CN103304964A - High-grade imitation jade material and preparation method thereof - Google Patents

High-grade imitation jade material and preparation method thereof Download PDF

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Publication number
CN103304964A
CN103304964A CN2013102360083A CN201310236008A CN103304964A CN 103304964 A CN103304964 A CN 103304964A CN 2013102360083 A CN2013102360083 A CN 2013102360083A CN 201310236008 A CN201310236008 A CN 201310236008A CN 103304964 A CN103304964 A CN 103304964A
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component
weight percent
phenylcarbinol
resins
epoxy
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CN2013102360083A
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Chinese (zh)
Inventor
陈坤森
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ZHANGZHOU LIDU CHEMICAL Co Ltd
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ZHANGZHOU LIDU CHEMICAL Co Ltd
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Abstract

The invention discloses a high-grade imitation jade material and a preparation method thereof. The high-grade imitation jade material comprises 2 parts of a component A, 1 part of a component B, a color concentrate and aluminum hydroxide powder, wherein the component A comprises epoxy resin E51, phenylcarbinol, an ultraviolet absorbent and an organic silicon defoaming agent; and the component B comprises 4,4'-diamino-dicyclohexylmethane, polyether amine D-230, epoxy resin and phenylcarbinol. The preparation method of the high-grade imitation jade material comprises the following steps of: respectively preparing the component A and the component B; adding the color concentrate, the aluminum hydroxide powder and 1 part of the component B into 2 parts of the component A, and uniformly mixing and stirring; vacuumizing and then molding by casting; and demolding to obtain the high-grade imitation jade material. The high-grade imitation jade material has readily-available raw materials, is attractive in appearance, corrosion-resistant, easy to clean, good in fire resistance, pollution-free and low in manufacturing cost, and can be used for imitating various jade handicraft articles including jade, amber, jade Buddhas, jade Goddess of mercy and the like.

Description

Imitative jade material of a kind of top grade and preparation method thereof
Technical field
The invention belongs to the artwork field, particularly imitative jade material of a kind of top grade and preparation method thereof.
Background technology
At present, the stone material for artwork processing mainly contains two kinds: a kind of is former stone, and its quantity is few, and moulding is slow, long processing time; Another kind is handicraft article made of unsaturated resin, its not environmental protection, and loss of properties on aging, more crisp, shrinking percentage is big, and is yielding.In the prior art, adopt Resins, epoxy to do jade, its moulding is fast, ageing-resistant performance is outstanding, anti-ly fall, non-friable and distortion, its weak point is the temperature variation sensitivity, need different ingredients in summer and winter, the technology of big part smallclothes is also different, and the later stage solidifies slower.
Summary of the invention
The present invention overcomes the problem that prior art exists, and imitative jade material of a kind of top grade and preparation method thereof is provided.
For achieving the above object, the present invention takes following technical scheme to realize: the imitative jade material of a kind of top grade comprises A component, B component, look essence and aluminium hydrate powder, the weight percent of described look essence is 0.1 %~1.0 % of A component, the weight percent of aluminium hydrate powder is 30%~80% of A component, wherein
Each composition and weight percent thereof are in the A component:
Resins, epoxy E51 86 %~91%
Phenylcarbinol 8 %~13%
Ultraviolet absorbers 0.5%~1.0%
Silicone antifoam agent 0.5 %~0.8%
Each composition and weight percent thereof are in the B component:
4,4 '-diamino-dicyclohexyl methane 10%~20%
Polyetheramine D-230 60%~70%
Resins, epoxy E51 8%~12 %
Phenylcarbinol 8%~12 %.
The present invention also provides the making method of the imitative jade material of above-mentioned top grade, may further comprise the steps:
Figure 2013102360083100002DEST_PATH_IMAGE001
The preparation of A component: Resins, epoxy E51 is dropped in the reactor, add phenylcarbinol, ultraviolet absorbers and silicone antifoam agent again, stir about 60 minutes is uniformly dispersed it, vacuumizes 10 minutes, filters packing;
Figure 2013102360083100002DEST_PATH_IMAGE002
The preparation of B component: with 4,4 '-diamino-dicyclohexyl methane drops in the reactor, drop into polyetheramine D-230 again, stir after (about 10 minutes), slowly drip the mixed solution of being formed by Resins, epoxy E51 and phenylcarbinol, after dripping in 30 minutes, mix and stir after 2 hours, vacuumize after-filtration packing in 15 minutes;
3. get 2 parts of A components, add look essence, aluminium hydrate powder in the A component, add 1 part of B component again, mixing and stirring vacuumizes the back casting, and the demoulding obtains high-grade imitative jade material.
The invention has the beneficial effects as follows: raw material is easy to get, and is handsome in appearance, and product is corrosion-resistant, easy cleaning, and good flame resistance, pollution-free, and cost of manufacture is low; This product can be widely used in imitative jade, amber, beautiful Buddhist, multiple jade handicraft such as Jade Goddess Of Mercy.
Embodiment
The invention will be further described with the following examples.
Embodiment 1:The imitative jade material of a kind of top grade of the present invention comprises 2 parts of A components, 1 part of B component, green essence and transparent aluminium hydrate powder, and described green smart weight percent is 0.2 % of A component, and the weight percent of transparent aluminium hydrate powder is 60% of A component, wherein,
Each composition and weight percent thereof are in the A component:
Resins, epoxy E51 90%
Phenylcarbinol 9%
Ultraviolet absorbers 0.5%
Silicone antifoam agent 0.5%
Each composition and weight percent thereof are in the B component:
4,4 '-diamino-dicyclohexyl methane 15%
Polyetheramine D-230 65%
Resins, epoxy E51 10%
Phenylcarbinol 10%.
The making method of embodiment 1 may further comprise the steps:
Figure 976544DEST_PATH_IMAGE001
The preparation of A component: Resins, epoxy E51 is dropped in the reactor, add phenylcarbinol, ultraviolet absorbers and silicone antifoam agent again, stir about 60 minutes is uniformly dispersed it, vacuumizes 10 minutes, filters packing;
Figure 893684DEST_PATH_IMAGE002
The preparation of B component: with 4,4 '-diamino-dicyclohexyl methane drops in the reactor, drop into polyetheramine D-230 again, stir after (about 10 minutes), slowly drip the mixed solution of being formed by Resins, epoxy E51 and phenylcarbinol, after dripping in 30 minutes, mix and stir after 2 hours, vacuumize after-filtration packing in 15 minutes;
3. get 2 parts of A components, the interpolation weight percent is that green smart, the weight percent of A component 0.2% are the transparent aluminium hydroxide powder of A component 60% in the A component, adds 1 part of B component again, mixing and stirring, vacuumize the back casting, the demoulding obtains high-grade imitative jade material.
The top grade that above-mentioned component and method make is imitated jade material, and emerald green, the real coloured light of being of product appearance is bright, and is similar to natural green jewel outward appearance.
Embodiment 2:The imitative jade material of a kind of top grade of the present invention comprises 2 parts of A components, 1 part of B component, white essence and transparent aluminium hydrate powder, and the smart weight percent of described white is 1.0% of A component, and the weight percent of transparent aluminium hydrate powder is 60% of A component, wherein,
Each composition and weight percent thereof are in the A component:
Resins, epoxy E51 88%
Phenylcarbinol 11%
Ultraviolet absorbers 0.5%
Silicone antifoam agent 0.5%
Each composition and weight percent thereof are in the B component:
4,4 '-diamino-dicyclohexyl methane 10%
Polyetheramine D-230 70%
Resins, epoxy E51 10%
Phenylcarbinol 10%.
The making method of embodiment 2 may further comprise the steps:
Figure 47323DEST_PATH_IMAGE001
The preparation of A component: Resins, epoxy E51 is dropped in the reactor, add phenylcarbinol, ultraviolet absorbers and silicone antifoam agent again, stir about 60 minutes is uniformly dispersed it, vacuumizes 10 minutes, filters packing;
Figure 317898DEST_PATH_IMAGE002
The preparation of B component: with 4,4 '-diamino-dicyclohexyl methane drops in the reactor, drop into polyetheramine D-230 again, stir after (about 10 minutes), slowly drip the mixed solution of being formed by Resins, epoxy E51 and phenylcarbinol, after dripping in 30 minutes, mix and stir after 2 hours, vacuumize after-filtration packing in 15 minutes;
3. get 2 parts of A components, the interpolation weight percent is that white essence, the weight percent of A component 1.0% are the transparent aluminium hydroxide powder of A component 60% in the A component, adds 1 part of B component again, mixing and stirring, vacuumize the back casting, the demoulding obtains high-grade imitative jade material.
The top grade that above-mentioned component and method make is imitated jade material, and product appearance is bright oyster white, and is soft and graceful naturally.
Embodiment 3:The imitative jade material of a kind of top grade of the present invention comprises 2 parts of A components, 1 part of B component, green essence and transparent aluminium hydrate powder, and described green smart weight percent is 0.2 % of A component, and the weight percent of transparent aluminium hydrate powder is 30% of A component, wherein,
Each composition and weight percent thereof are in the A component:
Resins, epoxy E51 88%
Phenylcarbinol 11%
Ultraviolet absorbers 0.5%
Silicone antifoam agent 0.5%
Each composition and weight percent thereof are in the B component:
4,4 '-diamino-dicyclohexyl methane 12%
Polyetheramine D-230 68%
Resins, epoxy E51 10%
Phenylcarbinol 10%.
The making method of embodiment 3 may further comprise the steps:
The preparation of A component: Resins, epoxy E51 is dropped in the reactor, add phenylcarbinol, ultraviolet absorbers and silicone antifoam agent again, stir about 60 minutes is uniformly dispersed it, vacuumizes 10 minutes, filters packing;
Figure 331564DEST_PATH_IMAGE002
The preparation of B component: with 4,4 '-diamino-dicyclohexyl methane drops in the reactor, drop into polyetheramine D-230 again, stir after (about 10 minutes), slowly drip the mixed solution of being formed by Resins, epoxy E51 and phenylcarbinol, after dripping in 30 minutes, mix and stir after 2 hours, vacuumize after-filtration packing in 15 minutes;
3. get 2 parts of A components, the interpolation weight percent is that green smart, the weight percent of A component 0.2% are the transparent aluminium hydroxide powder of A component 30% in the A component, adds 1 part of B component again, mixing and stirring, vacuumize the back casting, the demoulding obtains high-grade imitative jade material.
The top grade that above-mentioned component and method make is imitated jade material, and being of product appearance is emerald green, translucent, and is similar to natural green jewel outward appearance.

Claims (3)

1. a top grade is imitated jade material, and it comprises A component, B component, look essence and aluminium hydrate powder, and the weight percent of described look essence is 0.1 %~1.0 % of A component, and the weight percent of aluminium hydrate powder is 30%~80% of A component, wherein,
Each composition and weight percent thereof are in the A component:
Resins, epoxy E51 86 %~91%
Phenylcarbinol 8 %~13%
Ultraviolet absorbers 0.5%~1.0%
Silicone antifoam agent 0.5 %~0.8%
Each composition and weight percent thereof are in the B component:
4,4 '-diamino-dicyclohexyl methane 10%~20%
Polyetheramine D-230 60%~70%
Resins, epoxy E51 8%~12 %
Phenylcarbinol 8%~12 %.
2. top grade as claimed in claim 1 is imitated jade material, it comprises 2 parts of A components, 1 part of B component, green essence and transparent aluminium hydrate powder, and described green smart weight percent is 0.2% of A component, and the weight percent of transparent aluminium hydrate powder is 60% of A component, wherein
Each composition and weight percent thereof are in the A component:
Resins, epoxy E51 90%
Phenylcarbinol 9%
Ultraviolet absorbers 0.5%
Silicone antifoam agent 0.5%
Each composition and weight percent thereof are in the B component:
4,4 '-diamino-dicyclohexyl methane 15%
Polyetheramine D-230 65%
Resins, epoxy E51 10%
Phenylcarbinol 10%.
3. method of making the imitative jade material of claim 1 or 2 described top grades may further comprise the steps:
Figure 2013102360083100001DEST_PATH_IMAGE001
The preparation of A component: Resins, epoxy E51 is dropped in the reactor, add phenylcarbinol, ultraviolet absorbers and silicone antifoam agent again, stir about 60 minutes is uniformly dispersed it, vacuumizes 10 minutes, filters packing;
The preparation of B component: with 4,4 '-diamino-dicyclohexyl methane drops in the reactor, drop into polyetheramine D-230 again, stir after (about 10 minutes), slowly drip the mixed solution of being formed by Resins, epoxy E51 and phenylcarbinol, after dripping in 30 minutes, mix and stir after 2 hours, vacuumize after-filtration packing in 15 minutes;
3. get the A component, add look essence, aluminium hydrate powder in the A component, add the B component again, mixing and stirring vacuumizes the back casting, and the demoulding obtains high-grade imitative jade material.
CN2013102360083A 2013-06-17 2013-06-17 High-grade imitation jade material and preparation method thereof Pending CN103304964A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104945845A (en) * 2015-05-10 2015-09-30 江苏兴盛化工有限公司 Double-component brominated epoxy resin artificial stone board, and granules and preparation method thereof
CN109401703A (en) * 2018-10-30 2019-03-01 湖南柯盛新材料有限公司 A kind of epoxy adhesive and its artificial stone and preparation method thereof prepared

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101314704A (en) * 2007-05-31 2008-12-03 湖南神力实业有限公司 Two-component epoxy resin adhesive for stone skin patching and preparation thereof
CN101337805A (en) * 2008-08-25 2009-01-07 张璐 Artificial quartz in lump and fabrication technology thereof
CN101585958A (en) * 2009-06-25 2009-11-25 南方医科大学 Composition and method for preparing artificial gem
CN101798378A (en) * 2009-02-05 2010-08-11 魏庆梅 Transparent epoxy resin curing agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101314704A (en) * 2007-05-31 2008-12-03 湖南神力实业有限公司 Two-component epoxy resin adhesive for stone skin patching and preparation thereof
CN101337805A (en) * 2008-08-25 2009-01-07 张璐 Artificial quartz in lump and fabrication technology thereof
CN101798378A (en) * 2009-02-05 2010-08-11 魏庆梅 Transparent epoxy resin curing agent
CN101585958A (en) * 2009-06-25 2009-11-25 南方医科大学 Composition and method for preparing artificial gem

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104945845A (en) * 2015-05-10 2015-09-30 江苏兴盛化工有限公司 Double-component brominated epoxy resin artificial stone board, and granules and preparation method thereof
CN104945845B (en) * 2015-05-10 2018-01-09 江苏兴盛化工有限公司 Two-component brominated epoxy resin artificial slabstone and its particle and preparation method
CN109401703A (en) * 2018-10-30 2019-03-01 湖南柯盛新材料有限公司 A kind of epoxy adhesive and its artificial stone and preparation method thereof prepared
CN109401703B (en) * 2018-10-30 2021-05-04 湖南柯盛新材料有限公司 Epoxy adhesive, artificial stone prepared from epoxy adhesive and preparation method of artificial stone

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Application publication date: 20130918