CN103319755B - A kind of half-hot-melting motorcycle tyre and preparation method thereof - Google Patents

A kind of half-hot-melting motorcycle tyre and preparation method thereof Download PDF

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Publication number
CN103319755B
CN103319755B CN201310247933.6A CN201310247933A CN103319755B CN 103319755 B CN103319755 B CN 103319755B CN 201310247933 A CN201310247933 A CN 201310247933A CN 103319755 B CN103319755 B CN 103319755B
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hot
melting
parts
ozone
motorcycle tyre
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CN103319755A (en
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周伟波
丛杰
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TIUMSUN RUBBER TIRE (WEIHAI) CO Ltd
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TIUMSUN RUBBER TIRE (WEIHAI) CO Ltd
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Abstract

The present invention relates to a kind of half-hot-melting motorcycle tyre and preparation method thereof, described half-hot-melting motorcycle tyre is mainly carried out mixing, sulfuration preparation by Material synthesis glue, Butadiene-Styrene Rubber, white carbon black N339, aromatic naphtha, zinc oxide, stearic acid, ozone-resistant age resistor, protection wax, sulfur, accelerator and antiscorching agent.Compared with prior art, present invention efficiently solves the use limitation problem of current full hot melt tire, achieve while improving tire earth-grasping force, making tire be prevented effectively from because of tyre surface, to cross soft mistake viscous and attach the foreign material such as too many sandstone dust, so that bend tire will not occur the phenomenons such as out of control, cabling skew easily, and then safety that vehicle run is greatly improved, there is provided for the high gripping power of vehicle, controllable property and safety and fully ensure, be suitable to promote the use of in associated tire applications such as motorcycles.

Description

A kind of half-hot-melting motorcycle tyre and preparation method thereof
Technical field
The present invention relates to rubber tyre and application and preparation technical field thereof, particularly relate to a kind of half-hot-melting motorcycle tyre and Its preparation method.
Background technology
At present, motorcycle is when using full hot melt tire, on the one hand, car is pushed ahead by tire with ground friction acting, On the other hand, produce colloid deliquescing after heat makes tread-rubber reach fusing point by friction work to become sticky, so that tire has Good traction, for the guarantee that safely provided of car body and jockey, but the generation of this kind of effect is only limitted to tire exists Travel on clean pavement of race course.But after buffer strip is rushed in racing car, the extraordinary full hot melt tire of earth-grasping force will adhere to greatly Amount stone and dust, similarly, use other vehicles of full hot melt tire to be also unsuitable on common urban pavement travelling, city The situation the most shallow the most same racing track buffer strip on road surface, city is full of dust and handstone, and on such road surface, full hot melt is curved Road tire there will be the phenomenons such as uncontrolled, cabling offsets, tracking property is inadequate.Furthermore, the road of motorcycle in general city Journey major part is all about half an hour, and when full hot melt tire just arrives to good operating temperature, car has reached substantially to destination, right In, the advantage of full hot melt tire has no chance to be played at all.Generally, there is yielding causing in the use of full hot melt tire The major defect that dynamic balancing forfeiture and tyre surface are easily cracked.Therefore, need badly and research and develop the tire with more preferable effect, it is possible to It is prevented effectively from the phenomenon occurring full hot melt tire to stick up a large amount of handstone and dust, simultaneously, additionally it is possible to play and full hot melt tire Close good earth-grasping force performance.
Summary of the invention
It is an object of the invention to, the problem existed for prior art, it is provided that a kind of half-hot-melting motorcycle tyre and system thereof Preparation Method, it is achieved tire has the earth-grasping force performance close to full hot melt tire after temperature raises, and, will not become sticky because of tyre surface meanwhile And attach the foreign material such as too many sandstone dust, make the wear intensity of tire be effectively controlled in permissible scope.
The present invention solves the technical scheme of problem: a kind of half-hot-melting motorcycle tyre, is made up of following raw material components: close Plastic, Butadiene-Styrene Rubber, white carbon black N339, aromatic naphtha, zinc oxide, stearic acid, ozone-resistant age resistor, protection wax, sulfur, promotion Agent, antiscorching agent.
Further, the raw material components of described half-hot-melting motorcycle tyre is as follows: rubber polymer 15~27 Part, Butadiene-Styrene Rubber 90~110 parts, white carbon black N33965~85 parts, aromatic naphtha 13~20 parts, zinc oxide 2.5~3 parts, stearic acid 1.5~2.0 parts, ozone-resistant age resistor 2.3~3.0 parts, protection wax 2.5~3.0 parts, sulfur 1.5~1.6 parts, accelerator 1.5~ 1.8 parts, antiscorching agent 0.11 part.
Further, described rubber polymer is synthesized by acrylonitrile and styrene, and wherein, the mass percent of acrylonitrile is preferably 22%, it is therefore intended that utilize the side base of acrylonitrile molecule, improve earth-grasping force further.
Further, in the raw material components of described half-hot-melting motorcycle tyre, described accelerator is that sulfenamide has Machine compound, described antiscorching agent is anti-scorching agent CTP i.e. N-cyclohexyl thio phthalic amide.
Further, in the raw material components of described half-hot-melting motorcycle tyre, described ozone-resistant age resistor includes anti-smelly Oxygen antioxidant 4020 and aftereffect ozone-resistant age resistor V-3100;Preferably, the weight portion of described ozone-resistant antioxidant 4020 is 1.5~2.0 parts, the weight portion of described aftereffect ozone-resistant age resistor V-3100 be 0.8~1.0 part;Wherein, aftereffect ozone-resistant The application of age resistor V-3100, it is possible to hot melt mold is effectively ensured more permanent hot melt effect.
Preferably, in the raw material components proportioning of described half-hot-melting motorcycle tyre, rubber polymer 15~24 parts, solution polymerized butylbenzene Glue 95~110 parts, white carbon black N33970~85 parts, aromatic naphtha 14~20 parts, zinc oxide 2.5~3.0 parts, stearic acid 1.5~1.8 Part, ozone-resistant age resistor 2.3~2.8 parts, protection wax 2.5~3.0 parts, sulfur 1.5~1.6 parts, accelerator 1.5~1.8 parts, anti- Burnt agent 0.11 part;Wherein, it is preferred that in ozone-resistant age resistor 2.3~2.8 parts, the weight portion of ozone-resistant antioxidant 4020 is 1.5 ~the weight portion of 2.0 parts, aftereffect ozone-resistant age resistor V-3100 is 0.8~1.0 part.
Present invention also offers the preparation method of a kind of half-hot-melting motorcycle tyre, comprise the steps: to rub by half hot melt The raw material components weight ratio of motorcycle tire weighs each raw material components: rubber polymer, Butadiene-Styrene Rubber, white carbon black N339, aromatic naphtha, oxidation Zinc, stearic acid, ozone-resistant age resistor, protection wax, sulfur, accelerator, antiscorching agent, after mixing each raw material components in banbury Carry out mixing;Vulcanize in vulcanizing press after mixing.
Preferably, in the preparation of half-hot-melting motorcycle tyre, curing temperature is 160 DEG C, and cure time is 30min;Also Can be adjusted according to practical condition, but curing temperature is preferably controlled to 130 DEG C~190 DEG C, cure time is preferably controlled It is made as 15min~50min.
Half-hot-melting motorcycle tyre of the present invention is carried out the hardness test after travelling test, room temperature and traveling, hot strength Test, stress test, elongation at break test, tearing strength etc. are tested, and result shows, it is possible to have grabbing close to full hot melt tire Soil fertility, but it is viscous and attach the foreign material such as too many sandstone dust to cross soft mistake because of tyre surface.
Compared with prior art, the invention has the beneficial effects as follows: the use efficiently solving current full hot melt tire is subject to Limit problem, it is achieved that improving while tire earth-grasping force, making tire be prevented effectively from because of tyre surface, to cross soft mistake viscous and attach too many sand The foreign material such as stone dust, so that bend tire will not occur the phenomenons such as out of control, cabling skew easily, and then are greatly improved vehicle fortune The safety of row, it is achieved provide for the high gripping power of vehicle, controllable property and safety and fully ensure, be suitable in phases such as motorcycles Close tire applications field to promote the use of.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated, but protection scope of the present invention is not limited to This.
Experimental technique used in following embodiment if no special instructions, is conventional method.
Material used in following embodiment, reagent etc., the most commercially obtain.
Embodiment 1
A kind of half-hot-melting motorcycle tyre, concrete raw material components proportioning is as shown in table 1.Half-hot-melting motorcycle tyre of the present invention Preparation method comprise the steps: that the raw material components weight ratio of half-hot-melting motorcycle tyre as shown in table 1 weighs each raw material group Point, carry out mixing after each raw material components is mixed in banbury;Vulcanize in vulcanizing press after mixing, curing temperature Being 160 DEG C, cure time is 30min.
Half-hot-melting motorcycle tyre of the present invention carries out performance detection, and concrete detection method and performance test results are shown in Table 2.
Embodiment 2
A kind of half-hot-melting motorcycle tyre, it is prepared substantially and method for testing performance is with embodiment 1, and its raw material components is shown in Table 1, properties of product testing result is shown in Table 2.
Embodiment 3
A kind of half-hot-melting motorcycle tyre, it is prepared substantially and method for testing performance is with embodiment 1, and its raw material components is shown in Table 1, properties of product testing result is shown in Table 2.
Embodiment 4
A kind of half-hot-melting motorcycle tyre, it is prepared substantially and method for testing performance is with embodiment 1, and its raw material components is shown in Table 1, properties of product testing result is shown in Table 2.
Embodiment 5
A kind of half-hot-melting motorcycle tyre, it is prepared substantially and method for testing performance is with embodiment 1, and its raw material components is shown in Table 1, properties of product testing result is shown in Table 2.
Table 1
Table 2
Existing conventional full hot melt tire and common tire detect via Shao Er A type hardness tester meter, respectively 50~52,60~ 62, as shown in Table 2, the hardness of half-hot-melting motorcycle tyre of the present invention all between full hot melt tire (50~52) and common tire (60~ 62) between, elongation at break reaches 537% to 756%, and which determining half-hot-melting motorcycle tyre of the present invention can after temperature raises Have an earth-grasping force close to full hot melt tire, but it is viscous and attach the foreign material such as too many sandstone dust to cross soft mistake because of tyre surface;Furthermore, Other tests of each embodiment gained sample also indicate that half-hot-melting motorcycle tyre performance synthesis of the present invention performance is stable;Additionally, After carrying out the walk test of about 1200 kms, the effect at aspects such as gripping power, controllable property and safeties is had outstanding performance, especially The effect of above-mentioned several respects when being to run on road surface, ordinary municipal relative to existing full hot melt tire and common tire improves aobvious Write.
The present invention is not limited to above-mentioned embodiment, in the case of without departing substantially from the flesh and blood of the present invention, and this area skill Art personnel it is contemplated that any deformation, improve, replace and each fall within the scope of the present invention.

Claims (6)

1. a half-hot-melting motorcycle tyre, it is characterised in that be made up of following raw material components: rubber polymer, Butadiene-Styrene Rubber, charcoal Black N339, aromatic naphtha, zinc oxide, stearic acid, ozone-resistant age resistor, protection wax, sulfur, accelerator, antiscorching agent, described rubber polymer For acrylonitrile and cinnamic synthetic, wherein, the weight/mass percentage composition of acrylonitrile is 22%;
The raw material components of described half-hot-melting motorcycle tyre is as follows: rubber polymer 15~27 parts, Butadiene-Styrene Rubber 90~ 110 parts, white carbon black N33965~85 parts, aromatic naphtha 13~20 parts, zinc oxide 2.5~3 parts, stearic acid 1.5~2.0 parts, ozone-resistant Age resistor 2.3~3.0 parts, protection wax 2.5~3.0 parts, sulfur 1.5~1.6 parts, accelerator 1.5~1.8 parts, antiscorching agent 0.11 Part.
2. half-hot-melting motorcycle tyre as claimed in claim 1, it is characterised in that described raw material components accelerator is time sulphonyl Amine organic compound, described antiscorching agent is anti-scorching agent CTP.
3. half-hot-melting motorcycle tyre as claimed in claim 1, it is characterised in that described raw material components ozone-resistant age resistor bag Include ozone-resistant antioxidant 4020 and aftereffect ozone-resistant age resistor V-3100.
4. half-hot-melting motorcycle tyre as claimed in claim 3, it is characterised in that described raw material components ozone-resistant age resistor The weight portion of 4020 is 1.5~2.0 parts, the weight portion of aftereffect ozone-resistant age resistor V-3100 is 0.8~1.0 part.
5. the method for the half-hot-melting motorcycle tyre prepared as according to any one of Claims 1-4, it is characterised in that Comprise the steps: to weigh each raw material components by the raw material components weight ratio of half-hot-melting motorcycle tyre: rubber polymer, solution polymerized butylbenzene Glue, white carbon black N339, aromatic naphtha, zinc oxide, stearic acid, ozone-resistant age resistor, protection wax, sulfur, accelerator, antiscorching agent, will be each Carry out mixing after raw material components mixing in banbury;Vulcanize in vulcanizing press after mixing.
6. the preparation method of half-hot-melting motorcycle tyre as claimed in claim 5, it is characterised in that curing temperature is 160 DEG C, Cure time is 30min.
CN201310247933.6A 2013-06-20 2013-06-20 A kind of half-hot-melting motorcycle tyre and preparation method thereof Active CN103319755B (en)

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Publication number Priority date Publication date Assignee Title
CN105802545B (en) * 2016-04-27 2018-06-08 江苏通用科技股份有限公司 Half hot melt adhesive of motorcycle tyre and preparation method
CN108329545A (en) * 2018-02-02 2018-07-27 四川远星橡胶有限责任公司 A kind of half hot melt tire tread glue formulation of motorcycle place contest and preparation method thereof
CN108503917A (en) * 2018-03-21 2018-09-07 腾森橡胶轮胎(威海)有限公司 A kind of motorcycle rider tournament vehicle tire tread compound
CN115627015A (en) * 2022-10-25 2023-01-20 联科华技术有限公司 Rubber tire prepared from monatomic zinc material with ultralow zinc content

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CN101434721A (en) * 2007-11-14 2009-05-20 韩国轮胎株式会社 Rubber composition for tyre tread
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CN101434721A (en) * 2007-11-14 2009-05-20 韩国轮胎株式会社 Rubber composition for tyre tread
CN102226019A (en) * 2011-06-10 2011-10-26 江苏通用科技股份有限公司 Fully synthetic crown compound of motorcycle tyre

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Denomination of invention: A semi hot melt motorcycle tire and its preparation method

Effective date of registration: 20221207

Granted publication date: 20160810

Pledgee: Weihai Commercial Bank Co.,Ltd. Economic and Technological Development Zone Sub branch

Pledgor: TIUMSUN RUBBER TIRE (WEIHAI) Co.,Ltd.

Registration number: Y2022980025460

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