CN103333501B - A kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber - Google Patents
A kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber Download PDFInfo
- Publication number
- CN103333501B CN103333501B CN201310252578.1A CN201310252578A CN103333501B CN 103333501 B CN103333501 B CN 103333501B CN 201310252578 A CN201310252578 A CN 201310252578A CN 103333501 B CN103333501 B CN 103333501B
- Authority
- CN
- China
- Prior art keywords
- parts
- plastic cement
- silicone rubber
- methyl phenyl
- vinyl silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber, be made up of according to weight ratio following composition: methyl phenyl vinyl silicone rubber 40 ~ 50 parts, poly-decoylamide 20 ~ 30 parts, dimethyl sulfoxide (DMSO) 10 ~ 20 parts, terpolycyantoamino-formaldehyde resin 40 ~ 50 parts, n-dodecane 10 ~ 20 parts, n-hexacosane 10 ~ 20 parts, trioctyl trimellitate 10 ~ 20 parts.The plastic cement containing methyl phenyl vinyl silicone rubber made has good Shock-resistant stretch-proof effect.
Description
Technical field
The present invention relates to a kind of Shock-resistant stretch-proof plastic cement, particularly relate to a kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber.
Background technology
Current those skilled in the art are also more and more deep to the research of plastic cement, the focus of research in a lot of performances of plastic cement, as corrosion-resistant, high temperature resistant, shock resistance, stretch-proof etc.Wherein they to shock resistance and stretch-proof performance study less, many plastic cement shock resistances and stretch-proof performance are also very general, as stretch-proof performance only has about 20 ~ 30Mpa, extremely constrain their popularization on a large scale industrially and enforcement, therefore study and a kind of not only there is the usage space that plastic cement that excellent impact resistance also can have a good stretch-proof performance can expand plastic cement, there are very good market outlook.
Summary of the invention
The technical problem solved: conventional plastic shock resistance and the poor problem of stretch-proof effect.
Technical scheme: the present invention is a kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber, is made up of according to weight ratio following composition: methyl phenyl vinyl silicone rubber 40 ~ 50 parts, poly-decoylamide 20 ~ 30 parts, dimethyl sulfoxide (DMSO) 10 ~ 20 parts, terpolycyantoamino-formaldehyde resin 40 ~ 50 parts, n-dodecane 10 ~ 20 parts, n-hexacosane 10 ~ 20 parts, trioctyl trimellitate 10 ~ 20 parts.At 80 DEG C, various composition is dropped into reaction vessel allotment, stir, be heated to 150 DEG C and keep 8h, the plastic cement with good Shock-resistant stretch-proof effect after cooling, can be obtained.
Beneficial effect: after preparing the Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber, its shock resistance and tensile property are tested.Adopt the shock resistance of ASTMD256 standard to plastic cement to test, result shows the Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber that the present invention makes, and shock resistance is 280 ~ 300J/M, has good shock resistance.Plastic cement is under GB/T1040-2006 standard in addition, and the Shock-resistant stretch-proof plastic cement tensile property containing methyl phenyl vinyl silicone rubber is 60 ~ 70Mpa, has good shock resistance and stretch-proof characteristic.
Embodiment
Embodiment 1
Open reaction vessel, temperature is adjusted to 80 DEG C, gets methyl phenyl vinyl silicone rubber 40kg, drop in reactor, stir, add poly-decoylamide 20kg simultaneously, then add dimethyl sulfoxide (DMSO) 10kg, add terpolycyantoamino-formaldehyde resin 40kg, add n-dodecane 10kg again, then add n-hexacosane 10kg successively, trioctyl trimellitate 10kg, treat post-heating to the 150 DEG C maintenance 8h that thoroughly stirs, after cooling, obtain the Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber.
Embodiment 2
Preparation method is with embodiment 1, and formula rate is as follows: methyl phenyl vinyl silicone rubber 50kg, poly-decoylamide 30kg, dimethyl sulfoxide (DMSO) 20kg, terpolycyantoamino-formaldehyde resin 50kg, n-dodecane 20kg, n-hexacosane 20kg, trioctyl trimellitate 20kg.
Embodiment 3
Preparation method is with embodiment 1, and formula rate is as follows: methyl phenyl vinyl silicone rubber 45kg, poly-decoylamide 25kg, dimethyl sulfoxide (DMSO) 15kg, terpolycyantoamino-formaldehyde resin 45kg, n-dodecane 15kg, n-hexacosane 15kg, trioctyl trimellitate 15kg.
The performance test results
In embodiment 1, the shock resistance of product is 280J/M, and tensile property is 60Mpa.In embodiment 2, the shock resistance of product is 290J/M, and tensile property is 65Mpa.In embodiment 3, the shock resistance of product is 300J/M, and tensile property is 70Mpa.Product all has good shock resistance and stretch-proof performance.
Claims (6)
1. the Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber, is characterized in that: be made up of according to weight ratio following composition: methyl phenyl vinyl silicone rubber 40 ~ 50 parts, poly-decoylamide 20 ~ 30 parts, dimethyl sulfoxide (DMSO) 10 ~ 20 parts, terpolycyantoamino-formaldehyde resin 40 ~ 50 parts, n-dodecane 10 ~ 20 parts, n-hexacosane 10 ~ 20 parts, trioctyl trimellitate 10 ~ 20 parts.
2. a kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber according to claim 1, is characterized in that: in plastic cement composition, methyl phenyl vinyl silicone rubber is 50 parts.
3. a kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber according to claim 1, is characterized in that: in plastic cement composition, poly-decoylamide is 20 parts.
4. a kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber according to claim 1, is characterized in that: in plastic cement composition, dimethyl sulfoxide (DMSO) is 10 parts.
5. a kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber according to claim 1, is characterized in that: in plastic cement composition, terpolycyantoamino-formaldehyde resin is 40 parts.
6. a kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber according to claim 1, is characterized in that: in plastic cement composition, n-dodecane is 10 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310252578.1A CN103333501B (en) | 2013-06-24 | 2013-06-24 | A kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310252578.1A CN103333501B (en) | 2013-06-24 | 2013-06-24 | A kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103333501A CN103333501A (en) | 2013-10-02 |
| CN103333501B true CN103333501B (en) | 2015-09-02 |
Family
ID=49241711
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310252578.1A Expired - Fee Related CN103333501B (en) | 2013-06-24 | 2013-06-24 | A kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103333501B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111572116B (en) * | 2020-05-19 | 2022-07-19 | 浙江四海新材料股份有限公司 | High-resistance nano-coating V belt and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2203917C1 (en) * | 2001-09-24 | 2003-05-10 | Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиационных материалов" | Heat-resistant adhesive composition |
| CN102719100A (en) * | 2012-07-02 | 2012-10-10 | 阳江市万丰实业有限公司 | Low-volatile silicone rubber compound and preparation method thereof |
| CN103102692A (en) * | 2013-02-21 | 2013-05-15 | 江苏顶塑实业有限公司 | Halogen-free flame retardant silicone rubber/modified polyamide thermoplastic elastomer and preparation method thereof |
-
2013
- 2013-06-24 CN CN201310252578.1A patent/CN103333501B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2203917C1 (en) * | 2001-09-24 | 2003-05-10 | Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиационных материалов" | Heat-resistant adhesive composition |
| CN102719100A (en) * | 2012-07-02 | 2012-10-10 | 阳江市万丰实业有限公司 | Low-volatile silicone rubber compound and preparation method thereof |
| CN103102692A (en) * | 2013-02-21 | 2013-05-15 | 江苏顶塑实业有限公司 | Halogen-free flame retardant silicone rubber/modified polyamide thermoplastic elastomer and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103333501A (en) | 2013-10-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105860030B (en) | Glycidyl amine type epoxy resin of structure containing Cardo and preparation method thereof | |
| CN106554313A (en) | A kind of acylthioureas imidazoline inhibitor and preparation method thereof | |
| CN103333501B (en) | A kind of Shock-resistant stretch-proof plastic cement containing methyl phenyl vinyl silicone rubber | |
| CN104987455A (en) | Dibutyl itaconate modified acrylic resin and preparation method thereof | |
| CN103910963A (en) | Modified polymethyl methacrylate | |
| CN103304988B (en) | A kind of Impact-resistant high-temperature-resplastic plastic containing polyarylsulphone | |
| CN103289501B (en) | A kind of waterproof heat resistant coating containing acrylonitrile-butadiene-styrene copolymer | |
| CN104151537A (en) | Low-odor acrylic modified alkyd resin and preparation method thereof | |
| CN103435500A (en) | Novel preparation method for diethanolisopropanolamine | |
| CN103289413B (en) | Shock resistant and stretch proof plastic containing dimethyl silicone rubber | |
| CN103435499B (en) | Novel preparation method for mono ethanol diisopropanolamine | |
| CN103333438B (en) | A kind of Shock-resistant stretch-proof plastics containing chlorotrifluoroethylene | |
| CN103333421B (en) | A kind of Shock-resistant stretch-proof plastics containing chlorosulfonated polyethylene | |
| CN103333444B (en) | A kind of shock resistance high-temperature resistance plastice containing polyvinyl acetate | |
| CN105647346A (en) | Fast-curing and heat-insulation as well as waterproof functional coating material | |
| CN103289336B (en) | Impact-resistant high-temperature-resistant plastic comprising polybutylene terephthalate | |
| CN106045886A (en) | Compound di-(biguanidino-p-phenyl) methane and synthetic method and application thereof | |
| CN104098755A (en) | Preparation method of epoxy resin | |
| CN103951909B (en) | A kind of heat-resisting impact-resistant complex plastic and preparation method thereof | |
| CN104073201A (en) | Novel preparation method of polyurethane adhesive | |
| Guo et al. | Cure kinetics and chemorheological behavior of epoxy resin used in advanced composites. | |
| CN103289145B (en) | Impact-resistant high-temperature-resistant plastic comprising bicyclopentadiene | |
| CN103937138B (en) | A kind of plastic cement with high heat resistance | |
| CN101508798A (en) | Process for preparing solidifying agent | |
| CN103289028B (en) | A flame retardant and acid and alkali resistant polyvinylidene chloride-containing plastic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150902 Termination date: 20160624 |