CN106634571A - Self-cleaning type outer wall coating and preparation method thereof - Google Patents

Self-cleaning type outer wall coating and preparation method thereof Download PDF

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Publication number
CN106634571A
CN106634571A CN201611169418.0A CN201611169418A CN106634571A CN 106634571 A CN106634571 A CN 106634571A CN 201611169418 A CN201611169418 A CN 201611169418A CN 106634571 A CN106634571 A CN 106634571A
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China
Prior art keywords
parts
latex
high speed
self
silicon
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Pending
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CN201611169418.0A
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Chinese (zh)
Inventor
廖凌峰
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Individual
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Individual
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Priority to CN201611169418.0A priority Critical patent/CN106634571A/en
Publication of CN106634571A publication Critical patent/CN106634571A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • C09D5/1675Polyorganosiloxane-containing compositions
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention relates to a self-cleaning type outer wall coating and a preparation method thereof, and belongs to the technical field of coatings. The self-cleaning type outer wall coating is prepared from the following raw materials in parts by weight: 30 to 40 parts of organic silicon latex, 20 to 30 parts of organic fluorine latex, 20 to 30 parts of silicon-scrylic latex, 0.5 to 1.0 part of a defoaming agent, 0.5 to 1 part of a sodium acrylate dispersing agent, 3 to 5 parts of a sodium hexametaphosphate dispersing agent, 1 to 2 parts of isopropyl alcohol, 25 to 30 parts of titanium dioxide, 10 to 15 parts of pigment and 50 to 100 parts of water. Due to the use of the organic silicon latex and the organic fluorine latex which are relatively low in polarity in the coating formula and the adding of a little of the silicon-scrylic latex, the adsorption capacity of an outer wall coating layer to pollutants and dust is effectively reduced, the pollutant resistance of the coating layer is enhanced, and relatively high self-cleaning property is realized; the long-term aesthetic property of an outer wall is improved, and the service life of the coating is prolonged.

Description

A kind of self-clean type exterior coating and preparation method thereof
Technical field
The present invention relates to a kind of coating and preparation method thereof, it is more particularly related to a kind of self-clean type exterior wall is applied Material and preparation method thereof, belongs to technical field of coatings.
Background technology
Polyacrylic acid latex is widely used at present as the primary raw material of pure polyacrylicresin outer wall paint, due to its excellent weatherability Property, preferably appearance of coat, can preferably compound processing characteristics, acrylic compounds exterior coating prepare in have highly important Using.But because general commercially available acrylic based emulsion has stronger polarity, there is stronger adsorption capacity to dust, greasy dirt etc., by Exterior coating coating prepared by it is caused the pollution of coating due to the absorption to above-mentioned substance and is stained, and has been had a strong impact on outer The spatter property of wall coating and attractive in appearance.Simultaneously as need Jing often to clean metope, considerably increase outer wall coating service life and Cost.
The content of the invention
Present invention seek to address that the problem that exterior coating easily pollutes in prior art, there is provided a kind of self-clean type exterior wall is applied Material, the coating has self-cleaning function, it is ensured that the cleaning of exterior wall surface.
In order to realize foregoing invention purpose, its specific technical scheme is as follows:
A kind of self-clean type exterior coating, it is characterised in that:Including following raw materials by weight:
Organosilicon latex 30-40 parts
Organic fluoride latex 20-30 parts
The latex 20-30 parts of silicon-the third
Defoamer 0.5-1.0 parts
PAA dispersant 0.5-1 parts
Calgon dispersant 3-5 parts
Isopropanol 1-2 parts
Titanium dioxide 25-30 parts
Pigment 10-15 parts
Water 50-100 parts.
A kind of preparation method of self-clean type exterior coating, it is characterised in that:Comprise the following steps that:
A, in a 100L rustless steel container accurately weigh isopropanol, titanium dioxide, pigment, water and PAA by recipe requirements Dispersant, calgon dispersant, isopropanol, preliminary stirring mixing;After above-mentioned each component dispersed with stirring is well mixed, transfer To high speed disperser, defoamer is added;Disperse 0.5-1.0h at a high speed in high speed disperser;
B, it is subsequently adding organosilicon latex, Organic fluoride latex, the latex of silicon-the third and disperses 2-3h at a high speed in high speed disperser;Again will It is transferred on double roller or three-roller through the scattered material of high speed and further mill dispersion 3-5 time;
C, cooling, discharging, filter, and are packaged to be product.
The Advantageous Effects that the present invention brings:
The present invention is by the relatively low organosilicon latex of polarity, Organic fluoride latex used in formulation for coating material, while adding a small amount of The latex of silicon third, effectively reduces outer wall coating to pollutant, the adsorption capacity of dust, improves the antipollution thing of paint coatings Property, with stronger self-cleaning.The long-term aesthetic property of exterior wall is not only increased, while improve the service life of coating.
Specific embodiment
Embodiment 1
A kind of self-clean type exterior coating, including following raw materials by weight:
30 parts of organosilicon latex
20 parts of Organic fluoride latex
20 parts of the latex of silicon-the third
0.5 part of defoamer
0.5 part of PAA dispersant
3 parts of calgon dispersant
1 part of isopropanol
25 parts of titanium dioxide
10 parts of pigment
50 parts of water.
Embodiment 2
A kind of self-clean type exterior coating, including following raw materials by weight:
40 parts of organosilicon latex
30 parts of Organic fluoride latex
30 parts of the latex of silicon-the third
1.0 parts of defoamer
1 part of PAA dispersant
5 parts of calgon dispersant
2 parts of isopropanol
30 parts of titanium dioxide
15 parts of pigment
100 parts of water.
Embodiment 3
A kind of self-clean type exterior coating, including following raw materials by weight:
35 parts of organosilicon latex
25 parts of Organic fluoride latex
25 parts of the latex of silicon-the third
0.7 part of defoamer
0.7 part of PAA dispersant
4 parts of calgon dispersant
1.5 parts of isopropanol
27 parts of titanium dioxide
13 parts of pigment
75 parts of water.
Embodiment 4
A kind of preparation method of self-clean type exterior coating, comprises the following steps that:
A, in a 100L rustless steel container accurately weigh isopropanol, titanium dioxide, pigment, water and PAA by recipe requirements Dispersant, calgon dispersant, isopropanol, preliminary stirring mixing;After above-mentioned each component dispersed with stirring is well mixed, transfer To high speed disperser, defoamer is added;Disperse 0.5h at a high speed in high speed disperser;
B, it is subsequently adding organosilicon latex, Organic fluoride latex, the latex of silicon-the third and disperses 2h at a high speed in high speed disperser;Again by Jing Cross the scattered material of high speed and to be transferred on double roller or three-roller further mill and disperse 3 times;
C, cooling, discharging, filter, and are packaged to be product.
Embodiment 5
A kind of preparation method of self-clean type exterior coating, comprises the following steps that:
A, in a 100L rustless steel container accurately weigh isopropanol, titanium dioxide, pigment, water and PAA by recipe requirements Dispersant, calgon dispersant, isopropanol, preliminary stirring mixing;After above-mentioned each component dispersed with stirring is well mixed, transfer To high speed disperser, defoamer is added;Disperse 1.0h at a high speed in high speed disperser;
B, it is subsequently adding organosilicon latex, Organic fluoride latex, the latex of silicon-the third and disperses 3h at a high speed in high speed disperser;Again by Jing Cross the scattered material of high speed and to be transferred on double roller or three-roller further mill and disperse 5 times;
C, cooling, discharging, filter, and are packaged to be product.
Embodiment 6
A kind of preparation method of self-clean type exterior coating, comprises the following steps that:
A, in a 100L rustless steel container accurately weigh isopropanol, titanium dioxide, pigment, water and PAA by recipe requirements Dispersant, calgon dispersant, isopropanol, preliminary stirring mixing;After above-mentioned each component dispersed with stirring is well mixed, transfer To high speed disperser, defoamer is added;Disperse 0.8h at a high speed in high speed disperser;
B, it is subsequently adding organosilicon latex, Organic fluoride latex, the latex of silicon-the third and disperses 2.5h at a high speed in high speed disperser;Again will It is transferred on double roller or three-roller through the scattered material of high speed and further mill dispersion 4 times;
C, cooling, discharging, filter, and are packaged to be product.

Claims (2)

1. a kind of self-clean type exterior coating, it is characterised in that:Including following raw materials by weight:
Organosilicon latex 30-40 parts
Organic fluoride latex 20-30 parts
The latex 20-30 parts of silicon-the third
Defoamer 0.5-1.0 parts
PAA dispersant 0.5-1 parts
Calgon dispersant 3-5 parts
Isopropanol 1-2 parts
Titanium dioxide 25-30 parts
Pigment 10-15 parts
Water 50-100 parts.
2. the preparation method of a kind of self-clean type exterior coating according to claim 1, it is characterised in that:Including following technique Step:
A, in a 100L rustless steel container accurately weigh isopropanol, titanium dioxide, pigment, water and PAA by recipe requirements Dispersant, calgon dispersant, isopropanol, preliminary stirring mixing;After above-mentioned each component dispersed with stirring is well mixed, transfer To high speed disperser, defoamer is added;Disperse 0.5-1.0h at a high speed in high speed disperser;
B, it is subsequently adding organosilicon latex, Organic fluoride latex, the latex of silicon-the third and disperses 2-3h at a high speed in high speed disperser;Again will It is transferred on double roller or three-roller through the scattered material of high speed and further mill dispersion 3-5 time;
C, cooling, discharging, filter, and are packaged to be product.
CN201611169418.0A 2016-12-16 2016-12-16 Self-cleaning type outer wall coating and preparation method thereof Pending CN106634571A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611169418.0A CN106634571A (en) 2016-12-16 2016-12-16 Self-cleaning type outer wall coating and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201611169418.0A CN106634571A (en) 2016-12-16 2016-12-16 Self-cleaning type outer wall coating and preparation method thereof

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Publication Number Publication Date
CN106634571A true CN106634571A (en) 2017-05-10

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110982364A (en) * 2019-12-06 2020-04-10 河南东风电力工程有限公司 Fireproof coating

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101067062A (en) * 2007-06-08 2007-11-07 东莞拓扑实业有限公司 High performance outer wall paint and its prepn
CN101724326A (en) * 2009-12-14 2010-06-09 杭州师范大学 Waterborne organic silicon-acrylic acid self-stratifying coating
CN102372979A (en) * 2010-08-24 2012-03-14 上海液光工贸发展有限公司 Anti-sticking aqueous fluoro-silicone coating and preparation method thereof
CN103387784A (en) * 2013-08-15 2013-11-13 安徽麒麟化工科技有限公司 Production method of novel hydrophobic healthy functional environment-friendly latex paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101067062A (en) * 2007-06-08 2007-11-07 东莞拓扑实业有限公司 High performance outer wall paint and its prepn
CN101724326A (en) * 2009-12-14 2010-06-09 杭州师范大学 Waterborne organic silicon-acrylic acid self-stratifying coating
CN102372979A (en) * 2010-08-24 2012-03-14 上海液光工贸发展有限公司 Anti-sticking aqueous fluoro-silicone coating and preparation method thereof
CN103387784A (en) * 2013-08-15 2013-11-13 安徽麒麟化工科技有限公司 Production method of novel hydrophobic healthy functional environment-friendly latex paint

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
陈治良: "《现代涂装手册》", 31 January 2010 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110982364A (en) * 2019-12-06 2020-04-10 河南东风电力工程有限公司 Fireproof coating

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Application publication date: 20170510