Background technology
Traditional winter executes spraying technique and often adopts OPC cement to add frostproofer, air entrapment agent, accelerating chemicals etc. to reach and reduce the liquid phase freezing point temperature, shorten time of coagulation, improve freezing tolerance and obtain early strength, but in the situation that-30 ℃ of very low temperature, because the hydration and hardening of Portland cement is slow, resist the ability extreme difference of very low temperature freeze injury, must add a large amount of antifreeze air entrapment agents, antifreeze and do not strengthen, fast solidifying and unhappy hard, the concrete bubble is many, impervious poor, therefore concrete later strength and weather resistance decrease.Normal occur cracking, crisp broken, peel off, emit water, seepage, extension ice, the tunnel defects such as moist, greatly affect construction quality.
For example: under central development of the West Regions decision-making, large quantities of engineering projects enter western part.Highway, railway, bridge, riverbed, hillside all need to build to be administered.The state key project financing the Qinghai-Tibet Railway need pass through 547 kilometers eternal frozen ground locations for many years, the Frozen Earth Railway Roadbed that dewaters is solidified, the broken section of the nearly 5000m of height above sea level along the line, weathered rock formation, richness (satisfy) ice soil property, landslide etc. all need outside supporting processes, the urgent need very low temperature slip casting of water frozen soil layer tunnel, injection that two total lengths are 3024 meters.Yet traditional material and Dong Shi technology can not meet the construction requirement of severe cold area fully, such as tooth timberline, tender timberline, the weak line in south etc., permafrost soil layer, Nan Han tunnel are due to the weather severe cold, general cracking in tunnel, crisp broken, peel off, hang ice, emit water, ponding, the tunnel defect such as icing, serious threat owner of a trading company or a workshop safety and work-ing life, maintenance work is heavy, administers very difficult.This is mainly because temperature is low, and the concrete Microstructure Fracture, due to infiltration, Chen Rong vicious cycle etc.
Summary of the invention
The purpose of this invention is to provide the rich ice of a kind of fine sand type soil property injecting paste material, be particularly suitable for sand content low use the frozen soil layer fracture grouting, prevent that soil layer from subsiding and reinforcing pre-treatment.
Technical scheme of the present invention is achieved in that the rich ice of a kind of fine sand type soil property injecting paste material, with C
3S-C
2S-
-CaO is that essential mineral grog, gypsum, industrial tailings intergrinding are made the gelling material masterbatch, and then adding particle diameter is that 6~10 μ m fine sands or CHARACTERISTICS OF TAILINGS SAND add water and stir and form.
The method for making of masterbatch has two kinds, method 1: with C
3S-C
2S-
-CaO is essential mineral grog 30~50%, gypsum 5~15% and industrial tailings 15~70%.Method 2: add CAS grog, OPC grog to be mixed, proportioning is: with C
3S-C
2S-
-CaO is essential mineral grog 10~15%, CAS grog 15~25%, OPC grog 5~10%, gypsum 5~15% and industrial tailings 15~70%.
The rich ice of fine sand type soil property injecting paste material is that 1 part of gelling material masterbatch adds 1~3 part of fine sand or CHARACTERISTICS OF TAILINGS SAND, and amount of water guarantees that water cement ratio is 0.8~1.2.
With C
3S-C
2S-
-CaO is that the method for making of essential mineral grog is: at CaO-SiO
2-Al
2O
3-Fe
2O
3-SO
3In the cement slurry of quinary system, excess has been introduced CaO, and the content of excessive oxidation calcium between b-CaO=5~8%, is controlled in basicity factor Km=1.0~1.3 scopes, and grog is made in calcining under the firing temperature of 1200 ℃~1300 ℃.
Beneficial effect of the present invention is: the rich ice of fine sand type of the present invention soil property injecting paste material adopts with C
3S-C
2S-
-CaO is that the configuration of essential mineral grog forms, and the general control Mortar'S Flowability is in the 400mm left and right, and the composite earth layer intensity the variation between grouting amount 3~20% and changed between 0.2~2.5Mpa between 30~60 minutes time of coagulation.Be particularly suitable for sand content low use the frozen soil layer fracture grouting, prevent that soil layer from subsiding and reinforcing pre-treatment.
Embodiment
Below in conjunction with specific embodiment, the present invention is further explained explanation.
Embodiment 1 is with C
3S-C
2S-
-CaO is that essential mineral grog 30%, gypsum 5% and industrial tailings 65% are made the gelatinous material masterbatch, and then adding particle diameter is that 6~10 μ m fine sands or CHARACTERISTICS OF TAILINGS SAND add water and stir and to form.The raw material materials are: 1 part of gelling material masterbatch adds 1 part of fine sand or CHARACTERISTICS OF TAILINGS SAND, and amount of water guarantees that water cement ratio is 0.8.
With C
3S-C
2S-
-CaO is that the method for making of essential mineral grog is: at CaO-SiO
2-Al
2O
3-Fe
2O
3-SO
3In the cement slurry of quinary system, excess has been introduced CaO, and the content of excessive oxidation calcium between b-CaO=5~8%, is controlled in basicity factor Km=1.0~1.3 scopes, and grog is made in calcining under the firing temperature of 1200 ℃~1300 ℃.
Embodiment 2 is with C
3S-C
2S-
-CaO is that essential mineral grog 10~15%, CAS grog 15~25%, OPC grog 5~10%, gypsum 5~15% and industrial tailings 15~70% are made the gelatinous material masterbatch, and then adding particle diameter is that 6~10 μ m fine sands or CHARACTERISTICS OF TAILINGS SAND add water and stir and to form.The raw material materials are: 1 part of gelling material masterbatch adds 3 parts of fine sands or CHARACTERISTICS OF TAILINGS SAND, and amount of water guarantees that water cement ratio is 1.2.
With C
3S-C
2S-
-CaO is that the method for making of essential mineral grog is: at CaO-SiO
2-Al
2O
3-Fe
2O
3-SO
3In the cement slurry of quinary system, excess has been introduced CaO, and the content of excessive oxidation calcium between b-CaO=5~8%, is controlled in basicity factor Km=1.0~1.3 scopes, and grog is made in calcining under the firing temperature of 1200 ℃~1300 ℃.
The above; only be the better embodiment of the present invention; but protection scope of the present invention is not limited to this; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to replacement or changed according to technical scheme of the present invention and inventive concept thereof, within all should being encompassed in protection scope of the present invention.