CN103382333A - Stain resistant environment-friendly latex paint for inner walls and preparation method thereof - Google Patents
Stain resistant environment-friendly latex paint for inner walls and preparation method thereof Download PDFInfo
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- CN103382333A CN103382333A CN2013102838911A CN201310283891A CN103382333A CN 103382333 A CN103382333 A CN 103382333A CN 2013102838911 A CN2013102838911 A CN 2013102838911A CN 201310283891 A CN201310283891 A CN 201310283891A CN 103382333 A CN103382333 A CN 103382333A
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- stain resistant
- resistant environment
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- interior wall
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Abstract
The invention relates to a stain resistant environment-friendly latex paint for inner walls and a preparation method thereof. The latex paint contains the following components by mass: 10-25 parts of a polyvinyl alcohol water solution, 9-22 parts of an organosilicon modified acrylic ester emulsion, 6.5-16 parts of silica sol, 5.5-9 parts of anatase nano-titanium dioxide, 7-16 parts of rutile titanium dioxide, 13-30 parts of heavy calcium carbonate, 3.5-8 parts of light calcium carbonate, 3-7 parts of ash calcium powder, 0.2-0.5 part of polyacrylic acid sodium salt, 0.27-0.67 part of polyacrylamide, 0.13-0.33 part of nucleoside 5'-thiophosphoryl amino acid ester, 0.27-0.7 part of tributyl phosphate, 0.45-1.17 parts of dimethylethanolamine, 0.1-1 part of fluorescent whitening agent, and 17-42.5 parts of water. The stain resistant environment-friendly latex paint for inner walls provided by the invention has the very strong stain resistance, and is environment-friendly and non-toxic.
Description
Technical field
The present invention relates to a kind of interior wall coating and preparation method thereof, relate in particular to a kind of interior wall stain resistant environment friendly emulsion paint and preparation method thereof.
Background technology
Along with improving constantly of people's living standard and quality of the life, it is more and more frequent that people carry out indoor decoration, and compared take clean and tidy practicality as main simple decoration with the past, now indoor decoration has been also had environmental protection, requirement attractive in appearance, also become important building and ornament materials as the interiro wall latex paint of inner wall decoration main tool.But due to problems such as people's daily routines and atmospheric pollutions, indoor wall is easy to be subject to the pollutions such as dust, grease.Simultaneously, as art work, indoor emulsion paint must environment-protecting asepsis.But indoor emulsion paint stain resistant performance in the market is low, and is also not high to the requirement of environmental protection.
Summary of the invention
The technical problem that solves:In the shortcoming aspect environmental protection and stain resistant performance, the invention provides a kind of interior wall stain resistant environment friendly emulsion paint and preparation method thereof for existing indoor emulsion paint.
Technical scheme:Interior wall stain resistant environment friendly emulsion paint, contain following composition in mass parts:
10~25 parts of polyvinyl alcohol water solutions
9~22 parts of organosilicon-modified acrylate emulsions
6.5~16 parts of silicon sol
5.5~9 parts of nanometer anatase titanias
7~16 parts of rutile titanium dioxides
13~30 parts of water-ground limestones
3.5~8 parts of light calcium carbonates
3~7 parts of ash calcium powders
0.2~0.5 part of polyacrylic acid sodium salt
0.27~0.67 part of polyacrylamide
Nucleosides 5 '-0.13~0.33 part of thiophosphoryl amino acid ester
0.27~0.7 part of tributyl phosphate
0.45~1.17 part of dimethylethanolamine
0.1~1 part of white dyes
17~42.5 parts, water.
Interior wall described above stain resistant environment friendly emulsion paint, contain following composition in mass parts:
13~20 parts of polyvinyl alcohol water solutions
13~19 parts of organosilicon-modified acrylate emulsions
9~15 parts of silicon sol
6.5~8 parts of nanometer anatase titanias
10~14 parts of rutile titanium dioxides
17~25 parts of water-ground limestones
4.8~7.2 parts of light calcium carbonates
4.5~6 parts of ash calcium powders
0.27~0.4 part of polyacrylic acid sodium salt
0.33~0.5 part of polyacrylamide
Nucleosides 5 '-0.2~0.3 part of thiophosphoryl amino acid ester
0.4~0.6 part of tributyl phosphate
0.65~1 part of dimethylethanolamine
0.3~0.8 part of white dyes
25~38 parts, water.
In polyvinyl alcohol water solution described above, the shared weight of polyvinyl alcohol is 10%.
Solid content in organosilicon-modified acrylate emulsion described above is 50%.
Interior wall described above with the stain resistant environment friendly emulsion paint preparation process as follows:
The first step: first water and polyacrylamide are added in agitator, mix to polyacrylamide and dissolve fully;
Second step: add in the agitator dimethylethanolamine, tributyl phosphate, polyacrylic acid sodium salt, nucleosides 5 '-thiophosphoryl amino acid ester and white dyes, stir;
The 3rd step: add silicon sol, nanometer anatase titania, rutile titanium dioxide in agitator, continue to stir;
The 4th step: add polyvinyl alcohol water solution, organosilicon-modified acrylate emulsion, water-ground limestone, light calcium carbonate and grey calcium powder in the most backward agitator, stir 45min, discharging namely gets interior wall stain resistant environment friendly emulsion paint.
Beneficial effect:Interior wall provided by the invention stain resistant environment friendly emulsion paint and preparation method thereof, this emulsion paint has very strong contamination resistance, and environment-protecting asepsis, its time of drying≤2h, washability number of times 〉=7000 time, prepared Chinese ink is infected with on filming, and the prepared Chinese ink of process 15h drying can thoroughly be washed, and this emulsion paint can keep the attractive in appearance of indoor wall.
Embodiment
Embodiment 1
The present embodiment provides a kind of interior wall stain resistant environment friendly emulsion paint, contains following composition in mass parts:
10 parts of polyvinyl alcohol water solutions
9 parts of organosilicon-modified acrylate emulsions
6.5 parts of silicon sol
5.5 parts of nanometer anatase titanias
7 parts of rutile titanium dioxides
13 parts of water-ground limestones
3.5 parts of light calcium carbonates
3 parts of ash calcium powders
0.2 part of polyacrylic acid sodium salt
0.27 part of polyacrylamide
Nucleosides 5 '-0.13 part of thiophosphoryl amino acid ester
0.27 part of tributyl phosphate
0.45 part of dimethylethanolamine
0.1 part of white dyes
17 parts, water.
Interior wall with the stain resistant environment friendly emulsion paint preparation process as follows:
The first step: first water and polyacrylamide are added in agitator, mix to polyacrylamide and dissolve fully;
Second step: add in the agitator dimethylethanolamine, tributyl phosphate, polyacrylic acid sodium salt, nucleosides 5 '-thiophosphoryl amino acid ester and white dyes, stir;
The 3rd step: add silicon sol, nanometer anatase titania, rutile titanium dioxide in agitator, continue to stir;
The 4th step: add polyvinyl alcohol water solution, organosilicon-modified acrylate emulsion, water-ground limestone, light calcium carbonate and grey calcium powder in the most backward agitator, stir 45min, discharging namely gets interior wall stain resistant environment friendly emulsion paint.
Embodiment 2
The present embodiment provides a kind of interior wall stain resistant environment friendly emulsion paint, contains following composition in mass parts:
25 parts of polyvinyl alcohol water solutions
22 parts of organosilicon-modified acrylate emulsions
16 parts of silicon sol
9 parts of nanometer anatase titanias
16 parts of rutile titanium dioxides
30 parts of water-ground limestones
8 parts of light calcium carbonates
7 parts of ash calcium powders
0.5 part of polyacrylic acid sodium salt
0.67 part of polyacrylamide
Nucleosides 5 '-0.33 part of thiophosphoryl amino acid ester
0.7 part of tributyl phosphate
1.17 parts of dimethylethanolamines
1 part of white dyes
42.5 parts, water.
Interior wall with the stain resistant environment friendly emulsion paint preparation process as follows:
The first step: first water and polyacrylamide are added in agitator, mix to polyacrylamide and dissolve fully;
Second step: add in the agitator dimethylethanolamine, tributyl phosphate, polyacrylic acid sodium salt, nucleosides 5 '-thiophosphoryl amino acid ester and white dyes, stir;
The 3rd step: add silicon sol, nanometer anatase titania, rutile titanium dioxide in agitator, continue to stir;
The 4th step: add polyvinyl alcohol water solution, organosilicon-modified acrylate emulsion, water-ground limestone, light calcium carbonate and grey calcium powder in the most backward agitator, stir 45min, discharging namely gets interior wall stain resistant environment friendly emulsion paint.
Embodiment 3
The present embodiment provides a kind of interior wall stain resistant environment friendly emulsion paint, contains following composition in mass parts:
13 parts of polyvinyl alcohol water solutions
13 parts of organosilicon-modified acrylate emulsions
9 parts of silicon sol
6.5 parts of nanometer anatase titanias
10 parts of rutile titanium dioxides
17 parts of water-ground limestones
4.8 parts of light calcium carbonates
4.5 parts of ash calcium powders
0.27 part of polyacrylic acid sodium salt
0.33 part of polyacrylamide
Nucleosides 5 '-0.2 part of thiophosphoryl amino acid ester
0.4 part of tributyl phosphate
0.65 part of dimethylethanolamine
0.3 part of white dyes
25 parts, water.
Interior wall with the stain resistant environment friendly emulsion paint preparation process as follows:
The first step: first water and polyacrylamide are added in agitator, mix to polyacrylamide and dissolve fully;
Second step: add in the agitator dimethylethanolamine, tributyl phosphate, polyacrylic acid sodium salt, nucleosides 5 '-thiophosphoryl amino acid ester and white dyes, stir;
The 3rd step: add silicon sol, nanometer anatase titania, rutile titanium dioxide in agitator, continue to stir;
The 4th step: add polyvinyl alcohol water solution, organosilicon-modified acrylate emulsion, water-ground limestone, light calcium carbonate and grey calcium powder in the most backward agitator, stir 45min, discharging namely gets interior wall stain resistant environment friendly emulsion paint.
Embodiment 4
The present embodiment provides a kind of interior wall stain resistant environment friendly emulsion paint, contains following composition in mass parts:
16.5 parts of polyvinyl alcohol water solutions
16 parts of organosilicon-modified acrylate emulsions
13 parts of silicon sol
7.3 parts of nanometer anatase titanias
12.5 parts of rutile titanium dioxides
21 parts of water-ground limestones
6.3 parts of light calcium carbonates
5.4 parts of ash calcium powders
0.35 part of polyacrylic acid sodium salt
0.4 part of polyacrylamide
Nucleosides 5 '-0.25 part of thiophosphoryl amino acid ester
0.5 part of tributyl phosphate
0.82 part of dimethylethanolamine
0.55 part of white dyes
32 parts, water.
Interior wall with the stain resistant environment friendly emulsion paint preparation process as follows:
The first step: first water and polyacrylamide are added in agitator, mix to polyacrylamide and dissolve fully;
Second step: add in the agitator dimethylethanolamine, tributyl phosphate, polyacrylic acid sodium salt, nucleosides 5 '-thiophosphoryl amino acid ester and white dyes, stir;
The 3rd step: add silicon sol, nanometer anatase titania, rutile titanium dioxide in agitator, continue to stir;
The 4th step: add polyvinyl alcohol water solution, organosilicon-modified acrylate emulsion, water-ground limestone, light calcium carbonate and grey calcium powder in the most backward agitator, stir 45min, discharging namely gets interior wall stain resistant environment friendly emulsion paint.
The above-mentioned interior wall of stating embodiment 1~embodiment 4 technical performance index of stain resistant environment friendly emulsion paint, its detected result is as follows:
Detected result
Test item | Technical indicator | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
Contamination resistance | GB/T9756-2008 | 0 grade | 0 grade | 0 grade | 0 grade |
Abrasion resistance | GB/T9266-1988 | 7000 times | 7056 times | 7112 times | 7150 times |
The above interior wall that the embodiment of the present invention is provided is described in detail with stain resistant environment friendly emulsion paint and preparation method thereof, for one of ordinary skill in the art, thought according to the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (5)
1. interior wall stain resistant environment friendly emulsion paint is characterized in that containing following composition in mass parts:
10~25 parts of polyvinyl alcohol water solutions
9~22 parts of organosilicon-modified acrylate emulsions
6.5~16 parts of silicon sol
5.5~9 parts of nanometer anatase titanias
7~16 parts of rutile titanium dioxides
13~30 parts of water-ground limestones
3.5~8 parts of light calcium carbonates
3~7 parts of ash calcium powders
0.2~0.5 part of polyacrylic acid sodium salt
0.27~0.67 part of polyacrylamide
Nucleosides 5 '-0.13~0.33 part of thiophosphoryl amino acid ester
0.27~0.7 part of tributyl phosphate
0.45~1.17 part of dimethylethanolamine
0.1~1 part of white dyes
17~42.5 parts, water.
2. interior wall according to claim 1 stain resistant environment friendly emulsion paint is characterized in that containing following composition in mass parts:
13~20 parts of polyvinyl alcohol water solutions
13~19 parts of organosilicon-modified acrylate emulsions
9~15 parts of silicon sol
6.5~8 parts of nanometer anatase titanias
10~14 parts of rutile titanium dioxides
17~25 parts of water-ground limestones
4.8~7.2 parts of light calcium carbonates
4.5~6 parts of ash calcium powders
0.27~0.4 part of polyacrylic acid sodium salt
0.33~0.5 part of polyacrylamide
Nucleosides 5 '-0.2~0.3 part of thiophosphoryl amino acid ester
0.4~0.6 part of tributyl phosphate
0.65~1 part of dimethylethanolamine
0.3~0.8 part of white dyes
25~38 parts, water.
3. interior wall according to claim 1 stain resistant environment friendly emulsion paint, is characterized in that in described polyvinyl alcohol water solution, the shared weight of polyvinyl alcohol is 10%.
4. interior wall according to claim 1 stain resistant environment friendly emulsion paint, is characterized in that the solid content in described organosilicon-modified acrylate emulsion is 50%.
5. interior wall as claimed in claim 1 with the preparation method of stain resistant environment friendly emulsion paint, is characterized in that the preparation process of the method is as follows:
The first step: first water and polyacrylamide are added in agitator, mix to polyacrylamide and dissolve fully;
Second step: add in the agitator dimethylethanolamine, tributyl phosphate, polyacrylic acid sodium salt, nucleosides 5 '-thiophosphoryl amino acid ester and white dyes, stir;
The 3rd step: add silicon sol, nanometer anatase titania, rutile titanium dioxide in agitator, continue to stir;
The 4th step: add polyvinyl alcohol water solution, organosilicon-modified acrylate emulsion, water-ground limestone, light calcium carbonate and grey calcium powder in the most backward agitator, stir 45min, discharging namely gets interior wall stain resistant environment friendly emulsion paint.
Priority Applications (1)
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CN2013102838911A CN103382333A (en) | 2013-07-08 | 2013-07-08 | Stain resistant environment-friendly latex paint for inner walls and preparation method thereof |
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CN2013102838911A CN103382333A (en) | 2013-07-08 | 2013-07-08 | Stain resistant environment-friendly latex paint for inner walls and preparation method thereof |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105171989A (en) * | 2015-09-18 | 2015-12-23 | 颍上县龙裕扬工贸有限公司 | Release agent for plastic product machining |
CN105175765A (en) * | 2015-09-18 | 2015-12-23 | 颍上县龙裕扬工贸有限公司 | Brightening paste for decorating and processing plastic product |
CN105176277A (en) * | 2015-09-18 | 2015-12-23 | 颍上县龙裕扬工贸有限公司 | Steeping liquid for brightening plastic product |
CN105255283A (en) * | 2015-11-05 | 2016-01-20 | 苏州明轩地坪涂料有限公司 | Latex paint for interior walls |
CN106519853A (en) * | 2016-11-29 | 2017-03-22 | 青岛海之星生物科技有限公司 | Formaldehyde removing latex paint based on titanium dioxide composite particles and preparation method of latex paint |
CN107151496A (en) * | 2017-05-24 | 2017-09-12 | 佛山实瑞先导材料研究院(普通合伙) | A kind of nano-TiO2Modified water-soluble composite coating and preparation method thereof |
CN107739560A (en) * | 2017-12-01 | 2018-02-27 | 和平世家钟表有限公司 | The environmental protection coating material and preparation method and its application method of a kind of laser cutting |
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CN1330119A (en) * | 2001-06-29 | 2002-01-09 | 邹侯招 | Anti-pollution emulsoid paint for internal wall and its preparing process |
JP2005015542A (en) * | 2003-06-24 | 2005-01-20 | Kuraray Co Ltd | Aqueous adhesive |
CN102268208A (en) * | 2011-06-02 | 2011-12-07 | 沈阳顺风新城建筑材料有限公司 | Nanometer silica sol modified exterior wall emulsion paint and preparation method thereof |
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JP2000169657A (en) * | 1998-12-08 | 2000-06-20 | Kuraray Co Ltd | Emulsion for flame-retarded foam sheet |
CN1330119A (en) * | 2001-06-29 | 2002-01-09 | 邹侯招 | Anti-pollution emulsoid paint for internal wall and its preparing process |
JP2005015542A (en) * | 2003-06-24 | 2005-01-20 | Kuraray Co Ltd | Aqueous adhesive |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105171989A (en) * | 2015-09-18 | 2015-12-23 | 颍上县龙裕扬工贸有限公司 | Release agent for plastic product machining |
CN105175765A (en) * | 2015-09-18 | 2015-12-23 | 颍上县龙裕扬工贸有限公司 | Brightening paste for decorating and processing plastic product |
CN105176277A (en) * | 2015-09-18 | 2015-12-23 | 颍上县龙裕扬工贸有限公司 | Steeping liquid for brightening plastic product |
CN105255283A (en) * | 2015-11-05 | 2016-01-20 | 苏州明轩地坪涂料有限公司 | Latex paint for interior walls |
CN106519853A (en) * | 2016-11-29 | 2017-03-22 | 青岛海之星生物科技有限公司 | Formaldehyde removing latex paint based on titanium dioxide composite particles and preparation method of latex paint |
CN107151496A (en) * | 2017-05-24 | 2017-09-12 | 佛山实瑞先导材料研究院(普通合伙) | A kind of nano-TiO2Modified water-soluble composite coating and preparation method thereof |
CN107739560A (en) * | 2017-12-01 | 2018-02-27 | 和平世家钟表有限公司 | The environmental protection coating material and preparation method and its application method of a kind of laser cutting |
CN107739560B (en) * | 2017-12-01 | 2018-10-12 | 和平世家钟表有限公司 | The environmental protection coating material and preparation method and its application method of a kind of laser cutting |
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Application publication date: 20131106 |