CN101314704A - Two-component epoxy resin adhesive for stone skin patching and preparation thereof - Google Patents
Two-component epoxy resin adhesive for stone skin patching and preparation thereof Download PDFInfo
- Publication number
- CN101314704A CN101314704A CNA2007100350306A CN200710035030A CN101314704A CN 101314704 A CN101314704 A CN 101314704A CN A2007100350306 A CNA2007100350306 A CN A2007100350306A CN 200710035030 A CN200710035030 A CN 200710035030A CN 101314704 A CN101314704 A CN 101314704A
- Authority
- CN
- China
- Prior art keywords
- component
- epoxy resin
- preparation
- resin adhesive
- solidifying agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004575 stone Substances 0.000 title claims abstract description 19
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 12
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000853 adhesive Substances 0.000 title claims abstract description 11
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000006096 absorbing agent Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000004593 Epoxy Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- 239000004841 bisphenol A epoxy resin Substances 0.000 claims description 7
- -1 polyethylene Polymers 0.000 claims description 5
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 3
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 claims description 3
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical group NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 3
- 229960004217 benzyl alcohol Drugs 0.000 claims description 3
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 3
- 229960001124 trientine Drugs 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 229920000768 polyamine Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 2
- 238000012986 modification Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 125000003944 tolyl group Chemical group 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 5
- 238000004383 yellowing Methods 0.000 abstract description 3
- 239000003085 diluting agent Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 238000005498 polishing Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 3
- 239000004579 marble Substances 0.000 description 3
- 208000013201 Stress fracture Diseases 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 229920006305 unsaturated polyester Polymers 0.000 description 2
- JCYHHICXJAGYEL-UHFFFAOYSA-N 3-butoxypropane-1,2-diol Chemical compound CCCCOCC(O)CO JCYHHICXJAGYEL-UHFFFAOYSA-N 0.000 description 1
- SYWDWCWQXBUCOP-UHFFFAOYSA-N benzene;ethene Chemical compound C=C.C1=CC=CC=C1 SYWDWCWQXBUCOP-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical class OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Abstract
The invention relates to a double-component epoxy resin adhesive for repairing stone surface and the preparation method thereof. The double epoxy resin adhesive is composed of a component A consisting of epoxy resin and diluting agent, and a component B consisting of curing agent, optical stabilizer and UV absorber. The double-component epoxy resin adhesive is used for repairing microcrack on stone surface and ant road, and has the advantages of moderate curing speed, good yellowing-resistant performance, good permeability, high glossiness after cured and polished, easily-obtained environment-friendly material, simple process, etc.
Description
Technical field
The present invention relates to a kind of two-component epoxy resin adhesive that is used for the stone material repairing and preparation method thereof, particularly relate to two-component epoxy resin adhesive of stone surface microfracture, the repairing of ant road and preparation method thereof.
Background technology
At present, the unsaturated polyester tackiness agent is mainly used in the repairing on stone surface microfracture, ant road, and it is fast that this tackiness agent has curing speed, and the brushing performance is good, and characteristics such as low price are occupied suitable share on market; But its weak point is to solidify polishing back low in glossiness, and anti-yellowing property is poor, and cure shrinkage is big.Solvent benzol ethene toxicity is bigger, has limited its application.
Summary of the invention
For solving the deficiency of above-mentioned tackiness agent use properties, the invention provides a kind of two-component epoxy resin adhesive that is used for stone skin patching and preparation method thereof, a kind of two-component epoxy resin adhesive that is applicable to stone surface tiny crack, the repairing of ant road and preparation method thereof particularly is provided.
The objective of the invention is to be achieved through the following technical solutions:
A component of the present invention is formed by bisphenol-A epoxy resin and E～51 Resins, epoxy and mixing diluents, and the B component is formulated by solidifying agent, photostabilizer, UV light absorber.
A component raw material and weight percent are:
Resins, epoxy (E～51) 60～70%
Bisphenol-A epoxy resin 20～30%
Thinner 10～15%
The weight percentage sum of various raw materials is 100%
The preparation method is as follows for the A component:
Hydrogenated Bisphenol A type epoxidation resin is added in E～51 Resins, epoxy, stirred 20～30 minutes, thorough mixing is even, adds thinner again, stirs 10～60 minutes, and blowing gets the A component.
B component raw material and weight percent are:
Solidifying agent 95～98%
Photostabilizer 1～3%
UV light absorber 1～2%
The weight percentage sum of various raw materials is 100%.
The preparation method is as follows for the B component:
Photostabilizer, UV light absorber are added in the solidifying agent, stirred 2～3 hours under 60～70 ℃ of conditions, treat that photostabilizer, UV light absorber dissolve fully, discharging gets the B component.
Can use after A, B two components mixed by weight 5～7: 1～2.
The solidifying agent that the present invention uses is diethylenetriamine, triethylene tetramine, tetraethylene pentamine, polyethylene polyamine, isophorone diamine, alicyclic amine solidifying agent or their mixture.
The thinner that the present invention uses is raw spirit, butylglycidyl ether, phenylcarbinol, 1.4 butyleneglycols or their mixture.
The ultraviolet absorbers that the present invention uses is UV-531, UV-327, UV-9.
The photostabilizer that the present invention uses is GW-540, GW-944.
Positively effect of the present invention is applied to stone surface after being product A of the present invention, B two components are mixed, and obtains surface gloss height, anti-yellowing property is good, cure shrinkage is low excellent results.
Embodiment
[embodiment 1] adds stirring with the 20g hydrogenated bisphenol A epoxy resin, 70gE-51 Resins, epoxy,, mix, add the 10g butylglycidyl ether again, stirred 30 minutes, obtain the A component.1g stablizer (GW-944), 1g UV light absorber (UV-531) are added in the 98g diethylenetriamine, under 60～70 ℃ of conditions, stir and be cooled to normal temperature in 2-3 hour, obtain the B component.
With A component and the impregnation in 7: 1 by weight of B component, mix, be coated onto marble surface, 25 ℃ of conditions were solidified in following 3 hours, and the glossiness that records stone material after the polishing is 96, ultraviolet lamp irradiation not flavescence in 4 hours down.
[embodiment 2] join the 25g bisphenol-A epoxy resin in the 65gE-51 Resins, epoxy, stir, and mix, and add the 10g phenylcarbinol again, stir 30 minutes, obtain the A component.1g photostabilizer (GW-540), 1g UV light absorber (UV-327) are added in the 98g triethylene tetramine and stirred 2～3 hours under 60～70 ℃ of conditions, be cooled to normal temperature, obtain the B component.
With A component and the impregnation in 7: 1 by weight of B component, mix, be coated onto marble surface, 25 ℃ of conditions were solidified in following 3 hours, and the glossiness that records stone material after the polishing is 95, ultraviolet lamp irradiation not flavescence in 4 hours down.
[reference examples] joins the 30g bisphenol-A epoxy resin in the 60gE-51 Resins, epoxy and stirs, and mixes, and adds the 10g butyl glyceryl ether that contracts again, stirs 30 minutes, obtains the A component.1g photostabilizer (GW-944), 1g UV light absorber (UV-531) be added to fully to stir under 60～70 ℃ of conditions in the 98g isophorone diamine be cooled to normal temperature in 2～3 hours, obtain the B component.
Get market and purchased certified products unsaturated polyester stone glue sample, impregnation to scale is applied to marble surface, and 25 ℃ solidified 3 hours down, and the glossiness that records stone material after the polishing is 92, and ultraviolet lamp is irradiation obvious flavescence in 4 hours down.
Claims (5)
1, a kind of two-component epoxy resin adhesive that is used for stone skin patching, the A component of being made up of Resins, epoxy, thinner and be made up of the B component that solidifying agent, photostabilizer, UV light absorber are formed is characterized in that:
The A component is 20～30% bisphenol-A epoxy resin by weight percent, 60～70% E～51 Resins, epoxy, and 10～15% thinner is formed,
The B component is 96～98% solidifying agent by weight percent, 1～2% photostabilizer, and 1～2% UV light absorber is formed, and two components weight percentage sum separately are 100.
2, the two-component epoxy resin adhesive that is used for stone skin patching according to claim 1 is characterized in that thinner is toluene, raw spirit, butylglycidyl ether, phenylcarbinol, 1.4-butyleneglycol or their mixture.
3, the epoxyn that is used for stone skin patching according to claim 1 is characterized in that solidifying agent is diethylenetriamine, triethylene tetramine, tetraethylene pentamine, polyethylene polyamine, isophorone diamine, modification aliphatic cyclic amine solidifying agent or their mixture.
4, the epoxyn that is used for stone skin patching according to claim 1 is characterized in that UV light absorber is UV～531, UV～327, UV～9.
5, a kind of preparation method who is used for the epoxyn of stone skin patching as claimed in claim 1 is characterized in that being made up of the following step:
(1) preparation of A component: bisphenol-A epoxy resin is added in E～51 Resins, epoxy, and stirring at normal temperature 20～30 minutes adds thinner again, stirs 10～60 minutes;
(2) preparation of B component: photostabilizer, UV light absorber are added in the solidifying agent, under 60～70 ℃ of conditions, stirred 2～3 hours.
A, B two components are mixed and can use by weight 5～7: 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100350306A CN101314704B (en) | 2007-05-31 | 2007-05-31 | Two-component epoxy resin adhesive for stone skin patching and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100350306A CN101314704B (en) | 2007-05-31 | 2007-05-31 | Two-component epoxy resin adhesive for stone skin patching and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101314704A true CN101314704A (en) | 2008-12-03 |
| CN101314704B CN101314704B (en) | 2011-09-21 |
Family
ID=40105854
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100350306A Active CN101314704B (en) | 2007-05-31 | 2007-05-31 | Two-component epoxy resin adhesive for stone skin patching and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101314704B (en) |
Cited By (22)
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|---|---|---|---|---|
| CN102320861A (en) * | 2011-06-10 | 2012-01-18 | 刘建平 | The working method of glued healing crack stone material |
| CN103289625A (en) * | 2013-06-17 | 2013-09-11 | 成都精湛科技有限公司 | Low-temperature-resistant stone drying hanging adhesive and preparation method thereof |
| CN103304964A (en) * | 2013-06-17 | 2013-09-18 | 漳州丽都化工有限公司 | High-grade imitation jade material and preparation method thereof |
| CN103964747A (en) * | 2014-04-10 | 2014-08-06 | 广东省建筑科学研究院 | Weather-proof and quick-drying pavement damage repairing material and preparation method thereof |
| CN104151530A (en) * | 2014-08-19 | 2014-11-19 | 湖南神力铃胶粘剂制造有限公司 | Yellowing-resistance epoxy curing agent and preparation method thereof |
| CN104479108A (en) * | 2014-11-27 | 2015-04-01 | 东莞暨南大学研究院 | Epoxy resin curing agent applied to marble stones and preparation method thereof |
| CN104592922A (en) * | 2014-12-31 | 2015-05-06 | 湖北绿色家园精细化工有限责任公司 | Transparent, high-hardness and yellowing-resistant epoxy ornament glue and preparation process thereof |
| CN105331314A (en) * | 2015-11-17 | 2016-02-17 | 万华化学集团股份有限公司 | Weather-resistant epoxy glue as well as preparation method and applications thereof |
| CN105542696A (en) * | 2016-02-29 | 2016-05-04 | 上海缠枝莲文化科技股份有限公司 | Preparation method of yellowing-resistant double-component ceramic repairing agent |
| CN105802451A (en) * | 2016-06-02 | 2016-07-27 | 湖南柯盛新材料有限公司 | Two-component epoxy decorating sealant and preparation method thereof |
| CN106800900A (en) * | 2015-11-26 | 2017-06-06 | 卡本复合材料（天津）有限公司 | A kind of normal temperature cured type high-temperature-resistant high builds epoxy adhesive preparation method |
| CN106867294A (en) * | 2017-02-27 | 2017-06-20 | 苏州科斯曼照明工程有限公司 | A kind of method for pasting decoration goldleaf in the loose stone surface of low-density |
| CN107353857A (en) * | 2017-06-20 | 2017-11-17 | 广州市白云化工实业有限公司 | Epoxy joint trimming agent composition and preparation method thereof |
| CN107629746A (en) * | 2017-08-17 | 2018-01-26 | 湖北绿色家园材料技术股份有限公司 | A kind of transparent, Thief zone, high intensity microcrack repair sheets and its construction technology |
| CN107916084A (en) * | 2016-10-11 | 2018-04-17 | 湖南神力铃胶粘剂制造有限公司 | A kind of stone material repairing epoxy adhesive and preparation method thereof |
| CN108084935A (en) * | 2017-12-30 | 2018-05-29 | 高俊 | A kind of stone material glue |
| CN109017109A (en) * | 2018-07-27 | 2018-12-18 | 苏州金螳螂文化发展股份有限公司 | A kind of water knife parquets board manufacturing method and water knife parquets pavement construction method |
| CN109439210A (en) * | 2018-10-25 | 2019-03-08 | 湖南神力铃胶粘剂制造有限公司 | Economical marble repairing two-component epoxy face glue and preparation method thereof |
| CN110107112A (en) * | 2019-05-21 | 2019-08-09 | 五冶集团上海有限公司 | A kind of healant and method for repairing and mending of distress in concrete |
| CN111253895A (en) * | 2020-03-04 | 2020-06-09 | 郑州石宝宝科技有限公司 | Marble pointing adhesive for stone repair and preparation method thereof |
| CN111875292A (en) * | 2020-07-29 | 2020-11-03 | 雅安正兴汉白玉股份有限公司 | Calcium carbonate powder coagulant for preparing artificial stone |
| CN113447329A (en) * | 2021-06-29 | 2021-09-28 | 特鲁利(苏州)材料科技有限公司 | Edge-protecting cold-inlaid material and preparation process thereof |
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| CN1850931A (en) * | 2006-03-16 | 2006-10-25 | 湖南神力实业有限公司 | Stone thin sheet composite rubber, and its preparing method |
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- 2007-05-31 CN CN2007100350306A patent/CN101314704B/en active Active
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| CN102320861B (en) * | 2011-06-10 | 2013-01-02 | 刘建平 | Method for producing cementation healing fussure stone |
| CN102320861A (en) * | 2011-06-10 | 2012-01-18 | 刘建平 | The working method of glued healing crack stone material |
| CN103289625B (en) * | 2013-06-17 | 2014-10-01 | 成都精湛科技有限公司 | Low-temperature-resistant stone drying hanging adhesive and preparation method thereof |
| CN103289625A (en) * | 2013-06-17 | 2013-09-11 | 成都精湛科技有限公司 | Low-temperature-resistant stone drying hanging adhesive and preparation method thereof |
| CN103304964A (en) * | 2013-06-17 | 2013-09-18 | 漳州丽都化工有限公司 | High-grade imitation jade material and preparation method thereof |
| CN103964747B (en) * | 2014-04-10 | 2016-01-20 | 广东省建筑科学研究院集团股份有限公司 | A kind of weather-proof quick-drying road surface breakage patching material and preparation method thereof |
| CN103964747A (en) * | 2014-04-10 | 2014-08-06 | 广东省建筑科学研究院 | Weather-proof and quick-drying pavement damage repairing material and preparation method thereof |
| CN104151530A (en) * | 2014-08-19 | 2014-11-19 | 湖南神力铃胶粘剂制造有限公司 | Yellowing-resistance epoxy curing agent and preparation method thereof |
| CN104479108A (en) * | 2014-11-27 | 2015-04-01 | 东莞暨南大学研究院 | Epoxy resin curing agent applied to marble stones and preparation method thereof |
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| CN107629746B (en) * | 2017-08-17 | 2021-11-05 | 湖北绿色家园材料技术股份有限公司 | Transparent, high-permeability and high-strength microcrack repairing adhesive and construction process thereof |
| CN108084935A (en) * | 2017-12-30 | 2018-05-29 | 高俊 | A kind of stone material glue |
| CN109017109A (en) * | 2018-07-27 | 2018-12-18 | 苏州金螳螂文化发展股份有限公司 | A kind of water knife parquets board manufacturing method and water knife parquets pavement construction method |
| CN109439210A (en) * | 2018-10-25 | 2019-03-08 | 湖南神力铃胶粘剂制造有限公司 | Economical marble repairing two-component epoxy face glue and preparation method thereof |
| CN110107112A (en) * | 2019-05-21 | 2019-08-09 | 五冶集团上海有限公司 | A kind of healant and method for repairing and mending of distress in concrete |
| CN111253895A (en) * | 2020-03-04 | 2020-06-09 | 郑州石宝宝科技有限公司 | Marble pointing adhesive for stone repair and preparation method thereof |
| CN111875292A (en) * | 2020-07-29 | 2020-11-03 | 雅安正兴汉白玉股份有限公司 | Calcium carbonate powder coagulant for preparing artificial stone |
| CN113447329A (en) * | 2021-06-29 | 2021-09-28 | 特鲁利(苏州)材料科技有限公司 | Edge-protecting cold-inlaid material and preparation process thereof |
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| Publication number | Publication date |
|---|---|
| CN101314704B (en) | 2011-09-21 |
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Address after: 410300 Hunan Liuyang Development Zone Hunan Shenli Industry Co., Ltd. Patentee after: Human Shenli Adhesive Group Co., Ltd. Address before: 410300 Hunan Liuyang Development Zone Hunan Shenli Industry Co., Ltd. Patentee before: Hunan Shenli Industrial Co., Ltd. |
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Denomination of invention: Two-component epoxy resin adhesive for stone skin patching and preparation thereof Effective date of registration: 20170505 Granted publication date: 20110921 Pledgee: Bank of Changsha Limited by Share Ltd Liuyang branch Pledgor: Human Shenli Adhesive Group Co., Ltd. Registration number: 2017430000027 |
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Denomination of invention: The invention relates to a two-component epoxy resin adhesive for stone surface repair and a preparation method thereof Effective date of registration: 20220303 Granted publication date: 20110921 Pledgee: Liuyang Rural Commercial Bank Co.,Ltd. of Hunan Province through its branch Pledgor: Human Shenli Adhesive Group Co.,Ltd. Registration number: Y2022980002115 |
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