CN103333014A - 富硒锗酵素酮聚酶的菜豆油 - Google Patents
富硒锗酵素酮聚酶的菜豆油 Download PDFInfo
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- CN103333014A CN103333014A CN2013102880406A CN201310288040A CN103333014A CN 103333014 A CN103333014 A CN 103333014A CN 2013102880406 A CN2013102880406 A CN 2013102880406A CN 201310288040 A CN201310288040 A CN 201310288040A CN 103333014 A CN103333014 A CN 103333014A
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Abstract
本发明公开了一种富硒锗酵素酮聚酶的菜豆油，是属于植物转化法高硒锗再榨油的高科技菜籽黄豆油生产技术领域。由促进植物生长微量元素、富硒锗螺旋藻微量元素、天然抗菌抗氧化清除自由基松针系列钢渣、促进植物根部供水消毒杀菌供氧、富硒锗硼除虫害杂草酵素“酮聚酶”钢、碱渣营养基肥组成。四蔬菜提取物“酮聚酶”，通过“药食同补”把含有这种药物分子输送到人体全身各器官细胞中，促进全身细胞自我恢复，对慢性疾病及各种疑难病有较好的补助治疗效果。酵素能分解血液的废物，使血液保持弱碱性，促进血液循环，消炎、杀菌，增强免疫力，活化巨噬细胞，有效地抵抗异物侵袭，强身健体。
Description
技术领域：
本发明公开了一种富硒锗酵素酮聚酶的菜豆油，是属于植物转化法高硒锗再榨油的高科技菜籽黄豆油生产技术领域。
背景技术：
植物转化法，主要是在油菜黄豆整个生长过程用富含硒锗诸元素钢、碱渣等作为营养基肥，在其生长的土壤，生长发育时叶面施硒锗元素营养基肥，或叶面喷硒锗元素气雾剂的方法，使粮食作物油菜黄豆增加硒锗元素的含量，因为中国是一个缺硒大国，三分之二地区缺硒，72％的人口需要补硒，硒与人类生长发育和疾病的发生，发展均有密切的关系，从国内外众多研究资料中证实，硒具有广泛的生物学作用，从流行病学，实验室和临床研究均表明，微量元素硒，可以增强人体免疫功能，抵抗多种感染和疾病，对人体各器官，心、肝、肾、脾、胃、肺、心脑血管神经、消化、内分泌等80多种疾病均有很好预防、治疗或辅助治疗的作用，是抗癌防癌的有力武器，硒被誉为“抗癌大王”，锗是一种具有多种生物活性的微量元素，锗对人体健康具有积极作用，具有抗肿瘤、抗炎症、抗病毒、抗衰老等的生理作用，有机锗被誉为“人体健康的保护神”、“人类疾病的克星”、“二十一世纪救命锗”和“生命的源泉”。它的药理作用主要表现，具有的独特的分子结构中有三个带氧的键，口服吸收能向全身各细胞提供大量的氧，改善新陈代谢、增强抗癌能力，抑制癌细胞形成，降低血粘稠度，增加血流量，改善血液循环，降低血压，防脑血栓形成，通过油菜和黄豆植物源性有机硒、锗是利用植物同化无机硒无机锗转化成有机硒有机锗的能力，富集油菜籽粒黄豆粒中，富含高硒锗量对这种菜籽、黄豆在常温下压榨生产出来的菜籽油、黄豆油中有机硒、有机锗安全性高，不易对人产生中毒等危害，且易被人体吸收利用，具有补硒锗诸元素效率高的特点。
硼肥是油菜正常生长发育所必需的，正常年景施用硼肥油菜增产42％，在花开而不结籽，较轻年景施用硼肥油菜增产76％，严重的施用硼肥的油菜籽亩产112.1kg，施用硼肥十基肥油菜籽亩产高产达150.6kg，见：白湖农场试验站中国农业科学1975(2)25-28印天寿论甘蓝型油菜“花而不实”的发病原因中国油料1984(4)：21-24。
黄豆又称大黄，全国各地均有栽培，有黑、黄、青、绿、斑数色、黄豆含钼最高，这是黄豆的一大特点，另外黄豆中铜、锰、镍、磷、钒、钾、铁、镁、钙、硼都是最高的。但人体中最需要的硒元素却为检出。
发明内容：
本发明的目的在于提供一种富硒锗酵素酮聚酶的菜豆油。
本发明的技术解决方案是：
一种富硒锗酵素酮聚酶的菜豆油，其特征是：由下列质量份配比组成％
(1)其中富硒锗除虫害杂草酵素“酮聚酶”钢、碱渣营养基肥，其特征是：由下列质量份配比组成％
①土壤肥力增强剂钢渣营养基肥
②天然清除病虫害杂草元素营养基肥
③富硒锗灵芝菌环保酵素碱渣营养基肥
④富硒螺旋藻松针系列碱渣基肥
⑤富硒锗硼螺旋藻灵芝菌丝体蔬菜“酮聚酶”钢渣营养基肥
(2)促进植物生长微量元素营养基肥
(3)富硒锗螺旋藻微量元素营养基肥
上述物料溶于100kg水中搅拌到溶解，临用时，稀释1倍，种植时用铺有25cm厚的锯木屑上种植，种植后踏紧，因为锯木屑疏松，透气性能好，用上述方法营养液浇灌，保温植物种子成活率高，成长速度快，种植时用原液，叶面喷施用1∶1稀释液。
(4)天然抗菌抗氧化清除植物自由基松针系列钢渣营养基肥
(5)促进植物根部保水消毒杀菌供氧营养基肥
按配方将玉米淀粉和水加入带有搅拌的反应釜内氧氮气吹入管和温度计的反应釜器内，在氮气的保护下于75℃经1h搅拌后，冷却至30℃下聚合反应3-3h，得白色悬浮液，在此悬浮液中加氢氧化钠溶液于95℃下，经水解得黄褐色粘稠液体，将此液体注入盘中，在90℃左右烘干，并用热风吹约15-20h。得产品干燥后再超细微粉碎成纳米粉，另外过氧化氢、尿素、稳定剂、包膜剂单独投向反应釜内，首先投入稳定剂用量为尿素的0.5％-1％和过氧化氢经过15℃搅拌下投入尿素，尿素∶过氧化氢1.0∶1.1摩尔比为宜，并在5℃-15℃搅拌反应1h，然后加入外包膜剂用量为尿素的0.1-0.3％，搅拌10min，离心过滤，滤液循环利用，干燥碎成纳米粉两粉混合均匀即得植物根部保水杀菌供氧的营养剂。
总之，以上各组分中各物料再用超低温真空冷冻干燥粉碎为宜，其目的以防破坏其植物中的活性成分，用常规二氧化碳萃取或用60％乙醇提取的方法提取，滤液经薄膜蒸发、回收乙醇，并浓缩成1∶1(即每毫升含源生药1g)，相对密度为1.03-1.05的流浸膏备用。用时将流浸膏超低温冷冻真空干燥研细与其他物料共同混合，将其混合物料再用纳米粒径超细微化通用装置将物料的大分子进行破碎、乳化、均质、分散，从而粒化成纳米级粒径的小分子过1800-2200目筛，中心粒径为0.1-5μm，因为药物的吸收常受药物在吸收部位溶出速度的支配，而减小粒径，可以增大在暴露在介质中的表面积，而促进溶解，进而提高药物的吸收度和利用率，增大了药效和治疗效果。使纳米级粒径的小分子进油菜大豆植物细胞最终进入油菜籽粒和大黄豆粒中，随压榨油时流出的菜籽油、黄豆油富含硒锗多元素酵素“酮聚酶”等活性物质有益于人体健康的植物油、菜油和大豆油。用营养基肥时要和土壤拌在一起放在植物根部周围。
硒是植物生长发育所必需的一种有益元素，具有刺激植物发育生长和提高农作物产量与品质，增强植物抗氧化作用，促进植物的新陈代谢和植物对环境胁迫的抗性，并具有拮抗重金属的作用，硒在植物体内与其他元素发生相互协同，优势互补的作用，因为中国是缺硒大国，土壤中由于近几十年来农药化肥的施用，使硒锗更显突出地缺乏，通过无机硒、无机锗经植物转化成具有生物活性的有机硒、有机锗储存在植物的籽粒和黄豆粒中经压榨变成菜籽油、黄豆油，人吃了，可以达到改善人缺硒锗营养状况，从而满足人体内硒锗营养元素平衡，促进人身体健康，不生病或少生病之目的。通过植物生物转化技术，根据植物体内硒分布的研究表明：植物蛋白质中，如大米中水溶性硒蛋白占大米硒含量的70％，大豆更高，大豆中水溶性硒蛋白占75％。参见张帆等植物硒的生理功能世界元素医学2010(17)4：25
施硒肥可增加植物中谷胱甘肽过氧化物酶系GSH-Px的活性，从而增强可清除植物内过量自由基，防止植物过氧化，大豆蛋白是主要富集硒的组分，由此可见，硒参与了植物中蛋白质的合成代谢，调控植物呼吸和光合作用代谢，促进叶绿素合成代谢，拮抗重金属汞、镉、砷、钯、铬等硒肥可以增强植物对病虫害和各种逆境的抵抗力。施用硼肥使油菜增产，增加油菜的出油量，锗在自然中是很分散的元素，土壤中锗含量高，植物叶、种，谷物中含锗量才会高，藻类是富集锗的优良载体及灵芝菌富硒锗螺旋藻灵芝菌丝体的菜籽油、黄豆油中的锗，它具有独特分子结构中有三个带氧的键，口服吸收能箱全身细胞提供大量的氧，改善新陈代谢，增强抗癌能力，抑制癌细胞形成，降低血粘稠度，降血压、血糖、血脂及甘油三脂和胆固醇，防血栓抗衰老，是被誉为“人类疾病的克星”、“健康的卫士”等。
黄豆中微量元素含量比较多，见陈祥友大豆中33种元素分析结果世界元素医学2011(18)1.2：29
黄大豆元素的分布
黄大豆黄豆瓣、黄豆胚、黄豆皮ICP法分析33种元素含量(μg/g)见下表
| 元素 | Ba | Bi | Cd | Co | Cr | Cu | Ge | Li | Mn | Mo | Ni |
| 黄豆瓣 | 0.993 | 1.380 | 0.002 | 0.299 | 0.633 | 12.98 | 1.510 | 0.492 | 25.45 | 24.71 | 3.04 |
| 黄豆胚 | 1.34 | 1.31 | 0.002 | 0.369 | 0.303 | 19.84 | 1.80 | 0.234 | 29.04 | 11.63 | 5.22 |
| 黄豆皮 | 16.85 | 1.30 | 0.073 | 0.335 | 0.420 | 10.45 | 2.14 | 0.145 | 6.490 | 2.740 | 1.390 |
| 元素 | P | Pb | Sb | Sn | Sr | Ti | V | Zn | Zr | Ce | Ga |
| 黄豆瓣 | 6031 | 2.09 | 0.021 | 0.016 | 3.51 | 0.189 | 0.906 | 43.83 | 0.220 | 1.280 | 1.220 |
| 黄豆胚 | 7671 | 1.69 | 0.021 | 0.016 | 6.05 | 0.327 | 0.532 | 91.79 | 0.166 | 1.06 | 0.651 |
| 黄豆皮 | 565 | 3.261 | 0.765 | 0.133 | 31.07 | 0.405 | 0.862 | 148.5 | 0.357 | 2.320 | 1.810 |
| 元素 | La | Nb | Sc | Th | K | Fe | Mg | Ca | Al | B | Na |
| 黄豆瓣 | 0.152 | 0.280 | 0.037 | 1.420 | 16230 | 117 | 2190 | 2060 | 6 | 7.820 | 11 |
| 黄豆胚 | 0.149 | 0.179 | 0.031 | 1.19 | 10560 | 163 | 1780 | 1300 | 5 | 11.48 | 31 |
| 黄豆皮 | 0.492 | 0.586 | 0.073 | 1.575 | 1520 | 242 | 1510 | 1990 | 18 | 3.310 | 98 |
从上表可见：黄豆瓣、黄豆胚、黄豆皮中钡、铋、钴、铬、铜、锗、锂、锰、钼、镍、磷、铅、锶、钛、钒、锌、锆、铈、镓、镧、铌、钪、钍、钾、铁、镁、钙、铝、硼、钠30种元素都有检出；除去有毒性的铋、铅，其中钡、钴、铬、铜、锗、锂、锰、钼、镍、磷、锶、钛、钒、锌、钾、铁、镁、钙、硼、铝、钠、镧、铈、镓、钍、锆、铌、钪28种元素都有检出，而且相对含量较高；特别是钴、铬、铜、锗、锂、锰、钼、镍、磷、锶、钒、锌、钾、铁、镁、钙、硼、钠18种元素有益元素相对含量较高非常重要。
黄豆瓣是黄豆的主体，其中铬、锂、钼、钒、钾、镁、钙、铋8元素含量较黄豆胚和黄豆皮高，是黄豆的主要营养所在。黄豆胚是黄豆生芽的胚，黄豆再生的胚体。其中钴、铜、锰、镍、磷、硼6种元素含量较高，这6种元素与植物生殖的重要性。黄豆皮是黄豆粒体的包膜，犹如胞衣。其中钠、钡、锶、锌、锗、钛、锆、铈、镓、镧、铌、钪、钍、铁、锡、铝、锑17种元素含量较高。有毒元素铅、镉含量相对高也是豆皮的一种保护作用的体现，但硒元素未被检出。
钢渣中微量元素钒、钛、钴、镍含量比天然矿石高出许多倍。碱渣组分进行了分析：钙为31.44％，镁为5.83％，钾4.02％，钠0.78％，铝0.51％，铁0.33％，锰446mg/kg，磷328.5mg/kg，钛293.9mg/kg，钒18.6mg/kg，钴13.51mg/kg，可溶硅11.6mg/kg，锶123.9mg/kg，锌220.5mg/kg，铬87.8mg/kg等碱渣中不仅含有氮、磷、钾等常规肥，还含钙、镁、氯、钠常量元素，还含有铁、锌、锰、铁、钒、铬、镍、锶、硼、铍、铜、钴、硅等植物和人都需要的必需的微量元素、有害元素含量小，不能对人体构成危害，碱渣作为基肥配制，不仅改良土壤中有益成分，而农作物吸收微量元素，对人体健康会产生有益的影响，它的PH值为11，可改善土壤的酸碱平衡。
天然矿石奇冰石、麦饭石、珊瑚化石、电气石，它们均为多孔穴吸附净水溶出多种微量元素释放负离子的偏硅酸盐类矿石，富含几十种对人体有益的元素，SiO2二氧化硅能有效预防紫外线放射伤害，Al2O3是具有远红外辐射式杀菌的代表，TiO2是光催化式杀菌的代表，Fe2O3、FeO是屏蔽电磁污染对植物病虫害及各种放射、污染的伤害。稻壳、豆饼、蔗渣、甲壳素均是天然营养肥料，及含多种微量元素天然强效抗氧剂清除植物体内自由基的松针系列和天然特殊四菜费菜、葛根、牛蒡、苦菜提取物“酮聚酶”的有效成分的加入，增加了菜油、豆油“酮聚酶”分子的含量通过“药食同源”，有效地保护心肌细胞，我们知道细胞修复器，线粒体受损，正常的细胞寿命必然缩短，但在心脏的“心肌纤维里”发现“酮聚酶”能够修复细胞线粒体的损伤，人的自身心肌纤维细胞具有分泌“酮聚酶”的功能，但是由于遗传因素等使这种分泌功能受到影响，以致使心肌纤维细胞里分泌“酮聚酶”减少或停止，一旦缺乏细胞内的线粒体得不到应有的保护，细胞线粒体营养转化，和自由基代谢，就会出现障碍，使细胞功能大大减退，最终导致全身免疫力、抵抗疾病的能力全面下降，出现多种慢性疾病，四种特殊蔬菜提取物“酮聚酶”在人们常食的菜油或豆油中通过“药食同源”食物的摄取，把含有这种药物分子输送到全身各器官细胞中，促进全身细胞自我恢复，对慢性疾病及各种疑难疾病有较好的治疗或补助治疗效果。
由9位诺贝尔奖得主反复研究证实，酵素能起到均衡营养，排毒解毒，还原身体机能，活化并再生细胞，所谓酵素是一种蛋白质，目前人体内已发现的酵素1000种以上，酵素是一切生命的基础生物若无酵素则无法生存，如何获得并活用酵素，关系到人的生命和健康，酵素是维持动物和植物生命活动的根源，菜籽油，豆油是由油菜籽和大黄豆粒在常温下经榨油机炸出来的没有温度所以保存了很多的活性酵素“酮聚酶”，这种神奇的物质酵素进入人体30分钟后就能分解老化的细胞，制造新生细胞在高倍显微镜下，我们可以发现组织中活细胞数量有大幅度增加，而且老龄化细胞也趋于饱满。同时酵素能分解血液的废物，使血液保持弱碱性，促进血液循环，还能消炎、杀菌，增强免疫力，增强机体抗感冒的能力，增强活化巨噬细胞，有效地抵抗异物侵袭。
下面结合实施例对本发明作进一步说明。
具体实施方式：
实施例1：
(1)其中富硒锗除虫害杂草酵素“酮聚酶”钢、碱渣营养基肥，其特征是：由下列质量份配比组成％
①土壤肥力增强剂钢渣营养基肥
②天然清除病虫害杂草元素营养基肥
③富硒锗灵芝菌环保酵素碱渣营养基肥
④富硒螺旋藻松针系列碱渣营养基肥
⑤富硒锗硼螺旋藻灵芝菌丝体蔬菜“酮聚酶”钢渣营养基肥
(2)促进植物生长微量元素营养基肥
(3)富硒锗螺旋藻微量元素营养基肥
上述物料溶于100kg水中搅拌到溶解，临用时，稀释1倍，种植时用铺有25cm厚的锯木屑上种植，种植后踏紧，因为锯木屑疏松，透气性能好，用上述方法营养液浇灌，保温植物种子成活率高，成长速度快，种植时用原液，叶面喷施用1∶1稀释液。
(4)天然抗菌抗氧化清除植物自由基松针系列铜渣营养基肥
(5)促进植物根部保水消毒杀毒供氧营养基肥
按配方将玉米淀粉和水加入带有搅拌的反应釜内氧氮气吹入管和温度计的反应釜器内，在氮气的保护下于75℃经1h搅拌后，冷却至30℃下聚合反应3-3h，得白色悬浮液，在此悬浮液中加氢氧化钠溶液于95℃下，经水解得黄褐色粘稠液体，将此液体注入盘中，在90℃下座右烘干，并用热风吹约15-20h。得产品干燥后再超细微粉碎成纳米粉，另外过氧化氢、尿素、稳定剂、膜剂单独向反应釜内首先投入稳定剂用量为尿素的0.5％-1％和过氧化氢经过15℃搅拌下投入尿素，尿素∶过氧化氢1.0∶1.1摩尔比为宜，并在5℃-15℃搅拌反应1h，然后加入外包膜剂用量为尿素的0.1-0.3％，搅拌10min，离心过滤，滤液循环利用，干燥碎成纳米粉两粉混合均匀即得植物根部保水杀菌供氧的营养剂。
将以上各组分中各物料再用超低温真空冷冻干燥粉碎为宜，其目的以防破坏其植物中的活性成分，用常规二氧化碳萃取或用60％乙醇提取的方法提取，滤液经薄膜蒸发、回收乙醇，并浓缩成1∶1(即每毫升含源生药1g)，相对密度为1.03-1.05的流浸膏备用。用时将流浸膏超低温冷冻真空干燥研细与其他物料共同混合，将其混合物料再用纳米粒径超细微化通用装置将物料的大分子进行破碎、乳化、均质、分散，从而粒化成纳米级粒径的小分子过1800-2200目筛，中心粒径为0.1-5μm，因为药物的吸收常受药物在吸收部位溶出速度的支配，而减小粒径，可以增大在暴露在介质中的表面积，而促进溶解，进而提高药物的吸收度和利用率，增大了药效和治疗效果。使纳米级粒径的小分子进油菜大豆植物细胞最终进入油菜籽粒和大黄豆粒中，随压榨油时流出的菜籽油、黄豆油富含硒锗多元素有益于人体健康的植物油、菜油和大豆油。用时将营养剂和土壤拌在一起放在植物根部周围。
一种富硒锗酵素酮聚酶的菜豆油，由促进植物生长微量元素营养基肥、富硒锗螺旋藻微量元素营养基肥、天然抗菌抗氧化清除自由基钢渣营养肥、促进植物根部供水消毒杀菌供氧营养肥、富硒锗硼除虫害杂草酵素“酮聚酶”钢、碱渣营养基肥组成，其特征是：由下列质量份配比组成％
实施例2：一种富硒锗酵素酮聚酶的菜豆油，由促进植物生长微量元素营养基肥、富硒锗螺旋藻微量元素营养基肥、天然抗菌抗氧化清除自由基钢渣营养肥、促进植物根部供水消毒杀菌供氧营养肥、富硒锗硼除虫害杂草酵素“酮聚酶”钢、碱渣营养基肥组成，其特征是：由下列质量份配比组成％
实施例3：一种富硒锗酵素酮聚酶的菜豆油，由促进植物生长微量元素营养基肥、富硒锗螺旋藻微量元素营养基肥、天然抗菌抗氧化清除自由基钢渣营养肥、促进植物根部供水消毒杀菌供氧营养肥、富硒锗硼除虫害杂草酵素“酮聚酶”钢、碱渣营养基肥组成，其特征是：由下列质量份配比组成％
实施例4：一种富硒锗酵素酮聚酶的菜豆油，由促进植物生长微量元素营养基肥、富硒锗螺旋藻微量元素营养基肥、天然抗菌抗氧化清除自由基钢渣营养肥、促进植物根部供水消毒杀菌供氧营养肥、富硒锗硼除虫害杂草酵素“酮聚酶”钢、碱渣营养基肥组成，其特征是：由下列质量份配比组成％
实施例5：一种富硒锗酵素酮聚酶的菜豆油，由促进植物生长微量元素营养基肥、富硒锗螺旋藻微量元素营养基肥、天然抗菌抗氧化清除自由基钢渣营养肥、促进植物根部供水消毒杀菌供氧营养肥、富硒锗硼除虫害杂草酵素“酮聚酶”钢、碱渣营养基肥组成，其特征是：由下列质量份配比组成％
Claims (1)
1.一种富硒锗酵素酮聚酶的菜豆油，其特征是：由下列质量份配比组成％
(1)其中富硒锗除虫害杂草酵素“酮聚酶”钢、碱渣基肥，其特征是：由下列质量份配比组成％
①土壤肥力增强剂钢渣营养基肥
②天然清除病虫害杂草元素营养花基肥
③富硒锗灵芝菌环保酵素碱渣基肥
④富硒螺旋藻松针系列碱渣基肥
⑤富硒锗硼螺旋藻灵芝菌丝体蔬菜“酮聚酶”钢渣营养基肥
(2)促进植物生长微量元素营养基肥
(3)富硒锗螺旋藻微量元素营养基肥
上述物料溶于100kg水中搅拌到溶解，临用时，稀释1倍，种植时用铺有25cm厚的锯木屑上种植，种植后踏紧，因为锯木屑疏松，透气性能好，用上述方法营养液浇灌，保温植物种子成活率高，成长速度快，种植时用原液，叶面喷施用1∶1稀释液。
(4)天然抗菌抗氧化清除植物自由基松针系列钢渣营养基肥
(5)促进植物根部保水消毒杀菌供氧营养基肥
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| CN105541447A (zh) * | 2015-11-09 | 2016-05-04 | 南通蛇类治疗研究所 | 培育一种低氟高硒锗保健茶叶的肥粉 |
| CN105541448A (zh) * | 2015-11-09 | 2016-05-04 | 南通蛇类治疗研究所 | 培育高硒锗防癌益寿西兰花的肥粉 |
| CN108383652A (zh) * | 2018-03-21 | 2018-08-10 | 南通蛇类治疗研究所 | 农业废弃物培育富硒锗绿色有机元素营养肥 |
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