000011651 chromium Substances 0.000 abstract description 2
- 230000005764 inhibitory process Effects 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000002161 passivation Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000007769 metal material Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 208000011117 substance-related disease Diseases 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The present invention discloses a kind of Anticorrosive paint for copper, and it is made according to weight proportion stirring by following raw materials according: 80-85 part epoxy resin, 20-25 part polystyrene resin, 10-15 part 424 resin, 10-14 part silicon-dioxide emulsion, 8-16 part dimethylbenzene, 3-9 part isobutyl acetate, 4-6 part polybenzimidazole, 8-10 part KH-560,10-14 part talcum powder, 3-7 part tributyl phosphate, 6-8 part cobalt oxide, 11-14 part petroleum sodium sulfonate and 50-70 part water. The product of the present invention proves through commerical test, the coating that the present invention obtains has extremely good waterproof anti-corrosion advantage, passivation and the inhibition of metal base can be realized, avoid the use of the heavy metals such as the chromium that can cause environmental pollution simultaneously, and prepare simple, cost is low, be easy to suitability for industrialized production.
Description
Technical field
The present invention relates to a kind of Anticorrosive paint for copper, belong to technical field of chemical paint.
Technical background
At present, the financial loss that the annual metallic corrosion of China causes accounts for the 3-5% of gross national product, and loss exceedes the summation that fire, disaster caused by a windstorm and earthquake cause loss. For a long time, in order to reduce the loss of corrosion, people take a lot of measure, such as electrochemical protection method, corrosive medium process method, tectum protection method etc. of metal. But sfgd. general, most economical, the most practical up to now or coating protection, anticorrosion with coat with its easy construction, economic and practical, not by device area, the constraint of shape and there is the features such as certain decorative effect and be widely used.
Copper metallic substance uses many metallic substance inside every field, is also the metallic substance being easy to be corroded. At present solvent based coating at the erosion shield great majority of copper material surface coating on the market, and preservative effects a lot of in this kind of coating and not obvious; Although and remaining other coating they there is the effect suppressing corrosion, but owing to they contain obnoxious flavour and the heavy metal that human body easily causes infringement, cause problem of environmental pollution, simultaneously solvent easily fire, explosive feature bring unsafe hidden danger to environment.
Summary of the invention
It is an object of the present invention to provide a kind of Anticorrosive paint for copper.
In order to achieve the above object, the present invention adopts the technical scheme to be: a kind of Anticorrosive paint for copper stirs according to weight proportion by following raw materials according and makes: 80-85 part epoxy resin, 20-25 part polystyrene resin, 10-15 part 424 resin, 10-14 part silicon-dioxide emulsion, 8-16 part dimethylbenzene, 3-9 part isobutyl acetate, 4-6 part polybenzimidazole, 8-10 part KH-560,10-14 part talcum powder, 3-7 part tributyl phosphate, 6-8 part cobalt oxide, 11-14 part petroleum sodium sulfonate and 50-70 part water.
The product of the present invention proves through commerical test, the coating that the present invention obtains has extremely good waterproof anti-corrosion advantage, passivation and the inhibition of metal base can be realized, avoid the use of the heavy metals such as the chromium that can cause environmental pollution simultaneously, and prepare simple, cost is low, be easy to suitability for industrialized production.
Embodiment
Embodiment 1
A kind of Anticorrosive paint for copper is made according to weight proportion stirring by following raw materials according: 80-85 part epoxy resin, 20-25 part polystyrene resin, 10-15 part 424 resin, 10-14 part silicon-dioxide emulsion, 8-16 part dimethylbenzene, 3-9 part isobutyl acetate, 4-6 part polybenzimidazole, 8-10 part KH-560,10-14 part talcum powder, 3-7 part tributyl phosphate, 6-8 part cobalt oxide, 11-14 part petroleum sodium sulfonate and 50-70 part water. The present embodiment coating performance is tested. Result is as follows: 2000h cut salt is tested: bubble-free, nothing come off, cut place corrosion diffusion 1mm; 5000h salt-fog test: nothing is bubbled, Wu comes off, non-corroding; Sticking power/MPaGB/T5210-2006:12-14.
Claims (1)
1. an Anticorrosive paint for copper, it is characterised in that be made up according to weight proportion stirring of following raw materials according: 80-85 part epoxy resin, 20-25 part polystyrene resin, 10-15 part 424 resin, 10-14 part silicon-dioxide emulsion, 8-16 part dimethylbenzene, 3-9 part isobutyl acetate, 4-6 part polybenzimidazole, 8-10 part KH-560,10-14 part talcum powder, 3-7 part tributyl phosphate, 6-8 part cobalt oxide, 11-14 part petroleum sodium sulfonate and 50-70 part water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310372612.9A CN103436140B (en) | 2013-08-23 | 2013-08-23 | A kind of Anticorrosive paint for copper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310372612.9A CN103436140B (en) | 2013-08-23 | 2013-08-23 | A kind of Anticorrosive paint for copper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103436140A CN103436140A (en) | 2013-12-11 |
| CN103436140B true CN103436140B (en) | 2016-06-01 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310372612.9A Expired - Fee Related CN103436140B (en) | 2013-08-23 | 2013-08-23 | A kind of Anticorrosive paint for copper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103436140B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106148934A (en) * | 2016-08-27 | 2016-11-23 | 合肥普庆新材料科技有限公司 | A kind of copper material passivator and preparation, application |
| CN108384417A (en) * | 2018-02-05 | 2018-08-10 | 安徽加隆工艺品有限公司 | A kind of indoor lamp copper pendant |
| CN109167483A (en) * | 2018-11-15 | 2019-01-08 | 南京腾图节能科技有限公司 | A kind of pump motor adjusts padded auxiliary tool |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63175078A (en) * | 1987-01-13 | 1988-07-19 | Kansai Paint Co Ltd | Composition for metal surface treatment |
| CN1051376A (en) * | 1989-11-01 | 1991-05-15 | 崔殿华 | Anti-rust oil with colour hard film |
| CN1536032A (en) * | 2003-04-07 | 2004-10-13 | 章浩龙 | Nano silicon dioxide emulsion, its preparation method and application |
| CN1611559A (en) * | 2003-10-29 | 2005-05-04 | 长春市绍兴给水管道清洗防腐股份合作公司 | Single-component anticorrosive coating and its preparing method |
| WO2011051313A1 (en) * | 2009-10-30 | 2011-05-05 | Bayer Materialscience Ag | Aqueous formulations |
| CN102993839A (en) * | 2012-11-02 | 2013-03-27 | 马建林 | Oil-resisting, waterproof, anticorrosive and mildew resistant paint and production process thereof |
-
2013
- 2013-08-23 CN CN201310372612.9A patent/CN103436140B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63175078A (en) * | 1987-01-13 | 1988-07-19 | Kansai Paint Co Ltd | Composition for metal surface treatment |
| CN1051376A (en) * | 1989-11-01 | 1991-05-15 | 崔殿华 | Anti-rust oil with colour hard film |
| CN1536032A (en) * | 2003-04-07 | 2004-10-13 | 章浩龙 | Nano silicon dioxide emulsion, its preparation method and application |
| CN1611559A (en) * | 2003-10-29 | 2005-05-04 | 长春市绍兴给水管道清洗防腐股份合作公司 | Single-component anticorrosive coating and its preparing method |
| WO2011051313A1 (en) * | 2009-10-30 | 2011-05-05 | Bayer Materialscience Ag | Aqueous formulations |
| CN102993839A (en) * | 2012-11-02 | 2013-03-27 | 马建林 | Oil-resisting, waterproof, anticorrosive and mildew resistant paint and production process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103436140A (en) | 2013-12-11 |
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Effective date of registration: 20160817 Address after: 211111 Jiangsu Province, Nanjing Zijin (Jiangning) technology start-ups in particular communities (Jiangning District Mo Zhou Road No. 12) Patentee after: NANJING YOUGU INTELLECTUAL PROPERTY SERVICE CO.,LTD. Address before: 215000 Jiangsu city of Suzhou province high tech Zone No. 121 Hua Feng Lu Patentee before: SUZHOU CHANGSHENG ELECTROMECHANICAL Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160601 |