CN103300012A - Insecticidal composition containing flutenzine - Google Patents
Insecticidal composition containing flutenzine Download PDFInfo
- Publication number
- CN103300012A CN103300012A CN2012100641143A CN201210064114A CN103300012A CN 103300012 A CN103300012 A CN 103300012A CN 2012100641143 A CN2012100641143 A CN 2012100641143A CN 201210064114 A CN201210064114 A CN 201210064114A CN 103300012 A CN103300012 A CN 103300012A
- Authority
- CN
- China
- Prior art keywords
- mite
- piperazine
- fluorine
- spiral shell
- fenisobromolate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 230000002508 compound effect Effects 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- UOAMTSKGCBMZTC-UHFFFAOYSA-N dicofol Chemical compound C=1C=C(Cl)C=CC=1C(C(Cl)(Cl)Cl)(O)C1=CC=C(Cl)C=C1 UOAMTSKGCBMZTC-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000003197 gene knockdown Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 201000003872 goiter Diseases 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- WYMSBXTXOHUIGT-UHFFFAOYSA-N paraoxon Chemical compound CCOP(=O)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 WYMSBXTXOHUIGT-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/14—Ethers
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an insecticidal composition containing flutenzine. The composition is mainly characterized by consisting of an active component A and an active component B, wherein the active component A is flutenzine, and the active component B is any one of spirodiclofen, halfenprox and bromopropylate; and the weight ratio of the active component A to the active component B is (1:80)-(80:1). The composition can be prepared into wettable powder, a water dispersible granule, a suspending agent, a suspoemulsion, an emulsion in water, a micro emulsion, a micro-capsule suspending agent and a micro-capsule suspension-suspending agent. The composition can prevent various injurious insects on wheat, cotton, fruit trees, vegetables, tee trees and ornamental flowers, and takes a remarkable synergistic effect; the composition is low in pesticide consumption, safe to human beings and animals, free from drug injury and good in environmental compatibility; and preparation is strong in adhesion and is rain-washing resistant.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination that contains fluorine mite piperazine.
Background technology
Fluorine mite piperazine (diflovidazin), molecular formula: C
14H
7CLF
2N
4, fluorine mite piperazine contacts the ovum and active through skin that goes out, and attracts the mite adult to take food, and also prevents and treats the acarid in pupa stage.This compound effects mechanism is unique, not only ovum and one-tenth mite is had excellent activity, and makes female mite produce unsound ovum, causes destroying the evidence of mite, simultaneously pear sucker, oystershell scale, leafhopper etc. is also had good effect, and to natural enemy and Environmental security.
Spiral shell mite ester (spirodiclofen), chemical name: 3-(2,4-dichlorophenyl)-2-oxygen-1-oxygen spiral shell [4.5] last of the ten Heavenly stems-3-alkene-4-base-2,2-dimethyl butyrate acid esters, chemical molecular formula: C
21H
24Cl
2O
4Spiral shell mite ester has the brand-new mechanism of action, shows to suppress the synthetic of lipid.All effective to each developmental stage of mite by tagging, comprise ovum.
Halfenprox (halfenprox), chemical name: 2-(4-bromine difluoro-methoxy phenyl)-2-methyl-propyl-3-phenoxy benzyl ether, halfenprox is a kind of ethers miticide, belong to non-pyrethroid medicament, but its space structure and pyrethroid has similarity.This product is a kind of broad spectrum activity, if to young mite mite with become mite to knock down, can also suppress the hatching of ovum, all effective to evil mite resistant strain and sensitive strain, under the normal using dosage to fruit tree without poisoning.This medicament is resistance of rainwater washing against not.To the medium poison of people, animal.Be applicable to the control of multiple mite on apple, the citrus.
Fenisobromolate (bromopropylate), chemical molecular formula: C
17H
16Br
2O
3, chemical formula: 4,4 '-dibromo diphenylglycollic acid isopropyl ester, fenisobromolate be a kind ofly kill that the mite spectrum is wide, the lasting period is long, toxicity is low, to the safer miticide of natural enemy, honeybee and crop.Tagging property is stronger, without interior absorption, if to becoming mite and ovum that certain lethal effect is all arranged.Variations in temperature is little on the drug effect impact.This medicine is applicable to the crops such as cotton, fruit tree, vegetables and tea, can prevent and treat the multiple harmful mites such as tetranychid, goitre mite, line mite.The evil mite has cross resistance to this medicine and dicofol, will note during use.
In the real process of agricultural production, the problem that pest control, evil mite the most easily produce is drug-fast generation.The different cultivars composition carries out composite, is control resistant insect, the very common method of evil mite.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Find through inventor's lot of experiments, after fluorine mite piperazine and spiral shell mite ester, halfenprox, fenisobromolate were composite, synergistic effect was remarkable, and Environmental compatibility is fabulous, has greatly reduced the agricultural chemicals dosage.
Summary of the invention
The Pesticidal combination that the present invention proposes any one two kinds of active components, also comprises an amount of surfactant and carrier in comprising fluorine mite piperazine and spiral shell mite ester, halfenprox, fenisobromolate.
A kind of Pesticidal combination that contains fluorine mite piperazine, comprise active components A, active component B, it is characterized in that: active components A is fluorine mite piperazine, and active component B is a kind of arbitrarily in spiral shell mite ester, halfenprox, the fenisobromolate, and the weight ratio of active components A and active component B is 1: 80～80: 1.
Described Pesticidal combination is characterized in that: the weight ratio of active components A and active component B is 1: 60～40: 1.
Described Pesticidal combination is characterized in that: the weight ratio of fluorine mite piperazine and spiral shell mite ester is 1: 20～20: 1, is preferably 1: 10～10: 1.
Described Pesticidal combination is characterized in that: the weight ratio of fluorine mite piperazine and halfenprox is 1: 20～20: 1, is preferably 1: 10～10: 1.
Described Pesticidal combination is characterized in that: the weight ratio of fluorine mite piperazine and fenisobromolate is 1: 30～10: 1, is preferably 1: 10～1: 1.
Described Pesticidal combination is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
Described Pesticidal combination is used for the application of insect on control wheat, cotton, fruit tree, vegetables, tea tree, the ornamental flower.
Described pest control comprises: two spotted spider mite, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker, oystershell scale, leafhopper.
At least comprise a kind of surfactant in the Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.The selected surfactant of Pesticidal combination of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, emulsifier or the defoamer.
Comprise following constituent content when making wetting powder: active components A 1%～80%, active component B 1%～80%, dispersant 3%～15%, wetting agent 2%～10%, filler surplus.
When making water dispersible granules, composition comprises following constituent content: active components A 1%～80%, active component B 1%～80%, dispersant 3%～12%, wetting agent 1%～10%, disintegrant 1%～10%, binding agent 0%～8%, filler surplus.
Comprise following constituent content when composition is made suspending agent: active components A 1%～60%, active component B 1%～60%, dispersant 2%～10%, wetting agent 2%～10%, defoamer 0.01%～2%, thickener 0.05%～2%, antifreeze 0%～8%, deionized water add to 100%.
Comprise following constituent content when composition is made suspension emulsion: active components A 1%～60%, active component B 1%～60%, emulsifier 2%～12%, dispersant 2%～10%, defoamer 0.01%～2%, thickener 0.05%～2%, antifreeze 0%～8%, stabilizing agent 0%～5%, solvent 0%～15%, deionized water add to 100%.
Comprise following constituent content when composition is made aqueous emulsion: active components A 1%～60%, active component B 1%～60%, solvent 0%～30%, emulsifier 1%～15%, antifreeze 0%～10%, thickener 0.05%～2%, defoamer 0.01%～2%, deionized water are supplied surplus.
Comprise following constituent content when composition is made microemulsion: active components A 1%～60%, active component B 1%～60%, solvent 0%～30%, emulsifier 3%～20%, antifreeze 0%～10%, thickener 0%～2%, defoamer 0.01%～2%, stabilizing agent 0%～4%, deionized water is supplied surplus.
Composition is made micro-capsule suspension and is comprised following constituent content: active components A 1%～60%, active component B 1%～60%, macromolecule cyst material 1%～12%, surfactant 2%～10%, organic solvent 1%～15%, emulsifier 1%～8%, pH adjusting agent 0.1%～5%, deionized water adds to 100%.
Composition comprises following constituent content when making microcapsule suspension-suspending agent: active components A 1%～60%, active component B 1%～60%, macromolecule cyst material 2%～12%, surfactant 3%～15%, organic solvent 1%～5%, emulsifier 1%～6%, defoamer 0.1%～5%, thickener 0.05%～2%, pH adjusting agent 0.1%～5%, water add to 100%.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension of the present invention-suspending agent the key technical indexes:
The invention has the advantages that:
(1) fluorine mite piperazine and spiral shell mite ester, halfenprox, fenisobromolate composite after, have notable synergistic and lasting effect;
(2) enlarged the control spectrum, the two spotted spider mite on wheat, cotton, fruit tree, vegetables, tea tree, the ornamental flower, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker, oystershell scale, leafhopper etc. have all been had greater activity;
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4) to the person poultry safety, Environmental compatibility is good, is difficult for developing immunity to drugs.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
Application Example one
Embodiment 181% fluorine mite piperazine spiral shell mite ester wetting powder
Fluorine mite piperazine 1%, spiral shell mite ester 80%, alkylnaphthalene sulfonate 6%, lauryl sodium sulfate 4%, starch add to 100%, and mixture carries out air-flow crushing, make 81% fluorine mite piperazine spiral shell mite ester wetting powder.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 270% fluorine mite piperazine spiral shell mite ester wetting powder
Fluorine mite piperazine 20%, spiral shell mite ester 50%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 5%, Nekal BX 3%, white carbon add to 100%, and mixture carries out air-flow crushing, make 70% fluorine mite piperazine spiral shell mite ester wetting powder.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 350% fluorine mite piperazine spiral shell mite ester wetting powder
Fluorine mite piperazine 40%, spiral shell mite ester 10%, aryl phenol polyoxyethylene succinate sulfonate 6%, tea are withered 5%, precipitated calcium carbonate adds to 100%, and mixture carries out air-flow crushing, makes 50% fluorine mite piperazine spiral shell mite ester wetting powder.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 435% fluorine mite piperazine spiral shell mite ester wetting powder
Fluorine mite piperazine 15%, spiral shell mite ester 20%, polycarboxylate 7%, soapberry powder 6%, bentonite add to 100%, and mixture carries out air-flow crushing, make 35% fluorine mite piperazine spiral shell mite ester wetting powder.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 580% fluorine mite piperazine spirodiclofen water dispersible granule
Fluorine mite piperazine 79%, spiral shell mite ester 1%, lignosulfonates 5%, silkworm excrement 4%, sodium bicarbonate 2.5%, kaolin add to 100%, mix to make 80% fluorine mite piperazine spirodiclofen water dispersible granule.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 675% fluorine mite piperazine spirodiclofen water dispersible granule
Fluorine mite piperazine 15%, spiral shell mite ester 60%, aliphatic alcohol polyethenoxy base ether 7%, neopelex 5%, aluminium chloride 3%, diatomite add to 100%, mix to make 75% fluorine mite piperazine spirodiclofen water dispersible granule.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 760% fluorine mite piperazine spirodiclofen water dispersible granule
Fluorine mite piperazine 30%, spiral shell mite ester 30%, alkyl benzene sulfonate calcium salt 8%, wetting and penetrating agent F4%, ammonium sulfate 2.1%, attapulgite add to 100%, mix to make 60% fluorine mite piperazine spirodiclofen water dispersible granule.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 840% fluorine mite piperazine spirodiclofen water dispersible granule
Fluorine mite piperazine 15%, spiral shell mite ester 25%, ester polyoxyethylene are phonetic 7%, lauryl sodium sulfate 5%, sodium carbonate 3%, kaolin add to 100%, mix making 40% fluorine mite piperazine spirodiclofen water dispersible granule.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 915% fluorine mite piperazine spiral shell mite ester suspending agent
Fluorine mite piperazine 5%, spiral shell mite ester 10%, alkylphenol-polyethenoxy are phonetic 6%, Nekal BX 5%, silicone oil 0.3%, CMC 0.15%, propane diols 1.7%, deionized water add to 100%, mix making 15% fluorine mite piperazine spiral shell mite ester suspending agent.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 1020% fluorine mite piperazine spiral shell mite ester suspending agent
Fluorine mite piperazine 10%, spiral shell mite ester 10%, aliphatic amine polyoxyethylene are phonetic 8%, sldium lauryl sulfate 5%, C
10～20Saturated fat acids 0.5%, PAA 0.17%, polyethylene glycol 1.5%, deionized water add to 100%, mix to make 20% fluorine mite piperazine spiral shell mite ester suspending agent.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 1130% fluorine mite piperazine spiral shell mite ester suspending agent
Fluorine mite piperazine 20%, spiral shell mite ester 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, silkworm excrement 4%, capric acid 0.2%, Magnesiumaluminumsilicate 0.11%, diethylene glycol (DEG) 1.8%, deionized water add to 100%, mix to make 30% fluorine mite piperazine spiral shell mite ester suspending agent.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 1235% fluorine mite piperazine spiral shell mite ester suspending agent
Fluorine mite piperazine 5%, spiral shell mite ester 30%, the phonetic formaldehyde condensation products sulphate 8% of alkylphenol-polyethenoxy, wetting and penetrating agent F 6%, silicone compound 0.1%, xanthans 0.08%, deionized water add to 100%, mix to make 35% fluorine mite piperazine spiral shell mite ester suspending agent.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 1311% fluorine mite piperazine spiral shell mite ester suspension emulsion
Fluorine mite piperazine 1%, spiral shell mite ester 10%, polyoxyethylene carboxylate 7%, lauryl sodium sulfate 4%, phenyl phenol polyoxy ethyl ether phosphate 5%, silicone oil 0.4%, crospolyvinylpyrrolidone 0.13%, propane diols 1.6%, cyclohexanone 2%, deionized water add to 100%, mix to make 11% fluorine mite piperazine spiral shell mite ester suspension emulsion.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 1425% fluorine mite piperazine spiral shell mite ester suspension emulsion
Fluorine mite piperazine 20%, spiral shell mite ester 5%, octylphenol polyethylene oxyethylene group ether sulfate 6%, Nekal BX 5%, alkylphenol-formaldehyde resin polyoxy ethyl ether 7%, vegetable oil 2.5%, silicone 0.2%, phenolic resins 0.12%, triethylene glycol 1.3%, deionized water add to 100%, mix to make 25% fluorine mite piperazine spiral shell mite ester suspension emulsion.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 1535% fluorine mite piperazine spiral shell mite ester suspension emulsion
Fluorine mite piperazine 15%, spiral shell mite ester 20%, alkylaryl APEO 8%, tea are withered 5%, alkyl biphenyl ether disulfonic acid magnesium salts 6%, ethyl acetate 2.2%, silicone 0.3%, glycerine 1.7%, white dextrin 0.14%, deionized water add to 100%, mix making 35% fluorine mite piperazine spiral shell mite ester suspension emulsion.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 1645% fluorine mite piperazine spiral shell mite ester suspension emulsion
Fluorine mite piperazine 40%, spiral shell mite ester 5%, alkyl benzene sulfonate calcium salt 8%, wetting and penetrating agent F 5%, phenethyl fluosite polyoxy ethyl ether 7%, toluene 2%, C
8～10Aliphatic alcohols 0.5%, polyvinyl alcohol 0.15%, glycerine 1.8%, deionized water add to 100%, mix to make 45% fluorine mite piperazine spiral shell mite ester suspension emulsion.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 1741% fluorine mite piperazine spirodiclofen microemulsion
Fluorine mite piperazine 40%, spiral shell mite ester 1%, ethylene oxide-propylene oxide block copolymer 6%, N, dinethylformamide 5%, acetone 4%, propane diols 0.13%, silicone compound 0.2%, deionized water supplies 100%, mixes to make 41% fluorine mite piperazine spirodiclofen microemulsion.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 1861% fluorine mite piperazine spirodiclofen microemulsion
Fluorine mite piperazine 1%, spiral shell mite ester 60%, 3-methyl cyclohexanol ketenes 7%, silicone 0.25%, castor oil polyoxyethylene ether 8%, diethylene glycol (DEG) 1.5%, methyl alcohol 6%, deionized water supplies 100%, makes 61% fluorine mite piperazine spirodiclofen microemulsion.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 1910% fluorine mite piperazine spirodiclofen water emulsion
Fluorine mite piperazine 5%, spiral shell mite ester 5%, ethylene glycol monomethyl ether 5%, propyl alcohol 6%, sorbitan monostearate 7%, capric acid 0.13%, triethylene glycol 1.7%, deionized water adds to 100%, mixes to make 10% fluorine mite piperazine spirodiclofen water emulsion.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 2020% fluorine mite piperazine spirodiclofen water emulsion
Fluorine mite piperazine 8%, spiral shell mite ester 12%, acetonitrile 6%, NOP 4%, fatty alcohol-polyoxyethylene ether 5%, ethylene glycol 1.3%, silicone oil 0.4%, gelatin 0.15%, deionized water add to 100%, make 20% fluorine mite piperazine spirodiclofen water emulsion through mixing.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 2130% fluorine mite piperazine spirodiclofen water emulsion
Fluorine mite piperazine 25%, spiral shell mite ester 5%, toluene 6%, ethyl acetate 7%, polyoxyethylene nonylphenol ether 4%, propane diols 1.2%, sodium alginate 0.12%, silicone compound 0.3%, deionized water adds to 100%, mixes to make 30% fluorine mite piperazine spirodiclofen water emulsion.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 2240% fluorine mite piperazine spirodiclofen water emulsion
Fluorine mite piperazine 30%, spiral shell mite ester 10%, cyclohexanone 7%, sorbitan fatty acid ester APEO 6%, CMC 0.17%, silicone oil 0.4%, butyl ether 4%, deionized water add to 100%, make 40% fluorine mite piperazine spirodiclofen water emulsion through mixing.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 2336% fluorine mite piperazine spiral shell mite ester micro-capsule suspension
Fluorine mite piperazine 4%, spiral shell mite ester 32%, polyfunctional group acyl halide dihydroxylic alcohols 2.8%, the phonetic formaldehyde condensation products sulphate 3% of alkylphenol-polyethenoxy, wetting agent T 4%, ester polyoxyethylene are phonetic 3.7%, carrene 4%, sodium polymethacrylate 5%; sorbic acid 0.7%, sodium hydroxide 1.2%, deionized water add to 100% weight portion, make 36% fluorine mite piperazine spiral shell mite ester micro-capsule suspension.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 2440% fluorine mite piperazine spiral shell mite ester micro capsule suspension-suspending agent
Fluorine mite piperazine 10%, spiral shell mite ester 30%, sodium alginate 4%, maltose 3%, PIC 1.5%, beta-schardinger dextrin-1.4%, alkylaryl polyoxyethylene poly-oxygen propylene aether 6%, polyoxyethylene nonylphenol ether phosphate 4%, silicone defoaming agent 0.4%, polyethylene glycol 1.7%, sodium hydroxide 0.6%, hydrochloric acid 0.9%, water add to 100% weight portion, make 40% fluorine mite piperazine spiral shell mite ester micro capsule suspension-suspending agent.
With effective active composition spiral shell mite ester be changed to halfenprox, fenisobromolate forms new embodiment.
Embodiment 2560% fluorine mite piperazine fenisobromolate wetting powder
Fluorine mite piperazine 15%, fenisobromolate 45%, alkyl benzene sulfonate calcium salt 5%, neopelex 6%, starch add to 100%, and mixture carries out air-flow crushing, make 60% fluorine mite piperazine fenisobromolate wetting powder.
With effective active composition fenisobromolate be changed to halfenprox, spiral shell mite ester forms new embodiment.
Embodiment 2650% fluorine mite piperazine fenisobromolate water dispersible granules
Fluorine mite piperazine 10%, fenisobromolate 40%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, soapberry powder 4%, urea 3%, attapulgite add to 100%, mix to make 50% fluorine mite piperazine fenisobromolate water dispersible granules.
With effective active composition fenisobromolate be changed to spiral shell mite ester, halfenprox forms new embodiment.
Embodiment 2745% fluorine mite piperazine fenisobromolate suspending agent
Fluorine mite piperazine 10%, fenisobromolate 35%, lignosulfonates 8%, silkworm excrement 5%, silicone compound 0.4%, polyvinylpyrrolidone 0.12%, ethylene glycol 1.8%, deionized water add to 100%, mix to make 45% fluorine mite piperazine fenisobromolate suspending agent.
With effective active composition fenisobromolate be changed to spiral shell mite ester, halfenprox forms new embodiment.
Embodiment 2815% fluorine mite piperazine fenisobromolate suspension emulsion
Fluorine mite piperazine 5%, fenisobromolate 10%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 7%, Nekal BX 5%, ethylene oxide-propylene oxide block copolymer 8%, cyclohexanone 3%, silicone oil 0.2%, methylcellulose 0.14%, propane diols 1.3%, deionized water add to 100%, mix to make 15% fluorine mite piperazine fenisobromolate suspension emulsion.
With effective active composition fenisobromolate be changed to spiral shell mite ester, halfenprox forms new embodiment.
Embodiment 2941% fluorine mite piperazine fenisobromolate microemulsion
Fluorine mite piperazine 1%, fenisobromolate 40%, cyclohexanone 5%, ethanol 5%, fatty alcohol-polyoxyethylene ether 6%, silicone 0.3%, diethylene glycol (DEG) 1.7%, deionized water supplies 100%, makes 41% fluorine mite piperazine fenisobromolate microemulsion.
With effective active composition fenisobromolate be changed to spiral shell mite ester, halfenprox forms new embodiment.
Embodiment 3030% fluorine mite piperazine fenisobromolate aqueous emulsion
Fluorine mite piperazine 10%, fenisobromolate 20%, N-pyrrolidones 6%, ethylene glycol monomethyl ether 5%, alkylphenol-formaldehyde resin polyoxy ethyl ether 7%, melon glue 0.12%, C
10～20Saturated fat acids 0.2%, deionized water adds to 100%, mixes to make 30% fluorine mite piperazine fenisobromolate aqueous emulsion.
With effective active composition fenisobromolate be changed to spiral shell mite ester, halfenprox forms new embodiment.
Embodiment 3144% fluorine mite piperazine fenisobromolate micro-capsule suspension
Fluorine mite piperazine 4%, fenisobromolate 40%, urea 6%, modified starch 4%, styrene-maleic anhydride copolymer sodium salt emulsion 3%, dodecylbenzene sodium sulfonate 2.5%, solvent naphtha 3%, alkylaryl polyoxyethylene polyoxypropylene ether 4%, citric acid 0.9%, sodium hydroxide 1.2%, deionized water add to 100% weight portion, make 44% fluorine mite piperazine fenisobromolate micro-capsule suspension.
With effective active composition fenisobromolate be changed to spiral shell mite ester, halfenprox forms new embodiment.
Embodiment 3220% fluorine mite piperazine fenisobromolate microcapsule suspension-suspending agent
Fluorine mite piperazine 15%, fenisobromolate 5%, formaldehyde 6%, polyfunctional group acyl halide polyamines 3.2%, Nekal BX 3.8%, polymeric polycarboxylic acid salt 3.1%, 2; 4-toluene di-isocyanate(TDI) 7%, styrene polyoxyethylene ether ammonium sulfate salt 5%, triethanolamine salt 3%, C
8～10Aliphatic alcohols 0.1%, methylcellulose 0.13%, sodium hydroxide 1.2%, sorbic acid 0.7%, water add to 100% weight portion, make 20% fluorine mite piperazine fenisobromolate microcapsule suspension-suspending agent.
With effective active composition fenisobromolate be changed to spiral shell mite ester, halfenprox forms new embodiment.
Embodiment 3325% fluorine mite piperazine halfenprox suspension emulsion
Fluorine mite piperazine 15%, halfenprox 10%, aliphatic amine polyoxyethylene are phonetic 5%, lauryl sodium sulfate 3%, phenethyl fluosite polyoxy ethyl ether 8%, acetone 2.5%, C
8～10Aliphatic alcohols 0.3%, xanthans 0.14%, polyethylene glycol 1.6%, deionized water add to 100%, mix to make 25% fluorine mite piperazine halfenprox suspension emulsion.
With effective active composition halfenprox be changed to spiral shell mite ester, fenisobromolate forms new embodiment.
Embodiment 3430% fluorine mite piperazine halfenprox suspension emulsion
Fluorine mite piperazine 20%, halfenprox 10%, lignosulfonates 7%, sldium lauryl sulfate 4%, alkylaryl polyoxyethylene poly-oxygen propylene aether 6%, silicone oil 0.17%, Magnesiumaluminumsilicate 0.12%, triethylene glycol 1.3%, deionized water add to 100%, mix to make 30% fluorine mite piperazine halfenprox suspension emulsion.
With effective active composition halfenprox be changed to spiral shell mite ester, fenisobromolate forms new embodiment.
Embodiment 3521% fluorine mite piperazine halfenprox microemulsion
Fluorine mite piperazine 20%, halfenprox 1%, vegetable oil 5%, toluene 4%, phenyl phenol polyoxy ethyl ether 6%, C
10～20Saturated fat acids 0.2%, propane diols 1.3%, deionized water supplies 100%, makes 21% fluorine mite piperazine halfenprox microemulsion.
With effective active composition halfenprox be changed to spiral shell mite ester, fenisobromolate forms new embodiment.
Embodiment 3611% fluorine mite piperazine halfenprox microemulsion
Fluorine mite piperazine 1%, halfenprox 10%, ethyl acetate 6%, cyclohexanone 3.5%, polyoxyethylene nonylphenol ether phosphate 5%, silicone compound 0.15%, ethylene glycol 1.6%, deionized water supplies 100%, makes 11% fluorine mite piperazine halfenprox microemulsion.
With effective active composition halfenprox be changed to spiral shell mite ester, fenisobromolate forms new embodiment.
Embodiment 3730% fluorine mite piperazine halfenprox aqueous emulsion
Fluorine mite piperazine 10%, halfenprox 20%, ethylene glycol monomethyl ether 6%, cyclohexanone 7%, phenethyl phenol polyoxy ethyl polypropylene-base ether 5%, PAA 0.12%, silicone compound 0.4%, deionized water adds to 100%, mixes to make 30% fluorine mite piperazine halfenprox aqueous emulsion.
With effective active composition halfenprox be changed to spiral shell mite ester, fenisobromolate forms new embodiment.
Embodiment 3835% fluorine mite piperazine halfenprox aqueous emulsion
Fluorine mite piperazine 30%, halfenprox 5%, 3-methyl cyclohexanol ketenes 5%, acetonitrile 4%, sorbitan fatty acid ester APEO 6%, methylcellulose 0.1%, capric acid 0.2%, deionized water adds to 100%, mixes to make 35% fluorine mite piperazine halfenprox aqueous emulsion.
With effective active composition halfenprox be changed to spiral shell mite ester, fenisobromolate forms new embodiment.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.First by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, places respectively beaker for subsequent use.Adopt and to soak first the method that connects worm behind the leaf, the blade of the same size that does not contact any medicament soaked in the liquid that configures behind the 5s take out, naturally dry, put into insect box, then connect for the examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat used examination borer population be 50, establishes simultaneously blank, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
The insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates thus the value of every kind of medicament.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (take fluorine mite piperazine as the standard medicament, its toxicity index is 100):
TI * the P of the theoretical toxicity index (TTI) of M=fluorine mite piperazine
Fluorine mite piperazineTI * P of+active component B
Active component B
In the formula: M is the mixture of different proportionings;
P
Active component BBe active component B shared ratio in composition;
P
Fluorine mite piperazineBe fluorine mite piperazine shared ratio in composition.
Annotate: active component B is a kind of arbitrarily in spiral shell mite ester, halfenprox, the fenisobromolate.
Application Example two:
For trying insect: two spotted spider mite.
Experimental scheme: effective lethal concentration scope of determining fluorine mite piperazine, the former medicine of spiral shell mite ester and the two different proportioning mixture through preliminary experiment.
Toxicity test result one
Table 1 fluorine mite piperazine and the toxicity test of the different proportionings of spiral shell mite ester to two spotted spider mite
As shown in Table 1, the composite control of fluorine mite piperazine and spiral shell mite ester two spotted spider mite fit at 80: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 80: 1 to 1: 80 all shows synergistic effect, especially when fluorine mite piperazine and spiral shell mite ester get proportioning at 10: 1 to 1: 10, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when fluorine mite piperazine and spiral shell mite ester weight ratio are 1: 1 wherein, and synergistic effect is the most obvious.Find simultaneously, fluorine mite piperazine and spiral shell mite ester proportioning were at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20 o'clock composite to two spotted spider mite, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker, oystershell scale, the insects such as leafhopper also have preferably synergistic effect, and co-toxicity coefficient is all greater than 120.
Application Example three:
For trying insect: blister mite.
Experimental scheme: effective lethal concentration scope of determining fluorine mite piperazine, the former medicine of fenisobromolate and the two different proportioning mixture through preliminary experiment.
Toxicity test result two
Table 2 fluorine mite piperazine proportionings different from fenisobromolate are to the toxicity test of blister mite
As shown in Table 2, the proportioning of the composite control blister mite of fluorine mite piperazine and fenisobromolate was at 80: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 80: 1 to 1: 80 all shows synergistic effect, especially when the proportioning of fluorine mite piperazine and fenisobromolate during at 10: 1 to 1: 20, synergistic effect is more obviously outstanding, wherein co-toxicity coefficient is maximum when fluorine mite piperazine and fenisobromolate weight ratio are 1: 5, synergistic effect is the most obvious, find simultaneously, fluorine mite piperazine and fenisobromolate proportioning were at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20,1: 21,1: 22,1: 23,1: 24,1: 25,1: 26,1: 27,1: 28,1: 29,1: 30 o'clock composite to two spotted spider mite, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker, oystershell scale, the insects such as leafhopper also have preferably synergistic effect, and co-toxicity coefficient is all greater than 120.
Application Example four:
For trying insect: Tetranychus urticae.
Experimental scheme: effective lethal concentration scope of determining fluorine mite piperazine, the former medicine of halfenprox and the two different proportioning mixture through preliminary experiment.
Toxicity test result three
Table 3 fluorine mite piperazine proportionings different from halfenprox are to the toxicity test of Tetranychus urticae
As shown in Table 3, the proportioning of the composite control Tetranychus urticae of fluorine mite piperazine and halfenprox was at 80: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 80: 1 to 1: 80 all shows synergistic effect, especially when the proportioning of fluorine mite piperazine and halfenprox during at 10: 1 to 1: 10, synergistic effect is more obviously outstanding, wherein co-toxicity coefficient is maximum when fluorine mite piperazine and halfenprox weight ratio are 1: 1, synergistic effect is the most obvious, find simultaneously, fluorine mite piperazine and halfenprox proportioning were at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20 o'clock composite to two spotted spider mite, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker, oystershell scale, the insects such as leafhopper also have preferably synergistic effect, and co-toxicity coefficient is all greater than 120.
Application Example five fluorine mite piperazines and spiral shell mite ester and the composite control citrus red mite test of pesticide effectiveness thereof
This experimental establishment is in the Haiyan County, Jiaxing City, Zhejiang Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% fluorine mite piperazine suspending agent (autogamy), 240 grams per liter spiral shell mite ester suspending agents (commercial).
Conventional spray-on process is adopted in test, and investigation citrus red mite insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and calculated preventive effect.
Experimental result is as follows:
Table 4 fluorine mite piperazine, spiral shell mite ester and the composite control citrus red mite test of pesticide effectiveness thereof
As can be seen from Table 4, can effectively prevent and treat citrus red mite after fluorine mite piperazine and spiral shell mite ester are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example hexafluoro mite piperazine and spiral shell mite ester and the composite control cotton yellow spider test of pesticide effectiveness thereof
This experimental establishment is in Weinan City Dali County, Shaanxi Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% fluorine mite piperazine suspending agent (autogamy), 240 grams per liter spiral shell mite ester suspending agents (commercial).
Conventional spray-on process is adopted in test, and investigation cotton yellow spider insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and calculated preventive effect before the medicine.
Experimental result is as follows:
Table 5 fluorine mite piperazine, spiral shell mite ester and the composite control cotton yellow spider test of pesticide effectiveness thereof
As can be seen from Table 5, can effectively prevent and treat the cotton yellow spider after fluorine mite piperazine and spiral shell mite ester are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
The Rose Red-mite test of pesticide effectiveness is viewed and admired in Application Example seven fluorine mite piperazines and spiral shell mite ester and composite control thereof
This experimental establishment is at the Jinan City, Shandong Province Pingying County, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% fluorine mite piperazine suspending agent (autogamy), 240 grams per liter spiral shell mite ester suspending agents (commercial).
Conventional spray-on process is adopted in test, and Rose Red-mite insect pest index is viewed and admired in investigation before the medicine, in the dispenser of insect pest initial stage of origination, investigates the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and calculates preventive effect.Experimental result is as follows:
The Rose Red-mite test of pesticide effectiveness is viewed and admired in table 6 fluorine mite piperazine, spiral shell mite ester and composite control thereof
As can be seen from Table 6, can effectively prevent and treat after fluorine mite piperazine and spiral shell mite ester are composite and view and admire Rose Red-mite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example octafluoro mite piperazine and fenisobromolate and the composite control wheat wheat leaf pawl mite test of pesticide effectiveness thereof
This experimental establishment is in Fengxiang County, Baoji, Shaanxi province city, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% fluorine mite piperazine suspending agent (autogamy), 500 grams per liter fenisobromolate missible oil (commercial).
Test and adopt conventional spray-on process, investigation wheat wheat leaf pawl acarid evil index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and is calculated preventive effect before the medicine.
Experimental result is as follows:
Table 7 fluorine mite piperazine, fenisobromolate and the composite control wheat wheat leaf pawl mite test of pesticide effectiveness thereof
As can be seen from Table 7, can effectively prevent and treat wheat wheat leaf pawl mite after fluorine mite piperazine and fenisobromolate are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example nine fluorine mite piperazines and fenisobromolate and the composite control apple Tetranychus urticae test of pesticide effectiveness thereof
This experimental establishment is in Weinan City Pucheng County, Shaanxi Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% fluorine mite piperazine suspending agent (autogamy), 500 grams per liter fenisobromolate missible oil (commercial).
Conventional spray-on process is adopted in test, and investigation apple Tetranychus urticae insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and calculated preventive effect before the medicine.
Experimental result is as follows:
Table 8 fluorine mite piperazine, fenisobromolate and the composite control apple Tetranychus urticae test of pesticide effectiveness thereof
As can be seen from Table 8, can effectively prevent and treat the apple Tetranychus urticae after fluorine mite piperazine and fenisobromolate are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example ten fluorine mite piperazines and halfenprox and the composite control oranges and tangerines blister mite test of pesticide effectiveness thereof
This experimental establishment is in the Yongshun County, Hunan Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% fluorine mite piperazine suspending agent (autogamy), 5% halfenprox missible oil (commercial).
Conventional spray-on process is adopted in test, and investigation oranges and tangerines blister mite insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and calculated preventive effect before the medicine.
Experimental result is as follows:
Table 9 fluorine mite piperazine, fenisobromolate and the composite control oranges and tangerines blister mite test of pesticide effectiveness thereof
As can be seen from Table 9, can effectively prevent and treat the oranges and tangerines blister mite after fluorine mite piperazine and halfenprox are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
After draw through different local throughout the country tests, fluorine mite piperazine and spiral shell mite ester, halfenprox, fenisobromolate be composite makes behind wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, the microcapsule suspension-suspending agent preventive effect of the common insects such as two spotted spider mite to all kinds of crops, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker, oystershell scale, leafhopper all more than 95%, be better than the single dose preventive effect, synergistic effect is obvious.
Claims (8)
1. Pesticidal combination that contains fluorine mite piperazine, comprise active components A, active component B, it is characterized in that: active components A is fluorine mite piperazine, and active component B is a kind of arbitrarily in spiral shell mite ester, halfenprox, the fenisobromolate, and the weight ratio of active components A and active component B is 1: 80～80: 1.
2. Pesticidal combination according to claim 1, it is characterized in that: the weight ratio of active components A and active component B is 1: 60～40: 1.
3. Pesticidal combination according to claim 2, it is characterized in that: the weight ratio of fluorine mite piperazine and spiral shell mite ester is 1: 20～20: 1.
4. Pesticidal combination according to claim 2, it is characterized in that: the weight ratio of fluorine mite piperazine and halfenprox is 1: 20～20: 1.
5. Pesticidal combination according to claim 2, it is characterized in that: the weight ratio of fluorine mite piperazine and fenisobromolate is 1: 30～10: 1.
6. the described Pesticidal combination of any one according to claim 1～5, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
7. Pesticidal combination according to claim 6 is used for the application of insect on control wheat, cotton, fruit tree, vegetables, tea tree, the ornamental flower.
8. application according to claim 7 is characterized in that institute's pest control comprises: two spotted spider mite, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker, oystershell scale, leafhopper.
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Also Published As
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| CN103300012B (en) | 2016-04-06 |
| CN105557707B (en) | 2018-04-03 |
| CN105557707A (en) | 2016-05-11 |
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