CN103301806A - Antibacterial deodorant for shoes - Google Patents
Antibacterial deodorant for shoes Download PDFInfo
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- CN103301806A CN103301806A CN 201310181469 CN201310181469A CN103301806A CN 103301806 A CN103301806 A CN 103301806A CN 201310181469 CN201310181469 CN 201310181469 CN 201310181469 A CN201310181469 A CN 201310181469A CN 103301806 A CN103301806 A CN 103301806A
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- antibacterial deodorant
- essential oil
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- footwear
- footwear antibacterial
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Abstract
The invention relates to a deodorant, and in particular relates to powder for disinfecting, deodorizing and flavoring a shoe body. The antibacterial deodorant for shoes comprises the following components in parts by weight: 15-35 parts of aluminum ammonium sulfate, 2-3 parts of benzoic acid, 15-25 parts of a nano composite antibacterial material, 10-25 parts of a flavor and 15-35 parts of a negative ion material. The antibacterial deodorant for shoes has functions of disinfecting, deodorizing, suppressing sweating, eliminating dampness and keeping soles dry, and can lastingly release fragrance to effectively reduce peculiar smells of the soles.
Description
Technical field
The present invention relates to adsorbent and preparation method thereof, particularly a kind of be used to taking off adsorbent of removing fluorine in water and preparation method thereof.
Background technology
In some areas of China, fluorine content is finished up to more than the 5.0mg/l in the drinking water, head and shoulders above the fluorine-containing index of defined in the national drinking water standard.Fluorine too high levels in the drinking water, its harmfulness is on record, for example, can make people's tooth blackening, produces deformity, also can make people's digestive system generation obstacle, also can make people Yi Zaocheng off one's dot etc.The method of removal of fluorine from water is a lot of at present, its pluses and minuses are respectively arranged: though 1. ion-exchange is commonly used, but because the anion exchange order is SO42-＞NO3-＞CrO42-＞Br-＞CN-＞Cl-＞F-, fluorine ion is in the position of unfavorable exchange, and selectively not high, equipment investment and operating cost are very large; 2. hyperfiltration power consumption is large, and expense is high; 3. aluminium salt precipitation method effect is better, but the consumption of aluminium salt is large, can not regenerate, and produce a large amount of precipitations; 4. electrocoagulation facility compact, effluent quality are good, but power consumption is large, and higher to water quality requirement; 5. the absorption method defluorination effect is good, and regeneration is easy, and sorbing material consumption is few, and chaff interference is few.Be used in the prior art mostly being bone carbon and activated alumina from the sorbing material of removing fluor in water, its shortcoming is that material price is high, and absorption property remains further to be improved.
Summary of the invention
The object of the present invention is to provide a kind of preparation method simple, easy to use, cheap, the fluorine that absorption property is good removes adsorbent and preparation method thereof.Technical scheme is as follows:
A kind of adsorbent be used to taking off removing fluorine in water, the component meter is composed of the following components by weight: 12-16 part calcium, 10-15 part aluminium, 2-3 part sodium, 25-42 part bentonite, 15-25 part active carbon.
A kind of preparation method of the adsorbent be used to taking off removing fluorine in water may further comprise the steps:
With active carbon and bentonite grind into powder, adopt kneading method to prepare active carbon and bentonitic compound, compound is through 80-120 ℃ of dry 12-16h, under 300-400 ℃ of inert gas shielding roasting 4-6 hour;
Prepare respectively calcium chloride, aluminium chloride, sodium chloride solution; three kinds of solution are mixed; the formation mixed liquor stirs; adopt co-impregnation that calcium, aluminium, sodium are loaded on active carbon and the bentonitic compound; product behind the dipping after filtration; 80-100 ℃ of dry 10-12h under 350-400 ℃ of inert gas shielding roasting 3-4 hour, obtains be used to the adsorbent that takes off removing fluorine in water after grinding screening.
Described active carbon and bentonitic compound sintering temperature are 350 ℃.
Product sintering temperature behind the described dipping is 380 ℃.
Adsorbent of the present invention has good absorption property, and during fluorine in removing water, the removal efficiency of fluorine reaches 92.3%.
The specific embodiment
In order better to understand and to implement, describe the present invention in detail below in conjunction with embodiment.
Embodiment 1
With 15 parts of active carbons and 25 parts of bentonite grind into powders, adopt kneading method to prepare active carbon and bentonitic compound, compound is through 80 ℃ of dry 12h, and roasting is 4 hours under 300 ℃ of inert gas shieldings; Prepare respectively calcium chloride, aluminium chloride, sodium chloride solution; three kinds of solution are mixed in the ratio of 12:10:2; the formation mixed liquor stirs; adopt co-impregnation that calcium, aluminium, sodium are loaded on active carbon and the bentonitic compound; product behind the dipping after filtration; 80 ℃ of dry 10h, roasting is 3 hours under 350 ℃ of inert gas shieldings, obtains be used to the adsorbent that takes off removing fluorine in water after the grinding screening.During fluorine in removing water, the removal efficiency of fluorine reaches 91.8%.
Embodiment 2
With 18 parts of active carbons and 32 parts of bentonite grind into powders, adopt kneading method to prepare active carbon and bentonitic compound, compound is through 90 ℃ of dry 14h, and roasting is 4 hours under 320 ℃ of inert gas shieldings; Prepare respectively calcium chloride, aluminium chloride, sodium chloride solution; three kinds of solution are mixed in the ratio of 13:11:2; the formation mixed liquor stirs; adopt co-impregnation that calcium, aluminium, sodium are loaded on active carbon and the bentonitic compound; product behind the dipping after filtration; 90 ℃ of dry 10h, roasting is 3 hours under 360 ℃ of inert gas shieldings, obtains be used to the adsorbent that takes off removing fluorine in water after the grinding screening.During fluorine in removing water, the removal efficiency of fluorine reaches 92.1%.
Embodiment 3
With 22 parts of active carbons and 38 parts of bentonite grind into powders, adopt kneading method to prepare active carbon and bentonitic compound, compound is through 100 ℃ of dry 15h, and roasting is 5 hours under 350 ℃ of inert gas shieldings; Prepare respectively calcium chloride, aluminium chloride, sodium chloride solution; three kinds of solution are mixed in the ratio of 15:13:3; the formation mixed liquor stirs; adopt co-impregnation that calcium, aluminium, sodium are loaded on active carbon and the bentonitic compound; product behind the dipping after filtration; 90 ℃ of dry 10h, roasting is 4 hours under 380 ℃ of inert gas shieldings, obtains be used to the adsorbent that takes off removing fluorine in water after the grinding screening.During fluorine in removing water, the removal efficiency of fluorine reaches 92.3%.
Embodiment 4
With 25 parts of active carbons and 42 parts of bentonite grind into powders, adopt kneading method to prepare active carbon and bentonitic compound, compound is through 120 ℃ of dry 16h, and roasting is 6 hours under 400 ℃ of inert gas shieldings; Prepare respectively calcium chloride, aluminium chloride, sodium chloride solution; three kinds of solution are mixed in the ratio of 16:15:3; the formation mixed liquor stirs; adopt co-impregnation that calcium, aluminium, sodium are loaded on active carbon and the bentonitic compound; product behind the dipping after filtration; 100 ℃ of dry 12h, roasting is 4 hours under 400 ℃ of inert gas shieldings, obtains be used to the adsorbent that takes off removing fluorine in water after the grinding screening.During fluorine in removing water, the removal efficiency of fluorine reaches 91.3%.
The above only is preferred embodiment of the present invention, does not limit the present invention, and all employings are equal to replaces or technical scheme that the mode of equivalent transformation obtains, all drops in protection scope of the present invention.
Claims (9)
1. a footwear antibacterial deodorant is characterized in that, comprises following component in parts by weight: alum 15-35 part, benzoic acid 2-3 part, nano composite antibiotic material 15-25 part, spices 10-25 part, anion material 15-35 part.
2. a kind of footwear antibacterial deodorant as claimed in claim 1 is characterized in that, described nano composite antibiotic material is with silicon-base oxide-SiO
2-XBe carrier, contain the composite of silver ion or zinc ion, wherein, the quality percentage composition of described silver ion or zinc ion is 5-12%.
3. a kind of footwear antibacterial deodorant as claimed in claim 1 is characterized in that, described spices has the sepiolite powder of plants essential oil for absorption.
4. such as claim 1 or 3 described a kind of footwear antibacterial deodorants, it is characterized in that, described spices prepares by following steps: sepiolite is dried rear pulverize, add the citric acid solution of 5wt%, carry out granulation by comminutor, under 200-250 ℃, carry out roasting; The particle of roasting gained is put into closed container to be fumigated with peppermint oil, spearmint essential oil, Lavender or mother chrysanthemum essential oil and namely gets absorption the sepiolite powder of plants essential oil is arranged.
5. a kind of footwear antibacterial deodorant as claimed in claim 4 is characterized in that, the consumption of described peppermint oil, spearmint essential oil, Lavender or mother chrysanthemum essential oil is 0.5%-1.5%.
6. footwear antibacterial deodorant according to claim 1 is characterized in that, described anion material is counted by weight and comprised following component: the negative ion powder of 75-85 part, the coupling agent of 5-10 part, the dispersant of 5-15 part.
7. footwear antibacterial deodorant according to claim 6 is characterized in that, described negative ion powder is tourmaline.
8. footwear antibacterial deodorant according to claim 6 is characterized in that, described coupling agent is selected from silane coupler, titanate coupling agent, aluminate coupling agent.
9. footwear antibacterial deodorant according to claim 6, it is characterized in that, described dispersant is N, the stearic amide of N '-ethylene group bis-stearamides or dolomol, zinc stearate, calcium stearate stearate and two kinds or two or more mixtures.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201310181469 CN103301806A (en) | 2013-05-16 | 2013-05-16 | Antibacterial deodorant for shoes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201310181469 CN103301806A (en) | 2013-05-16 | 2013-05-16 | Antibacterial deodorant for shoes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103301806A true CN103301806A (en) | 2013-09-18 |
Family
ID=49127781
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201310181469 Pending CN103301806A (en) | 2013-05-16 | 2013-05-16 | Antibacterial deodorant for shoes |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103301806A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103800928A (en) * | 2014-03-06 | 2014-05-21 | 苏州爱德芬生物科技有限公司 | Antibiotic deodorant |
| CN114681650A (en) * | 2020-12-30 | 2022-07-01 | 象鼻山香(杭州)生物科技有限公司 | Composition with deodorization function and preparation method thereof |
-
2013
- 2013-05-16 CN CN 201310181469 patent/CN103301806A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103800928A (en) * | 2014-03-06 | 2014-05-21 | 苏州爱德芬生物科技有限公司 | Antibiotic deodorant |
| CN114681650A (en) * | 2020-12-30 | 2022-07-01 | 象鼻山香(杭州)生物科技有限公司 | Composition with deodorization function and preparation method thereof |
| CN114681650B (en) * | 2020-12-30 | 2024-05-07 | 象鼻山香(杭州)生物科技有限公司 | Composition with deodorizing function and preparation method thereof |
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| PB01 | Publication | ||
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130918 |