CN103333444A - mpact resistant and high temperature resistant plastic containing polyvinyl acetate - Google Patents
mpact resistant and high temperature resistant plastic containing polyvinyl acetate Download PDFInfo
- Publication number
- CN103333444A CN103333444A CN 201310277504 CN201310277504A CN103333444A CN 103333444 A CN103333444 A CN 103333444A CN 201310277504 CN201310277504 CN 201310277504 CN 201310277504 A CN201310277504 A CN 201310277504A CN 103333444 A CN103333444 A CN 103333444A
- Authority
- CN
- China
- Prior art keywords
- parts
- polyvinyl acetate
- shock resistance
- high temperature
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002689 polyvinyl acetate Polymers 0.000 title claims abstract description 24
- 239000011118 polyvinyl acetate Substances 0.000 title claims abstract description 24
- 229920003023 plastic Polymers 0.000 title claims abstract description 19
- 239000004033 plastic Substances 0.000 title claims abstract description 19
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920002472 Starch Polymers 0.000 claims abstract description 7
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 7
- 239000010425 asbestos Substances 0.000 claims abstract description 7
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims abstract description 7
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 7
- 235000019698 starch Nutrition 0.000 claims abstract description 7
- 239000008107 starch Substances 0.000 claims abstract description 7
- 230000035939 shock Effects 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 239000005062 Polybutadiene Substances 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229960001124 trientine Drugs 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to an impact resistant and high temperature resistant plastic containing polyvinyl acetate. The plastic consists of the following components according to weight ratio: 50-60 parts of polyvinyl acetate, 10-20 parts of an ABS resin, 30-40 parts of polybutadiene, 10-20 parts of asbestos, 10-20 parts of carboxymethyl starch, 20-30 parts of carboxymethyl starch and 20-30 parts of tributyl citrate. The prepared plastic containing polyvinyl acetate has good impact resistant and high temperature resistant effect.
Description
Technical field
The present invention relates to a kind of shock resistance high-temperature resistance plastice, particularly relate to a kind of shock resistance high-temperature resistance plastice that contains polyvinyl acetate.
Background technology
The purposes of plastics is more and more wider in the market, and the quality standard requirement to plastics also is more and more tighter simultaneously.In the professional domain that relates to the shock resistance high-temperature resistance plastice, also be more harsh thereupon to the requirement of shock resistance high-temperature resistance plastice, some scholars also further investigate the high temperature resistant and shock resistance of plastics, but effect is not preferably all arranged.Therefore have the plastics variety of shock resistance and high-temperature resistant result in the market simultaneously seldom, develop and a kind ofly have good resistance simultaneously and impact resistant to elevated temperatures plastics industrial prospect is arranged very much.
Summary of the invention
The technical problem that solves: conventional plastics shock resistance and the relatively poor problem of high-temperature resistant result.
Technical scheme: the present invention is a kind of shock resistance high-temperature resistance plastice that contains polyvinyl acetate, is made up of according to weight ratio following composition: 50～60 parts of polyvinyl acetate, 10～20 parts of ABS resin, 30～40 parts of polyhutadiene, 10～20 parts in asbestos, 10～20 parts of carboxymethyl starch, 20～30 parts of tributyl citrates, 20～30 parts of triethylene tetramines.Under 70 ℃, various compositions are dropped into the reaction vessel allotment, stir, be heated to 160 ℃ and keep 8h, can obtain to have the plastics that good resistance is impacted high-temperature resistant result after the cooling.
Beneficial effect: after preparing the shock resistance high-temperature resistance plastice that contains polyvinyl acetate, to its shock resistance and high temperature resistant the experiment.Adopt the ASTMD256 standard that the shock resistance of plastics is tested, the result shows the shock resistance high-temperature resistance plastice that contains polyvinyl acetate that the present invention makes, and shock resistance is 270～280J/M, has good shock resistance.Plastics are 800～900 ℃ of maintenance 20h down in temperature in addition, and the shock resistance high-temperature resistance plastice that contains polyvinyl acetate produces without any unusual phenomenon, has good shock resistance high-temperature stability.
Embodiment
Embodiment 1
Open reaction vessel, temperature transfers to 70 ℃, gets polyvinyl acetate 50kg, drop in the reactor, stir, add ABS resin 10kg simultaneously, add polyhutadiene 30kg again, add asbestos 10kg, add carboxymethyl starch 10kg again, add tributyl citrate 20kg, triethylene tetramine 20kg more successively, the post-heating to 160 ℃ for the treatment of thoroughly to stir keeps 8h, and the cooling back obtains to contain the shock resistance high-temperature resistance plastice of polyvinyl acetate.
Embodiment 2
The preparation method is with embodiment 1, and it is as follows to fill a prescription: polyvinyl acetate 60kg, ABS resin 20kg, polyhutadiene 40kg, asbestos 20kg, carboxymethyl starch 20kg, tributyl citrate 30kg, triethylene tetramine 30kg.
Embodiment 3
The preparation method is with embodiment 1, and it is as follows to fill a prescription: polyvinyl acetate 55kg, ABS resin 15kg, polyhutadiene 35kg, asbestos 15kg, carboxymethyl starch 15kg, tributyl citrate 25kg, triethylene tetramine 25kg.
High thermal resistance and shock resistance are investigated the result
| ? | Shock resistance | High thermal resistance |
| Embodiment 1 | 270J/M | 800 ℃ keep 20h down, do not change |
| Embodiment 2 | 280J/M | 900 ℃ keep 20h down, do not change |
| Embodiment 3 | 275J/M | 850 ℃ keep 20h down, do not change |
From table, can find out that the plastics that the present invention contains polyvinyl acetate have possessed good high temperature resistant and shock resistance effect.
Claims (6)
1. a shock resistance high-temperature resistance plastice that contains polyvinyl acetate is characterized in that: be made up of according to weight ratio following composition: 50～60 parts of polyvinyl acetate, 10～20 parts of ABS resin, 30～40 parts of polyhutadiene, 10～20 parts in asbestos, 10～20 parts of carboxymethyl starch, 20～30 parts of tributyl citrates, 20～30 parts of triethylene tetramines.
2. a kind of shock resistance high-temperature resistance plastice that contains polyvinyl acetate according to claim 1 is characterized in that: polyvinyl acetate was 50 parts during plastics were formed.
3. a kind of shock resistance high-temperature resistance plastice that contains polyvinyl acetate according to claim 1 is characterized in that: ABS resin was 20 parts during plastics were formed.
4. a kind of shock resistance high-temperature resistance plastice that contains polyvinyl acetate according to claim 1 is characterized in that: polyhutadiene was 30 parts during plastics were formed.
5. a kind of shock resistance high-temperature resistance plastice that contains polyvinyl acetate according to claim 1 is characterized in that: asbestos were 20 parts during plastics were formed.
6. a kind of shock resistance high-temperature resistance plastice that contains polyvinyl acetate according to claim 1 is characterized in that: tributyl citrate was 20 parts during plastics were formed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310277504.3A CN103333444B (en) | 2013-07-03 | 2013-07-03 | A kind of shock resistance high-temperature resistance plastice containing polyvinyl acetate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310277504.3A CN103333444B (en) | 2013-07-03 | 2013-07-03 | A kind of shock resistance high-temperature resistance plastice containing polyvinyl acetate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103333444A true CN103333444A (en) | 2013-10-02 |
| CN103333444B CN103333444B (en) | 2016-02-24 |
Family
ID=49241655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310277504.3A Expired - Fee Related CN103333444B (en) | 2013-07-03 | 2013-07-03 | A kind of shock resistance high-temperature resistance plastice containing polyvinyl acetate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103333444B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206809A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of poster paper that color fastness is high |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1259544A (en) * | 2000-01-31 | 2000-07-12 | 权宁逸 | Poly vinyl acetate material |
| CN102040790B (en) * | 2009-08-18 | 2015-12-09 | 中国科学院成都有机化学有限公司 | A kind of fireproof polyvinyl acetate emulsion and preparation method thereof |
| CN102952501A (en) * | 2011-08-25 | 2013-03-06 | 张苏侠 | Preparation method of polyvinyl acetate sealant |
| CN103160235B (en) * | 2012-04-17 | 2014-10-29 | 南京彤天广元高分子材料有限公司 | Resin powder bonding agent |
-
2013
- 2013-07-03 CN CN201310277504.3A patent/CN103333444B/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109206809A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of poster paper that color fastness is high |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103333444B (en) | 2016-02-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: SUZHOU JINGYU NEW MATERIAL CO., LTD. Free format text: FORMER OWNER: WUJIANG TIANYUAN PLASTICS CO., LTD. Effective date: 20150626 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Yan Huan Inventor before: Xiao Weirong |
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| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: XIAO WEIRONG TO: YAN HUAN |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20150626 Address after: Wujiang District of Suzhou City, Jiangsu province 215200 Song Ling Zhen Wu with the roadside Applicant after: Suzhou Jing Yu novel material company limited Address before: Wujiang District of Suzhou City, Jiangsu province 215212 Lili Town Industrial Park of arch bridge Applicant before: Wujiang Tianyuan Plastic Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Xiao Weirong Inventor before: Yan Huan |
|
| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160317 Address after: Wujiang District of Suzhou City, Jiangsu province 215200 Lili Town Industrial Park of arch bridge Patentee after: Wujiang Tianyuan Plastic Co., Ltd. Address before: Wujiang District of Suzhou City, Jiangsu province 215200 Song Ling Zhen Wu with the roadside Patentee before: Suzhou Jing Yu novel material company limited |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160224 Termination date: 20160703 |