CN103367520A - InP-base lattice matching InGaAsBi detector structure with cutoff wavelength capable of being adjusted in wide range and preparation method thereof - Google Patents

InP-base lattice matching InGaAsBi detector structure with cutoff wavelength capable of being adjusted in wide range and preparation method thereof Download PDF

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CN103367520A
CN103367520A CN2013102644206A CN201310264420A CN103367520A CN 103367520 A CN103367520 A CN 103367520A CN 2013102644206 A CN2013102644206 A CN 2013102644206A CN 201310264420 A CN201310264420 A CN 201310264420A CN 103367520 A CN103367520 A CN 103367520A
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inp
ingaasbi
detector structure
lattice matching
wavelength
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顾溢
王庶民
张永刚
宋禹忻
叶虹
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Shanghai Institute of Microsystem and Information Technology of CAS
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Shanghai Institute of Microsystem and Information Technology of CAS
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Abstract

The invention relates to an InP-base lattice matching InGaAsBi detector structure with cutoff wavelength capable of being adjusted in a wide range and a preparation method thereof. From the bottom to the top, the detector structure sequentially comprises an InP substrate, a highly-doped n-type InP buffer layer, an absorbing layer and a highly-doped p-type InP cap layer. The absorbing layer is a lightly-doped n-type In<y>Ga<1-y>As<1-x>Bi<x> absorbing layer, wherein x is more than zero and less than or equal to 0.34 and y is more than or equal to zero and less than 0.53. The preparation method comprises the steps of 1) growing a highly-doped InP buffer layer on an InP substrate; 2) growing a lightly-doped n-type In<y>Ga<1-y>As<1-x>Bi<x> absorbing layer; 3) growing a cap layer; and 4) preparing an infrared detector structure. The detector provided by the invention can be matched with lattices of the InP substrate, the cutoff wavelength lambda can be adjusted within the wide range that lambda is more than 1.7mum and less than or equal to 5.9mum, the growth can be realized by using a conventional method and the preparation method is simple.

Description

Adjustable Lattice Matching InGaAsBi panel detector structure and the preparation thereof on a large scale of InP base cut-off wavelength
Technical field
The invention belongs to infrared detector structure and preparation field thereof, particularly a kind of InP base cut-off wavelength adjustable Lattice Matching InGaAsBi panel detector structure and preparation thereof on a large scale.
Background technology
Infrared Detectors has broad application prospects in information communication, space to ground detection, satellite remote sensing, multispectral imaging analysis, night vision imaging, military surveillance and numerous civilian and militaries such as supervision, infrared early warning field.Study for the ease of the infrared light to different wave length, people are divided into infrared spectrum following zone usually: near-infrared (0.7-2.0 μ m), in infrared (2.0-30 μ m) and far infrared (wavelength is at 30-1000 μ m).Simultaneously, according to several common atmospheric windows, infrared band habitually is divided into again short-wave infrared (1-3 μ m), medium-wave infrared (3-5 μ m), LONG WAVE INFRARED (8-14 μ m) and myriametric wave infrared (〉 14 μ m) etc.It is multiple that semiconductor detector comprises photoconduction type detector, photovoltaic detector, quantum well detector, quantum dot detector etc. by operation principle.Utilize the photovoltaic detector of PN junction photovoltaic effect to have simple in structure, quantum efficiency advantages of higher.
In with InP substrate lattice coupling 0.53Ga 0.47As ternary system material has the characteristics of direct band gap and high electron mobility, the about 0.74eV of the energy gap under its room temperature, and about 1.7 microns of corresponding wavelength can cover 1310nm and the 1550nm of longwave optical fiber communication just, so adopts In 0.53Ga 0.47The photodetector that As ternary system material is made has obtained generally to use at optical communication field, and at aspects such as remote sensing, sensing and imagings important use is arranged also.For In xGa 1-xAs ternary system material, change the ratio that the component value x(of group iii elements In wherein namely changes two kinds of element In of III family and Ga) its energy gap is changed between 0.36~1.43eV continuously, x particularly〉0.53 material, its corresponding wavelength can expand to〉1.7 microns wave band, for example: when the x value was increased to 0.8, the response wave length of material can expand to about 2.5 microns.The In of wavelength spread xGa 1-xThe As detector has widely purposes in fields such as remote sensing.But, along with the increase of In component value x, In xGa 1-xThe lattice constant of As ternary system material can corresponding increase, as x〉after 0.53, In xGa 1-xCan produce the positive mismatch of corresponding lattice between As ternary system material and its most frequently used InP substrate, be more greatly generation and the extension that will cause misfit dislocation and work as mismatch, thereby affect the quality of epitaxial material.
Summary of the invention
Technical problem to be solved by this invention provides adjustable Lattice Matching InGaAsBi panel detector structure and the preparation thereof on a large scale of a kind of InP base cut-off wavelength, the cut-off wavelength wide region of this infrared detector structure can be regulated, while is with InP substrate lattice coupling or have less lattice mismatch, preparation technology is simple, and is easy to control.
A kind of InP base cut-off wavelength of the present invention is adjustable Lattice Matching InGaAsBi panel detector structure on a large scale, this panel detector structure from bottom to top comprises successively: InP substrate, highly doped N-shaped InP resilient coating, absorbed layer and highly doped p-type InP cap layer, described absorbed layer is low-doped N-shaped In yGa 1-yAs 1-xBi xAbsorbed layer, wherein 0<x≤0.34,0≤y<0.53.
Described In yGa 1-yAs 1-xBi xAbsorbed layer and InP substrate lattice coupling.
Described detector cut-off wavelength λ is adjustable on a large scale, and adjustable range is 1.7 μ m<λ≤5.9 μ m.
Described absorbed layer is In 0.34Ga 0.66As 0.88Bi 0.12Material.
A kind of InP base cut-off wavelength of the present invention is the preparation method of adjustable Lattice Matching InGaAsBi infrared detector structure on a large scale, comprising:
(1) on the InP substrate, grows first the highly doped N-shaped InP of one deck material as resilient coating, simultaneously as lower contact layer;
(2) the low-doped N-shaped In of growth yGa 1-yAs 1-xBi xMaterial is as the absorbed layer of detector, wherein 0<x≤0.34,0≤y<0.53;
(3) the highly doped p-type InP material of growth simultaneously as upper contact layer, is finished the growth of material for detector as the cap layer;
(4) above-mentioned material for detector is prepared into infrared detector structure, gets final product.
X=0.12 described in the step (2), y=0.34, the cut-off wavelength of resulting InP base InGaAsBi infrared detector structure is 3 microns.
Can be by regulating In among the present invention yGa 1-yAs 1-xBi xThe component of In and Bi in (0<x≤0.34,0≤y<0.53) absorbed layer is mated the cut-off wavelength λ that regulates detector under the prerequisite on a large scale at detector and InP substrate lattice, and adjustable range is 1.7 μ m<λ≤5.9 μ m; Described In yGa 1-yAs 1-xBi x(0<x≤0.34,0≤y<0.53) absorbed layer and InP substrate lattice coupling.
Beneficial effect:
(1) InP of the present invention base InGaAsBi infrared detector structure cut-off wavelength adjustable while of wide region and InP substrate lattice coupling are by regulating the cut-off wavelength that the component of In and Bi can be regulated detector in the InGaAsBi absorbed layer;
(2) this panel detector structure can be grown with methods such as conventional molecular beam epitaxy, metal organic chemical vapor depositions, and operating procedure is simple, and is easy to control.
Description of drawings
Fig. 1 is the basic cut-off wavelength of the InP of this invention schematic diagram of adjustable Lattice Matching InGaAsBi panel detector structure on a large scale;
Fig. 2 is the InGaAsBi absorbed layer energy gap of calculating and the relation of Bi component x and In component y;
Fig. 3 be among the embodiment 13 microns of a kind of cut-off wavelengths and with the InGaAsBi infrared detector structure schematic diagram of InP substrate lattice coupling.
Embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used for explanation the present invention and be not used in and limit the scope of the invention.Should be understood that in addition those skilled in the art can make various changes or modifications the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims limited range equally.
Embodiment 1
Below on the InP substrate InGaAaBi detector and preparation method thereof of 3 microns of cut-off wavelengths this kind InP base cut-off wavelength adjustable Lattice Matching panel detector structure and preparation method thereof on a large scale is described as example:
(1) will be at the Lattice Matching InGaAaBi detector of 3 microns of InP substrate preparation cut-off wavelengths, the corresponding energy gap of absorbed layer should be 0.41eV, only draw the contour of every interval 0.1eV owing to spatial relationship among Fig. 2, but in fact can obtain more high-precision energy gap value.Can get In by Fig. 2 0.34Ga 0.66As 0.88Bi 0.12Material can be 0.41eV with InP Lattice Matching and energy gap.
(2) the 1 μ m doping content of growing first on the InP substrate is 2 * 10 18Cm -3N-shaped InP resilient coating, simultaneously as lower contact layer;
(3) growth 2 μ m doping contents are 3 * 10 6Cm -3N-shaped In 0.34Ga 0.66As 0.88Bi 0.12Absorbed layer, its room temperature energy gap is 0.41eV, the respective devices cut-off wavelength is 3 microns;
(4) growth 0.5 μ m doping content is 2 * 10 18Cm -3P-type InP cap layer, simultaneously as upper contact layer, finish the growth of material for detector;
(5) material of growing is prepared the table top panel detector structure by conventional semiconductor technology.

Claims (6)

1. InP base cut-off wavelength adjustable Lattice Matching InGaAsBi panel detector structure on a large scale, this infrared detector structure from bottom to top comprises successively: InP substrate, highly doped N-shaped InP resilient coating, absorbed layer and highly doped p-type InP cap layer, it is characterized in that described absorbed layer is low-doped N-shaped In yGa 1-yAs 1-xBi xAbsorbed layer, wherein 0<x≤0.34,0≤y<0.53.
2. a kind of InP base cut-off wavelength according to claim 1 adjustable Lattice Matching InGaAsBi panel detector structure on a large scale is characterized in that described In yGa 1-yAs 1-xBi xAbsorbed layer and InP substrate lattice coupling.
3. a kind of InP base cut-off wavelength according to claim 1 adjustable Lattice Matching InGaAsBi panel detector structure on a large scale is characterized in that described detector cut-off wavelength λ is adjustable on a large scale, and adjustable range is 1.7 μ m<λ≤5.9 μ m.
4. a kind of InP base cut-off wavelength according to claim 1 adjustable Lattice Matching InGaAsBi panel detector structure on a large scale is characterized in that described absorbed layer is In 0.34Ga 0.66As 0.88Bi 0.12Material.
5. the InP base cut-off wavelength preparation method of adjustable Lattice Matching InGaAsBi panel detector structure on a large scale comprises:
(1) the highly doped N-shaped InP of one deck resilient coating of growing first on the InP substrate is simultaneously as lower contact layer;
(2) the low-doped N-shaped In of growth yGa 1-yAs 1-xBi xMaterial is as the absorbed layer of detector; 0<x≤0.34,0≤y<0.53 wherein;
(3) the highly doped p-type InP of growth simultaneously as upper contact layer, finishes the growth of material for detector as the cap layer;
(4) above-mentioned material for detector is prepared into infrared detector structure, gets final product.
6. a kind of InP base cut-off wavelength according to claim 5 preparation method of adjustable Lattice Matching InGaAsBi panel detector structure on a large scale, it is characterized in that, x=0.12 described in the step (2), y=0.34, the cut-off wavelength of resulting InP base InGaAsBi infrared detector structure is 3 microns.
CN2013102644206A 2013-06-27 2013-06-27 InP-base lattice matching InGaAsBi detector structure with cutoff wavelength capable of being adjusted in wide range and preparation method thereof Pending CN103367520A (en)

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Cited By (9)

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CN103794693A (en) * 2014-02-14 2014-05-14 中国科学院上海微系统与信息技术研究所 Light emitting diode and OCT imaging system
CN105609582A (en) * 2015-12-01 2016-05-25 中国科学院上海微系统与信息技术研究所 Inter-band and inter-sub-valence band absorption-based rare bismuth quantum well detector and preparation method thereof
CN105826423A (en) * 2016-05-20 2016-08-03 中山市厚源电子科技有限公司 Wide-band infrared detector
CN106784119A (en) * 2016-11-29 2017-05-31 苏州苏纳光电有限公司 Detector of compound optoelectronic containing Bi and preparation method thereof
CN109786510A (en) * 2019-03-11 2019-05-21 中国科学院上海微系统与信息技术研究所 A kind of preparation method of four-element detector system and thus obtained indium gallium arsenic bismuth four-element detector system
CN110896120A (en) * 2019-11-11 2020-03-20 中国科学院上海技术物理研究所 Multilayer InGaAs detector material structure and preparation method
CN110896114A (en) * 2019-11-11 2020-03-20 中国科学院上海技术物理研究所 PIIN type high In component InGaAs detector material structure and preparation method
CN111418120A (en) * 2017-12-04 2020-07-14 三菱电机株式会社 Electric field absorption modulator, optical semiconductor device, and optical module
CN114914313A (en) * 2022-06-30 2022-08-16 山东云海国创云计算装备产业创新中心有限公司 Infrared photoelectric detector for photonic chip and manufacturing method thereof

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Cited By (12)

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CN103794693A (en) * 2014-02-14 2014-05-14 中国科学院上海微系统与信息技术研究所 Light emitting diode and OCT imaging system
CN103794693B (en) * 2014-02-14 2016-05-18 中国科学院上海微系统与信息技术研究所 A kind of light emitting diode and optical coherence tomography system
CN105609582A (en) * 2015-12-01 2016-05-25 中国科学院上海微系统与信息技术研究所 Inter-band and inter-sub-valence band absorption-based rare bismuth quantum well detector and preparation method thereof
CN105826423A (en) * 2016-05-20 2016-08-03 中山市厚源电子科技有限公司 Wide-band infrared detector
CN106784119A (en) * 2016-11-29 2017-05-31 苏州苏纳光电有限公司 Detector of compound optoelectronic containing Bi and preparation method thereof
CN106784119B (en) * 2016-11-29 2018-04-03 苏州苏纳光电有限公司 Detector of compound optoelectronic containing Bi and preparation method thereof
CN111418120A (en) * 2017-12-04 2020-07-14 三菱电机株式会社 Electric field absorption modulator, optical semiconductor device, and optical module
CN109786510A (en) * 2019-03-11 2019-05-21 中国科学院上海微系统与信息技术研究所 A kind of preparation method of four-element detector system and thus obtained indium gallium arsenic bismuth four-element detector system
CN110896120A (en) * 2019-11-11 2020-03-20 中国科学院上海技术物理研究所 Multilayer InGaAs detector material structure and preparation method
CN110896114A (en) * 2019-11-11 2020-03-20 中国科学院上海技术物理研究所 PIIN type high In component InGaAs detector material structure and preparation method
CN110896114B (en) * 2019-11-11 2021-10-01 中国科学院上海技术物理研究所 PIIN type high In component InGaAs detector material structure and preparation method
CN114914313A (en) * 2022-06-30 2022-08-16 山东云海国创云计算装备产业创新中心有限公司 Infrared photoelectric detector for photonic chip and manufacturing method thereof

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