CN103318985A - Water body antidote for aquaculture - Google Patents
Water body antidote for aquaculture Download PDFInfo
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- CN103318985A CN103318985A CN2013102827476A CN201310282747A CN103318985A CN 103318985 A CN103318985 A CN 103318985A CN 2013102827476 A CN2013102827476 A CN 2013102827476A CN 201310282747 A CN201310282747 A CN 201310282747A CN 103318985 A CN103318985 A CN 103318985A
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Abstract
The invention discloses an aquaculture pond detoxification composition which is characterized by containing polymeric ferric sulfate, calcium peroxide, humic acid and zeolite powder. The four ingredients can be directly and uniformly mixed by a stirrer to form powder or processed by a tablet machine to form granules. The granules can be directly thrown into a fish pond when in use. The composition can be used for quickly relieving and reducing the toxic symptoms of aquatic animals caused by such harmful substances in the aquaculture pond as ammonia nitrogen, hydrogen sulfide, algal toxins, heavy metals and pesticides, and also quickly and effectively increasing the dissolved oxygen in the water body, thereby being suitable for high-density aquaculture water bodies.
Description
Technical field
The present invention relates to the aquaculture system toxinicide, particularly a kind of toxinicide of poisoning of hydrogen sulfide, ammonia nitrogen, algae toxin, heavy metal and the agricultural chemicals that easily produces for Aquacultural water.
Technical background
The density of at present aquaculture is increasing along with the raising of aquaculture cost, the output of per unit area yield constantly refreshes, strengthened the load of cultivating pool water body self-purification ability, also easily cause dissolved oxygen content reduction in the water body, the content increase of hydrogen sulfide, ammonia nitrogen, nitrite easily causes cultivated animals death owing to water quality deterioration.In addition, blue-green algae and Euglena break out and sudden death all can cause the poisoning of Aquatic farming animals algae toxin, also be one of factor that causes the large quantities of death of aquatic animal.And in actual breeding process, because raiser's educational level is generally not high, often misapplies the heavy metal sterilant and cause the phenomenon of aquatic animal poisoning also to happen occasionally; The generation of cultivated animals disease after the pollution at water source, pond also can cause aquaculture water to pollute.Above these phenomenons all are phenomenons common in the aquaculture process, deal with improperly often to cause cultivating the large quantities of death of object and all death that arrives, and the raiser can't regain one's original capital.By developing a kind of product that detoxifies fast, reach quick releasing toxic substance toxicity, the aquatic animal that reduces after poisoning is dead in enormous quantities, saves fisherman's loss.
Summary of the invention
The input that the objective of the invention is various toxin in a kind of quick releasing water body of assembly plays and reduces aquatic animal because of various poisonings and the murderous effect of anoxic.Thing of the present invention reaches following three greatly effects: 1, the organism of quick adsorption water body, salubrious water body environment; 2, increase the dissolved oxygen of water body; 3, eliminate the toxic substance of water body hydrogen sulfide, ammonia nitrogen, algae toxin, heavy metal.
The present invention has adopted following several components to process:
Bodied ferric sulfate of the present invention is solid ferric polysulfate, molecular formula: [Fe
2(OH) n (SO
4)
3-n/2] m, 1% aqueous solution pH2.0-3.0 is a kind of novel, high-quality, efficient molysite class inorganic polymer flocculant.Have coagulation performance good, alumen ustum is closely knit, the characteristics that settling velocity is fast; To turbidity removal, decolouring, de-oiling, dehydration, degerming, deodorizing, except algae, to remove in the water effects such as COD, BOD and heavy metal ion remarkable, and purifying water effect is good, water quality is good, do not contain aluminium, chlorine and heavy metal ion objectionable impurities, the also water of non-iron-ion transfer, nontoxic, harmless, safe and reliable.It is 4~11 that bodied ferric sulfate adapts to the water pH value wide ranges, and the optimal ph scope is 6~9, meets the pH scope of aquaculture water, and pH value and the total alkalinity rangeability of former water are little after purifying, and keeps the stability of water body.Dosage is few, and cost is low, and processing costs is not high.
Calcium peroxide in the component, molecular formula: CaO
2, water insoluble, be dissolved in ethanol, ether, acid.Oxygen discharging speed is very slow when using separately in actual breeding process, can only be as the auxiliary oxygenation agent, and just inapplicable when running into water hypoxia, floating head, poisoning emergency situation.But itself and acid-respons formula are CaO
2+ 2H
+=Ca
2++ H
2O
2, calcium peroxide dissolving rapid reaction Hydrogen Peroxide under sour environment.Hydrogen peroxide is unstable, can decompose and emit oxygen, and simultaneously, hydrogen peroxide also is a kind of strong oxidizer, can effectively remove fast hydrogen sulfide, ammonia nitrogen and algae toxin in the water body by oxygenizement.
Humic acids in the component generally is the complex mixture of the aromatic carboxylic acid that extracts from low level coal (peat, brown coal, weathered coal), great chemically reactive and biological activity are arranged, with metal ion the effect of exchange, absorption, complexing, chelating is arranged, the toxicity of energy efficient solution removing heavy metals, being used as the water quality toxinicide in aquaculture has extraordinary effect.
Component mesolite powder is a kind of carrier, draws materials conveniently, price is low, can also play good adsorption simultaneously, and is helpful to water quality improvement.
Above-mentioned four kinds of components are mixed with stirrer, can play multi-efficiency:
One, bodied ferric sulfate can turbidity removal, degerming, deodorizing, except algae, to remove in the water effect of COD, BOD and heavy metal ion remarkable, these characteristics are given its good detoxicating functions;
Two, the aqueous solution pH of bodied ferric sulfate is 2~3, but calcium peroxide and its mixed dissolution rapid reaction Hydrogen Peroxide, but hydrogen peroxide oxygenation, simultaneously oxidable hydrogen sulfide, ammonia nitrogen, algae toxin objectionable impurities;
Three, humic acids and metal ion have the effect of exchange, absorption, complexing, chelating, have the effect of removing heavy metal toxicity;
Four, zeolite powder mainly plays the effect of filling and excipient, can also play the effect of auxiliary improvement water quality.
Composition of the present invention can be made commodity selling by the various ways processing.The first with above-mentioned bodied ferric sulfate, calcium peroxide, humic acids, four kinds of compounds of zeolite powder directly according to mass percent mixing and stirring, then packing; It two is with the machinery granulate machine above-mentioned bodied ferric sulfate, calcium peroxide, humic acids, four kinds of compounds of zeolite powder to be processed into different shape granule type commodity, then packing.
Using method, when above-mentioned composition is pulvis, with the time need to dilute dissolving with the water more than 50 times, then in the pond, evenly splash; When above-mentioned composition is made particle shape, but Direct Uniform is shed in the pond.
Embodiment
Embodiment 1: take by weighing 700kg bodied ferric sulfate, 200kg calcium peroxide, 50kg humic acids, 50kg zeolite powder, with these four kinds of compound accurate weighings, pour into and mix 5 minutes in the stirrer, then direct packaging or the again packing of tablet of using tabletting machine to make the 3-5 millimeter.
Embodiment 2: take by weighing 500kg bodied ferric sulfate, 300kg calcium peroxide, 100kg humic acids, 100kg zeolite powder, with these four kinds of compound accurate weighings, pour into and mix 5 minutes in the stirrer, then direct packaging or the again packing of tablet of using tabletting machine to make the 3-5 millimeter.
Embodiment 3: take by weighing 700kg bodied ferric sulfate, 100kg calcium peroxide, 100kg humic acids, 100kg zeolite powder; with these four kinds of compound accurate weighings; pour into and mix 5 minutes in the stirrer, then direct packaging or use the roll-in nodulizer to make packing behind the particle of 3-5 millimeter.
Use case
1.2012 on August 3,, the pool, one culturing carps fishpond, Yutian, Tangshan finds that fish does not ingest, the shoal of fish roams the limit of lying prone, drive oxygenating machine more serious, a small amount of Trichodina is arranged on the gill, uses the Nanjing intelligent Water Test Kits of special peace MR220A to measure water quality and find, hydrogen sulfide be 0.21mg/L, water has peculiar smell, is judged to be hydrogen sulfide poisoning.Used the dust composition in above-described embodiment 1, every 667m3 water body 1000g.Use after one hour, shoal of fish roaming quantity reduces gradually, to using this composition the 10th hour, symptom disappears substantially, and hydrogen sulfide is measured as 0.12mg/L, re-uses this composition once, to the 24th hour, it is normal that the cultivated animals in this pond recovers, and dead movement pattern of fish condition does not occur.
2.2012 break out blue-green algae in the water in good 50 mu of pond of Tianjin Wuqing District pornographic books and magazines on August 12,, causes the fish food bad, water quality has stench flavor.The raiser kills blue-green algae with copper sulfate, because after the blue-green algae death, generation algae toxin is concentrated and is discharged in the water, the copper sulfate consumption also is that escalated dose is used in addition, and water body pH reduces behind the algae extremely, and copper sulfate toxicity further strengthens.The toxicity symptom that above-mentioned two kinds of factors cause cultivating that carp, flower silver carp class keep to the edge, mad trip, the water surface are spinned.In 9 dust compositions that used in above-described embodiment 1 in morning August 13, every 667m
3Water body 1500g.Used rear one hour, shoal of fish trip limit quantity reduces gradually, to using this composition the 10th hour, transference cure, the water surface find no the fish activity of unusual phenomenon, to using this composition one order 24 hours, it is normal that cultivated animals in this pond recovers, and it is normal that material feeding recovers.
3.2012 on September 11,, 5 mu of leg Shrimp Litopenaeus vannamei Culture Raceway-type Ponds pools, Binzhou City, Shandong Province Qiao Zhuan town owing to not taking to improve for a long time the measure of substrate in breeding process, cause the residual bait ight soil accumulation of substrate too much, cause the substrate acidifying, sulfurated hydrogen detection is 0.26 mg/litre.Unusual spring appears in Penaeus vannamei, a small amount of dead situation then occurs.The raiser uses the particulate composition of above-described embodiment 2, according to 667m
3Water body uses 1000g, 10 uses of that morning, and the observation of 3 o'clock of afternoon, Penaeus vannamei unusual spring quantity occurs and has reduced 90%, during to 7 o'clock of dusk, does not find that prawn has above-mentioned symptom.The second day raiser observes the prawn death condition at dive under water oxygenating machine bottom, finds new dead individuality.
Claims (2)
1. an aquaculture system toxinicide is characterized in that its effective constituent contains following four kinds of compositions: contain 5~85 parts of bodied ferric sulfates, 5~85 parts of calcium peroxides, 5~85 parts of 5~85 parts of humic acidss and zeolite powders.
2. according to claims 1 described aquaculture system toxinicide, it is characterized in that tablet, circular granular, irregular particle and the pulvis made take bodied ferric sulfate, calcium peroxide, humic acids and zeolite powder as effective constituent.
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103947678A (en) * | 2014-04-02 | 2014-07-30 | 温震烨 | Novel fish pond disinfectant |
CN104591482A (en) * | 2014-12-25 | 2015-05-06 | 苏州市阳澄湖现代农业发展有限公司 | Oxygenation treatment method for aquaculture water body |
CN105923784A (en) * | 2016-04-27 | 2016-09-07 | 石家庄民康水处理技术有限公司 | Water purifier, and preparation method and use thereof |
CN108101170A (en) * | 2017-12-26 | 2018-06-01 | 深圳地天国际生物工程科技有限公司 | A kind of water purification pulvis and its preparation process for being used to kill Euglena |
CN108275747A (en) * | 2018-02-08 | 2018-07-13 | 上海山恒生态科技股份有限公司 | A kind of ecological, environmental protective water purification agent of quick elimination black and odorous water ammonia nitrogen |
CN109319941A (en) * | 2017-07-31 | 2019-02-12 | 天津市渔生堂生物技术有限公司 | A kind of Water body antidote for aquaculture and its application method |
CN109354143A (en) * | 2018-11-16 | 2019-02-19 | 同济大学 | A method of algae blooms water is handled based on calper calcium peroxide enhanced coagulation |
CN112939135A (en) * | 2021-01-26 | 2021-06-11 | 南京乐透思环保科技有限公司 | COD (chemical oxygen demand) and ammonia nitrogen remover for tail water treatment |
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CN1850660A (en) * | 2006-05-17 | 2006-10-25 | 天津生机集团有限公司 | Improved composition of base of aquatic cultivation pool |
CN101580281A (en) * | 2009-06-08 | 2009-11-18 | 无锡中顺生物技术有限公司 | Substrate modifier for aquiculture and preparation method |
WO2011026910A1 (en) * | 2009-09-07 | 2011-03-10 | Tetra Gmbh | Continuous purification of aquaculture water holding aquatic animals and/or aquatic plants |
CN102963986A (en) * | 2012-12-04 | 2013-03-13 | 沧州旺发生物技术研究所有限公司 | Biological sediment modifier for fishpond |
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Patent Citations (4)
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CN1850660A (en) * | 2006-05-17 | 2006-10-25 | 天津生机集团有限公司 | Improved composition of base of aquatic cultivation pool |
CN101580281A (en) * | 2009-06-08 | 2009-11-18 | 无锡中顺生物技术有限公司 | Substrate modifier for aquiculture and preparation method |
WO2011026910A1 (en) * | 2009-09-07 | 2011-03-10 | Tetra Gmbh | Continuous purification of aquaculture water holding aquatic animals and/or aquatic plants |
CN102963986A (en) * | 2012-12-04 | 2013-03-13 | 沧州旺发生物技术研究所有限公司 | Biological sediment modifier for fishpond |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103947678A (en) * | 2014-04-02 | 2014-07-30 | 温震烨 | Novel fish pond disinfectant |
CN103947678B (en) * | 2014-04-02 | 2015-12-30 | 新昌县新诚工业产品设计有限公司 | A kind of fish pond disinfectant |
CN104591482A (en) * | 2014-12-25 | 2015-05-06 | 苏州市阳澄湖现代农业发展有限公司 | Oxygenation treatment method for aquaculture water body |
CN105923784A (en) * | 2016-04-27 | 2016-09-07 | 石家庄民康水处理技术有限公司 | Water purifier, and preparation method and use thereof |
CN105923784B (en) * | 2016-04-27 | 2018-10-02 | 河北泽世康环保科技有限公司 | Water quality cleansing agent and preparation method thereof, purposes |
CN109319941A (en) * | 2017-07-31 | 2019-02-12 | 天津市渔生堂生物技术有限公司 | A kind of Water body antidote for aquaculture and its application method |
CN108101170A (en) * | 2017-12-26 | 2018-06-01 | 深圳地天国际生物工程科技有限公司 | A kind of water purification pulvis and its preparation process for being used to kill Euglena |
CN108275747A (en) * | 2018-02-08 | 2018-07-13 | 上海山恒生态科技股份有限公司 | A kind of ecological, environmental protective water purification agent of quick elimination black and odorous water ammonia nitrogen |
CN109354143A (en) * | 2018-11-16 | 2019-02-19 | 同济大学 | A method of algae blooms water is handled based on calper calcium peroxide enhanced coagulation |
CN109354143B (en) * | 2018-11-16 | 2022-02-18 | 同济大学 | Method for treating high algae content water based on calcium peroxide reinforced coagulation |
CN112939135A (en) * | 2021-01-26 | 2021-06-11 | 南京乐透思环保科技有限公司 | COD (chemical oxygen demand) and ammonia nitrogen remover for tail water treatment |
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Application publication date: 20130925 |