CN1033980A

CN1033980A - By providing proton to come the method and apparatus for the treatment of water

Info

Publication number: CN1033980A
Application number: CN 88100067
Authority: CN
Inventors: 西村勤
Original assignee: Astec Co Ltd
Current assignee: Astec Co Ltd
Priority date: 1986-07-11
Filing date: 1988-01-09
Publication date: 1989-07-19

Abstract

A kind of method and apparatus that is used for treating water, it provides proton or provides proton and magnetic field for pending water, the proton amount or the proton amount of release and the intensity in magnetic field that go out by sustained release, just can make contained material flocculating in the water, be adsorbed onto on the throw out, gelatinizing or float on the water surface and separate, removed, reduced, eliminated, suppressed hyperplasia thus or reclaimed them.

Description

By providing proton to come the method and apparatus for the treatment of water

The present invention relates to a kind of method and apparatus for the treatment of water, available it purify fresh water (comprising general sanitary wastewater, sewage, agricultural effluent, trade effluent, construction waste water, river, Chi Shui, lake water and bog water, tap water, underground water, spring, rainwater and slime water etc.), seawater (comprising bay seawater, harbour seawater and inland sea seawater etc.) and the water miscellaneous that mixes seawater (comprising salt lake saline, river mouth water, seawater lake water etc.) and so on; Softening of water; And the oil, protein or other material that separate or reclaim trace.Or rather, the method and apparatus that is used for treating water involved in the present invention has following feature: proton or proton and magnetic field are provided for the water of intending handling, proton amount that the while sustained release goes out or proton amount and the magneticstrength that discharges, with be controlling index, thereby intend water, the softening of water of handling or the oil that separates or reclaim trace, protein etc. by making the material flocculating that is contained in this kind water, they are adsorbed onto on the throw out, make it to become means such as colloid or the showy water surface then separate and handle, purifying thus.

The pollution of enclosed waterss such as phosphorus and nutrient rich confrontation lake, marsh and inland sea, current not only in Japan but also become a significant problem in the whole world.As everyone knows, the development that this class the is polluted contained rich nutritive material among rural sewage and sanitary wastewater etc. that has its source, they flow to lake, marsh, inland sea and have reduced in the waters of water level because of the exploitation of seashore.

For this reason, implemented certain methods and limited rich nutritive material and flow into enclosed waters, for example, to urban life type domestic waste water, agriculture Residential areas waste water and make concentration by the native eluted material of table that rural sewage and rainwater produce; Adopted the whole bag of tricks to keep simultaneously and improved self-purification capacity, for example adopted the method for removing sedimentary mud and algae and in water, add lime one compounds and be blown into the method for oxygen or air.

As for the method for softening of water, make alkaline-earth metal (for example CaO) precipitation in one period of known handlebar hard water seasoning, with the method for distilling or spent ion exchange resin is removed, and precipitate the method that this metalloid uses supernatant liquid by boiling.

But, above-mentioned these prior arts relate to more following problems: in the situation that adopts sorbent material, flocculation agent, neutralizing agent, oxygenant and reductive agent etc., and in the situation of carrying out biological treatment, owing to there is secondary pollutant to sneak in the treating water, produce a large amount of mud simultaneously, just must eliminate them; And adopting the situation of other method, even invested a large amount of equipment and working cost, still can produce satisfied effect so far.

Also having, isolate the oil that is contained in the oil in the pending water or is dissolved in the water with trace as milk sap, also is very difficult even adopt centrifugal method.

For some time that hard water is stored in prior art softens in its method, if the alkaline-earth metal concentration that is dissolved in this kind water is very high, then the pH of water becomes weakly alkaline under most situations.Like this, just can allow static segment length's time of water produce and be settled out calcium hydroxide or similar substance afterwards, however this effect and non-stable, and also along with the reducing of concentration, it is less that the sediment yield of generation also becomes.On the other hand, in spent ion exchange resin, distillation or the situation of boiling softening water, cost is improved, so that be difficult to handle a large amount of water.

Therefore, primary and foremost purpose of the present invention provides a kind of method and apparatus for the treatment of water, and they can remove, and reduces, eliminate the oil or the similar substance of anti-hyperplasia or recovery positively charged ion, anionic part, rich nutritive material, chlorophyll, algae, bacterium, protein and trace.

Another object of the present invention then provides a kind of method for the treatment of water, and it can prevent that secondary pollutant is mixed in the water, and this phenomenon then is inevitably in prior art, also only produces a spot of mud simultaneously.

In order to achieve the above object, in the method that has provided a kind for the treatment of water in aspect first of the present invention, it is characterized in that: for the water of intending handling provides proton or proton and magnetic field, the proton amount or the proton amount that discharges and the intensity in magnetic field that go out of sustained release simultaneously, by make it to flocculate, be adsorbed onto on the throw out, gelatinizing or float to the water surface separated remove, minimizing, elimination, anti-hyperplasia or reclaim the oil or the similar substance of positively charged ion contained in this water, anionic part, rich nutritive material, chlorophyll, algae, bacterium, trace.

Second aspect of the present invention is the method that provides a kind for the treatment of water, wherein, above-mentioned proton be to finish by the crystalline mineral that the release proton that contains crystal water is provided.

The 3rd aspect of the present invention is the method that provides a kind for the treatment of water, and it can make the latter diffuse into the former by with the treated water of pending water dilution with above-mentioned water treatment method gained, thereby removes, minimizing, elimination, anti-hyperplasia or a time zhang bright perch economize again

The 4th aspect of the present invention is the method that provides a kind for the treatment of water, when for producing the necessary positively charged ion amount of the precipitation nuclear that helps sedimentary formation and growth when also insufficient, can add this cationoid of minute quantity.

The 5th aspect of the present invention is the equipment that provides a kind for the treatment of water, and this equipment comprises: a water flow grooves or water pipe wherein fill the crystalline mineral of the release proton that contains crystal water; In this water flow grooves or water pipe outside magnet coil is housed, or in this gutter channel or water pipe, is provided with a kind of magneticsubstance or magnetic storage part; In above-mentioned water flow grooves or water pipe, be provided with to clean and use nozzle, by the air of ejection and/or water is cleaned the material of release proton and attached to the throw out on above-mentioned magneticsubstance or the magnetic storage part.

The 6th aspect of the present invention is the equipment that provides a kind for the treatment of water, wherein, in aforesaid device, be used for keeping containing crystal water the release proton crystalline mineral be a kind of cylinder that blocks the material that discharges proton, it can suitably rotate and its body is reticulated structure.

The drawing of accompanying drawing is described as follows:

Fig. 1 to 4 shows the embodiment of bright a kind of equipment of the present invention, wherein

Figure 1A is the vertical cross section of a treatment trough, and intercepting is from the plane that is parallel to the diameter that comprises a water pipe;

Figure 1B is vertical vertical cross section of the water pipe shown in Figure 1A;

Fig. 2 A is the orthographic plan that has adopted a kind of water flow grooves structure of discoid magnet;

Fig. 2 B is the vertical cross section of structure shown in Fig. 2 A;

Fig. 2 C is the skeleton view of disc magnet shown in Fig. 2 A;

Fig. 3 is the skeleton view that has adopted a kind of water flow grooves structure of flaky magnet;

Fig. 4 A is the side direction vertical cross section that the water flow grooves of the cylinder 8 that keeps cristobalite is housed;

Fig. 4 B is vertical vertical cross section of the water flow grooves shown in Fig. 4 A;

Fig. 5 schematically shows the method that adopts a kind of dilution method to come treating water;

Fig. 6 schematically shows a kind of experimental equipment that adopts above-mentioned dilution method;

Fig. 7 to 14 is a graphic representation, shows with the ion behavior in the various water-reducible various processing waters of intending in the example 4 handling.

In Fig. 9 to 14, indicate the eigenwert of untreated water (before dilution) with mark zero, first indication initial value wherein, and the value of second indication after handling.Equally with mark ● indicate the eigenwert of water of dilution back, first indication initial value wherein, and the value after second indication processing.

Figure 15 is a graphic representation, shows in example 5 variation of the behavior of phosphorus (P) and nitrogen (N) under the various situations with dilute strength and digestion time;

Figure 16 and 17 is a graphic representation, when showing in example 6 by dilution process in batches, and the behavior and the transmittance of the phosphorus of water (P) and nitrogen (N) in the fishpond;

Figure 18 is a graphic representation, the phosphorus (P) when showing in example 7 by the continuous flow dilution process in the water and the behavior and the transmittance of nitrogen (N).

The present invention is described in more detail with reference to following example, not limited by these examples but should understand the present invention.

Be removed as being contained in the material in the pending water, reduce, elimination, anti-hyperplasia or recovery, can list oil or the similar substance of cation, partial cation, rich nutritive material, chlorophyll, algae, bacterium, protein and trace.

As the method that gives proton, that can support utilization has water electrolysis method, ion-exchange, electron collision method and crystalline mineral method of the release proton that contains the crystallization water etc. is provided. As for the crystalline mineral of the release proton that contains the crystallization water, that can support utilization for example has natural cristobalite, artificial cristobalite, zeolite and a class gel mineral, but any mineral with the feature that is easy to discharge proton can adopt.

In following example, the used method that the crystalline mineral of the release proton that contains the crystallization water is provided is method the easiest, the most cheap and safest supply proton.

The proton amount that discharges can be according to the kind of the crystalline mineral of the release proton that contains the crystallization water, intend the free adjustment such as the water yield processed and processing time.

The proton amount that discharges, namely it be high or in/low proton concentration, can come by the pH value of measuring water system definite, be equipped with in this kind water system cristobalite and so on the release proton material and it was left standstill 24 hours. In other words, the proton amount that discharges will be controlled like this according to the purpose of processing water, that is, it is high proton concentration that the pH value is no more than at 5.5 o'clock, and pH to be not less than at 5.6 o'clock be medium or low proton concentration.

Magnetic field provides with conventional method, namely water-flowing path itself is placed a coil and encourages this coil (can freely regulate its magnetic flux density by the number of turn that changes this coil); Perhaps a magnetic material or magnetic storage part are placed this water-flowing path according to following manner, make the distribution equalization of magnetic flux, get so that the resistance of operating water reduces to minimum (referring to Fig. 1,2,3 and 4). As for this kind magnetic material or magnetic storage part, employing be general magnetic material and ferrite, barium ferrite or similar material, and take plastics as adhesive. It is suitable using plastics.

In following example, be to form magnetic field by ferrite lattice and flat thin magnet (tablet that ferrite is pressed into is arranged the N utmost point and the S utmost point by net state).

As for providing of proton and magnetic field, the proton amount that then ought disengage is medium or lower concentration, and the peakflux density that magneticstrength is low to moderate in the treatment trough is about when the 100-600 Gauss (making G with postscript), be contained in the material in the pending water, particularly positively charged ion just flocculates very soon, a part of negatively charged ion (phosphate ion) coprecipitation, organonitrogen and algae etc. are then precipitated for throw out is adsorbed, and simultaneously the oil of trace then floats to the water surface and separated.

When adding the proton amount that discharges, and when making magneticstrength increase to peakflux density in the groove to be the high magnetic field intensity of about 1000～2000G, this moment water in contained material, particularly positively charged ion, phosphate ion, grease and protein etc. promptly become colloid, thereby can not become the nutrition source of bacterium, prevent that simultaneously the bottom that organic substance is deposited to enclosed waters from maybe can reduce this kind precipitation capacity.Application can disengage the synthetic zeolite of the proton of excess, also can be identical with the situation that high-intensity magnetic field is provided, quicken this colloidal dispersion process.Should select proton amount that discharges or proton amount and the magneticstrength that discharges according to the purpose for the treatment of water.

According to the present invention, can be directly provide proton or proton and magnetic field to handle to be contained in material in this water of intending processing for the water of intending handling, also can be with the treated water that is obtained in formerly handling, the promptly so-called water of handling, dilution and being distributed in the water of intend handling is so that handle the material that is contained in the water of intending processing.In above-mentioned treatment process, for generation is used for the positively charged ion that the precipitation nuclear of the formation of accelerate precipitation thing and growth needs, manage water herein or the amount in the water of processing intended when insufficient, then be preferably in a spot of positively charged ion of interpolation in the treating processes.When the material in being contained in the water of intending processing is chlorophyll and algae, then can be by discharging moderate quatity or a spot of proton, and adopt about 100 to 600G or low magnetic field intensity as the peakflux density that is equipped with in the treatment trough of cristobalite, make the above-mentioned substance rapid flocculation and remove fully.

When the water of intending processing is hard water, be that this is when intending in the water of processing contained material and being mainly a class alkaline-earth metal ions such as calcium ion and magnesium ion, then can be by discharging moderate quatity or a spot of proton, and adopt about 100 to 600G alkali intensity of field as the peakflux density in the treatment trough, flocculate this class ion and it is removed fully, thus hard water is transformed into soft water.

When contained material in the water of intending processing is protein and/or trace oily, if when giving proton by the crystalline mineral that the release proton that contains crystal water directly is provided, the proton amount of then being supplied with will be determined according to following index, promptly when being about 100 with magneticstrength to 600G or low field intensity when being used as peakflux density in the treatment trough, the pH that intends the water of processing belongs to neutral range.

When the water (in the dilution process situation) by being dissolved with proton when proton is provided, the quantity of the required interpolation of this processing water (being dissolved with the water of proton) should be determined according to following index, i.e. pH in the processed water that is added with this kind processing water, pH in the water that is untreated than primary is low more than 0.3, and the pH of this processed water after dilution is in 6 to 8 neutral range.

Come to give directly or indirectly the water of intending processing to provide proton at crystalline mineral to separate under two kinds of fuel-displaced situations with the release proton that contains crystal water, the proton amount that is given will be determined according to following index, be that milk sap will disappear, oil droplet will swim on the water surface fully, and the pH of the water of being handled is in aforementioned dress encloses.

Adopt aforesaid method, when protein is flocculated, when coagulation and sedimentation, trace amount then be float on the water surface separated and remove.

For separate and recycle-water in protein, pH regulator to 6.9～6.0 of the water of the plan processing that the water that is dissolved with proton by interpolation was diluted preferably.In order to isolate the oil of trace, adopt and add the water that is dissolved with proton, promptly adopt the method for dilution process the most effective.

The analysis rule of various elements is according to No. 13 of environment office announcements or JIS(Japanese Industrial Standards) analytical method.

More particularly, various elements are analyzed by following mode.

1. phosphorus

The reference liquid of iron is added on the sample to be analyzed, and further to wherein adding nitric acid and perchloric acid.With this mixture heating up, concentrated and complete oxidation, organism is decomposed.With molybdenum blue method phosphorus is carried out quantitative analysis.

2. nitrogen

Survey nitrogen method or Dai Shi (Devorda) reductibility Ji Yeda-Nessler method with Ji Yeda-Nessler (Kjeldahl-Nessler), sample is carried out colorimetric analysis.

3. calcium

Hydrochloric acid is added on the sample to be analyzed dissolves throw out, and do quantitative analysis with atomic absorption spectrometry.

4. sodium and potassium

Hydrochloric acid and water are added on the sample of intending analysis, and do quantitative analysis with atomic absorption spectrometry.

In following each example, N(is as NH ⁺ ₄), P(is as PO ^3- ₄), R.N, R.F, COD and SS refer to respectively: as NH ⁺ ₄The nitrogen that exists, as PO ^3- ₄The solid matter of phosphorus, organonitrogen, initial value, chemical oxygen demand (COD) and the suspension that exists.

T representative " whole " among T.N, T.P and the T.Fe.T.N promptly represents whole NH ⁺ ₄The nitrogen of type (N), organonitrogen (N) and NO _XThe nitrogen of type (N).T.P then represents whole phosphate compoundss and organophosphorus (P), and T.Fe then represents whole iron (Fe), Fe ⁺⁺With Fe ⁺⁺⁺The iron of type (Fe).

Example 1

T.N, T.P and COD etc. are over time

In the experiment of example 1, investigated the water that the untreated water of the sanitary sewage Omi-hachiman urban residential development sewage work of company with table 1 ingredients listed and compound value, water that elementary reason is crossed and second-stage treatment are crossed).

Is that the flat thin magnet of 340G is packed in-500 milliliters the beaker with the cristobalites of 100 grams with field intensity, make they therewith the inwall of beaker closely contact.The water that water that 400 milliliters of untreated water, primary treatment are crossed and second-stage treatment are crossed adds respectively in the corresponding beaker.The time sequence of handling determines that between 30 minutes to 300 minutes the sample that had reached this pre-determined process-time is already measured this filtrate that has separated throw out and studied time dependent behaviors such as T.N, T.P and COD immediately by the GF/F filter paper filtering.The result is shown in table 2.

(tr in the table represents trace)

Find out the T.P in untreated water, NH from The above results ₄, T.Fe and Ca demonstrate the favourable tendency that prolongs in time and reduce.But, NO is arranged in coexistence ^- ₃When (in the situation of first treating water and secondary treatment water),, do not observed obvious processing result except for the phosphorus (P).Above-mentioned untreated water then contains a large amount of organic SS(suspended solidss), they are colloidal state along with the prolongation of time, and just looking at is the reason that increases the COD value.

Example 2

T.P, NH ⁺ ₄With the variation with peakflux density such as COD.

In the experiment of example 2, studied near the irrigation Chi Shui in Kakogawa city that green alga is arranged.800 milliliters water this to be studied are added in 1 liter of beaker that the natural cristobalite of 200 grams is housed in.Respectively the water in a collection of like this beaker is applied 180,600 and the maximum magnetic field strength of 1000G, then all through 120 minutes after-filtration.Various filtrates total phosphorus (P) and total NH have been measured ⁺ ₄And COD value and transmittance.Experimental result is listed in table 3.

In above experimental result, in very wide magneticflux-density scope, observe the favourable trend that phosphorus (P) amount exists minimizing.On the other hand with regard to NH ⁺ ₄It seems that it is similar to aforementioned aphid and chases after to waste time from Χ  beginning and spoil black mole and in the high magnetic flux density scope in the low magnetic flux density range, can think the NH that separates as throw out ⁺ ₄, will become colloidal form once more along with the prolongation of time and remain.

Example 3

Remollescent hard water example

To the experiment of having carried out removing calcium ion in the following sample that has been subjected to the hard water harmful effect.Also with the form of throw out, removed the magnesium ion of trace etc. by the same way as of calcium ion situation simultaneously.

(sample)

(a) Chi Shui in Koyama park (underground water),

(b) the agricultural irrigation Chi Shui in Higashi-Kakogawa district (containing sanitary sewage and rural sewage);

(c) Sweden, the geographic water of Bosta-Trask (lake water);

(d) Sweden, the geographic water of Bruns-Viken (life underground water).

With the cristobalites (port, Japanese autumn fields area produce) of 100 grams and field intensity is that the flat thin magnet of 240G places respectively in a collection of 300 milliliters beaker, respectively adds 250 milliliters sample water.Each beaker all covers with watch glass, leaves standstill after 24 hours to collect 50 milliliters filtrate and add 10 milliliters hydrochloric acid by the GF/F filter paper filtering, carries out aas determination by 100 milliliters constant volumes.

Collect an amount of untreated water, according to the same manner aas determination.Calcium (Ca) ionic concn in water that is untreated and the water handled is listed in the table 4.

In above experiment, any tap water all demonstrates a kind of favourable tendency of removing calcium ion, and obviously, method of the present invention can be used for softening of water and can prevent that calcium from depositing on water pipe or other similar containers.

Example 4

By the ion behavior in the various processing waters that various untreated water diluted.

1. handle the preparation of water

(a) the processing mixing water of forming by sewage and seawater

Can think that the rich nutritive material that flows in inland sea, bay, pond, lake and the marsh all originates from general sanitary wastewater.In these experiments, suppose that sanitary wastewater is to flow into seawater, blended seawater (sanitary wastewater and seawater were by 1: 1 mixed) is injected the treatment trough that has adopted cristobalite and magnetic field (220G), it was left standstill 24 hours, make the processing water thus.Be used for the processing water that obtains as stated above of dilution process purpose, its pH fixes between about 5.0 to 3.0.

(b) processing sewage

According to identical mode in the last example (a), sanitary sewage disposal factory (Himeji city, Ebuna develop house company water treatment plant, wastewater flow rate: the waste water of Pai Chuing 600 ton per days) have been handled.In addition, also alumina gel is added to handle water (a) with (b) in make the processing water.

2. the ion behavior of research in the water of dilution

In order to study the ion behavior in the water of dilution, with untreated water (the i.e. waste water of Pai Chuing, blended seawater and seawater, in following table, be referred to as A, B and C respectively) handle waters and (be designated as a after in the table respectively with handling water (promptly wherein being mixed with the waste water of discharge and the processing water of seawater), handle the sewage of usefulness and be added with preceding two kinds of alumina gel therein, b, a+gel(gel represents gelinite) and b+gel) combination as shown in table 5, form throw out, investigated phosphorus (P) and nitrogen (N) and other cationic behavior.

The treatment time of various situations is 60 minutes.Mix after 60 minutes, measured each the ionic concentration that is kept in each filtrate, and settling is washed in the original beaker, measure various ionic concentration in this settling with wash bottle.

(measuring result)

Measuring result is shown in the graphic representation of Fig. 7 to 14.In Fig. 9 to 14, the eigenwert of the water (before the dilution) that symbol zero finger is untreated.Wherein first refers to initial value, and second value after refer to handling.

Equally, symbol ● refer to dilute the eigenwert of back water, wherein first refer to that just the multiple  Che earthworm of the humorous  crucian carp of merchant load  makes a noise idle

Although pH tends to acidic side, CaO, MgO, Al ₂O ₃, Fe ₃O ₄Can precipitate with the positively charged ion of ZnO and similar substance, and when particularly being in the weak acid attitude, the ion that forms oxyhydroxide will react sharp, be enough to make apace Al ₂O ₃, Fe ₃O ₄, ZnO and similar species precipitate.The ion (for example MgO and CaO and so on) that produces oxyhydroxide in alkaline side then becomes settling gradually through segment length's time.Phosphorus (P) is closely related with removing with above-mentioned these cationic depositions of nitrogen (N), and P is as PO here ^-3 ₄And N is as NH ⁺ ₄, they particularly acidic side sharp with trace (1 to the 5ppm) cationic compound that produces oxyhydroxide, from water, remove therefrom.Therefore, in order to remove dephosphorization (P) and nitrogen (N) from water, extremely important is will allow handle in water and/or the pending water contain an amount of positively charged ion, need have an amount of proton and magneticflux-density simultaneously.There is not an amount of positively charged ion if handle in water and/or the pending water, then can comes to remove fully dephosphorization (P) by adding 1 to 5ppm aluminium (Al) ion (iron (Fe) ion etc.) at this kind.Adopt common alkaline purification method to be difficult to isolate the positively charged ion that is no more than several ppm as oxyhydroxide.

If in handling water and/or pending water, contain an amount of positively charged ion,, also can generate throw out fast enough and reach this even the pH after dilution reaches 6.5 to 6.8

Used the experimental installation of taking dilution method shown in Figure 6, pending water with handle water respectively with 1500 milliliters/hour with 150 milliliters/hour flow continuously stream give.As pending water, adopted the waste water (waste water that the sewage work of Ebuna housing development company discharges) of fishpond water and discharge; As handling water a is arranged then: the waste water+seawater of discharge; B: the waste water of discharge, and b+gel; The waste water of the discharge that is added with the alumina gel body and handled by example 4 the same manners.Pending water is to mix naturally in a tempering tank with handling water, to produce throw out and be settled out settling in above-mentioned subsider.Top clear liquid is flowed out and the acquisition treated water, and measured following each numerical value.When collecting various water, being used as each initial value by analyzing the numerical value that obtains.At (replacing transmittance) obtainable satisfactory result aspect dephosphorization, nitrogen and algae, have in some graphic representations that are given in Figure 18.The experimental result of relevant this kind continuous flow dilution process is listed in the table 7.

Carried out senile experiment according to table 6.The result is shown in the graphic representation among Figure 15.

In the analysis, allow the throw out that generates by the GF-F filter paper filtering, and measured T.P and the T.N that stays in the filtrate, in order to investigate the processing water of effective classification, effective dilution time and aging effect.

As indicated in the graphic representation among Figure 15:

1. in the situation of mixing water+processing with the mixing seawater, even through 100 times of dilutions, also demonstrate good dephosphorization (P) and denitrogenate (N) effect, simultaneously, burin-in process also produces the good effect of removing the evil.

2. in the situation of the waste water of discharging+processing, only be through 10 times of purposes with the waste water of discharging.

Obviously, can make DISTRIBUTION OF MAGNETIC FIELD obtain homogenizing to a great extent by dilution process.

Example 5

The relation of phosphorus under the various situations (P) and nitrogen (N) and dilute strength and digestion time.

As the water of intend handling, what use is to mix the seawater and the waste water of this factory's discharge by the waste water (waste water that sewage work of Himeji municipal administration Ebuna housing development company discharges) of 1: 1 blended seawater and discharge.

Handle water and be according to the same way as in the example 4 and handle the waste water of above-mentioned mixing seawater, above-mentioned discharge and the above-mentioned waste water that has added 2.65ppm equivalent aluminium (Al) gelinite.In order to study the ion behavior of diluted treated water, with the water of the plan processing in the table 6 ((promptly the waste water of Pai Chuing with mix seawater, be called A and B in the following table respectively) and ((i.e. processing is in the processing processing water that obtains in the waste water of discharging with seawater, processing with the waste water of discharging and by the alumina gel body that adds the 2.65ppm equivalent to handle water, be referred to as a, b and c in the following table respectively) mix, form throw out, and investigated phosphorus (P), nitrogen (N) and other cationic behavior.Dilution just demonstrates dephosphorization and efficiencies of nitrogen removal in conjunction with last burin-in process again.

This fact shows that the low pari fine strain of millet of the circuitous inferior Χ  merchant's chlorine of dragonfly quilt Guang  technetium shelves soil Song  meets Yin fine strain of millet  water caltrop Α

3. the processing at the waste water of discharging+be added with the alumina gel body also demonstrates very good phosphor-removing effect with the situation of discharging waste water even dilute 100 times, because the proton amount is very little, even be at pH, still contains an amount of positively charged ion after the processing at 6.7 to 6.8 o'clock.Efficiencies of nitrogen removal also is good, demonstrates the trend that is similar to aging effect.

Provable by above result, if the water of intend handling and/or handle water and contain or make it contain an amount of positively charged ion provides an amount of proton these positively charged ions that flocculate simultaneously, then also can further improve the degree of dilution.

Example 6

Under dilution process in batches, the phosphorus of water, nitrogen and transmittance in the fishpond.

Water in the employing fishpond, adopts " a " as for handling water as pending water: the waste water of discharge+press the seawater that the same manner was handled in the example 4, " b ": press the fishpond water that the same manner was handled in the example 4; " b+gel " (gel shows gelinite): the water in the fishpond is added with the alumina gel body and handled according to example 4 the same manners.Dilute 10 times of phosphorus during with 20 times (p) and be shown in Figure 16 and 17, wherein also show the behavior of clear phosphorus (P) and nitrogen (N) and the relation of transmittance and dilute strength with nitrogen (N) amount and the time dependent situation of transmittance.

Example 7

The phosphorus of the water under the continuous flow dilution process (P) with nitrogen (N) trip is and transmittance.

Fig. 6 has shown that schematically employing the present invention's processing water comes a kind of experimental installation of dilution water so that water is handled.The storagetank of the water that reference number (14) expression is untreated, (1) treatment trough in cristobalite and magnetic field has been adopted in expression, (15) expression seawater and the storagetank of handling water, (16) storagetank of water is handled in expression, (17) expression pump of constant delivery type, (9) expression tempering tank and (10) are subsider.

With the treated water that is obtained by the experiment of continuous flow dilution process in the example 7, generate throw out once more with fishpond water dilution (* 11 * 5 to * 11 * 50), and by same way as.Measured the T.P and T.N and the transmittance that stay in the supernatant liquid, thus certainly, remained valid through the processing water of 11 times of dilutions.Result shown in below from Figure 17 can prove that the water of this dilution still maintains suitable ability.

As for the effect of the water of handling, in the situation of the processing water+50ppm gelinite of waste water+discharges of discharging, can dilute 550 times effectively, and, can effectively arrive and dilute 330 times in the situation of the waste water+seawater of discharging.

The above example has according to this obtained to draw a conclusion:

When a kind of element when lower pH forms oxyhydroxide, it just has higher deionization tendency, even but be a kind of element at alkaline side generation oxyhydroxide, it also can demonstrate deionized tendency, although processing of the present invention is carried out in the weak acid side.

2. this indicated class is inclined to and effect in the present invention's the method, all is identical for batch treatment with continuous processing.

3. in treatment process of the present invention, even the positively charged ion of trace also can become settling, and a kind of like this tendency is for especially remarkable the element that produces oxyhydroxide in low pH scope.

4. in treatment process of the present invention, positively charged ion is at first flocculated, and a part of negatively charged ion then is the adsorbed and flocculation of this kind positively charged ion when positively charged ion flocculates, and removes this positively charged ion and anionic part therefrom from the water of handling.

5. in treatment process of the present invention, very importantly, intend to handle or in the treated water, should contain an amount of positively charged ion (preferably 1 to 5ppm iron (Fe), aluminium (Al) or analogous element, but this quantity can change and can adopt other ion).Therefore, the factors such as ionic concn in the water of depend on ionic concn in the water of treatment time, treatment process, plan processing, handling where necessary, can be added the positively charged ion of trace before handling.

6. in treatment process of the present invention, very importantly, in intending the water of handling or handle in the water, should there be the proton (handling the proton amount in the water) of essential quantity according to the positively charged ion amount according to predetermined pH, by treatment time control.

7. investigate by continuous flow and handle the purifying treatment ability that still keeps in the processing water (through diluting 11 times) that is obtained, found that, proton in the discharge waste water of handling usefulness still maintains effect until 50 times of dilutions (for untreated water, then being 550 times of dilutions); And ion that in handling the mixing seawater of usefulness, is kept and proton the two, when diluting 30 times, still work.When the mixing seawater of handling usefulness diluted 50 times, the ratio of the phosphorus of being removed (P) greatly reduced.It seems this be since cationic quantity because of the formation of throw out become insufficient due to.

8. relatively eigenwert before and after the experiment is handled in this continuous flow, finds that removing aspect BOD, T.P, algae and the Chlorophyll A be very effective.

Example 8

Processing contains construction waste water, river and the spring (promptly containing bentonitic water) of clay

(sample water)

1.Shimane the river in county.

2.Shimane the waste water in one construction site between county's lofty mountains.

3.Aichi the waste water in one construction site between county's lofty mountains.

4.Himeji the waste water in building site, hypogee, city.

5.Himeji the waste water in one construction site between city effect district the foot of a mountain.

6.Kanuma the spring in city

7.Hiuga the spring in city

(handling the preparation of water)

1 kilogram cristobalite (granularity＜20 millimeter) is immersed in 1 liter the common river, under the peakflux density of 230G, in treatment trough, kept 6 hours, so that make proton fully soluble in water.The pH of the water that obtains like this is 4.5.Then iron (Fe) ion of 3ppm or aluminium (Al) ion are added in this water that is dissolved with proton and regulate its function, so just be mixed with this kind processing water.

(experiment rank)

1. 1,1 liter+processing of sample water water is 2 milliliters

2. 2,1 liters+processing of sample water water is 5 milliliters

3. 3,1 liters+processing of sample water water is 5 milliliters

4. 4,1 liters+processing of sample water water is 3 milliliters

5. 5,1 liters+processing of sample water water is 3 milliliters

6. 6,1 liters+processing of sample water water is 2 milliliters

7. 7,1 liters+processing of sample water water is 2 milliliters

(handling the experiment of the water of argillaceous)

The processing water that foundation the present invention is mixed with adds in the bentonitic slime water that contains dissolved state or colloidal state, promptly contains in construction waste water, river and the spring of clay, and the pH after the interpolation makes and is in neutral range.Mixing gently immediately after adding, amalgamation time again after two minutes.Leave standstill this mixture then, make positively charged ion contained in the water and colloidal materials change flocculent precipitate sedimentation simultaneously into.The settling velocity of the throw out of Xing Chenging is 30 centimetres/30 minutes like this.Stay the time as for left alone without help in settling bath, 60 minutes is enough.

(measuring result)

The measured value of various compositions is listed in the table 8 before and after handling.Value after the processing is the analytical value of upper strata clear water.

According to above experimental result as can be seen, for precipitation from contain bentonitic water with form alkaline-earth metal ions, burin-in process is necessary, and the solid matter of other positively charged ion, suspension and colloidal materials then change into to be separated and flocculent precipitate that remove very soon.

Example 9

Dispose of sewage by continuous dirty mixing

(sample water)

The input water of the sewage work in Himeji city

(handling the preparation of water)

With 10 kilograms natural cristobalites (granularity＜20 millimeter), immerse 15 and go up and state in the waste water that treatment plant discharges, in groove, under the peakflux density of 230G, kept 6 hours, so that proton is fully soluble in water.The pH of water is 4.45 in this case.Iron (Fe) ion or aluminium (Al) ion with 2ppm adds in this water that is dissolved with proton the function of regulating it then.So just obtained being dissolved with the processing water of proton.

(disposing of sewage) by continuous dirty mixing

Raw sewerage and the water that is dissolved with proton is respectively from the storagetank of the unprocessed water of-100 liters of capacity and the storagetank of a processing water, dirty continuously with 10 liters of/hour speed with 0.02 liter/hour separately.Carry out sedimentary aging and depositing treatment in the settling bath with-20 liters of capacity of this blended water introducing then.Because this upper strata clear water (sewage after treatment) is to discharge continuously, just from then on the bottom of settling bath extracted out by throw out, and introduce a pump filter pocket, by separating water and the throw out that has filtered here with pump purt method.This water that has filtered is discharged from.

The Capacity design of this settling bath becomes to have 120 minutes of 200% safety coefficient left alone without help and stays the time.

(measuring result)

By the environment measurement station measured this untreated sewage with handle the waste water of discharging the back variously become score value.

The result who measures shows bright in table 9

Find out to have extra high treatment effect for BOD, T.P, SS, colon bacillus bacterium colony and visibility meter from above experimental result.

In the conventional treatment method of sewage, after the biological treatment of having carried out elementary and secondary, often need do tertiary treatment (adopting aggregate and precipitate method and calcium phosphate crystal method etc.), and the performance of dephosphorization is rather not enough.According to the present invention, only need be just much of that with the one-level processing, and also easy and simple to handle, the rank of the water of being handled is equivalent to the water by tertiary treatment.

Particularly aspect dephosphorization effect, the present invention is superior more than any other method.The water of treated mistake is colourless, demonstrates the good transparency and almost is scentless.

Example 10 separation of iron (Fe), aluminium (Al) ion and/or SS

The crystalline mineral of the used in the present embodiment release proton that contains crystal water is a granularity less than 20 millimeters, contain 87.2%SiO ₂Natural cristobalite with 5.25% crystal water.

As for sample water, adopted the waste liquid of flowing water, the geographic spring of (2) Izumo and the generation of (3) ironmaking process of (1) Ii korneforos.

1 kilogram natural cristobalite immersed in 1 liter the water (pH7.0) 3 to 8 hours, and proton is fully discharged and be dissolved in the water.In this case, be dissolved with the pH of the water of proton, be 5.20 after this kind water is gone through 3 hours, and be 4.05 after 8 hours.Extract this kind water then out, get 10 milliliters and add respectively in above-mentioned (1), (2) and (3) various sample water of one liter with 100 milliliters.Allow this kind mixture leave standstill 60 minutes.

At above-mentioned water and the iron ion in the solution, aluminum ion or SS, in being transformed into the process of flocculent precipitate, they low precipitate.Resulting supernatant liquid shows the tendency of having removed iron ion, aluminum ion or SS significantly.

According to JIS(Japanese Industrial Standards) in correlation method analyzed water and solution and water of handling and the solution that this kind is untreated.Analytical results is listed in table 10.

Example 11 is separated the oil of trace

(sample water)

Adopt Himeji municipal wastewater treatment plant to receive the water that contains trace amount at a side place

(supplying with the method for proton)

10 kilograms natural cristobalites (granularity＜20 millimeter) were dipped in 15 liters of waste water of discharging from above-mentioned treatment plant trough 6 hours, and peakflux density is 230G, and proton fully is dissolved in the water, and this moment, the pH of water was 4.45.Iron ion or the aluminum ion of 2ppm are joined in this water that is dissolved with proton, regulate its performance to obtain to be dissolved with this processing water of proton.Provide proton by this water that is dissolved with proton.

(separating the experiment of trace amount)

Will be dissolved with the water and the sewage that is untreated that contains trace amount of proton, flow down continuously with 0.02 liter of/hour speed respectively and mix with 10 liters/hour, introduce in the subsider.Various ions, suspended solids and bacterium etc. in the sewage all deposit as flocculent precipitate.After this flocculent precipitate left standstill 120 minutes, the oil of trace promptly rose to liquid level and is separated.

The observed value of various compositions is listed in table 11 before and after handling.

(note: the value after the processing is the observed value of upper strata clear water)

The numerical value of n-hexane extract and visibility meter from table is present in oil in the untreated water with solution state or form of emulsion as can be seen, and is separated and remove in very high ratio.

Example 12 trace oil separating

(sample water)

General sewage contains part and is the trace amount of milk sap part for the oil of water soluble.

(method of proton is provided)

1. provide proton by the water that is dissolved with proton in the example 11.

2. directly provide proton by natural cristobalite.

(separating the experiment of trace amount)

1. 2 milliliters of water that are dissolved with proton are joined in 1 liter of sample water and mix.This mixed solution is transferred to pH7.1, left standstill 60 minutes, allow the throw out that generates deposit, make oil rise to liquid level as oil droplet.

2. the 500 natural cristobalites of gram (granularity＜20 millimeter) are immersed in 1 liter the sample water, allow these both in a groove, leaving standstill 120 minutes under the peakflux density of 230G.PH after the processing transfers to 6.4, and the oil of trace promptly rises to liquid level and separated as oil droplet.

(measuring result)

To the water gaging of untreated water in

top

1 and 2 and processing pH, n-hexane extract and turbidity.The value that records is listed in table 12.Value after the processing is the observed value of upper strata clear water.

Because oil is trace, n-hexane extract in any sample water all less than 0.5ppm, eigenwert before or after handling finds no difference, but rise to liquid level and this two aspect of turbidity be it seems from oil droplet, there is very big difference between the numerical value before and after handling, concludes with solution or the trace amount that is contained in the water as form of emulsion separated thus.

In above-mentioned

partition method

1 and 2 any, contained trace amount rises to liquid level as oil droplet and in separated, emulsion disappears at once in water, thereby oil separates from water fully.By the observed value of above turbidity as can be seen, above-mentioned partition method 1(dilution process method) be used for separating that to be contained in the trace amount of water with solution or form of emulsion the most effective.

The oil of example 13 isolated proteins and trace

(sample water)

1. protein-contg water.

2. the water that cures fish (comprising seawater).

3. Jia Gongshipin water (containing water-soluble proteic water).

4. the water that contains vegetable-protein.

(method of proton is provided)

10 kilograms natural cristobalites (granularity＜20 millimeter) are dipped in the waste water of discharging in 15 liters of grooves by a sewage work, be to leave standstill 6 hours under the condition of 230G in peakflux density, proton is dissolved in the water all sidedly, and the pH of the water of acquisition is 4.45 like this.Iron ion or the aluminum ion of 2ppm are added in this water that is dissolved with proton, regulate its performance to obtain this processing water that is dissolved with proton.Plant the water that is dissolved with proton thus and provide proton.

(experiment of isolated protein and trace amount)

1 to 5 milliliter the above-mentioned water that is dissolved with proton added in above these four kinds of sample water of one liter and mix.It is 6.1 to 6.8 scope that this type of mixture is transferred to pH, leaves standstill to make the slaking precipitation in 60 minutes.Go out protein by settlement separate, the oil of trace rises to liquid level as oil droplet and separates simultaneously.As the water gaging of handling the upper strata clear water.

In this processing, pH regulates with the water that is dissolved with proton, goes out and contained protein and other material are precipitated in the water.In order to conclude that whether can regulate pH with any other method generates precipitation, has adopted 0.1NHCl, L-xitix (10% weight/volume) and 1NH ₂SO ₄Regulated pH, but throw out does not form.It is fixed to be had by this fact, is contained in protein precipitation phenomenon in the water and is a kind of reaction that can only generate by the above-mentioned method that proton is provided.

(measuring result)

Handling the observed value of the various compositions of front and back lists in table 13.Value after the processing is the analytical value of upper strata clear water.

In above any water of having handled, all formed the excellent protein coagulating precipitate thereby can from water, isolate and reclaim protein (recovery percent is 92～95%).

About being less than the trace oil separating of 0.5ppm, its accurate numerical value can't be measured, and significantly reduces this fact and obtains proof but its separation can rise to liquid level and turbidity from oil droplet.

In the difference of handling the fore-and-aft survey value, can find out that the oil of trace obtains separating from the normal hexane extraction amount of the water that contains vegetable-protein significantly.

Example 14

Fig. 1 to 4 has shown the embodiment of the present invention's equipment.A kind of water purifying equipment shown in Figure 1 utilizes water pipe (1) itself (water passage pipe) as treatment trough.Coil (2) is subjected to encouraging for this reason providing magnetic field in the pipe on this water pipe (1).Magneticflux-density is determined by the number of turn of this coil.Cristobalite (6) places in the water pipe (1), is provided with an insulation covering (5) in the outside of coil (2).Raw water is flowed in the water pipe (1), encourage above-mentioned coil to provide magnetic field simultaneously to purify the water that flows into.Periodically spray into the airflow and/or the water of 2 to 5 kg/cm from washing nozzle (4), clean this cristobalite and similar substance.In filter vat, subsider or induction separator tank, isolate throw out.

A kind of equipment utilization water flow grooves (1) of purifying waste water that Fig. 2 shows is as treatment trough.This is a kind of equipment example that has adopted disc flat thin magnet (3) (plastics binder+ferrite magnet).In magnet iron piece (3), the N utmost point and the S utmost point arrange that alternately the optimum distance between these flat thin magnets is 2 to 3 centimetres.Their arrangement mode will make that the distribution of magneticflux-density is even as far as possible.The configuration of magnet iron piece (3), magneticflux-density and similar character can freely be selected, as long as be fit to produce the purpose of high-intensity magnetic field.Make the water (7) that is untreated flow into water flow grooves (1) and accept processing.Periodically spurt into the airflow and/or the water of 2 to 5 kg/cm by washing nozzle (4), be attached to cristobalite (6) and the lip-deep throw out of magnet iron piece (3) with cleaning.Throw out that generates and colloid are handled according to the same manner shown in Figure 1.

A kind of water purifying equipment shown in Figure 3 utilizes water flow grooves (1) as treatment trough, and the N utmost point and the S utmost point of wherein set flat thin magnet (3) are alternately arranged.Flat thin magnet (3) is a kind of magnetized plastic sheet, and the magneticflux-density that can freely select can be provided for it.The N utmost point and the S utmost point are by netted arrangement, and the optimum distance between these flat thin magnets (3) is 2 to 3 centimetres.They are suitable for downfield and quicken the growth of throw out.Commercially available multiple this series products has 180 to 160G field intensity.Periodically spray into the airflow and/or the water of 2 to 5 kg/cm by washing nozzle (4), be attached to the lip-deep throw out of cristobalite (6) and flat thin magnet (3) with cleaning.Throw out that generates and colloid are handled by the same manner shown in Figure 1.

A kind of water purifying equipment shown in Figure 4 has utilized water flow grooves (1) as treatment trough, has adopted flat thin magnet (3) simultaneously.Cristobalite is contained in rotatable cristobalite and keeps in the cylinder (8) (cristobalite basket), and the latter's main part is netted.Can rotate the cylinder that this is used to keep cristobalite as required, thereby can remove being attached to the lip-deep throw out of this cristobalite easily.

Example 15

Fig. 5 and 6 shows clear embodiments of the invention.Fig. 5 has then schematically shown the method that adopts the treating water of dilution method.

In Fig. 5, reference number (1) has referred to utilize the treatment trough in cristobalite and magnetic field.Manage discharging proton storage tape simultaneously in the groove (1) herein, obtain to handle water thus.Reference number (a) expression one tempering tank, proton wherein and DISTRIBUTION OF MAGNETIC FIELD are that cationic flocculation develops gradually uniformly, and phosphate ion is precipitated, and the nitrogen of organic is adsorbed and precipitates, and algae also is adsorbed and precipitates simultaneously.Reference number (10) refers to be used to precipitate, wear out and isolating subsider.Reference number (11) refers to a filter vat, and the nitrogen of aluminum phosphate, trimagnesium phosphate, calcium phosphate, nitrogen phosphate, tertiary iron phosphate, organic, ammonium salt are separated in groove with the settling of algae and so on.The dehydration in a deposition dewatering tank (12) of these isolated materials, fertile as farming.Reference number (13) expression one positively charged ion adds groove, is used for when needing positively charged ion is added in treatment trough (1) or the tempering tank (9).

Fig. 6 has schematically shown a kind of experimental installation that adopts this kind dilution method.

In Fig. 6, numeral 14,1,15,16,17,9 and 10 refers to the storagetank of the storagetank of a water that is untreated, the treatment trough with cristobalite and magnetic field, seawater and treated water, storagetank, pump of constant delivery type, tempering tank and a subsider of treated water respectively.In this experimental installation, the waste water that adopts the discharge of Ebuna housing development company is as untreated water.The untreated water of this kind is handled in the treatment trough 1 with cristobalite and magnetic field, after treatment, a part wherein is incorporated in the storagetank 15 of seawater and treating water, the water of having handled of the mixing that waste water (the 50%)+seawater (50%) of discharging as Ebuna housing development company is formed; And rest part is incorporated in the storagetank 16 of the water of handling, as the waste water of the discharge of handling of Ebuna housing development company itself.These two kinds treated water, introduce respectively in two tempering tanks (capacity be respectively 1.8 liters with 4.5 liters) (9) by pump of constant delivery type by 150 milliliters/hour speed.On the other hand, adopt the waste water A of discharging ₂With fishpond B ₂In the water that is untreated as raw water.With the waste water of the undressed discharge of Ebuna housing development company, introduce the tempering tank 9(A of 1.8 liters of capacity that contain the above-mentioned water of handling that mixes ₃) in; And water unprocessed in the fishpond is introduced the tempering tank 9(B of 4.5 liters of capacity that contain the water that the said firm handled ₃) in, both introducing speed is 1500 milliliters/hour.In this tempering tank 9, the coprecipitation of cationic flocculation, phosphonium ion, the absorption of organonitrogen and absorption and the precipitation of precipitation and algae have been finished.At subsider 10(A ₄, B ₄) in finish precipitation, aging and separate, discharge the water that purifies simultaneously.

Industrial applicability

From top elaboration as can be known, according to water treatment technology of the present invention, can purify water, the softening of water under all environment or reclaim useful material, and be by the proton amount of selective liberation or proton amount and so a kind of simple operating type of magnetic field intensity of selective liberation, just can freely dispose and control. Like this, technology of the present invention just has the economic benefit that is used for processing water with low equipment cost and running cost.

According to the present invention, by the quantity of selecting proton or quantity and the magnetic field intensity of selecting proton, just can remove, reduce, eliminate, restrain the wet goods of hyperplasia or recovery phosphorus (P), nitrogen (N) and other cation, anionic part, rich nutritive material, chlorophyll, algae, bacterium, protein and trace.

Processing method of the present invention can be brought very high practical value, because the secondary pollution material that brings in the time of can being mingled with hardly by employing adsorbent, flocculant, nertralizer, oxidant, reducing agent or similar inorganic agent or execution biological treatment, and the sludge quantity that produces also seldom.

Adopt this method for treating water of the present invention, can softening of water and remove contained trace heavy metal or similar substance in the waste water of factory's discharge or the similar sewage. Equally, protein remaining in the sewage or the oil of trace can also be isolated and reclaim to this method. The present invention can also isolate with form of emulsion and be contained in the pending water or be dissolved in the oil of trace wherein, and this is namely to use centrifugal process also to be difficult to separate in the past.

The water of the high activity that is obtained by the present invention's method for treating water, suppressed to tap a blast furnace from the inwall dissolving of steel pipe, also suppressed the generation of iron hydroxide, thereby prevented from narrowing down or making line clogging owing to bulky ferric hydroxide precipitate deposits the interior thorax cause pipe in pipe.

In according to treated water of the present invention, the activity of bacterium is suppressed, and has stoped simultaneously the generation of green alga or similar substance.

When containing an amount of iron ion and/or aluminium ion in the sewage, just can show to the flocculating effect of green alga with to NH₄The nitrogen of type, the nitrogen of organic form, PO₄Height absorption and sedimentary effect with similar substance.

Dilute by the water of having processed (namely processing water) that the present invention is obtained with pending water, be aided with in case of necessity cation, in just can be the from then on pending water except anion, chlorophyll, algae and the similar substance of decationizing, part.

When diluting this kind processing water and purify the pending water of with it combination, just can purify a large amount of pending water by means of processing a small amount of pending water, and because this processing method is very perfect, can any chemical reagent or power be engaged in purification, thereby it especially can demonstrate very big ability when purifying the waters of wide region.

Although the present invention's processing method has above-mentioned many-sided advantage, easy and simple to handle, equipment cost is not high and operating cost is low, thus water treatment field is made very big contribution.

Claims

1, a kind of method for the treatment of water, it is characterized in that: for pending water provides proton or provides proton and magnetic field, by controlling proton amount or the proton amount of disengaging and the intensity in magnetic field of being disengaged, make in the water contained material by flocculation, be adsorbed onto on the throw out, gelatinizing, float to mode such as separate on the water surface, removed, eliminated, suppressed hyperplasia or recovery.

2, the method for a kind for the treatment of water as claimed in claim 1, the wherein said proton that provides is by providing the crystalline mineral that disengages proton that contains crystal water to realize.

3, the method for a kind for the treatment of water as claimed in claim 2, the wherein said crystalline mineral that disengages proton that contains crystal water is a cristobalite.

4, a kind of method for the treatment of water, it is characterized in that: for pending water provides proton or provides proton and magnetic field, by controlling proton amount or the proton amount of disengaging and the intensity in magnetic field of being disengaged, make that contained material is adsorbed onto on the throw out by flocculation in the water, gelatinizing, float on the water surface and separate, removed thus, reduce, eliminate, suppress hyperplasia one-tenth or recovery, when in pending water, during the positively charged ion quantity not sufficient of precipitation nuclear required usefulness in its forming process of using for the formation and the growth of accelerate precipitation thing, then add a spot of positively charged ion in the reason herein.

5, a kind of method for the treatment of water, it is characterized in that: for pending water provides proton or provides proton and magnetic field, by controlling proton amount or the proton amount of disengaging and the intensity in magnetic field of being disengaged, make contained material flocculating in the water, be adsorbed onto on the throw out, gelatinizing or float to above the water surface separates, thereby removed, reduced, eliminated, suppressed hyperplasia or recovery, obtained the water handled therefrom, the water dilution of having handled this also is diffused in the water of intending processings, is just handled the material that is contained in the water of this plan processing.

6, a kind of method for the treatment of water, it is characterized in that: for pending water provides proton or provides proton and magnetic field, by controlling proton amount or the proton amount of disengaging and the intensity in magnetic field of being disengaged, make contained material flocculating in the water, be adsorbed onto on the throw out, gelatinizing or float on the water surface and separate, thereby removed, reduce, eliminate, suppress hyperplasia or recovery, obtain the water handled thus, the promptly so-called water of handling, with its dilution and be diffused in the water of intending processing, just handled contained material in this water of intending processing, when intending in the water of processing at this, during the positively charged ion quantity not sufficient of precipitation nuclear required usefulness in its forming process of using for the formation and the growth of accelerate precipitation thing, then add a spot of positively charged ion in the reason herein.

7, be used for a kind of equipment for the treatment of water, comprise: a water flow grooves or water pipe (1), be equipped with the crystalline mineral (6) of the release proton that contains crystal water in it; Be installed in the outside magnet coil (2) of above-mentioned water flow grooves or water pipe (1), or be arranged at this water flow grooves or inner magneticsubstance or the magnetic storage part (3) of water pipe (1); And a washing nozzle (4), inject air or water by it, clean the crystalline mineral (6) and magneticsubstance or the lip-deep throw out of magnetic storage part (3) that are attached to above-mentioned release proton.

8, the equipment of a kind for the treatment of water as claimed in claim 7, the wherein said crystalline mineral that contains the release proton of crystal water are to be contained in one to be used to keep in the rotating cylinder (8) of this crystalline mineral that discharges proton, and the latter's body part is reticulated structure.