CN103360993B - A kind of White emulsion composite paper box adhesive and preparation method thereof - Google Patents
A kind of White emulsion composite paper box adhesive and preparation method thereof Download PDFInfo
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- CN103360993B CN103360993B CN201310280619.8A CN201310280619A CN103360993B CN 103360993 B CN103360993 B CN 103360993B CN 201310280619 A CN201310280619 A CN 201310280619A CN 103360993 B CN103360993 B CN 103360993B
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- paper box
- composite paper
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- white emulsion
- box adhesive
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Abstract
A kind of White emulsion composite paper box adhesive, is characterized in that being made up of the raw material of following weight part: polyoxyethylene glycol 3-4, hydrogen peroxide 6-8, TriMethylolPropane(TMP) 3-4, tolylene diisocyanate 2-3, neopentyl glycol 3-4, sodium bicarbonate 2-3, citric acid 1-2, benzene emulsion 12-14, polyvinyl alcohol 8-10, white glue with vinyl 5-7, polyaminoester microball 3-4, morpholine 1-2, Sodium Persulfate 2-3, chitosan 5-6, polyvinylpyrrolidone 4-5, vinylformic acid 2-3, water 80-90.Invention adhesive is not containing organic solvent, not release formaldehyde, and adhesivity is good, stripping strength and hold tack high, for packed in cases, also can be applicable to Flexible-Packaging Industry.
Description
Technical field
The present invention relates to a kind of chemical materials, more specifically relate to a kind of tackiness agent.
Background technology
At present, a lot of for carton adhesive kind, there are three-aldehyde glue and white glue with vinyl etc.Some tackiness agent production and application process in can discharge free state formaldehyde, to human body and environmental hazard serious; Some tackiness agent, water tolerance and wet fastness poor, easily moisture absorption in damp atmosphere, bonding strength is not high; At high temperature use can produce creep, Joint strength is declined, below-5 DEG C, stores easy freezing, and emulsion is damaged, and therefore causes its application greatly limited.The bonding strength needing research to make new advances is high, the tackiness agent of safety and environmental protection, good stability.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of White emulsion composite paper box adhesive and preparation method thereof is provided.
Technical scheme of the present invention is as follows:
A kind of White emulsion composite paper box adhesive, is characterized in that being made up of the raw material of following weight part: polyoxyethylene glycol 3-4, hydrogen peroxide 6-8, TriMethylolPropane(TMP) 3-4, tolylene diisocyanate 2-3, neopentyl glycol 3-4, sodium bicarbonate 2-3, citric acid 1-2, benzene emulsion 12-14, polyvinyl alcohol 8-10, white glue with vinyl 5-7, polyaminoester microball 3-4, morpholine 1-2, Sodium Persulfate 2-3, chitosan 5-6, polyvinylpyrrolidone 4-5, vinylformic acid 2-3, water 80-90.
The preparation method of described White emulsion composite paper box adhesive, is characterized in that comprising the following steps:
(1), by polyvinyl alcohol, chitosan, polyvinylpyrrolidone, polyoxyethylene glycol, sodium bicarbonate add water, be heated to 65-75 DEG C of dissolving, then add polyaminoester microball, morpholine, Sodium Persulfate, stirring reaction 1-2 hour;
(2), hydrogen peroxide, TriMethylolPropane(TMP), neopentyl glycol, vinylformic acid, tolylene diisocyanate are added in step (1) material, continue to stir 2-3 hour;
(3), by step (2) material mix with other remaining component, be heated to 60-70 DEG C, stir 1-2 hour, to obtain final product.
Invention adhesive is not containing organic solvent, not release formaldehyde, and adhesivity is good, stripping strength and hold tack high, for packed in cases, also can be applicable to Flexible-Packaging Industry.
Embodiment
A kind of White emulsion composite paper box adhesive, is made up of the raw material of following weight part (kilogram): polyoxyethylene glycol 3, hydrogen peroxide 6, TriMethylolPropane(TMP) 4, tolylene diisocyanate 2, neopentyl glycol 4, sodium bicarbonate 2, citric acid 1, benzene emulsion 14, polyvinyl alcohol 8, white glue with vinyl 7, polyaminoester microball 3, morpholine 2, Sodium Persulfate 2, chitosan 6, polyvinylpyrrolidone 5, vinylformic acid 2, water 80.
The preparation method of White emulsion composite paper box adhesive, comprises the following steps:
(1), by polyvinyl alcohol, chitosan, polyvinylpyrrolidone, polyoxyethylene glycol, sodium bicarbonate add water, be heated to 65-75 DEG C of dissolving, then add polyaminoester microball, morpholine, Sodium Persulfate, stirring reaction 1-2 hour;
(2), hydrogen peroxide, TriMethylolPropane(TMP), neopentyl glycol, vinylformic acid, tolylene diisocyanate are added in step (1) material, continue to stir 2-3 hour;
(3), by step (2) material mix with other remaining component, be heated to 60-70 DEG C, stir 1-2 hour, to obtain final product.
Tackiness agent prepared by the present invention, through detecting: after 4 hours, bonding strength reaches 19Mpa, water-tolerant.After bonding, put into 40 DEG C of water and soak 2 hours, bonding strength is 15Mpa.
Claims (1)
1. a White emulsion composite paper box adhesive, is characterized in that being made up of the raw material of following weight part: polyoxyethylene glycol 3-4, hydrogen peroxide 6-8, TriMethylolPropane(TMP) 3-4, tolylene diisocyanate 2-3, neopentyl glycol 3-4, sodium bicarbonate 2-3, citric acid 1-2, benzene emulsion 12-14, polyvinyl alcohol 8-10, white glue with vinyl 5-7, polyaminoester microball 3-4, morpholine 1-2, Sodium Persulfate 2-3, chitosan 5-6, polyvinylpyrrolidone 4-5, vinylformic acid 2-3, water 80-90;
The preparation method of described White emulsion composite paper box adhesive comprises the following steps:
(1), by polyvinyl alcohol, chitosan, polyvinylpyrrolidone, polyoxyethylene glycol, sodium bicarbonate add water, be heated to 65-75 DEG C of dissolving, then add polyaminoester microball, morpholine, Sodium Persulfate, stirring reaction 1-2 hour;
(2), hydrogen peroxide, TriMethylolPropane(TMP), neopentyl glycol, vinylformic acid, tolylene diisocyanate are added in step (1) material, continue to stir 2-3 hour;
(3), by step (2) material mix with other remaining component, be heated to 60-70 DEG C, stir 1-2 hour, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310280619.8A CN103360993B (en) | 2013-07-05 | 2013-07-05 | A kind of White emulsion composite paper box adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310280619.8A CN103360993B (en) | 2013-07-05 | 2013-07-05 | A kind of White emulsion composite paper box adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103360993A CN103360993A (en) | 2013-10-23 |
| CN103360993B true CN103360993B (en) | 2016-03-16 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310280619.8A Expired - Fee Related CN103360993B (en) | 2013-07-05 | 2013-07-05 | A kind of White emulsion composite paper box adhesive and preparation method thereof |
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| CN (1) | CN103360993B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327787B (en) * | 2014-11-11 | 2016-05-25 | 句容市茂源织造厂 | A kind of carton processing adhesive |
| CN104628989B (en) * | 2015-02-15 | 2017-05-17 | 佛山市柏杰油墨科技有限公司 | Aqueous jet ink for cotton fabric and preparation method thereof |
| CN106336850A (en) * | 2016-06-17 | 2017-01-18 | 临泉县亚泰包装有限公司 | Environmentally-friendly non-formaldehyde carton adhesive and preparation method thereof |
| CN112721346B (en) * | 2020-11-27 | 2024-05-03 | 长治市宏瑞祥环保科技有限公司 | Negative oxygen ion bottom plate, preparation method thereof and application thereof in wood floor |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102137755A (en) * | 2008-07-22 | 2011-07-27 | 东洋制罐株式会社 | Multilayer film using solvent-free adhesive, method for producing same and packaging container using same |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2002328410B2 (en) * | 2001-09-05 | 2008-06-26 | Mitsubishi Gas Chemical Company, Inc. | Adhesive for gas barrier laminates and laminated films |
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2013
- 2013-07-05 CN CN201310280619.8A patent/CN103360993B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102137755A (en) * | 2008-07-22 | 2011-07-27 | 东洋制罐株式会社 | Multilayer film using solvent-free adhesive, method for producing same and packaging container using same |
Non-Patent Citations (2)
| Title |
|---|
| 复合膜及泡罩用胶粘剂状况分析;张宝堂;《包装材料》;20051231(第1期);第50-53页 * |
| 解析软包装复合胶的配方、生产和技术要求;刘家聚;《湖南包装》;20061231;第21、25-27页 * |
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| CN103360993A (en) | 2013-10-23 |
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Inventor after: Wei Renxing Inventor before: Bi Quanzhong |
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Effective date of registration: 20170614 Address after: 516000 Tengda road Guangdong Huizhou Zhongkai hi tech Industrial Development Zone Patentee after: Huizhou xinsaida Industrial Co., Ltd. Address before: 239500 Anhui city of Chuzhou province Quanjiao County town of six liquor farmers Park Patentee before: Quanjiao Haifeng Printing Packaging Co., Ltd. |
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