CN103360090A - Cement rotary kiln firebrick laying mortar - Google Patents

Cement rotary kiln firebrick laying mortar Download PDF

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Publication number
CN103360090A
CN103360090A CN2013103086508A CN201310308650A CN103360090A CN 103360090 A CN103360090 A CN 103360090A CN 2013103086508 A CN2013103086508 A CN 2013103086508A CN 201310308650 A CN201310308650 A CN 201310308650A CN 103360090 A CN103360090 A CN 103360090A
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China
Prior art keywords
aggregate
mass percent
clay
granularity
cement kiln
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CN2013103086508A
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CN103360090B (en
Inventor
范圣良
曾大凡
肖家祥
陈幼荣
蒋晓臻
张松立
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ZHEJIANG RUITAI REFRACTORY TECHNOLOGY Co Ltd
South Cement Co Ltd
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ZHEJIANG RUITAI REFRACTORY TECHNOLOGY Co Ltd
South Cement Co Ltd
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Publication of CN103360090A publication Critical patent/CN103360090A/en
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Publication of CN103360090B publication Critical patent/CN103360090B/en
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  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses cement rotary kiln firebrick laying mortar which comprises the following components: by weight, 80-85% of aggregate, 14-19% of a binder and 1-3% of a coagulation accelerator. By selecting a reasonable ratio of the aggregate to the binder, each element in the fireproof mortar is used at the operating temperature to firmly combine firebricks together through a series of chemical reactions or ceramic reactions between the fireproof mortar and firebricks. Thus, firebricks made from different materials are laid to form an integral body.

Description

A kind of for rotary cement kiln laying fireproof bricks clay
Technical field
The present invention relates to a kind of for rotary cement kiln laying fireproof bricks clay.
Background technology
Domestic rotary cement kiln laying fireproof bricks mode mainly adopts wet the block, namely builds refractory brick with refractory mortar/chamotte by laying bricks or stones as cakingagent.The working condition of rotary cement kiln different sites differs greatly, and different sites need to use different refractory brick, to consistence and the economy that reaches work-ing life.Generally, each refractory brick all needs to configure independent refractory mortar/chamotte, and this just causes needs to use multiple refractory mortar/chamotte in construction process, causes construction inconvenience.If control is improper in the construction process, use low-grade refractory mortar/chamotte to build high temperature position refractory brick by laying bricks or stones after, easily cause the strength decreased of building by laying bricks or stones of high temperature position refractory brick, easily cause the lot of refractory brick to damage, serious harm the normal operation of rotary cement kiln.
Summary of the invention
Problem to be solved by this invention provides a kind of for rotary cement kiln laying fireproof bricks clay, can be complementary with the various refractory brick that rotary cement kiln mainly uses, reduce clay kind in the rotary cement kiln building process, improve masonry quality, has good workability under applied widely, the good combination property, normal temperature.
In order to solve the problems of the technologies described above, the present invention adopts following technical scheme: a kind of for rotary cement kiln laying fireproof bricks clay, comprise that the mass percent of following component and each component is: aggregate 80~85%; Wedding agent 14~19%; Setting accelerator 1~3%.Select rational aggregate and wedding agent composition proportion, make in the refractory mortar each element under the working temperature of blast furnace, by series of chemical or the pottery reaction that occurs between the composition, refractory mortar is sticked on the refractory brick securely, thereby make the refractory brick of unlike material be built by laying bricks or stones in aggregates.
Improved, the mass percent of each component is: aggregate 80%; Wedding agent 19%; Setting accelerator 1%.
Improved, the mass percent of each component is: aggregate 85%; Wedding agent 14%; Setting accelerator 1%.
Improved, the mass percent of each component is: aggregate 82%; Wedding agent 15%; Setting accelerator 3%.
Improved, described aggregate comprises that granularity is 0.3~0.088mm; Granularity is 0.088~0.044mm; Granularity is less than three kinds of specifications of 0.044mm, and the mass percent of the aggregate of three kinds of specifications is respectively: granularity is the aggregate 20~30% of 0.3~0.088mm; Granularity is the aggregate 45~60% of 0.088~0.044mm; Granularity is less than the aggregate 15~25% of 0.044mm.
Improved, described aggregate comprises that the mass percent of following component and each component is: Al 2O 380~85%, SiO 210~13%, Fe3~5%, all the other are TiO 2The major ingredient that guarantees refractory mortar is close with the major ingredient of various material refractory brick, thereby makes refractory mortar with having preferably chemical affinity between the refractory brick.
Improved, described wedding agent comprises that the mass percent of following component and each component is: silicon sol 80-85%, polyacrylic acid 15-20%.Make refractory mortar under the normal temperature curing condition, by silicon sol, polyacrylic series of chemical, impel refractory mortar generation curing reaction, thereby produce intensity.
Improved, described setting accelerator comprises at least a in aluminate cement, alkalimetal oxide and the alkali metal hydroxide.Utilize aluminate cement or alkalimetal oxide or alkali metal hydroxide to react with silicon sol, polyacrylic acid in the wedding agent, impel silicon sol, polyacrylic sclerosis, improve the refractory mortar early strength.
Improved, described setting accelerator comprises aluminate cement at least, and the mass percent that described aluminate cement accounts for relative clay is 1~3%.Better with silicon sol in the wedding agent, polyacrylic reaction effect.
Beneficial effect:
After adopting technique scheme, this is a kind of for rotary cement kiln laying fireproof bricks clay, rational aggregate and Binder Composition proportioning have been selected, make in the refractory mortar each element under the working temperature of cement rotary kiln, by series of chemical or the pottery reaction that occurs between the composition, stick to securely refractory mortar on the refractory brick, thereby make the refractory brick of unlike material be built by laying bricks or stones in aggregates, possess enough refractoriness and refractoriness under load and good coefficient of thermal expansion and resistance to fouling, and between the various unlike material bricks of rotary cement kiln enough strong cohesive strength is arranged all, but have good workability and other use properties.
Embodiment
A kind ofly comprise aggregate, wedding agent and setting accelerator for rotary cement kiln laying fireproof bricks clay, wherein the mass percent of aggregate is 80~85%, and the mass percent of wedding agent is 14~19%, and the mass percent of setting accelerator is 1~3%.
Described aggregate comprises that granularity is 0.3~0.088mm, granularity is 0.088~0.044mm, granularity is less than three kinds of specifications of 0.044mm, wherein granularity is that the mass percent of the aggregate of 0.3~0.088mm is 20~30%, granularity is that the mass percent of the aggregate of 0.088~0.044mm is 45~60%, granularity is 15~25% less than the mass percent of the aggregate of 0.044mm, as preferably, granularity is that the mass percent of the aggregate of 0.3~0.088mm is 20%, granularity is that the mass percent of the aggregate of 0.088~0.044mm is 60%, granularity is 20% less than the mass percent of the aggregate of 0.044mm, perhaps granularity is that the mass percent of the aggregate of 0.3~0.088mm is 30%, granularity is that the mass percent of the aggregate of 0.088~0.044mm is 45%, granularity is 25% less than the mass percent of the aggregate of 0.044mm, perhaps granularity is that the mass percent of the aggregate of 0.3~0.088mm is 25%, granularity is that the mass percent of the aggregate of 0.088~0.044mm is 60%, and granularity is 15% less than the mass percent of the aggregate of 0.044mm; Described aggregate comprises Al 2O 3, and SiO 2And Fe, wherein Al 2O 3Mass percent be 80~85%, SiO 2Mass percent be that the mass percent of 10~13%, Fe is 3~5%, all the other are TiO 2
Described wedding agent comprises silicon sol and polyacrylic acid, wherein the mass percent of silicon sol is 80~85%, the polyacrylic acid mass percent is 15~20%, as preferably, the mass percent of silicon sol is 80%, and the polyacrylic acid mass percent is 20%, perhaps the mass percent of silicon sol is 85%, the polyacrylic acid mass percent is 15%, and perhaps the mass percent of silicon sol is 82%, and the polyacrylic acid mass percent is 18%.
Described setting accelerator comprises at least a in aluminate cement, alkalimetal oxide and the alkali metal hydroxide, as preferably, at least comprise aluminate cement in the described setting accelerator, the mass percent that described aluminate cement accounts for relative clay is 1~3%, as preferably, described setting accelerator is aluminate cement or aluminate cement, both mixtures of alkalimetal oxide or aluminate cement, both mixtures of alkali metal hydroxide or aluminate cement, alkalimetal oxide, alkali metal hydroxide three's mixture.
Embodiment one:
In the present embodiment, aggregate is 80%, wedding agent is 19%, and setting accelerator is 1%.Al in the aggregate 2O 3Content is 81%, SiO 2Content is that 12.5%, Fe content is 4.5%, and granularity is the aggregate 25% of 0.3~0.088mm, and granularity is that the aggregate of 0.088~0.044mm is 55%, and granularity is 20% less than the aggregate of 0.044mm.Silicon sol content is 80% in the wedding agent, and polyacrylic acid content is 20%.Setting accelerator aluminium acid salt cement.
Embodiment two:
In the present embodiment, aggregate is 85%; Wedding agent is 14%; Setting accelerator is 1%.
Embodiment three:
In the present embodiment, aggregate is 82%; Wedding agent is 15%; Setting accelerator is 3%.
With the full and uniform mixing of the above-mentioned aggregate that has prepared, before construction, join in the slurry mixer, then add wedding agent and setting accelerator, be stirred to and build required denseness by laying bricks or stones and can use.After tested, the performance of clay: 1720 ℃ of refractoriness, refractoriness under load T 0.2=1510 ℃, (1400 ℃ * 3h)-1%, have good physicals of line velocity of variation.
Except above preferred embodiment, the present invention also has other embodiment, and those skilled in the art can make according to the present invention various changes and distortion, only otherwise break away from spirit of the present invention, all should belong to the defined scope of claims of the present invention.

Claims (9)

1. one kind is used for rotary cement kiln laying fireproof bricks clay, and it is characterized in that: the mass percent that comprises following component and each component is: aggregate 80~85%; Wedding agent 14~19%; Setting accelerator 1~3%.
2. according to claim 1 a kind of for rotary cement kiln laying fireproof bricks clay, it is characterized in that: the mass percent of each component is: aggregate 80%; Wedding agent 19%; Setting accelerator 1%.
3. according to claim 1 a kind of for rotary cement kiln laying fireproof bricks clay, it is characterized in that: the mass percent of each component is: aggregate 85%; Wedding agent 14%; Setting accelerator 1%.
4. according to claim 1 a kind of for rotary cement kiln laying fireproof bricks clay, it is characterized in that: the mass percent of each component is: aggregate 82%; Wedding agent 15%; Setting accelerator 3%.
5. according to claim 1 to 4 arbitrary described a kind of for rotary cement kiln laying fireproof bricks clay, it is characterized in that: described aggregate comprise granularity be 0.3~0.088mm, granularity be 0.088~0.044mm, granularity less than three kinds of specifications of 0.044mm, the mass percent of the aggregate of three kinds of specifications is respectively: granularity is the aggregate 20~30% of 0.3~0.088mm; Granularity is the aggregate 45~60% of 0.088~0.044mm; Granularity is less than the aggregate 15~25% of 0.044mm.
6. according to claim 5 a kind of for rotary cement kiln laying fireproof bricks clay, it is characterized in that: described aggregate comprises that the mass percent of following component and each component is: Al 2O 380~85%, SiO 210~13%, Fe3~5%, all the other are TiO 2
7. according to claim 1 to 4 arbitrary described a kind of for rotary cement kiln laying fireproof bricks clay, it is characterized in that: described wedding agent comprises that the mass percent of following component and each component is: silicon sol 80~85%, polyacrylic acid 15~20%.
8. according to claim 1 to 4 arbitrary described a kind of for rotary cement kiln laying fireproof bricks clay, it is characterized in that: described setting accelerator comprises at least a in aluminate cement, alkalimetal oxide and the alkali metal hydroxide.
9. according to claim 8 a kind of for rotary cement kiln laying fireproof bricks clay, it is characterized in that: described setting accelerator comprises aluminate cement at least, and the mass percent that described aluminate cement accounts for relative clay is 1~3%.
CN201310308650.8A 2013-07-18 2013-07-18 Cement rotary kiln firebrick laying mortar Active CN103360090B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104944978A (en) * 2015-05-29 2015-09-30 萍乡市科兴窑炉材料有限公司 Efficient and energy-saving type high temperature mortar for cement rotary kilns, and preparation method thereof
CN105601297A (en) * 2015-12-30 2016-05-25 宜兴市集创新材料科技有限公司 Refractory cement gum for masonry of firebrick

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1040573A (en) * 1988-08-31 1990-03-21 江西省工业设备安装公司 High temperature clay and compound method thereof
CN1214327A (en) * 1997-10-09 1999-04-21 济南东方工业炉新技术开发总公司 Inorganic combined high-strength refractory deposit material and its preparation
CN1232806A (en) * 1999-05-28 1999-10-27 冶金工业部钢铁研究总院 Fire clay for building blast furnace
CN102701753A (en) * 2012-01-10 2012-10-03 河南安瑞高温材料股份有限公司 Special daub for fireproofing materials of building carbon calcinator wall and production method of special daub

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1040573A (en) * 1988-08-31 1990-03-21 江西省工业设备安装公司 High temperature clay and compound method thereof
CN1214327A (en) * 1997-10-09 1999-04-21 济南东方工业炉新技术开发总公司 Inorganic combined high-strength refractory deposit material and its preparation
CN1232806A (en) * 1999-05-28 1999-10-27 冶金工业部钢铁研究总院 Fire clay for building blast furnace
CN102701753A (en) * 2012-01-10 2012-10-03 河南安瑞高温材料股份有限公司 Special daub for fireproofing materials of building carbon calcinator wall and production method of special daub

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104944978A (en) * 2015-05-29 2015-09-30 萍乡市科兴窑炉材料有限公司 Efficient and energy-saving type high temperature mortar for cement rotary kilns, and preparation method thereof
CN105601297A (en) * 2015-12-30 2016-05-25 宜兴市集创新材料科技有限公司 Refractory cement gum for masonry of firebrick

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