CN103290152A - Hogskin suede vamp leather after-tanning wet finishing method - Google Patents
Hogskin suede vamp leather after-tanning wet finishing method Download PDFInfo
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Abstract
The invention discloses a hogskin suede vamp leather after-tanning wet finishing method which comprises the following steps: squeezing of hogskin vamp blue wet leather, primary shaving (flesh side), secondary light shaving (grain surface), wet milling, weighing, rewetting, water washing, retanning, water washing, neutralizing, water washing, primary greasing, filling, water washing, bulging, primary drying, secondary drying, remoistening, softening by vibration, dry milling, weighing, tempering, water washing, dyeing, secondary greasing, top dyeing, water washing, bulging, drying, remoistening, softening by throwing, (other steps), scaling, and warehousing. The finished product has the advantages of thin and short fuzz and no obvious pores, and is basically uniform; and the leather is plump and soft, has the advantages of high thickness, favorable fastness and high yield.
Description
Technical field
The invention belongs to the leather tanning field, wet ornamenting working method after particularly the positive suede upper leather of a kind of pigskin is tanned.
Background technology
The positive suede upper leather of pigskin (market also claims pig Ba Ge) is to process by the pigskin tannin.On the market, for high-quality pig Ba Ge requirement be: pore is not obvious, and fine hair is fine and closely woven, and is even substantially; Thickness is more than 0.9mm, and general thickness is 1.2-1.5mm; The plentiful softness of leather body, fastness is good; The position difference is little, and deburring is few, the yield of leather height.
The weave construction characteristics that pigskin is main:
(1) grain is coarse, and the pig hair is generally three at surface, and isosceles triangle is arranged.Pore seems thick especially in surface exit flare.Grain nipple projection is obvious, and rill is darker, so the grain that seems is coarse;
(2) the position difference is big, and the position difference shows as greatly: difference in thickness is big, fibrage difference is big and grain difference is big;
(3) difference in thickness: the buttocks of pigskin, belly difference in thickness can change from 4.5mm-1.0mm;
(4) fibrage difference: the stern back fibrous bundle of pigskin is sturdy, is the cruciform braiding, and braiding is tight, and limit belly fibrous bundle is very thin, mostly is the waviness braiding, and braiding is loose, and the neck braiding falls between;
(5) grain difference: the pore thickness of buttocks part of pighide, neck and belly and density, the grain rill depth are all obviously different.Generally, the buttocks grain is flat thin than belly;
Particular tissues constructional feature in view of above-mentioned pigskin, so processing high-quality pig Ba Ge must will keep on improving in technology, formulate process program according to pigskin histological characteristic, the detrimentally affect that reduces that the pigskin grain is coarse, the position difference is big etc. and bring, it is poor that the position of pigskin is dwindled in emphasis, the control buffing degree of depth makes finished leather feel, fine hair even as far as possible.
Pig Ba Ge is because be velour, so prepare workshop section, tanning workshop section before its production is only tanned strictly speaking and back three workshop sections of wet finishing workshop section that tan.Forefathers are for the processing of pig Ba Ge, with focus concentrate on tan before workshop section and tanning workshop section, Special attention will be given to degreasing, depilation liming, softening pickling, in conjunction with the importance of operations such as tanning, and the arrangement of the technical process of workshop section and tanning workshop section before tanning.For the back wet finishing workshop section of tanning, only pay close attention to the several single operations of buffing, dyeing and stuffing to the influence of pig Ba Ge quality, back each inter process of wet finishing workshop section of tanning is lacked a global design, arrangement, often occurs following problem easily so it produces pig Ba Ge:
The buffing degree of depth is big, the hide thickness low LCL, and generally between 0.9-1.2mm, fastness is not enough; Fennel is obvious, and fine hair is different in size, and is inhomogeneous; The inclined to one side plate of leather body is hard; Problems such as the position difference is big, and deburring is serious, and yield of leather is low.
Summary of the invention
The objective of the invention is in order to overcome the shortcoming and defect that prior art exists, and provide a kind of finished product fine hair that processes carefully short, even substantially, there is not obvious pore; The plentiful softness of leather body; Thickness is thicker, and fastness is good; Wet ornamenting working method after the positive suede upper leather of a kind of pigskin of the high-quality pig Ba Ge that yield of leather is higher is tanned.
For achieving the above object, technical scheme of the present invention is to comprise following operation:
A pigskin vamp wet blue leather → water squeezing → shaving (cutting the flesh noodles) → light shaving of secondary (cutting grain) → wet-milling → weigh → return is wet → washing → retanning → washing → neutralization → washing → one time stuffing, filling → wash, go out drum → primary drying → redrying → get damp again → shake soft → dry grind → weigh → backwater → washing → dyeing, secondary stuffing → (dye on the top) → wash, go out drum → drying → soft → (other operations) that get damp again → fall → row's chi, warehouse-in
(1) pigskin vamp wet blue leather: select to be combined tanning with other tanning agents for the leather of processing pig Ba Ge through chrome tanning agent tanning or chrome tanning agent;
(2) water squeezing: conventional operation;
(3) shavings: cut flesh noodles, thickness is with the many 0.1-0.4mm of finished product pig Ba Ge thickness;
(4) the light shaving of secondary: cut grain, cut with complete opening, grain is stretched to cut brokenly be advisable, thickness is not changed to some extent;
(5) wet-milling: the wet blue leather buffing, with the 80-200 emery cloth, demand perfection to open is ground to, and destroys grain;
(6) weigh, return wet, washing, retanning, washing and neutralization, general in and between the pH to 5.0-6.5;
(7) washing;
(8) stuffings, filling: a small amount of stuffing, the fatting agent total amount accounts for the 3-8% of tare weight; The stuffing later stage adds the vegetable tanning agent of tare weight 2-5% and fills; This step stuffing amount by quality ratio;
(9) wash, go out drum;
(10) primary drying: adopt vacuum-drying or paste drying that moisture in the skin is down to 30-40%, by quality ratio, require grain flat thin;
(11) redrying: employing nature extension dries in the air or the drying tunnel extension dries in the air is down to 14-18% with moisture in the skin, by quality ratio;
(12) moisture regain: make tare weight moisture remain on 30% ± 5, by quality ratio;
(13) shake soft: adopt the vibration staking machine to handle, softness is advisable to be fit to buffing;
(14) dry grinding: the crust leather dry grinding, adopt the 150-400 emery cloth, the gradation buffing, emery cloth variation from coarse to fine, first mill flesh noodles, abrasive particle face then is during the abrasive particle face, directly with the direct buffing of big buffing machine, or earlier with little buffing machine edging belly and neck neck, adopt the method for whole buffing of big buffing machine then, require no obvious pore, fine hair is carefully short, even substantially.
(15) weigh, backwater and washing;
(16) dyeing, secondary stuffing, secondary stuffing will consider to deduct that part of stuffing amount that has added in stuffing operation; Total stuffing amount is according to the hide requirement, and fatting agent type and effect have difference, and general pig Ba Ge stuffing total amount is to change between the 5-15%.The secondary stuffing is stuffing amount of total stuffing amount deduction.
(17) drum is dyed (at the dark color leather, light leather can omit), washes and goes out on the top;
(18) drying: adopt vacuum-drying and extension to dry dryly to combine, paste drying dries dry combining with extension, perhaps extension dries dry;
(19) moisture regain: tare weight moisture is remained on about 30%, by quality ratio
(20) fall soft, row chi and warehouse-in.
Further arranging is that described step (20) is fallen and also had other technologies between soft row's chi, and these other technologies are spray hand feeling agent and/or spray dyestuff.
For obtaining even, careful fine hair, the present invention adopts a wet-milling, the buffing mode that vegetable tanning agent is filled and the secondary dry grinding combines.Wet-milling makes the basic napping of grain; Add vegetable tanning agent during a stuffing, make grain be conducive to buffing; Gradation buffing during dry grinding, corase grind back fine grinding earlier makes grain fine hair even, careful.
For obtaining not having the fine hair outward appearance of obvious pore, need accomplish the buffing degree of depth be pore trumpet type dwindle the place.The pigskin grain is coarse, and pore is at surface exit flare opening shape.If direct buffing grinds shallowly, the hydraucone inner wall smooth does not have fine hair, and pore is very obvious; Grind deeply, pore is not obvious, but variation in thickness is big, influences the finished leather fastness.The mode that the present invention adopts secondary shaving (cutting grain) to combine with buffing.When cutting grain, obtain more smooth grain by shear action, buffing is controlled the buffing degree of depth easily then, and buffing is to the place that dwindles of pore trumpet type.
For obtaining soft and full pig Ba Ge, the present invention adopts the processing mode of a stuffing, dry arrangement, secondary stuffing, dry arrangement.Fatliquoring in multi-step is conducive to fatting agent and evenly distributes at each position, improves pliability and the fullness ratio of finished leather.Multi stage drying is conducive to finished leather and has good hand feeling and performance.
In order to obtain being generally 1.2-1.5mm more than the thickness 0.9mm, the pig Ba Ge that fastness is good, the change total amount to thickness of needs control shaving and buffing.The pigskin grain is coarse, and grain nipple projection is obvious, and rill is darker, and pore is in surface exit flare.General working method adopt a simple shaving and repeatedly the buffing mode change thickness, in order to pursue fine hair quality and limit belly napping, often the buffing degree of depth is darker, causes hide thickness obviously to descend, and influences the fastness of finished leather during buffing.The mode that the present invention adopts a shaving (cutting flesh noodles), secondary shaving (cutting grain) to combine with buffing.A shaving (cutting flesh noodles) gives hide a basic thickness uniformly; Secondary shaving (cutting grain) does not change to thickness, mainly is to cut brokenly opening the stretching of pigskin grain entirely; Wet-milling and dry grinding combine, and mainly are the napping effects, change little to thickness.When realizing good thickness, finished leather position difference is little, the yield of leather height.
Below in conjunction with embodiment the present invention is done further introduction.
Embodiment
Carry out concrete description below by the present invention of embodiment; only be used for the present invention is further specified; can not be interpreted as the restriction to protection domain of the present invention, the technician in this field can make some nonessential improvement and adjustment to the present invention according to the content of foregoing invention.
Embodiment 1(light color pig Ba Ge)
A pigskin vamp wet blue leather → water squeezing → shaving (cutting the flesh noodles) → light shaving of secondary (cutting grain) → wet-milling → weigh → return is wet → washing → retanning → washing → neutralization → washing → one time stuffing, filling → wash, go out drum → primary drying → redrying → get damp again → shake soft → dry grind → weigh → backwater → washing → dyeing, secondary stuffing → wash, go out drum → drying → soft → (other operations) that get damp again → fall → row's chi, warehouse-in
(1) pigskin vamp wet blue leather: the leather that is used for processing pig Ba Ge through the chrome tanning agent tanning.
(2) water squeezing: making the hide water content is 45%-50%
(3) shavings (cutting flesh noodles): shaving thickness 1.5mm.
(4) the light shaving of secondary (cutting grain): cut grain, grain is stretched cut brokenly, complete opening cut.
(5) wet-milling: with No. 80 emery cloth buffings, complete opening is ground to, and destroys grain.
(6) weigh.As later raw materials used benchmark, percentage ratio meter by weight.
(7) return wet: tare weight 400% water, temperature 35 degree add 0.1% formic acid, 0.2% grease-removing agent rotates 45min, control water.
(8) washing: tare weight 400% water, temperature 35 degree rotate 10min, control water.
(9) retanning: tare weight 100% water, temperature 35 degree add 4% chrome tanning agent, rotate 90min, add 1% sodium formiate, rotate 30min, add 0.8% sodium bicarbonate, rotate 90min, pH=4.0-4.2.Change and stop in conjunction with spending the night control water.
(10) washing: tare weight 400% water, temperature 35 degree rotate 10min, control water.
(11) neutralization: tare weight 200% water, temperature 35 degree add in 1.5% and tannin, and 1% sodium formiate rotates 30min, adds 0.8% sodium bicarbonate, rotates 90min, pH=5.0, control water.
(12) washing: tare weight 400% water, temperature 35 degree rotate 10min, control water.
(13) stuffings, filling: tare weight 150% water, temperature 45 degree add 3% fatting agent, rotate 30min, add 4% vegetable tanning agent, rotate 30min, add 0.8% formic acid, rotate 30min, pH=3.8.Control water.
(14) wash, go out drum: tare weight 400% water, temperature normal temperature rotates 10min, control water.Triplicate goes out drum.
(15) primary drying: adopt vacuum-drying moisture to the skin to be down to 40%.
(16) redrying: adopt drying tunnel to hang to dry in the air moisture in the skin is down to 18%.
(17) moisture regain: water spray, leave standstill, tare weight moisture is remained on about 30%.
(18) shake soft: adopt the vibration staking machine to handle.
(19) dry grinding: the crust leather dry grinding, with No. 150 emery cloth mill flesh noodles, use emery cloth abrasive particle face again No. 150 earlier, use emery cloth abrasive particle face twice at last No. 250, there is not obvious pore, fine hair is carefully short, even substantially.
(20) weigh: weightening finish 300%, as later raw materials used benchmark, percentage ratio meter by weight.
(21) backwater: tare weight 400% water, temperature 35 degree add 0.5% ammoniacal liquor, and 0.05% permeate agent changes and stops in conjunction with spending the night control water.
(22) washing: tare weight 400% water, temperature 35 degree rotate 10min, control water.
(23) dyeing, secondary stuffing: tare weight 150% water, temperature 40 degree add 0.5% dyestuff, rotate 30min, add 5% fatting agent, rotate 30min, add 100% hot water, temperature is the 45-50 degree in making, and rotates 30min, add 0.5% formic acid, rotate 30min, pH=3.8, control water.
(24) wash, go out drum: tare weight 400% water, temperature normal temperature rotates 10min, control water.Triplicate goes out drum.
(25) drying: adopt vacuum-drying moisture to the skin to be down to 40%.Adopt drying tunnel to hang to dry in the air again moisture in the skin is down to 18%.
(26) moisture regain: water spray, leave standstill, tare weight moisture is remained on about 30%.
(27) fall soft: fall soft 30-60min.
(28) row's chi, warehouse-in.
Embodiment 2(light color pig Ba Ge)
A pigskin vamp wet blue leather → water squeezing → shaving (cutting the flesh noodles) → light shaving of secondary (cutting grain) → wet-milling → weigh → return is wet → washing → retanning → washing → neutralization → washing → one time stuffing, filling → wash, go out drum → primary drying → redrying → get damp again → shake soft → dry grind → weigh → backwater → washing → dyeing, secondary stuffing → wash, go out bulging → drying → get damp again → fall soft → spray feel → row's chi, warehouse-in
(1) pigskin vamp wet blue leather: be combined tanning with vegetable tanning agent for the leather of processing pig Ba Ge through chrome tanning agent.
(2) water squeezing: making the hide water content is 45%-50%
(3) shavings (cutting flesh noodles): shaving thickness 1.3mm.
(4) the light shaving of secondary (cutting grain): cut grain, grain is stretched cut brokenly, complete opening cut.
(5) wet-milling: with No. 150 emery cloth buffings, complete opening is ground to, and destroys grain.
(6) weigh.As later raw materials used benchmark, percentage ratio meter by weight.
(7) return wet: tare weight 400% water, temperature 35 degree add 0.2% formic acid, 0.15% grease-removing agent rotates 45min, control water.
(8) washing: tare weight 400% water, temperature 35 degree rotate 10min, control water.
(9) retanning: tare weight 100% water, temperature 35 degree add 5% chrome tanning agent, rotate 90min, add 1% sodium formiate, rotate 30min, add 0.8% sodium bicarbonate, rotate 90min, pH=4.0-4.2.Change and stop in conjunction with spending the night control water.
(10) washing: tare weight 400% water, temperature 35 degree rotate 10min, control water.
(11) neutralization: tare weight 200% water, temperature 35 degree add in 1.5% and tannin, and 1% sodium formiate rotates 30min, adds 1.0% sodium bicarbonate, rotates 90min, pH=5.5, control water.
(12) washing: tare weight 400% water, temperature 35 degree rotate 10min, control water.
(13) stuffings, filling: tare weight 150% water, temperature 45 degree add 5% fatting agent, rotate 30min, add 2% vegetable tanning agent, rotate 30min, add 1.0% formic acid, rotate 30min, pH=3.8.Control water.
(14) wash, go out drum: tare weight 400% water, temperature normal temperature rotates 10min, control water.Triplicate goes out drum.
(15) primary drying: adopt paste drying moisture to the skin to be down to 40%.
(16) redrying: adopt to hang to dry and dry moisture in the skin is down to 14%.
(17) moisture regain: water spray, leave standstill, tare weight moisture is remained on about 30%.
(18) shake soft: adopt the vibration staking machine to handle.
(19) dry grinding: the crust leather dry grinding, with No. 150 emery cloth mill flesh noodles, use emery cloth abrasive particle face again No. 150 earlier, use emery cloth abrasive particle face twice at last No. 400, there is not obvious pore, fine hair is carefully short, even substantially.
(20) weigh: weightening finish 300%, as later raw materials used benchmark, percentage ratio meter by weight.
(21) backwater: tare weight 400% water, temperature 35 degree add 0.6% ammoniacal liquor, and 0.05% permeate agent changes and stops in conjunction with spending the night control water.
(22) washing: tare weight 400% water, temperature 35 degree rotate 10min, control water.
(23) dyeing, secondary stuffing: tare weight 150% water, temperature 40 degree add 0.5% dyestuff, rotate 30min, add 6% fatting agent, rotate 30min, add 100% hot water, temperature is the 45-50 degree in making, and rotates 30min, add 0.5% formic acid, rotate 30min, pH=3.8, control water.
(24) wash, go out drum: tare weight 400% water, temperature normal temperature rotates 10min, control water.Triplicate goes out drum.
(25) drying: adopt paste drying moisture to the skin to be down to 40%.Adopt drying tunnel to hang to dry in the air again moisture in the skin is down to 18%.
(26) moisture regain: water spray, leave standstill, tare weight moisture is remained on about 30%.
(27) fall soft: fall soft 90-120min.
(28) row's chi, warehouse-in.
Embodiment 3(black pig Ba Ge)
A pigskin vamp wet blue leather → water squeezing → shaving (cutting the flesh noodles) → light shaving of secondary (cutting grain) → wet-milling → weigh → return is wet → washing → retanning → washing → neutralization → washing → one time stuffing, filling → wash, go out drum → primary drying → redrying → get damp again → shake soft → dry grind → weigh → that bulging → drying → get damp again → fall is dyed → washed, goes out in backwater → washing → dyeing, secondary stuffing → top is soft → spray dyestuff → row's chi, warehouse-in
(1) pigskin vamp wet blue leather: process chrome tanning agent and Syntan Combination Tannage system are used for the leather of processing pig Ba Ge.
(2) water squeezing: making the hide water content is 45%-50%
(3) shavings (cutting flesh noodles): shaving thickness 1.6mm.
(4) the light shaving of secondary (cutting grain): cut grain, grain is stretched cut brokenly, complete opening cut.
(5) wet-milling: with No. 150 emery cloth buffings, complete opening is ground to, and destroys grain.
(6) weigh.As later raw materials used benchmark, percentage ratio meter by weight.
(7) return wet: tare weight 400% water, temperature 35 degree add 0.2% formic acid, 0.2% grease-removing agent rotates 45min, control water.
(8) washing: tare weight 400% water, temperature 35 degree rotate 10min, control water.
(9) retanning: tare weight 100% water, temperature 35 degree add 6% chrome tanning agent, rotate 90min, add 1% sodium formiate, rotate 30min, add 1.0% sodium bicarbonate, rotate 90min, pH=4.0-4.2.Change and stop in conjunction with spending the night control water.
(10) washing: tare weight 400% water, temperature 35 degree rotate 10min, control water.
(11) neutralization: tare weight 200% water, temperature 35 degree add in 1.5% and tannin, and 1% sodium formiate rotates 30min, adds 1.5% sodium bicarbonate, rotates 90min, pH=6.5, control water.
(12) washing: tare weight 400% water, temperature 35 degree rotate 10min, control water.
(13) stuffings, filling: tare weight 150% water, temperature 45 degree add 7% fatting agent, rotate 30min, add 5% vegetable tanning agent, rotate 30min, add 1.5% formic acid, rotate 30min, pH=3.8.Control water.
(14) wash, go out drum: tare weight 400% water, temperature normal temperature rotates 10min, control water.Triplicate goes out drum.
(15) primary drying: adopt vacuum-drying moisture to the skin to be down to 40%.
(16) redrying: adopt drying tunnel to hang to dry and dry moisture in the skin is down to 16%.
(17) moisture regain: water spray, leave standstill, tare weight moisture is remained on about 30%.
(18) shake soft: adopt the vibration staking machine to handle.
(19) dry grinding: crust leather dry grinding, grind flesh noodles with No. 150 big buffing machines of emery cloth earlier, use No. 150 emery cloth little buffing machine abrasive particle neck surfaces and belly again, use the big buffing machine abrasive particle of emery cloth face then No. 250, use the big buffing machine abrasive particle of emery cloth face at last No. 400, do not have obvious pore, fine hair is carefully short, even substantially.
(20) weigh: weightening finish 300%, as later raw materials used benchmark, percentage ratio meter by weight.
(21) backwater: tare weight 400% water, temperature 35 degree add 0.8% ammoniacal liquor, and 0.1% permeate agent changes and stops in conjunction with spending the night control water.
(22) washing: tare weight 400% water, temperature 35 degree rotate 10min, control water.
(23) dyeing, secondary stuffing: tare weight 150% water, temperature 40 degree add 2.5% dyestuff, rotate 30min, add 7% fatting agent, rotate 30min, add 100% hot water, temperature is the 45-50 degree in making, and rotates 30min, add 0.8% formic acid, rotate 30min, pH=3.8, control water.
(24) dye on the top: tare weight 200% water, temperature 50 degree add 0.5% dyestuff, rotate 30min, add 0.3% formic acid, rotate 30min, pH=3.8, control water.
(25) wash, go out drum: tare weight 400% water, temperature normal temperature rotates 10min, control water.Triplicate goes out drum.
(26) drying: adopt drying tunnel to hang to dry in the air moisture in the skin is down to 18%.
(27) moisture regain: water spray, leave standstill, tare weight moisture is remained on about 30%.
(28) fall soft: fall soft 60-90min.
(29) other operations: spray dyestuff.
(30) row's chi, warehouse-in.
Claims (2)
1. wet ornamenting working method after the positive suede upper leather of pigskin is tanned is characterized in that comprising following operation:
(1) selects pigskin vamp wet blue leather: select to be combined tanning with other tanning agents for the leather of processing pig Ba Ge through chrome tanning agent tanning or chrome tanning agent;
(2) water squeezing: conventional operation;
(3) shavings: cut flesh noodles, thickness is with the many 0.1-0.4mm of finished product pig Ba Ge thickness;
(4) the light shaving of secondary: cut grain, cut with complete opening, grain is stretched to cut brokenly be advisable, thickness is not changed to some extent;
(5) wet-milling: the wet blue leather buffing, with the 80-200 emery cloth, demand perfection to open is ground to, and destroys grain;
(6) weigh, return wet, washing, retanning, washing and neutralization, general in and between the pH to 5.0-6.5;
(7) washing;
(8) stuffings, filling: a small amount of stuffing, the fatting agent total amount accounts for the 3-8% of tare weight; The stuffing later stage adds the vegetable tanning agent of tare weight 2-5% and fills; This step stuffing amount by quality ratio;
(9) wash, go out drum;
(10) primary drying: adopt vacuum-drying or paste drying that moisture in the skin is down to 30-40%, by quality ratio, require grain flat thin;
(11) redrying: employing nature extension dries in the air or the drying tunnel extension dries in the air is down to 14-18% with moisture in the skin, by quality ratio;
(12) moisture regain: tare weight moisture is remained on about 30% ± 5, by quality ratio;
(13) shake soft: adopt the vibration staking machine to handle, softness is advisable to be fit to buffing;
(14) dry grinding: the crust leather dry grinding, adopt the 150-400 emery cloth, the gradation buffing, emery cloth variation from coarse to fine, first mill flesh noodles, abrasive particle face then is during the abrasive particle face, directly with the direct buffing of big buffing machine, or earlier with little buffing machine edging belly and neck neck, adopt the method for whole buffing of big buffing machine then, require no obvious pore, fine hair is carefully short, even substantially;
(15) weigh, backwater and washing;
(16) dyeing, secondary stuffing, secondary stuffing will consider to deduct that part of stuffing amount that has added in stuffing operation;
(17) top is dyed, is washed and goes out drum;
(18) drying: adopt vacuum-drying and extension to dry dryly to combine, paste drying dries dry combining with extension, perhaps extension dries dry;
(19) moisture regain: tare weight moisture is remained on about 30%, by quality ratio
(20) fall soft, row chi and warehouse-in.
2. wet ornamenting working method after the positive suede upper leather of a kind of pigskin according to claim 1 is tanned is characterized in that: described step (20) is fallen also has other technologies between soft row's chi, these other technologies are for the spray hand feeling agent and/or spray dyestuff.
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CN107338337A (en) * | 2017-09-04 | 2017-11-10 | 焦作隆丰皮草企业有限公司 | A kind of preparation method of sheep shearing wax change effect leather |
CN107604107A (en) * | 2017-09-20 | 2018-01-19 | 安徽乐踏鞋业有限公司 | A kind of drying means of chrome tanning leather |
CN108018384A (en) * | 2017-12-20 | 2018-05-11 | 海宁卡森皮革有限公司 | A kind of production method of high strength flexible ox-hide sofa artificial leather |
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CN107338337A (en) * | 2017-09-04 | 2017-11-10 | 焦作隆丰皮草企业有限公司 | A kind of preparation method of sheep shearing wax change effect leather |
CN107338337B (en) * | 2017-09-04 | 2020-01-31 | 焦作隆丰皮草企业有限公司 | Preparation method of cashmere wax variation effect leather |
CN107604107A (en) * | 2017-09-20 | 2018-01-19 | 安徽乐踏鞋业有限公司 | A kind of drying means of chrome tanning leather |
CN108018384A (en) * | 2017-12-20 | 2018-05-11 | 海宁卡森皮革有限公司 | A kind of production method of high strength flexible ox-hide sofa artificial leather |
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