CN103343490B - Mosquito-proof nonwoven wallpaper of a kind of aerosol type and preparation method thereof - Google Patents
Mosquito-proof nonwoven wallpaper of a kind of aerosol type and preparation method thereof Download PDFInfo
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- CN103343490B CN103343490B CN201310286297.8A CN201310286297A CN103343490B CN 103343490 B CN103343490 B CN 103343490B CN 201310286297 A CN201310286297 A CN 201310286297A CN 103343490 B CN103343490 B CN 103343490B
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Abstract
The present invention relates to mosquito-proof nonwoven wallpaper of a kind of aerosol type and preparation method thereof, this wallpaper comprises nonwoven wallpaper base stock, and nonwoven wallpaper base stock mixes copy paper by functional fibre, wood pulp fibre and adhesive and makes or adopt adhesive on-line coater to make by functional fibre, wood pulp fibre after mixing copy paper; The surface spray of described nonwoven wallpaper base stock is provided with anophelifuge, and the spray amount of anophelifuge is the quantitative 5-30% of paper.The present invention is owing to have employed above technical scheme, and the mosquito-proof type nonwoven wallpaper produced with the present invention, in its product 60min, the rate of knockdown of mosquito can reach 97%.And wallpaper product adds and do not shrink in process man-hour, free from dampness sense, takes off paper complete, and the pliability of paper is very good, has the function of knocking down and being attached to wallpaper surface mosquito.
Description
Technical field
The present invention relates to a kind of wallpaper, particularly relate to a kind of functional wallpaper with mosquito-proof performance.
Background technology
Nonwoven wallpaper is a kind of novel decorative material for wall surface.It has rich color, myoplasm sense is strong, pattern is gorgeous, environmental protection, easy construction, affordable, the features such as decorative effect elegant, be other multiple indoor ornament materials incomparable.But wallpaper base stock is in the past material based on wood pulp fibre all, this wallpaper low price, shortcoming be poor performance, not water-fast, be not easy to cleaning, be not easy to construction, the moisture content in air can be absorbed in a large number due to wood pulp fibre, can there be damp on surface often, and the time has been grown and can show stain.When changing wallpaper base stock, due to himself intensity difference, causing and peeling off not exclusively, occurring stick wall phenomenon.
The Chinese invention patent (application number: 200810060243.9 applyings date: 2008-03-31) of applicant's application discloses nonwoven wallpaper base stock, comprise fibre stuff and adhesive, fibre stuff comprises wood pulp fibre and functional fibre, wood pulp fibre and functional fibre are 0 ~ 95%:5 ~ 100% by part by weight between the two, and adhesive accounts for 1 ~ 10% of body paper gross weight.Wallpaper base stock product of the present invention adds and does not shrink in process man-hour, and free from dampness sense, takes off paper complete, and the pliability of paper is very good.
The Chinese invention patent (application number: 200810063378.0 applyings date: 2008-08-12) of applicant's application discloses nonwoven wallpaper base stock; this body paper comprises fibre stuff and adhesive; fibre stuff comprises wood pulp fibre and functional fibre; wood pulp fibre and functional fibre are 0 ~ 95%: 5 ~ 100% by part by weight between the two, and adhesive accounts for 1 ~ 10% of body paper gross weight; It is 0.8 ~ 25D that described functional fibre at least contains a kind of fineness, and length is the functional fibre of 15 ~ 60MM.The surface of wallpaper base stock of the present invention can show natural striped, good looking appearance, does not need to process in addition.Meanwhile, wallpaper base stock product adds and does not shrink in process man-hour, and free from dampness sense, takes off paper complete, and the pliability of paper is very good.
In above-mentioned two patents, nonwoven wallpaper base stock cannot reach effect that is mosquito-proof, that kill mosquito.For this reason, applicant has applied for that number of patent application is: 2013102008215,2013102008003,2013102007458, the patent of invention of 201310200822X, these patents individually disclose and adopt mosquito-proof fiber to prepare mosquito-proof type nonwoven wallpaper base stock, the mosquito-proof fiber price adopted in the method is higher, this results in the rising of production cost, be suitable only for expensive goods, for mill run, then still need to consider production cost.
Summary of the invention
In order to solve above-mentioned technical problem, an object of the present invention is to provide the mosquito-proof nonwoven wallpaper of a kind of aerosol type, this wallpaper reduces production cost, this wallpaper base stock can mosquito-proof, water resistant, mildew-resistant, resistance to wiping, easily peel off, good processability, second object of the present invention is to provide the preparation method of above-mentioned mosquito-proof type nonwoven wallpaper, it adopts copy paper method to prepare, and the method technique is simple, enforcement is convenient.
In order to realize first above-mentioned object, present invention employs following technical scheme:
The mosquito-proof nonwoven wallpaper of a kind of aerosol type, this wallpaper comprises nonwoven wallpaper base stock, and nonwoven wallpaper base stock mixes copy paper by functional fibre, wood pulp fibre and adhesive and makes or adopt adhesive on-line coater to make by functional fibre, wood pulp fibre after mixing copy paper; The surface spray of described nonwoven wallpaper base stock is provided with anophelifuge, and the spray amount of anophelifuge is the quantitative 5-30% of paper.
As preferably, the coating weight of described anophelifuge coating is the quantitative 15-25% of paper.
As preferably, described mosquito-proof pesticide is pyrethroid or the mosquito-proof pesticide of extracted form natural plant, is preferably decis or lambda-cyhalothrin.
As preferably, described mosquito-proof pesticide is the mosquito-proof pesticide of pyrethroid built type, and described pyrethroid is preferably decis or lambda-cyhalothrin.
As preferably, described functional fibre is one or more mixing in animal fiber, synthetic fiber and artificial fibre.
As preferably, described functional fibre is one or more in collagenous fibres, keratin fiber, fibroin fiber, regenerated celulose fibre and azlon; As preferred again, keratin fiber is wool, regenerated celulose fibre is one or more in viscose, copper ammonia fibre, acetic ester fiber, and azlon is one or more in casein fibre, Zein fibers, ground nut fiber, soybean fiber.
As preferably, described functional fibre is one or more in polyacrylonitrile fibre, polypropylene fibre, polyethylene fiber, polyvinyl acetal fiber, polyvinyl chloride fibre, polytetrafluoroethylene fibre, polyester fiber, polyamide fiber, polyurethane elastomeric fiber, polyimide fiber, polybenzimidazole fiber and polyhenylene three nitrine fiber.
As preferably, described adhesive comprise in natural adhesive and synthetic adhesive one or more; As preferably, described natural adhesive is one or more in shellac, gelatinized corn starch, specimens of one's blood and natural rubber adhesive; Synthetic adhesive is one or more in thermosetting adhesive, thermoplastic adhesive, rubber based adhesives and inorganic adhesive; As preferred again, described thermosetting adhesive comprise in phenolic aldehyde, urea aldehyde, epoxy, polyester, organosilicon, polyurethane one or more; Thermoplastic adhesive comprise in vinyl esters, esters of acrylic acid, phenylethylene, cellulose family, alkyd resins class one or more; Rubber based adhesives comprise in reclaimed rubber, butadiene-styrene rubber, neoprene, cyano group rubber, butyl rubber, silicon rubber, polyurethane rubber one or more.
As preferably, described nonwoven wallpaper base stock adds Cypres when on-line coater, and the consumption of Cypres is the 0.5%-5% of adhesive consumption; As preferably, described adhesive adopts polyvinyl alcohol, starch, by solution oven dry weight vinyl alcohol: starch: Cypres is 2 ~ 8:0.5 ~ 2:0.04 ~ 0.15, and use amount accounts for 5 ~ 15% of body paper gross weight.
In order to realize second above-mentioned object, present invention employs following technical scheme:
A kind of preparation method of the described mosquito-proof nonwoven wallpaper of aerosol type, this wallpaper is provided with anophelifuge by the surface spray of nonwoven wallpaper base stock, the spray amount of anophelifuge is the quantitative 5-30% of paper, and nonwoven wallpaper base stock mixes copy paper by functional fibre, wood pulp fibre and adhesive and makes or adopt adhesive on-line coater to make by functional fibre, wood pulp fibre after mixing copy paper.
Nonwoven wallpaper base stock of the present invention can adopt the method in Chinese invention patent (application number: 200810060243.9 applyings date: 2008-03-31) and Chinese invention patent (application number: 200810063378.0 applyings date: 2008-08-12) described in any one technical scheme to prepare.
The present invention is owing to have employed above technical scheme, and the mosquito-proof type nonwoven wallpaper produced with the present invention, in its product 60min, the rate of knockdown of mosquito can reach 97%.And wallpaper product adds and do not shrink in process man-hour, free from dampness sense, takes off paper complete, and the pliability of paper is very good, has the function of knocking down and being attached to wallpaper surface mosquito.
Detailed description of the invention
embodiment 1
Fibre furnish: softwood pulp 50%, broad-leaved slurry 30%, mixing beating degree 20 ° of SR, polyster fibre 20%, 1.5 × 10mm, the quantitative 100g/m of base paper
2, dip-coating polyvinyl alcohol, starch and Cypres in machine, coating fluid concentration 4%, coating weight 6%.Polyvinyl alcohol: starch: Cypres=4:1:0.8(all refers to solution oven dry weight), obtain the quantitative 106g/m of body paper
2.
Machine external spraying 20g/m
2, Sprayable formulations, mosquito-proof pesticide consumption 60%, mosquito-proof pesticide is lambda-cyhalothrin, bleeding agent consumption 20%, and the consumption of organic solvent is 20%, spray shaping.Become paper index as follows: quantitatively 126g/m
2, tightness 0.50g/cm
3, tensile strength 3.6kN/m, wet strength 1.5kN/m, surface absorption 30g/m
2, opacity 80%, tearability longitudinal 1600mN, horizontal 2000mN, expansion and contraction 0.4%.There is mosquito-proof effect.Page has been placed in mosquito environment, above mosquito can not be attached to, has the mosquito knocked down under it.
embodiment 2
Fibre furnish: softwood pulp 40%, broad-leaved slurry 30%, beating degree 18 ° of SR, soybean fiber 30%, 3.5D × 5mm, the quantitative 83g/m of base paper
2, in machine, dip-coating epoxy resin and Cypres=10:0.5(all refer to solution oven dry weight), coating fluid concentration 4%, coating weight 5%.Obtain the quantitative 91g/m of body paper
2.
Machine external spraying 30g/m
2, Sprayable formulations, mosquito-proof pesticide consumption 100%, mosquito-proof pesticide is purchased from Shaoxing China Textile Institute Jiangnan Branch Institute Co., Ltd (as shown in Chinese invention patent 201010549444.2), secondary spray shaping.Become paper index as follows: quantitatively 121g/m
2, tightness 0.53g/cm
3, tensile strength 4.5kN/m, wet strength 1.8kN/m, surface absorption 32g/m
2, opacity 80%, tearability longitudinal 1650mN, horizontal 2100mN, expansion and contraction 0.4%.There is mosquito-proof effect.Page has been placed in mosquito environment, above mosquito can not be attached to, has the mosquito knocked down under it.
embodiment 3
Fibre furnish: softwood pulp 20%, beating degree 25 ° of SR, viscose 80%, 5D × 2mm, the quantitative 100g/m of base paper
2, in machine, dip-coating butadiene-styrene rubber and Cypres=20:1(all refer to solution oven dry weight), coating fluid concentration 4%, coating weight 6%, obtains the quantitative 106g/m of body paper
2.
Machine external spraying 20g/m
2, Sprayable formulations, mosquito-proof pesticide consumption 60%, mosquito-proof pesticide is decis, bleeding agent consumption 20%, and the consumption of organic solvent is 20%, secondary spray shaping.Become paper index as follows: quantitatively 125g/m
2, tightness 0.53g/cm
3, tensile strength 4.5kN/m, wet strength 1.8kN/m, surface absorption 32g/m
2, opacity 80%, tearability longitudinal 1650mN, horizontal 2100mN, expansion and contraction 0.4%.There is mosquito-proof effect.Page has been placed in mosquito environment, above mosquito can not be attached to, has the mosquito knocked down under it.
embodiment 4
Fibre furnish: softwood pulp 40%, broad-leaved slurry 40%, beating degree 27 ° of SR, nylon fibre 20%, 15D × 10mm, the quantitative 122g/m of base paper
2, dip-coating polyvinyl alcohol and Cypres in machine, coating fluid concentration 4%, coating weight 4%, polyvinyl alcohol: Cypres=4:0.8(all refers to solution oven dry weight), obtain the quantitative 135g/m of body paper
2.
Machine external spraying 15g/m
2, Sprayable formulations, mosquito-proof pesticide consumption 70%, mosquito-proof pesticide is decis, bleeding agent consumption 10%, and the consumption of organic solvent is 20%, spray shaping.Become paper index as follows: quantitatively 140g/m
2, tightness 0.53g/cm
3, tensile strength 4.5kN/m, wet strength 1.8kN/m, surface absorption 32g/m
2, opacity 80%, tearability longitudinal 1650mN, horizontal 2100mN, expansion and contraction 0.4%.There is mosquito-proof effect.Page has been placed in mosquito environment, above mosquito can not be attached to, has the mosquito knocked down under it.
embodiment 5
Fibre furnish: softwood pulp 30%, beating degree 20 ° of SR, polypropylene fiber 70%, 15D × 10mm, the quantitative 90g/m of base paper
2, dip-coating polyvinyl alcohol, starch and Cypres in machine, coating fluid concentration 10%, coating weight 10%, polyvinyl alcohol: starch: Cypres=4:1:0.8(all refers to solution oven dry weight), obtain the quantitative 100g/m of body paper
2.
Machine external spraying 10g/m
2, Sprayable formulations, mosquito-proof pesticide is purchased from Shaoxing China Textile Institute Jiangnan Branch Institute Co., Ltd (as shown in Chinese invention patent 201010549444.2), a spray shaping.Become paper index as follows: quantitatively 109g/m
2, tightness 0.53g/cm
3, tensile strength 4.5kN/m, wet strength 1.8kN/m, surface absorption 32g/m
2, opacity 80%, tearability longitudinal 1650mN, horizontal 2100mN, expansion and contraction 0.4%.There is mosquito-proof effect.Page has been placed in mosquito environment, above mosquito can not be attached to, has the mosquito knocked down under it.
embodiment 6
Fibre furnish: softwood pulp 20%, broad-leaved slurry 60%, mixing beating degree 20 ° of SR, polyster fibre 10%, 1.5 × 6mm, 10%, 1.5 × 12mm, the quantitative 85g/m of base paper
2, the water-soluble acrylic resin of dip-coating and Cypres in machine, coating fluid concentration 4%, coating weight 4%.Water-soluble acrylic resin: Cypres=4:0.8(all refers to solution oven dry weight), obtain the quantitative 87.5g/m of body paper
2.
Machine external spraying 10g/m
2, Sprayable formulations, mosquito-proof pesticide consumption 60%, mosquito-proof pesticide is lambda-cyhalothrin, bleeding agent consumption 20%, and the consumption of organic solvent is 20%, spray shaping.Become paper index as follows: quantitatively 97g/m
2, tightness 0.53g/cm
3, tensile strength 4.5kN/m, wet strength 1.8kN/m, surface absorption 32g/m
2, opacity 80%, tearability longitudinal 1650mN, horizontal 2100mN, expansion and contraction 0.4%.There is mosquito-proof effect.Page has been placed in mosquito environment, above mosquito can not be attached to, has the mosquito knocked down under it.
embodiment 7
Fibre furnish: softwood pulp 60%, broad-leaved slurry 20%, beating degree 18 ° of SR, polyster fibre 10%1.5 × 6mm, 10%1.5 × 12mm, the quantitative 65g/m of base paper
2, in machine, add the bleeding agent of 3.2% and water-soluble polyurethane resin, the china clay of 10%, the organic solvent of 10% of 4%.Obtain the quantitative 80.2g/m of body paper
2.
Machine external spraying 20g/m
2, Sprayable formulations, mosquito-proof pesticide consumption 100%, mosquito-proof pesticide is mosquito-proof pesticide is purchased from Shaoxing China Textile Institute Jiangnan Branch Institute Co., Ltd (as shown in Chinese invention patent 201010549444.2), three spray shapings.Become paper index as follows: quantitatively 100g/m
2, tightness 0.53g/cm
3, tensile strength 4.5kN/m, wet strength 1.8kN/m, surface absorption 32g/m
2, opacity 80%, tearability longitudinal 1650mN, horizontal 2100mN, expansion and contraction 0.4%.There is mosquito-proof effect.Page has been placed in mosquito environment, above mosquito can not be attached to, has the mosquito knocked down under it.
Method of testing:
The determination method that quantitative GB/T451.2 paper and paperboard is quantitative
The determination method of thickness G B/T451.3 paper and paperboard thickness
The determination method of tearability GB/T455.1 paper tearability
The determination method of expansion and contraction GB/T451.3 paper retractility
The determination method of tensile strength after wet strength GB/T465.2 paper and paperboard soaks in required time
The absorptive determination method of surface absorption GB/T1540 paper and paperboard
The determination method of thickness G B/T1543 paper opacity
The determination method of tensile strength GB/T12914 paper and paperboard tensile strength
Fire resistance method of testing: U.S.'s fire proofing standard is ANSI/UL-94-2003 standard.
Claims (4)
1. the mosquito-proof nonwoven wallpaper of aerosol type, is characterized in that: the fibre furnish of this nonwoven wallpaper: softwood pulp 50%, broad-leaved slurry 30%, mixing beating degree 20 ° of SR, polyster fibre 20%, 1.5 × 10mm, the quantitative 100g/m of base paper
2, dip-coating polyvinyl alcohol, starch and Cypres in machine, coating fluid concentration 4%, coating weight 6%; Polyvinyl alcohol: starch: Cypres=4:1:0.8, refers to solution oven dry weight, obtains the quantitative 106g/m of body paper
2; Machine external spraying 20g/m
2, Sprayable formulations, mosquito-proof pesticide consumption 60%, mosquito-proof pesticide is lambda-cyhalothrin, bleeding agent consumption 20%, and the consumption of organic solvent is 20%, spray shaping; Become paper index as follows: quantitatively 126g/m
2, tightness 0.50g/cm
3, tensile strength 3.6kN/m, wet strength 1.5kN/m, surface absorption 30g/m
2, opacity 80%, tearability longitudinal 1600mN, horizontal 2000mN, expansion and contraction 0.4%.
2. the mosquito-proof nonwoven wallpaper of aerosol type, is characterized in that: the fibre furnish of this nonwoven wallpaper: softwood pulp 20%, beating degree 25 ° of SR, viscose 80%, 5D × 2mm, the quantitative 100g/m of base paper
2, in machine, dip-coating butadiene-styrene rubber and Cypres=20:1, refer to solution oven dry weight, coating fluid concentration 4%, coating weight 6%, obtains the quantitative 106g/m of body paper
2; Machine external spraying 20g/m
2, Sprayable formulations, mosquito-proof pesticide consumption 60%, mosquito-proof pesticide is decis, bleeding agent consumption 20%, and the consumption of organic solvent is 20%, secondary spray shaping; Become paper index as follows: quantitatively 125g/m
2, tightness 0.53g/cm
3, tensile strength 4.5kN/m, wet strength 1.8kN/m, surface absorption 32g/m
2, opacity 80%, tearability longitudinal 1650mN, horizontal 2100mN, expansion and contraction 0.4%.
3. the mosquito-proof nonwoven wallpaper of aerosol type, is characterized in that: the fibre furnish of this nonwoven wallpaper: softwood pulp 40%, broad-leaved slurry 40%, beating degree 27 ° of SR, nylon fibre 20%, 15D × 10mm, the quantitative 122g/m of base paper
2, dip-coating polyvinyl alcohol and Cypres in machine, coating fluid concentration 4%, coating weight 4%, polyvinyl alcohol: Cypres=4:0.8, refers to solution oven dry weight, obtains the quantitative 135g/m of body paper
2; Machine external spraying 15g/m
2, Sprayable formulations, mosquito-proof pesticide consumption 70%, mosquito-proof pesticide is decis, bleeding agent consumption 10%, and the consumption of organic solvent is 20%, spray shaping; Become paper index as follows: quantitatively 140g/m
2, tightness 0.53g/cm
3, tensile strength 4.5kN/m, wet strength 1.8kN/m, surface absorption 32g/m
2, opacity 80%, tearability longitudinal 1650mN, horizontal 2100mN, expansion and contraction 0.4%.
4. the mosquito-proof nonwoven wallpaper of aerosol type, is characterized in that: the fibre furnish of this nonwoven wallpaper: softwood pulp 20%, broad-leaved slurry 60%, mixing beating degree 20 ° of SR, polyster fibre 10%, 1.5 × 6mm, 10%, 1.5 × 12mm, the quantitative 85g/m of base paper
2, the water-soluble acrylic resin of dip-coating and Cypres in machine, coating fluid concentration 4%, coating weight 4%; Water-soluble acrylic resin: Cypres=4:0.8, refers to solution oven dry weight, obtains the quantitative 87.5g/m of body paper
2; Machine external spraying 10g/m
2, Sprayable formulations, mosquito-proof pesticide consumption 60%, mosquito-proof pesticide is lambda-cyhalothrin, bleeding agent consumption 20%, and the consumption of organic solvent is 20%, spray shaping; Become paper index as follows: quantitatively 97g/m
2, tightness 0.53g/cm
3, tensile strength 4.5kN/m, wet strength 1.8kN/m, surface absorption 32g/m
2, opacity 80%, tearability longitudinal 1650mN, horizontal 2100mN, expansion and contraction 0.4%.
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104060371A (en) * | 2014-07-02 | 2014-09-24 | 张家港市杨舍新米洋针织厂 | Artificial blended fiber fabric |
| CN104947314A (en) * | 2015-07-14 | 2015-09-30 | 爱谱诗（苏州）服装有限公司 | Production technology of mosquito-preventing nonwoven fabric |
| CN106906699A (en) * | 2017-04-06 | 2017-06-30 | 合肥欧克斯新型建材有限公司 | A kind of moistureproof mosquito repellent wallpaper |
| CN111851128A (en) * | 2020-07-28 | 2020-10-30 | 太和县昌达工贸有限公司 | Air-permeable uniform anti-fouling non-woven fabric mesh belt and preparation method thereof |
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| CN101225260A (en) * | 2008-01-31 | 2008-07-23 | 奥顿开林（江苏）化工有限公司 | Inner wall paint having disinsection efficiency |
| CN101255665A (en) * | 2008-03-31 | 2008-09-03 | 浙江凯恩特种材料股份有限公司 | Nonwoven wallpaper base paper and manufacture method thereof as well as nonwoven wallpaper produced from the same |
| CN102261010A (en) * | 2011-07-22 | 2011-11-30 | 浙江舜浦纸业有限公司 | Method for producing paper |
| CN102308842A (en) * | 2011-09-21 | 2012-01-11 | 江苏扬农化工股份有限公司 | Long-acting insecticidal spraying agent and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5158626B2 (en) * | 2007-07-31 | 2013-03-06 | 学校法人 久留米大学 | Pest repellent sheet or paper |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225260A (en) * | 2008-01-31 | 2008-07-23 | 奥顿开林（江苏）化工有限公司 | Inner wall paint having disinsection efficiency |
| CN101255665A (en) * | 2008-03-31 | 2008-09-03 | 浙江凯恩特种材料股份有限公司 | Nonwoven wallpaper base paper and manufacture method thereof as well as nonwoven wallpaper produced from the same |
| CN102261010A (en) * | 2011-07-22 | 2011-11-30 | 浙江舜浦纸业有限公司 | Method for producing paper |
| CN102308842A (en) * | 2011-09-21 | 2012-01-11 | 江苏扬农化工股份有限公司 | Long-acting insecticidal spraying agent and application thereof |
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Effective date of registration: 20210928 Address after: 323300 Yuankou Village, Miaogao Street, Suichang County, Lishui City, Zhejiang Province Patentee after: Zhejiang Kaien New Material Co.,Ltd. Patentee after: ZHEJIANG KAN SPECIAL PAPER Co.,Ltd. Address before: 323300 No. 108, Kaien Road, Suichang County, Lishui City, Zhejiang Province Patentee before: ZHEJIANG KAN SPECIALTIES MATERIAL Co.,Ltd. |