CN103304924A - PVC (Polyvinyl Chloride) sole material with thermal stability - Google Patents
PVC (Polyvinyl Chloride) sole material with thermal stability Download PDFInfo
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- CN103304924A CN103304924A CN2013102497508A CN201310249750A CN103304924A CN 103304924 A CN103304924 A CN 103304924A CN 2013102497508 A CN2013102497508 A CN 2013102497508A CN 201310249750 A CN201310249750 A CN 201310249750A CN 103304924 A CN103304924 A CN 103304924A
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- pvc
- sole
- shoe
- pvc material
- thermostability
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- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a PVC (Polyvinyl Chloride) sole material with thermal stability. The PVC sole material comprises the following ingredients in percentage by weight: 60-65% of PVC, 25-30% of DBP (dibutyl phthalate), 0.1-0.2% of RH-208, 6-7% of CaCO3, and 2.8-3.9% of Ca-Zn thermal stabilizer. The Ca-Zn thermal stabilizer adding in the PVC sole material has good synergic stability effect, the long-time stability and ultraviolet aging resistance can be obviously improved.
Description
Technical field:
The present invention relates to footwear material technical field, relate in particular to a kind of PVC material for sole of shoe.
Background technology:
PVC is one of five large synthetic resins of in the world consumption maximum, is the linear polymkeric substance of thermoplasticity that is generated through Raolical polymerizable by vinyl chloride monomer.The PVC material has that intensity is high, cheap, chemical resistance is good, and electrical insulating property is good and be difficult to the advantages such as burning, is widely used in engineering construction, food product pack, electric and shoe industry.
When PVC is used for making sole, owing to containing branch point in the PVC polymer chain structure, the existence of the labile factors such as two keys and initiator residue, so that PVC molecule chlorosity is on the face easily deviate from from molecular chain, the characteristics that namely have poor heat stability, generally speaking, the PVC material for sole of shoe can decomposition discharge hydrogenchloride more than 100 ℃, prolongation along with the time, HCl deviates from a large number and is accumulated in the material, because HCl has katalysis to PVC degraded, thus the PVC degradation speed greatly accelerate, deviate from behind the HCl that a large amount of formation has the conjugated double bond of generation in the molecular chain, thereby the color of PVC material for sole of shoe is sharply deepened, and physical and mechanical properties descends.Therefore, when the machine-shaping of PVC sole, must use thermo-stabilizer.
The thermo-stabilizer that the PVC material is commonly used has lead salts thermo-stabilizer, organic tin thermo-stabilizer, antimony type thermal stabilizing agent, rare earth class thermo-stabilizer, calcium zinc heat stabilizer etc.Wherein lead salts thermo-stabilizer toxicity is large, has biological accumulation, has generated dust, and also can cause serious pollution to environment after discarded; The organic tin thermo-stabilizer has good thermostability and processibility, but manufacturing cost is high, can distribute certain peculiar smell in the course of processing, and part is poisonous; Antimony type thermal stabilizing agent is subjected to the uviolizing meeting that brown-black metachromasia occurs, and causes the anti-ultraviolet property of goods poor; Rare earth thermal stabilizer is because rare earth needs higher activation energy ability complexing chlorion, so that complex reaction speed is slow; For calcium zinc stabilizer, it is nontoxic, the environment protection thermal stablizer of generally acknowledging both at home and abroad at present, and in the PVC sole course of processing, the HCl reaction that the zn cpds in the calcium zinc heat stabilizer discharges after degrading with PVC generates ZnCl
2, be the catalyzer of PVC material for sole of shoe degraded, and calcium cpd can absorb HCl gas, also the unstable chlorine on the replaceable molecular chain plays the main stabilizer effect.
Summary of the invention:
The purpose of this invention is to provide a kind of thermostability PVC material for sole of shoe that has, the PVC sole that is made by this material has good thermostability and anti-ultraviolet ageing.
Purpose of the present invention is achieved through the following technical solutions:
A kind of high-wearing feature PVC material for sole of shoe comprises following component by weight percentage:
Preferred as technique scheme, described PVC content is 63-65%.
Preferred as technique scheme, described DBP is dibutyl phthalate, by the compound that carbon, hydrogen, oxygen element form, its chemical formula is C
16H
22O
4
Preferred as technique scheme, described RH-208 is that effect agent, a kind of trisiloxanes of modification are oozed in the organosilicon exhibition.
Preferred as technique scheme, described Ca-Zn thermo-stabilizer is less fatty calcium salt and the zinc salt of carbon number that is soluble in organic solvent, and main component has calcium stearate, ricinolic acid calcium, Zinic stearas, zinc ricinate and epoxy soybean oil, UV light absorber.
Beneficial effect of the present invention is: the Ca-Zn thermo-stabilizer of its adding has good collaborative stabilization, can significantly improve long-term thermal stability and anti-ultraviolet ageing.
Embodiment:
In order to deepen the understanding of the present invention, the invention will be further described below in conjunction with embodiment, and this embodiment only is used for explaining the present invention, does not consist of the restriction to protection domain of the present invention.
Embodiment 1:
Take by weighing PVC material 60g, DBP 30g, RH-208 0.2g, CaCO
37g, Ca-Zn thermo-stabilizer 2.8g, on the miniature high-speed agitator that mixing of materials is even, be 150-160 ℃ in the roller temperature, the 5-10min that plasticates on the open type dual-roller machine of roll spacing 1-2mm, plasticizing is descended fully afterwards sheet and be get final product.
Embodiment 2:
Take by weighing PVC material 65g, DBP 25g, RH-208 0.1g, CaCO
36g, Ca-Zn thermo-stabilizer 3.9g, on the miniature high-speed agitator that mixing of materials is even, be 150-160 ℃ in the roller temperature, the 5-10min that plasticates on the open type dual-roller machine of roll spacing 1-2mm is after the plasticizing fully and get final product.
Claims (5)
1. PVC material for sole of shoe with thermostability is characterized in that: comprise by weight percentage following component:
2. a kind of PVC material for sole of shoe with thermostability according to claim 1, it is characterized in that: described PVC content is 63-65%.
3. a kind of PVC material for sole of shoe with thermostability according to claim 1, it is characterized in that: described DBP is dibutyl phthalate, by the compound that carbon, hydrogen, oxygen element form, its chemical formula is C
16H
22O
4
4. a kind of PVC material for sole of shoe with thermostability according to claim 1 is characterized in that: described RH-208 is that effect agent, a kind of trisiloxanes of modification are oozed in the organosilicon exhibition.
5. a kind of PVC material for sole of shoe with thermostability according to claim 1, it is characterized in that: described Ca-Zn thermo-stabilizer is less fatty calcium salt and the zinc salt of carbon number that is soluble in organic solvent, and main component has calcium stearate, ricinolic acid calcium, Zinic stearas, zinc ricinate and epoxy soybean oil, UV light absorber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102497508A CN103304924A (en) | 2013-06-21 | 2013-06-21 | PVC (Polyvinyl Chloride) sole material with thermal stability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102497508A CN103304924A (en) | 2013-06-21 | 2013-06-21 | PVC (Polyvinyl Chloride) sole material with thermal stability |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103304924A true CN103304924A (en) | 2013-09-18 |
Family
ID=49130667
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102497508A Pending CN103304924A (en) | 2013-06-21 | 2013-06-21 | PVC (Polyvinyl Chloride) sole material with thermal stability |
Country Status (1)
| Country | Link |
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| CN (1) | CN103304924A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589087A (en) * | 2013-10-15 | 2014-02-19 | 苏州市景荣科技有限公司 | Antibacterial odor-resistant PVC (Polyvinyl Chloride) sole material |
| CN104262855A (en) * | 2014-10-22 | 2015-01-07 | 苏州市景荣科技有限公司 | Highly bending-resistant PVC (Polyvinyl Chloride) shoe material and manufacturing method thereof |
| CN114805927A (en) * | 2022-04-11 | 2022-07-29 | 安徽华文塑胶科技有限公司 | Liquid calcium-zinc composite stabilizer and processing method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2204052A (en) * | 1987-04-10 | 1988-11-02 | Croydon Sa | Odorized footwear |
| JP2004143235A (en) * | 2002-10-23 | 2004-05-20 | Achilles Corp | Vinyl chloride-based resin composition for injection-molded shoe |
| CN1733834A (en) * | 2005-08-23 | 2006-02-15 | 邓立富 | Shoes material formula |
| CN101270215A (en) * | 2008-05-05 | 2008-09-24 | 特变电工(德阳)电缆股份有限公司 | Fragrant environment protection polyvinyl chloride granules |
| CN101438869A (en) * | 2008-11-14 | 2009-05-27 | 苏州新纶超净技术有限公司 | Shoes with antibiotic antistatic/conductive function and method for producing the same |
| CN101538392A (en) * | 2009-04-07 | 2009-09-23 | 苏州新纶超净技术有限公司 | Conductive polyvinyl chloride shoe material and manufacturing method thereof |
-
2013
- 2013-06-21 CN CN2013102497508A patent/CN103304924A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2204052A (en) * | 1987-04-10 | 1988-11-02 | Croydon Sa | Odorized footwear |
| JP2004143235A (en) * | 2002-10-23 | 2004-05-20 | Achilles Corp | Vinyl chloride-based resin composition for injection-molded shoe |
| CN1733834A (en) * | 2005-08-23 | 2006-02-15 | 邓立富 | Shoes material formula |
| CN101270215A (en) * | 2008-05-05 | 2008-09-24 | 特变电工(德阳)电缆股份有限公司 | Fragrant environment protection polyvinyl chloride granules |
| CN101438869A (en) * | 2008-11-14 | 2009-05-27 | 苏州新纶超净技术有限公司 | Shoes with antibiotic antistatic/conductive function and method for producing the same |
| CN101538392A (en) * | 2009-04-07 | 2009-09-23 | 苏州新纶超净技术有限公司 | Conductive polyvinyl chloride shoe material and manufacturing method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 林美娟等: "Ca-Zn复合热稳定剂在PVC中的应用", 《现代塑料加工应用》, vol. 17, no. 1, 31 December 2005 (2005-12-31), pages 51 - 54 * |
| 林美娟等: "高校钙锌复合热稳定剂的研究", 《中国塑料》, vol. 19, no. 2, 28 February 2005 (2005-02-28), pages 70 - 73 * |
| 肖卫东等: "《聚合物材料用化学助剂》", 31 August 2003, 化学工业出版社, article "助剂" * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589087A (en) * | 2013-10-15 | 2014-02-19 | 苏州市景荣科技有限公司 | Antibacterial odor-resistant PVC (Polyvinyl Chloride) sole material |
| CN104262855A (en) * | 2014-10-22 | 2015-01-07 | 苏州市景荣科技有限公司 | Highly bending-resistant PVC (Polyvinyl Chloride) shoe material and manufacturing method thereof |
| CN114805927A (en) * | 2022-04-11 | 2022-07-29 | 安徽华文塑胶科技有限公司 | Liquid calcium-zinc composite stabilizer and processing method thereof |
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Application publication date: 20130918 |