CN103274556B - The High-capacity waste water degradation reactor of the photocatalyst main inducement parameter Auto-Sensing of reunion - Google Patents

Abstract

The present invention relates to the High-capacity waste water degradation reactor of a kind of photocatalyst main inducement parameter Auto-Sensing of reunion, belong to technical field of waste water processing.In existing related background art, having that nano photo-catalytic runs off, microwave energy waste, reactor list tank wastewater treatment capacity is less than normal and internal liquid systemic circulation intensity not enough, degradation reaction terminal moment difficulty is distinguished, agglomeration thing cannot strength dissipates in situ, agglomeration occurs immediately to be perceived etc. problem, this case is for above-mentioned series of problems.This case retrains microwave with metal cage, is achieved in the significantly dilatation of reactor；Its structure of this case also strengthens internal liquid systemic circulation；Its external cascade filter is beneficial to the fine interception for catalyst particles；Its structure energy strong catalyst agglomerate in situ, the most incidentally ultrasonic clean quartz ampoule；Its structure also automatic immediate can close line related when degradation reaction reaches terminal；Its structure and can Auto-Sensing agglomeration main inducement parameter.

Description

The High-capacity waste water degradation reactor of the photocatalyst main inducement parameter Auto-Sensing of reunion

Technical field

The present invention relates to the High-capacity waste water degradation reactor of a kind of photocatalyst main inducement parameter Auto-Sensing of reunion, belong to C02F Technical field of waste water processing.

Background technology

Microwave and photo catalysis degradation treatment technology, as a kind of effective for the harmless treatment skill containing organic pollution industrial wastewater Art, the most interesting.

About microwave and photo catalysis degradation technique, as an example, may refer to the Chinese patent Shen of Publication No. CN102260003A Please case.

The disclosure number is the Chinese patent application case of CN102260003A, is using microwave as excitaton source, excites electrodeless ultraviolet lamp Launching ultraviolet, irradiate the suspension mixed with photocatalyst titanium dioxide in liquid internal, this electrodeless ultraviolet lamp is by quartz ampoule institute cage Cover protects, and is free air pump persistently to inject air to this quartz ampoule inner chamber, quartz cavity the air overflowed via pipeline be positioned at anti- Answering the micro porous aeration head UNICOM bottom device, the lower zone of this inside reactor is aeration zone, the upper area of this inside reactor Being microwave and photo catalysis reaction zone, the program also with the membrane separation assemblies that reactor is built-in, carries the water after analysis purifies, and with this film Separation assembly realizes retaining of photocatalyst titanium dioxide fine particles and uses；The program also non-polar ultraviolet light source and membrane separation assemblies it Between set up dividing plate, for preventing the ultraviolet radiation damage to organic membrane separation assemblies；It is passed through the air of inside reactor, Part the most directly participates in relying on the photocatalytic degradation of photocatalyst titanium dioxide to react, some air, direct at ultraviolet light Under irradiation, generating a certain amount of ozone, the ozone of this generation the most also plays the direct oxidative degradation for organic pollution Effect.

The disclosure number is that the Chinese patent application case of CN102260003A is certainly for microwave and photo catalysis wastewater degradation technology Progress serves very important impetus, and the work that its research staff is launched in this field is admirable.

Meaning based on sincere admiration, and, common striving direction, to be talked below us is problem.

The problem below will spoken of, has 11；These 11 problems are arranged side by side 11 problems；The priority of its sequence Consider easily merely for the sake of discussing.

One of problem:

The disclosure number is the Chinese patent application case of CN102260003A, and it divides for the film intercepting catalyst titanium dioxide fine particles It is to be placed in reactor inner chamber from assembly, is immersed among process object liquid, and relies on washing away containing ozone bubbles of ascension Membrane separation assemblies, the institute's catalyst particles that adsorbs, be detained that thereby removes its surface, reach the recovery of catalyst particles, recycling Purpose, meanwhile, it is self-cleaning and keep its separating power that membrane separation assemblies is also dependent on this mode, then, based on this structure, only Business curtain hollow fiber film assembly or plate film assembly can be selected, and, this membrane separation assemblies is to need to be immersed in ozone In the context of the strong oxidizing property of bubble ascension, therefore, the tolerance against oxidative power of membrane separation assemblies is necessarily required, common material The organic membrane separation assembly of matter is not resistant to such use environment, therefore can only select the membrane separation assemblies of PVDF material, this Point clearly illustrates in the 0009th section of word of this case disclosure and claim 3；This kind needs special tolerance against oxidative power Its material of filter membrane is relatively costly, and its commercially available price is certainly also above common organic micro-filtration membrane module of non-oxidation durability requirements；Change Sentence is talked about, and the frame mode of this case causes the material of membrane separation assemblies to be limited to PVDF material costly.Further, dress Putting interior possible ultraviolet light to reveal, may touch organic membrane assembly, this organic membrane assembly material also required that in device can be resisted Ultraviolet light irradiation, from the point of view of this, organization plan based on this device, the material of organic membrane separation assembly also can only be limited in PVDF material costly.

Organic membrane assembly, compared to ceramic filter assemblies, has its obvious advantage；About this point, special for filtering technique For the personage of industry, it is known, does not the most launch to repeat.

So, under the premise using organic material membrane module, this PVDF filter membrane material limitation can be bypassed？This is One needs the problem solved, and this is one of problem.

The two of problem:

In view of scouring force, the cleaning capacity of described ascension bubble are more weak, therefore, with this cleaning mode with the use of membrance separation The filter opening aperture of bigger microfiltration rank can only be selected in its aperture of assembly, and the filter opening aperture of this microfiltration rank is 0.1-0.2 micron, About this point, have in the 0009th section of word of this case disclosure and claim 3 equally and clearly limit, this kind of filter opening aperture Limit, from the type selecting of the such membrane separation assemblies of this case, built-in and soak from the point of view of occupation mode, the self-cleaning method of ascension bubble, be Inevitable, its filter opening aperture can only be limited in microfiltration rank.In other words, this in the way of ascension bubble washes away its scouring force, Cleaning force is the most weak, to such an extent as to cannot tackle the filter membrane of more small-bore at all, and thus, in this case device, filter sizes limits Between 0.1 micron-0.2 micron, it it is the inevitable choice not discussing leeway.

The filter opening aperture of so-called 0.1-0.2 micron, if changing a measurement unit, corresponding is exactly the filter opening hole of 100-200 nanometer Footpath；That is any concept？For 100 nanometer filter opening apertures of its lower limit, its size of catalyst particles that it can intercept Must be more than 100 nanometers, and cannot be intercepted less than the catalyst particles of 100 nanometers；In other words, less than 100 The catalyst particles of nanometer by being directed through, by the filter opening of membrane module, be mixed into so-called water purification that degradation reaction device exported it In.

Need now to have a talk the particle diameter of photocatalyst involved by ultraviolet catalytic degradation reaction and photocatalyst dosage form selection.

The professional person being engaged in photocatalytic degradation research both knows about, and reacts with the photochemical degradating of uv light induction, and its catalyst is many Select titanium dioxide fine particles catalyst；At present, laboratory level has been developed for various in style urging based on titanium-dioxide photo Changing the light degradation particle catalyst of characteristic, certainly, the light degradation catalyst that these different preparation methods are formed, its particle diameter is also It is various；Its particle diameter of photocatalyst that different preparation methoies are made is little to 20 nanometers, greatly to 100000 nanometers namely 100 microns, Have, be wherein no lack of the photocatalyst kind of excellent performance；But, due to performance long-time stability evaluate, preparation cost and The restriction of market expansion etc. aspect factor, most of its deliverability of described photocatalyst is limited only to laboratory level, And do not have to form the most commercially available level of production；The most known can make a big purchase in large quantities commercially available can be actual a large amount of The photocatalyst for ultraviolet light wave band used is famous gas phase titanium dioxide P25；Its concrete skill of gas phase titanium dioxide P25 Art implication, insider both knows about, and does not the most launch to repeat；The mean diameter of gas phase titanium dioxide P25 is 21 nanometers；Gas Phase titanic oxide P25 performance not very optimum, but, its stable performance, it is important to can commercially make a big purchase in large quantities and obtain, and Can use the most in a large number, therefore, the most usually be used as weighing respectively with P25 catalyst in photocatalysis specialized laboratory Plant reference pointer or the contrast pointer of self-made photocatalyst catalytic performance, it is true that in view of the feature of ultraviolet catalytic degradation reaction, The photocatalyst that dispersion is the highest, is suitable for the needs of this type reaction, say, that mean diameter is at the light of 21 ran Catalyst its catalyst interfacial area that can provide, anti-settling ability, catalytic performance long-time stability etc. aspect, comprehensive and Speech, is optimal.Simply, at present, good and cheap, it is possible to the actual ready-made commercially available business making a big purchase in large quantities, using The photocatalyst of the ultraviolet light wave band of grade, it is simply that mean diameter is the gas phase titanium dioxide P25 catalyst of 21 nanometers；In industry The application of scale, this mean diameter be the photocatalyst of 21 nanometers be actual first-selection.

Already described above and, the disclosure number is the Chinese patent application case of CN102260003A, and it is for intercepting the film of photocatalyst Assembly, is the catalyst particles that stripping film assembly surface adsorbs, deposits that washes away with ascension bubble, but, this kind is to rise Rise its scouring force of mode that bubble washes away, cleaning force the most weak, to such an extent as to the filter membrane of more small-bore cannot be tackled at all, therefore, In this case device, filter sizes is limited at microfiltration filter opening rank between 0.1 micron-0.2 micron, for changing a measurement unit, In this case device, filter sizes is limited at the microfiltration filter opening rank between 100 nanometer-200 nanometers, and this is not discuss leeway Inevitable choice；This case certainly cannot intercept as above flat without the microfiltration filter opening between selectable 100 nanometer-200 nanometers All particle diameters are the gas phase titanium dioxide P25 granule of 21 nanometers；So, if using P25 photocatalyst, this catalyst will completely Cannot intercept, and flow in so-called water purification, form secondary pollution, certainly also result in the heavy losses of catalyst and unrenewable； Even if using the titanium dioxide optical catalyst of the big particle diameter special for this of other kind, it collides because of mutual during using Or collide with wall, inevitable also can produce a large amount of small particle fragment, wherein particle diameter is less than the fragment of 100 nanometers, equally can not be by Microfiltration filter opening between 100 nanometer-200 nanometers is intercepted, these fractionlets also can through its membrane module enter so-called water purification it In, form secondary pollution.

Visible, the disclosure number is the Chinese patent application case of CN102260003A, and it is for the interception structure of photocatalyst microgranule The cleaning solution of scheme and related film assembly is the most undesirable.

Therefore, how under the premise of this case advantage of incorporating things of diverse nature, reach the fine interception for photocatalyst microgranule and return Receiving use again, be a important topic the most worth thinking deeply about, this is the two of problem.

The three of problem:

It is known that liquid water body itself also is able to absorb the energy of microwave, and cause the liquid water body that is processed itself Temperature-rise effect, and this with wastewater treatment process the temperature-rise effect that occurs, be not the most our situation of being expected, in other words Saying, the microwave energy from magnetron is used for exciting electrodeless ultraviolet lamp the most completely, and has quite a few should be served only for swashing The microwave energy sending out electrodeless ultraviolet lamp is dissipated in described temperature-rise effect, and it is unnecessary that the temperature-rise effect that this kind is not fond of causes Microwave energy waste, in view of disclosed above number be CN102260003A the apparatus structure side that shown of Chinese patent application case Case, its rational approach, can only be to reduce single tank process capacity in other words by the volume of minimizing microwave and photo catalysis reactor to come Reach the purpose weakening the unnecessary dissipation of microwave, about this point, in this its detailed description of the invention of CN102260003A application case Clearly have expressed the suitable size overall about this apparatus structure, what its expressed preferred size was corresponding is exactly that a profile is the least Device, then, consequently, it is possible to the distance of reactor wall and microwave radiation source is little, the wastewater flow rate contacted with microwave is little, The microwave energy that waste water is absorbed is the least, corresponds ground, and the wastewater treatment capacity of single tank is the least, more specifically Ground is said, the internal capacity corresponding to device suitable size expressed in embodiment is 40 liters, namely single tank wastewater treatment capacity is 40 liters, i.e. 0.04 cube, in other words, its once a complete set of, substantial length of operation solve only the industrial wastewater of 0.04 cube, then, Being accomplished by the repetition operated by a complete set of head to tail carried out many times, the cumulative of its treating capacity just has plant-scale meaning, So to say, the most individual analogy substantially, 0.04 cube of such waste water of single tank that its preferred structure size of this case is generally corresponding to Treating capacity, need to repeat 1000 times by a complete set of head to tail, substantial length of operation, its accumulation amount, can be only achieved 40 cubes such one Individual have industrial level wastewater treatment capacity, the most loaded down with trivial details repetitive operation will cause the serious waste of human and material resources, Visible, the wastewater degradation treatment effeciency of its reality of scheme that this kind is shown by CN102260003A may not be fully up to expectations. Therefore, how on the premise of not causing the waste of more microwave energy or reducing microwave energy waste, increase single tank wastewater treatment capacity, Reduce the unnecessary too many by the repetitive operation number of times of head to tail of this batch (-type) wastewater treatment equipment, improve its waste water and process effect Rate, is a significant technical problem merited attention, and this is the three of problem.

The four of problem:

The scheme that this kind is shown by CN102260003A, the bubble of the internal unrestrained cloth ascension of its retort, for driving a reaction tank The shuttling movement of the relatively large yardstick of internal liquid, contributes the most inadequate；Certainly, this weak point, for CN102260003A In scheme such as its detailed description of the invention the fact that clear expression for upper corresponding small size, low capacity device, almost without what Observable impact.From the point of view of plant-scale application demand, undersized can not the device of divergence process amount certainly the most much Captivation；So, as a kind of probability, if there being certain mode to be capable of the significantly expansion for the treatment of capacity, under this situation, Its importance of shuttling movement of the relatively large yardstick of retort internal liquid will highlight naturally；Imagine the most this process The probability that amount is significantly expanded, then, how to strengthen the shuttling movement of the relatively large yardstick of retort internal liquid, be certainly exactly Individual problem, this is the four of problem.

The five of problem:

For the photochemical catalysis oxidation reaction of ultraviolet light wave band, this kind of oxidation is anti-to have the most several following key element to influence whether The efficiency answered, first ultraviolet wavelength, intensity, it two is photocatalyst in the particle diameter of photocatalyst, unit volume reactant liquor Usage amount, himself catalytic performance etc. of photocatalyst, it three is organic concentration in oxidized object i.e. water body, has Oxidation complexity that machine thing molecular structure is determined himself etc., it four is the sufficient degree of oxygen atmosphere, in other condition In the case of identical, the sufficient degree of oxygen atmosphere, will become and affect an act foot of photochemical catalysis oxidative degradation ability gently The key element of weight.

The scheme shown such as CN102260003A, its numerous micro porous aeration heads being placed in reactor inner chamber bottom overflow cloth the end of at Portion, and by its alleged water distributing plate so that this micro porous aeration head overflows the effect of cloth arrangement and becomes more very, certainly, this for For using the situation of oarse-grained micron-sized photocatalyst of relatively easy sedimentation, really there is its favourable one side, but, From the point of view of another side, this micro porous aeration head overflows the mode that cloth arranges, and the supply of oxygen atmosphere excessively disperses, and needs most The region that need to strengthen oxygen supply is the most effective region of photochemical catalysis oxidation, due to effective in liquid water body of short wave ultraviolet Penetration depth only has 20 cm, therefore, needs most enhanced oxygen blowing real with the effective coverage promoting photochemical catalysis oxidation course It is exactly the region within quartz ampoule periphery about 20 cm distance on border, in other words, within quartz ampoule periphery about 20 cm distance Region be the region really needing the supply of enriched with oxygen atmosphere to ensure, oxygen atmosphere supply in this region is the strongest, and oxidation reaction is also Just it is proceeded more quickly；The most especially, producing electrodeless ultraviolet emission in microwave excitation mode, its feature can be accomplished greatly exactly Power, high intensity, this is the strong point of this lamp-type of electrodeless ultraviolet lamp, but, just because of its purple extraradial high power, high-strength Degree, just mates with greater need for powerful oxygen atmosphere supply capacity, and otherwise, that powerful ultraviolet radiation energy power is just Really major part is wasted.Above it is stated that, the scheme shown such as CN102260003A, factors limits Its reactor size, limits its actual treatment capacity, as its specific embodiment clearly illustrates, that Can be a single tank single treatment amount little reactor that only has about 40 liters, in the case of such little reactor, little inner chamber, Because size is the least, then, its shortcoming in terms of photochemical catalysis oxidation effective coverage oxygen supply concentration degree, would not The most obvious, it might even be possible to ignore, a problem the most non-existent can be regarded the most completely as, in the face of such Undersized little reactor, the shortcoming problem in terms of oxygen supply concentration degree, not may float mind；However, it is contemplated that Once, if described many limiting factors can be overcome, if can have that way actual implementation one is large-scale, high throughput anti- Answer device, then within above-mentioned quartz ampoule periphery 20 cm distance, effective coverage oxygen supply strengthening problem will show especially out, particularly with Using electrodeless ultraviolet lamp as the situation of UV source, within above-mentioned quartz ampoule periphery 20 cm distance, effective coverage oxygen supply is strengthened Problem is not more allowed to despise, therefore, how among the structure of possible large-scale photo-catalytical oxidation degradation reaction device, Strengthen the oxygen supply concentration degree of described effective coverage, improve the usefulness of wastewater degradation equipment, it is simply that the problem that individual needs are kept a close watch on, this is The five of problem.

The six of problem:

Within this CN102260003A scheme pumps air into the quartz ampoule including electrodeless ultraviolet lamp, reach the logical of electrodeless ultraviolet lamp Wind cooling, the purpose of cooling, and those flowings are through the air of quartz ampoule, because of by ultraviolet irradiation, some air meeting Being changed into ozone, therefore, the air flowed out from quartz ampoule is exactly the air containing some ozone certainly, and this is contained smelly by the program Oxygen air is transferred to be positioned at micro porous aeration head below reactor, and disengages from micro porous aeration head, these containing ozone bubbles from lower On ascension during, ozone contained therein can meet with the organic molecule that runs among distance and redox reaction occurs, This redox reaction can consume a part of ozone certainly, this be do not have doubt, but, above it is stated that, as The scheme that CN102260003A is shown, the many factors that cannot ignore certainly existed limit its reactor size, Limiting its actual treatment capacity, as clearly illustrating in its specific embodiment, that can only be a single tank single Treating capacity only has the little reactor of about 40 liters, in the case of such little reactor, little inner chamber, because overall dimension itself The least, then, the longitudinal size of its reactor inner chamber or regard as with reckoning in every item contain the liquid degree of depth also can only be one the least Size, clearly illustrates among this size such as its detailed description of the invention, the most about 40 centimetres, and the Sheng that reckons in every item liquid is deep Spend the most only 40 centimetres, actually contain the liquid degree of depth and be certainly less than this number, just analyze with the Sheng liquid degree of depth of 40 centimetres, that , this Sheng liquid degree of depth of 40 centimetres is what concept？That is to say, containing ozone-air ascension by the path of waste water only Having short 40 centimetre, this path is the shortest, passes through at a gallop containing ozone-air bubble and only only has 40 centimetres of deep water bodys, The shortest for time of contact with water body, contained in bubble ozone, can only have small part to be used for oxidative degradation Organic substance, And most ozone actually simply passes by liquid simply, effusion emptying through exhaust port from liquid level, briefly, The Oxidation potentiality major part of these ozone is wasted, and, effusion, the ozone that is wasted actually can cause need not The air pollution wanted；This case main inventive people once beat via micro porous aeration head with normal domestic use ozone machine in one meter of deep tank Enter containing ozone-air, in the case of the depth of water degree of depth reaches one meter, remain able to substantially smell the abnormal smells from the patient of ozone near the water surface, can See, that 40 centimetres of deep Sheng liquid degree of depth, it is clear that be to be not enough to fully utilized ozone；Visible, electrodeless ultraviolet light chemistry is urged For changing the such equipment of wastewater degradation reactor, ozone utilizes incomplete problem to be also required to pay close attention to, it is clear that Ren Mengeng It is contemplated that the reactor of wastewater degradation without extreme ultraviolet that ozone utilizes more completely, contaminative exhaust emissions is less, this is the six of problem.

The seven of problem:

Its running of waste water catalytic degradation reaction device, requires the expenditure of energy, and therefore, operator are bound to wish, work as wastewater degradation When reaction proceeds to terminal, it is possible to impartially, the most lately immediately stop continuing to inject to inside reactor Energy；If the moment stopping Implantation Energy is too early, then wastewater degradation is incomplete；And if reaching reaction end already, the most still The most unceasingly to inside reactor Implantation Energy, that is certainly the energy in waste preciousness.As this case technical background Its structure of CN102260003A scheme can not provide any instant information to the wastewater degradation reaction end moment, then, just The terminal that wastewater degradation reacts can only be estimated by experience；And estimate, by experience, the terminal that wastewater degradation reacts, that obviously can not Satisfactory；So, how to make neither the most undelayed instant information output for the wastewater degradation reaction end moment, And immediately close the energy input to reactor in the just right moment, it is simply that a technical threshold that can not despise, this is The seven of problem.

The eight of problem:

Accept the described industrial wastewater of microwave and photo catalysis degradation treatment, be mingled with some the most unavoidably and originate from mechanical system abrasion process The material of metal particle and carbon granules etc, even if quantity is small, its existence is almost difficult to avoid that, the disclosure number is Described organic membrane separation assemblies in the Chinese patent application case of CN102260003A is installed in microwave and photo catalysis reaction zone, its In be installed between quartz ampoule and membrane separation assemblies certainly do not stop microwave for intercepting the dividing plate of ultraviolet, so, micro- The practical function region of ripple necessarily covers organic membrane separation assemblies institute installation area described in the program, based on membrane separation assemblies Working mechanism, its accumulation process on membrane separation assemblies organic matter top layer of the microgranule of metal particle as above and carbon granules etc It is difficult to avoid that, and the microgranule of this type of described metal particle and carbon granules etc, exactly the good absorption medium of microwave energy, inhale The microgranule of described metal particle and the carbon granules of having received the accumulation state of microwave energy etc, its organic plasma membrane being close to can be divided by nature Produce from the top layer of assembly and based on heat penetration erosion mechanism lasting pierce destruction, be as noted previously, as this CN102260003A The structures shape of its device of application case can only select polyvinylidene fluoride film material, this polyvinylidene fluoride film material heatproof about 140 degrees Celsius, More certain than general film material heatproof high much, but, described metal particle and carbon granules of absorbing the accumulation state of microwave energy etc Its point-like of microgranule pierce the heat penetration erosion effect of formula and the most easily break through the heatproof temperature limit of this polyvinylidene fluoride film material, due to above-mentioned former Cause, well imagines, the pvdf membrane material in this its device of CN102260003A application case its actual life will be the lowest In the preferable service life expected, the structure of this CN102260003A its device of application case, determine in this structural frames Under frame, above-mentioned point-like pierce formula heat penetration erosion destruction problem cannot avoid；Therefore, how to get around this point-like and pierce the heat penetration erosion of formula Destruction problem, also needs to consider, and this is the eight of problem.

The nine of problem:

The disclosure number is the Chinese patent application case of CN102260003A, the 0008th section of word of its description disclosure text And claim Section 2, the catalyst particle size scope being suitable for for its device, there is a restriction, this particle size range limits It is that 20 nanometers are to 100 microns.It is known that some pH value be pre-adjusted not in place, pH value inappropriate in the case of, Titanium dioxide fine particles is susceptible to reunite, and then affects its effective working interface area, affects its photocatalysis usefulness；Particularly with The section of those the relatively small particle diameters among this particle size range, easily occurs because of presetting not in place, the pH value of pH value not especially The agglomeration traits appropriately caused；For this catalyst particles in the case of of reuniting, it is immediately to adopt an effective measure, enters The depolymerization of aggregate is operated by the hand-manipulating of needle；But, we, among this CN102260003A scheme, do not see any having Help immediately dissolve the structure of this problem or can immediately dissolve the scheme prompting of this problem.For such as CN102260003A scheme can only be the reactor of small scale structures because factors limits just like that, still can the most directly carry React device, carries out toppling over and inspecting outside reactor, process above-mentioned reunion situation, then, hold if likely expanding it Amount, the most so to say, if being the several cubes of large-scale reactors to dozens of cube or huge reactor, that is the most not It is manual to topple over it and operate the problem that can tackle, then, for this catalyst particles in the case of of mutually reuniting, how Realize instant disposal in situ, it is simply that a technical problem, this is the nine of problem.

The ten of problem:

The disclosure number be CN102260003A Chinese patent application case expressed by apparatus structure in, protect electrodeless purple for screen The quartz ampoule of outer lamp, its outer wall, refer to the outer wall of quartz ampoule, through for a long time with the contacting, unavoidably of processed industrial wastewater Gradually dirty, the material that dirt amasss the most mainly is difficult to the mineral-type impurity touched by light-catalyzed reaction, because of the formation of this mechanism Dirty phenomenon, is easy to be observed after equipment long-play；It is attached to the dirty lamination of described quartz ampoule outer wall, although The veryyest thin one layer, also be enough to cause the ultraviolet radiation of electrodeless ultraviolet lamp significantly stop, and this will cause this microwave light to be urged The actual treatment effect changing reaction treating device significantly reduces；In its reactor, the bubble of unrestrained cloth ascension is because excessively disperseing, scouring force Measuring more weak, if only relying on this more scattered bubble to maintain the bright and clean of quartz ampoule surface, really undertaking to do what is apparently beyond one's ability, in other words Saying, this more scattered bubble, what it was more weak wash away strength is still not enough to stop completely the dirty process on this quartz ampoule surface；? During the use of laboratory yardstick, above-mentioned fouling problem is subtle, but, on commercial Application yardstick, this fouling problem Certainly will highlight；Therefore, how on the premise of not tearing machine open, immediately, effectively remove on this quartz ampoule outer wall Dirt lamination, maintains the lasting high efficiency of this microwave and photo catalysis processing means, and this problem is the most very important, and this is the ten of problem.

The 11 of problem:

Nine its problems derived of this problem problem by addressing above.Above speak of, some pH value be pre-adjusted less than In the case of position, pH value are inappropriate, titanium dioxide fine particles is susceptible to reunite, and then affects its effective working interface area, Affect its photocatalysis usefulness；Particularly with among its suitable catalyst particle size range that this CN102260003A scheme is touched upon The section of those relatively small particle diameters, easily occur especially because of pH value presetting not in place, pH value is incorrect and the group that causes Poly-problem；For this catalyst particles in the case of of reuniting, it is immediately to adopt an effective measure, carries out for aggregate Depolymerization operates；Based on this its framework of CN102260003A scheme, operator cannot immediately perceive inside reactor and institute occurs State the situation of reunion, thus also cannot make instant disposal, thus, should be limited by factors and can only be small scale structures Its limited usefulness of reactor can reduce further；Therefore, among the application of reactor operates, particularly, for example, Among the application of possible large-scale reactor or huge reactor operates, the most immediately awareness inside reactor catalyst particles The main inducing parameter reunited, is a key issue, and this is the 11 of problem.

Summary of the invention

The technical problem to be solved is, for one of problem addressed above, two, three, four, five, six, seven, Eight, nine, ten, 11, research and develop a kind of novel waste water microwave and photo catalysis degraded that can solve described series of problems totally Processing means.

The present invention solves described technical problem by following scheme, and the program provides the main inducement parameter of a kind of photocatalyst reunion automatically to detect The High-capacity waste water degradation reactor surveyed, the structure of this reactor includes a container, and its appearance profile of described container is cube Shape, cuboid, cylindrical, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form, at described container intracavity Bottom position be equiped with many micro porous aeration head, and, quartz ampoule, this quartz ampoule is erected at the cavity position of described container, The two ends of this quartz ampoule are equiped with closure headkerchief, lay respectively at and all offer ventilation on the described closure headkerchief at quartz ampoule two ends and connect Mouthful, and, electrodeless ultraviolet lamp, this electrodeless ultraviolet lamp is bar-shaped, ring-type, spherical, Asterias amurensis Lutken shape or Hemicentrotus seu Strongylocentrotus shape, and this is without extreme ultraviolet The quantity of lamp is at least at more than one, and this quantity is at least in more than one electrodeless ultraviolet lamp is all erected at described quartz ampoule Portion, and, air pump, this air pump is installed in the outside of described container, the ventilation on described quartz ampoule one end seal blanking cover head Interface couples via breather line and through described wall of a container with the gas outlet of described air pump, its another end seal of described quartz ampoule Ventilation interface on blanking cover head couples with the micro porous aeration head being positioned at bottom described container intracavity via another breather line, with And, microwave generator, this microwave generator is installed in the outside of described container, and this microwave generator is magnetron, and, ripple Conduit, this waveguide is the component for transmitting microwave, one end of this waveguide and described magnetron UNICOM, this waveguide another One end passes through the described wall of a container inner chamber towards described container, and, water pump, this water pump is for the inner chamber pump of described container Sending the described waste water containing organic pollution, this water pump is positioned at the outside of described container, and the outlet of this water pump is via ventilating water pipe also Lead to the inner chamber of described container through described wall of a container, the top of described container offers exhaust port, it is important that, this ripple That one end through described wall of a container of conduit extends much further into the inner chamber of described container, and this gos deep into described container intracavity That one end of waveguide and further a closure headkerchief through described quartz ampoule probe into the inside of quartz ampoule, and, should The structure of reactor also includes the microwave constrainer of the caged of metal material, containing many holes in the microwave constrainer of this caged Or mesh, the function of the microwave constrainer of this caged is constraint microwave, contains its unhelpful dissipation, simultaneously, it is allowed to major part ultraviolet Light penetrates, and the installation position of the microwave constrainer of this caged is positioned at the inside of described quartz ampoule, and the microwave constrainer of this caged is in it That one end UNICOM probeing into quartz ampoule of chamber and described waveguide, described in be erected at the electrodeless ultraviolet lamp within quartz ampoule the most described The microwave constrainer of caged is rolled in wherein, and, circulating guide, the function of this circulation guide is that pack is from micro-pore aeration The ascension path containing ozone-air bubble of head, and the strength that pulls by the bubble stream of the ascension because being strengthened by pack leads Described container internal liquid makees the shuttling movement of relatively large yardstick, and this circulation guide is installed in the cavity position of described container, should Circulation its profile shape of guide is like the through simple cone in two ends, and its osculum end of this circulation guide vertically upward, draw by this circulation Leading its big opening end of device vertically downward, this its axis of circulation guide is mutually perpendicular to the inner chamber bottom surface of described container, and this circulation is drawn Its locations of structures of osculum end vertically upward leading device is in the underface of described quartz ampoule, this circulation guide vertically downward Lateral separation between its edge of big opening end and described container inner wall between 5 centimetres and 300 centimetres, this circulation guide Fore-and-aft distance between its edge of big opening end vertically downward and described container intracavity bottom surface between 5 centimetres and 100 centimetres, And, the micro porous aeration head of described many is to be installed in its big opening end edge of described circulation guide with gathering at described container intracavity Within the scope of bottom surface vertical projection is drawn a circle to approve, and, booster pump, it is micro-that this booster pump is mixed with a large amount of catalyst for supercharging pumping Water after the degraded of grain, its water inlet of this booster pump is via another ventilating water pipe and through described wall of a container and described container Inner chamber couple, and, the preposition prefilter of back flush type, this back flush type its water inlet of preposition prefilter and described supercharging The outlet of pump couples, and, back flush type doughnut membrane microfiltration filter, it is clean for the preposition prefilter of described back flush type Water out couples via the water inlet of first water purifying valve with this back flush type doughnut membrane microfiltration filter, and, backwash Formula hollow-fibre membrane ultra filtration filter, described back flush type doughnut its pure water inlet of membrane microfiltration filter is via second water purification Valve couples with the water inlet of this back flush type hollow-fibre membrane ultra filtration filter, this back flush type hollow-fibre membrane ultra filtration filter its The entrance point of pure water inlet and the 3rd water purifying valve couples, and the water side of the 3rd water purifying valve is the water outlet of outlet terminal water purification End, described back flush type its outlet of sewer of preposition prefilter couples with the inner chamber of described container via first sewage valve, described Back flush type doughnut its outlet of sewer of membrane microfiltration filter couples with the inner chamber of described container via second sewage valve, described Back flush type hollow-fibre membrane its outlet of sewer of ultra filtration filter couples with the inner chamber of described container via the 3rd sewage valve, each institute Stating filter and be used to retain catalyst particles, each its outlet of sewer of described filter is all converted as being returned by retaining catalyst particles Receive and use delivery outlet again with delivery outlet or backflow again, and, ozone sensor, the sampling port of this its probe tube of ozone sensor is adjacent Nearly described exhaust port or probe into the inside of described exhaust port, and, ozone content display, ozone attention device or smelly Oxygen content display and the composite structure of ozone attention device, this ozone sensor shows via Article 1 cable and this ozone content Device, ozone attention device or ozone content display couple with the composite structure of ozone attention device, and, power-supply controller of electric, this is smelly Its output electric signal of oxygen sensor couples with this power-supply controller of electric via Article 2 cable, and this power-supply controller of electric is via Article 3 cable Coupling with described magnetron, this power-supply controller of electric couples with described air pump via Article 4 cable, and this power-supply controller of electric is can The power-supply controller of electric of on and off switch action is carried out according to its described electric signal received, and, ultrasonic transducer, this container Inner chamber bottom surface is the most hollow to central area by periphery, described its gradient hollow between 5 degree and 35 degree, this ultrasonic waves Can device be installed in its part vessel bottom wall corresponding to hollow bosom of this container intracavity bottom surface lateral surface position with attaching Or medial surface position, and, higher-order of oscillation electric signal transmission cable, one end of this higher-order of oscillation electric signal transmission cable surpasses with this Acoustic wave transducer couple, and, higher-order of oscillation electric signal generator, the other end of described higher-order of oscillation electric signal transmission cable with This higher-order of oscillation electric signal generator couples, and, pH pops one's head in, and, pH analyser, this pH probe and pH analyser Be coupled to each other, this pH analyser and coupling with siren, this siren for the pH value situation of transfiniting is sent alarm, this pH Probe stretches into described container intracavity through the top of described container, and, through the micropore rustless steel sleeve that powder sintering process is made, This micropore rustless steel sleeve is cap for brush shape, and this micropore rustless steel sleeve is positioned at described container intracavity, this micropore its envelope of rustless steel sleeve Down, upward, this its opening upward of micropore rustless steel sleeve is via buffer compartment for this micropore its opening of rustless steel sleeve for closed end Coupling with described container top from pad, this pH its that part stretching into described container intracavity of popping one's head in probes into this micropore stainless steel sleeve Within Tong, this its material of buffering isolating pad is fluorubber or silicone rubber.

Involved pH probe is commercially available；Described pH probe also known as pH sensor；PH probe or say itself skill of pH sensor Art is meant that known.

Involved pH analyser is commercially available；Itself art-recognized meanings of pH analyser is known.This case pH analyser one word is general Refer to pH can be utilized to detect, picking up, showing pH value information of any model, and can externally export pH and be correlated with electric signal Instrument, market is sold simple or complicated but all meet the pH correlate meter of this basic demand it is various in style, Can select as required.

Involved buffering its thickness of isolating pad does not limits；But, have a preferred range, the preferred scope of this buffering its thickness of isolating pad Between 1 millimeter to 8 millimeter.

Themselves art-recognized meanings of involved fluorubber and involved silicone rubber is known；Involved fluorubber and involved silicone rubber, city Field is the most on sale.

Involved micropore its wall thickness of rustless steel sleeve does not limits；But, also have an associated preferred scope, this micropore rustless steel The preferred scope of its wall thickness of sleeve is between 3 millimeters to 30 millimeters.

An involved powder sintered word, the art-recognized meanings of itself, for the professional of metallurgical technology field, is known.

Involved micropore rustless steel sleeve, can customize to relevant powder metallurgy specialized factory.

The sleeve-shaped micropore stainless steel filter conversion that can be made by powder sintering process is the micropore stainless steel sleeve described in this case Cylinder；The sleeve-shaped micropore stainless steel filter that described powder sintering process is made is commercially available.

The aperture of involved micropore rustless steel its micropore of sleeve does not limits；But, the aperture of this micropore is also to have a preferred range, should The preferred scope of micropore size is between 0.5 micron to 50 micron.

This its opening upward of micropore rustless steel sleeve couples with described container top via buffering isolating pad, refers to this connection Connecing is flexible connection, in place of this connection, has described buffer compartment mediate from pad.

Described siren is can to send audio frequency warning message or the device of optical frequency warning message according to its received electric signal； Itself art-recognized meanings of described siren is known；Described siren is commercially available.

Itself art-recognized meanings of ultrasonic transducer one word is known for the professional in ultrasonic technology field.

Itself art-recognized meanings of higher-order of oscillation electric signal transmission cable one word is for the professional in ultrasonic technology field Also it is known.

Ultrasonic transducer and higher-order of oscillation electric signal transmission cable market are the most on sale；Described ultrasonic transducer and higher-order of oscillation electricity Signal transmission cables etc. also can customize to ultrasonic transducer specialized factory and cable specialized factory.

Itself art-recognized meanings of higher-order of oscillation electric signal generator one word for the professional in ultrasonic technology field also It is known；Various higher-order of oscillation electric signal generator is commercially available；Described higher-order of oscillation electric signal generator also can be to ultrasound wave Equipment specialized factory customizes.

Involved ozone sensor is commercially available；Customize to ozone sensor specialized factory also dependent on needs.

Involved ozone content monitor market is on sale；Also dependent on needs to the customization of ozone content display specialized factory；Ozone passes Matching used ozone content display is generally also sold by sensor producer.

Involved ozone attention device, refers to warn that sound or alarm flashing or warning sound combines with alarm flashing that both are double And have for warning mechanism；Ozone attention device is commercially available；Also can be to the customization of ozone attention device specialized factory；Ozone passes Matching used ozone attention device generally also can be sold by sensor producer.

This power-supply controller of electric involved is the power-supply controller of electric that can carry out on and off switch action according to its described electric signal received； The power-supply controller of electric of on and off switch action can be carried out only with regard to its circuit engineering itself according to its electric signal received, be Through ripe, known technology；Described power-supply controller of electric is commercially available；It is possible with commercially available power-supply controller of electric to enter as required The row transformation of the way；Described power-supply controller of electric also can customize to power-supply controller of electric specialised manufacturers；The electronic device of power-supply controller of electric etc its Specialised manufacturers spreads all over the world.

In this case statement, retort one word refer to implication and described container one word to refer to implication identical；Described container simultaneously when It also it is so one of the main member of reactor.

Described metal material one word, the art-recognized meanings of itself, is known.

Described magnetron, and, waveguide device, its art-recognized meanings is known for the professional of microwave technical field. Described magnetron, and, waveguide etc., it is commercially available；Described waveguide can certainly self manufacture, this system as required Making for the professional of microwave technical field, the making of waveguide device is simple.

Described quartz ampoule, its art-recognized meanings is known；Described quartz ampoule is commercially available.

Described electrodeless ultraviolet lamp, its art-recognized meanings is known for the professional of light sources technical field；Described electrodeless purple Outer lamp is commercially available；Its shape of described electrodeless ultraviolet lamp, size, internal filled gas, lamp wall material, lamp wall thickness, etc. Deng, it is also possible to according to specific design needs, customize to electric light source manufacturing enterprise.It is of course also possible to self manufacture.Without extreme ultraviolet Making for possessing the professional of electric light source Professional knowledge of lamp, its manufacturing technology is simple.

Described water pump and booster pump, be all the pump for carrying clear or turbid all kinds of water, and certainly, its pumping pressure can As desired to select arbitrarily, and, various pump market is the most on sale；This case uses different names, is intended merely to conveniently Statement, the convenient pump distinguishing each different structure position.

Its material of microwave constrainer of this caged can be any selected metal, but, in view of it is residing by strong ultraviolet light The ozone gaseous mixture environment that radiation is formed, and, for the most defeated by complicated direct reflection mechanism as much as possible Going out considering of the ultraviolet light launched by electrodeless ultraviolet lamp, the preferred metal material being suitable to make the microwave constrainer of this caged is Through the punching rustless steel that mirror finish processes.

Can welded with bright finished punching corrosion resistant plate, splicing or mould pressing process make described microwave constrainer.

The microwave constrainer of this caged can certainly be made with the braiding of bright finished stainless steel silk.

For convenience of operating for the cleaning periodically carried out inside described container and maintenance etc., row can be offered in the bottom of described container Dirty mouth, this sewage draining exit is used for deslagging, removes contamination, and can install blowoff valve at this Location for Sewage, and described blowoff valve is for blowdown The valve controlled；If desired, it is possible to use described container internal liquid is emptied completely by this sewage draining exit being positioned at described container bottom. Described sewage draining exit and blowoff valve are not necessarily.

Described water purifying valve, sewage valve, blowoff valve, be all water valve, and various water valve market is the most on sale；About water valve, this word its The art-recognized meanings of body is known；This case uses different titles, is intended merely to conveniently state, conveniently distinguish each different structure The water valve of position.

The material of described circulation guide does not limits, and the material of described circulation guide can be such as politef material, glass Material, ceramic material, metal material, etc., but, circulation its preferred material of guide is rustless steel.

In this case device, by means of metal cage to the isolation in microwave exposure spatial domain and restriction effect, in metal cage outer wall and described appearance Region between device inwall, defines microwave zero irradiation zone or the weak irradiation zone of microwave, owing to microwave basically can not shadow Ringing to this region, the unhelpful dissipation of energy that microwave causes because the simple pyrogenicity of waste water absorbs in this region is contained, as This, no matter how this Domain Volume expands, and is all to allow；Based on this, the structure of this case device, it is allowed to expand significantly Single tank Design Treatment capacity of described reactor, it is allowed to expand the volume of reactor significantly, certainly, be to be come by metal cage Limit microwave exposure spatial domain, and the design volume in significantly spatial domain between expanded metal cage outer wall and described container inner wall realizes 's.

In this case structure, the micro porous aeration head of described many is to be installed in its big opening end edge of described circulation guide with gathering in institute State within the scope of vertical projection in container intracavity bottom surface drawn a circle to approve.Be positioned at the projection of described vertical drawn a circle to approve within the scope of described perhaps Many micro porous aeration heads, both can be tiling be installed in bottom described container intracavity and drawn a circle to approve within the scope of, certainly, at this Within the scope of individual delineation, it is also possible to take the most intensive another kind of installing mode, the most intensive described installing mode, refer to It is the micro porous aeration head of described many can be set in three-dimensional enterprising windrow superimposed, in this way they are gathered formation tool There is the cluster-shaped micro porous aeration head cluster of three-dimensional stacked framework；It is the hugest that this kind of cluster-shaped micro porous aeration head cluster can accommodate quantity Big micro porous aeration head；This kind of mode can carry bigger air flux.

The preferred scope in its filter opening aperture of the preposition prefilter of described back flush type is between 5 microns and 300 microns, certainly, It is also that this case is allowed that other preposition pre-filtering aperture outside this preferred scope selects；Described back flush type hollow-fibre membrane The preferred scope in its filter opening aperture of microfiltration filter is between 25 nanometers and 1000 nanometers, certainly, this preferred scope it It is also that this case is allowed that other outer microfiltration aperture selects；Described its filter opening aperture of back flush type hollow-fibre membrane ultra filtration filter Preferred scope be between 15 nanometers and 2 nanometers, certainly, other ultrafiltration aperture outside this scope selects also to be this Case is allowed.

The preposition prefilter of described back flush type is also referred to as back flush type fore filter or back flush type prefilter, described backwash Itself art-recognized meanings of the preposition prefilter of formula is known；The preposition prefilter of described back flush type is commercially available.

Described back flush type doughnut membrane microfiltration filter is adapted for the filter of microfiltration；Itself technology of described microfiltration one word It is meant that known；Itself art-recognized meanings of described back flush type doughnut membrane microfiltration filter is for technical field of membrane separation Professional for, be known；Described back flush type doughnut membrane microfiltration filter is commercially available.

Described back flush type hollow-fibre membrane ultra filtration filter is adapted for the filter of ultrafiltration；Itself technology of described ultrafiltration one word It is meant that known；Itself art-recognized meanings of described back flush type hollow-fibre membrane ultra filtration filter is for technical field of membrane separation Professional for, be known；Described back flush type hollow-fibre membrane ultra filtration filter is commercially available.

In ultrafiltration link, this back flush type hollow-fibre membrane ultra filtration filter can be that only a back flush type hollow-fibre membrane surpasses Filter the form of filter monomer；Certainly, this back flush type hollow-fibre membrane ultra filtration filter can also be at more than one by quantity Back flush type hollow-fibre membrane ultra filtration filter monomer parallel with one another couple composition.

Expressing an involved word in parallel, the art-recognized meanings itself referred to is clearly.

Express involved monomer one word, refer to itself function and structure equipment completely is individual.

Similarly, in microfiltration link, this back flush type doughnut membrane microfiltration filter can be an only back flush type hollow The form of fibrous membrane microfiltration filter monomer；Certainly, this back flush type doughnut membrane microfiltration filter can also be to be existed by quantity More than one back flush type doughnut membrane microfiltration filter monomer is parallel with one another couples composition.

At described back flush type doughnut its pure water inlet of membrane microfiltration filter and described back flush type hollow-fibre membrane ultra filtration Second booster pump can be installed on the connecting pipeline of the water inlet of filter further, this second booster pump be used for augmenting hydraulic pressure with Meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter；This second booster pump is not necessarily.

The preferred scope of hole or mesh, described hole or its bore of mesh of being a mass of in himself structure of described metal cage be between Between 0.5 centimetre and 3.0 centimetres；Certainly, if hole or the net of other bore outside preferred scope must be selected at this Eye, that is also that this case is allowed.

The structure of this case device, it is also possible to include some adnexaes, described adnexa such as: the cooling being connected with magnetron cooling pipe Water circulation system or air cooling system；Described adnexa the most such as electrodeless ultraviolet lamp is fixed on cage-like microwave constrainer it Interior fixed support；Described adnexa the most such as being fixed on the support within described quartz ampoule by the microwave constrainer of cage-like Component；Described adnexa can certainly include being fixed on described quartz ampoule the support within described container or fixed mount；Described attached Described circulation guide is the most such as carried out the fixed mount of unsettled location, bracing frame or suspension bracket within described container by part；Described attached Part is the most such as installed in the filter for intercepting impurity of reactor influent waste water end, etc..

It is an advantage of the invention that to be placed in the microwave constrainer of the caged of the metal material within described quartz ampoule, by electrodeless purple Outer lamp is wrapped among its inner chamber, its inner chamber of microwave constrainer of caged and with the waveguide UNICOM goed deep within described container, Described UNICOM refers to the UNICOM in microwave channel meaning, by this structure, is constrained in by the microwave come via waveguide transmissions Within its effective working area, containing the microwave unhelpful dissipation to periphery waste water water body, this case structure allows reactor significantly to expand it Design volume, it is allowed to reactor list tank wastewater treatment capacity is substantially improved, and need not worry that microwave energy dissipates too much in unhelpful again Waste water water body temperature-rise effect.

In the case of using bright finished punching rustless steel to make microwave constrainer, and, bright finished stainless using In the case of steel mesh cage is as microwave constrainer, via complicated direct reflection mechanism, both of which can to greatest extent in the future Go out from the ultra-violet light transmission of electrodeless ultraviolet lamp, and make up described himself entity of microwave constrainer to greatest extent to light screening The loss that gear, absorption are caused.

Structure based on this case, the most single tank wastewater treatment capacity of the design volume of reactor can be expanded to several cubes and stand to dozens of Side；The volume of hundreds of cubes of even single tank, is also to allow；Based on this structure of this case, can be greatly reduced a complete set, The saving of the frequency of substantial length of operation, beneficially human and material resources.

On the other hand, its existence of the described circulation guide in this case apparatus structure, it is possible to guide the liquid stream edge within described container The inner passage rapid increase of this circulation guide, and impact, by quartz ampoule peripheral light catalytic degradation reaction region after, Spread to surrounding by top area, sink via neighboring area, arrive described container intracavity bottom section, then through circulation guide Horn mouth converge to circulate guide inner passage, continue its circulation；Certainly, by the drag force of ascension bubble stream of pack Amount is the major impetus of this circulation；The liquid systemic circulation campaign of this relatively large yardstick guided, contributes to guaranteeing described appearance The homogenization of device internal liquid degradation reaction process, for this degradation reaction device the most large-scale for this case, is necessary.

Its UV source of this case device is to rely on microwave excited electrodeless ultraviolet lamp, and the ultraviolet radiation feature of this lamp-type is exactly permissible Accomplish high-power, high intensity, but the Effective depth penetration that ultraviolet is in liquid water body only has about 20 centimetres, therefore, stone Region within English pipe periphery about 20 cm distance is effective coverage, and this region is exactly photochemical catalysis oxidative degradation Efficient region；This case device is with described circulation guide, and pack is from the bubble stream of numerous micro porous aeration heads so that it is concentrate Ground discharges towards quartz ampoule peripheral light chemical catalytic oxidation effective coverage, and this mode is favorably improved effective district described in quartz ampoule periphery The oxygen atmosphere supply intensity in territory, helps speed up ultraviolet catalytic oxidation degradation reaction process.

Can significantly expand based on this case structure, the capacity of reactor or treating capacity, described significantly expand, be by significantly expanding The design volume of microwave zero irradiation zone or the weak irradiation zone of microwave realizes, then, from the appearance, reactor horizontal Size, longitudinal size are the most all significantly to expand, and therefore, inside reactor is contained the liquid degree of depth and can be added significantly similarly Deeply, for example, it is possible to deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, etc., containing, liquid is deep In the case of degree is enough deep, containing ozone-air bubble ascension path long enough, steep the time long enough contacted with water body containing ozone-air, During its ascension just can with abundant reducing substances fortune, and thoroughly or be close to exhaust up hill and dale in bubble contained smelly Oxygen, thus, utilizes incomplete problem to be solved containing ozone composition oxidation potential in ozone-air bubble, and, Owing to long ascension path causes ozone depletion, reactor tail gas re-entrainment would not there is the ozone that can cause environmental pollution.

This case with external multistage filter, reaches the little yardstick from aggregate bulky grain to ten number nanometer to catalyst particles Collision fragment interception step by step, be close to up hill and dale reclaim, reuse photocatalyst, be close to up hill and dale take precautions against catalyst loss and make The secondary pollution become；This interception structure secondary filter can be protected to make its filtration passage from large particulate matter step by step Rigid obstruction；Wherein the pre-filtering aperture of the first order is between 5 microns and 300 microns, and its aperture of the microfiltration of the second level is 25 Between nanometer and 1000 nanometers, its aperture of the ultrafiltration of the third level is between 15 nanometers and 2 nanometers；Such interception structure, Can fully intercept nano level photocatalyst, it can be close to interception gas phase this average particle of titanium dioxide P25 up hill and dale certainly Footpath is the catalyst of 21 nanometers；Address above, the gas phase titanium deoxide catalyst of nano level P25 etc, be can be a large amount of The commercially available catalyst buied, is also durability, stability, the known excellent photocatalyst of ultraviolet light wave band photocatalysis performance, Certainly, it is also the photocatalyst in fact paying the utmost attention in industrial scale applications select；This case catalyst interception structure and catalyst The practical capacity of market supply, actual kind match, blend.

Further, it is external that this case catalyst intercepts mechanism, and its filter element need not be soaked in the Strong oxdiative of inside reactor, strong ultraviolet irradiation Liquid in, therefore, it can need not consider ultraviolet irradiation, the tolerance of Strong oxdiative condition completely, so, in filter element material Select and upper can select in more vast optional material kind the most just without the restriction in terms of special type tolerance, and complete Material completely without the PVDF must being confined to again costly etc.

Involved filters at different levels are commercially available, commercially available filters at different levels, the discharge of draining-off sewage when its sewage draining exit is exactly backwash Mouthful, this case uses this kind of back flush type equipment, is used to intercept step by step catalyst particles, the sewage draining exit of the most commercially available equipment, The recycling delivery outlet or backflow that are used as by retaining catalyst particles by conversion in this case use delivery outlet again.

Already described above and, can significantly expand based on this case structure, the capacity of reactor or treating capacity, described significantly expand, be Realized by the design volume significantly expanding microwave zero irradiation zone or the weak irradiation zone of microwave, then, from the appearance, The lateral dimension of reactor, longitudinal size are the most all significantly to expand, and therefore, inside reactor contains the liquid degree of depth similarly Can deepen significantly, for example, it is possible to deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, etc. Deng, in the case of the Sheng liquid degree of depth is enough deep, containing ozone-air bubble ascension path long enough, the bubble containing ozone-air contacts with water body Time long enough, just can be with abundant reducing substances fortune during its ascension, and thoroughly or be close to and exhaust up hill and dale Ozone contained in bubble, thus, utilizes incomplete problem to obtain containing ozone composition oxidation potential in ozone-air bubble Thoroughly solve, and, owing to long ascension path causes ozone depletion, reactor tail gas re-entrainment would not have and can cause The ozone of environmental pollution；Only when being subject to processing reducing substances in water body i.e. organic pollution is degraded totally, in water body Through again without being available for the organic pollution of ozone oxidation reaction, those unnecessary ozone it is possible to no longer consume and pass through long Ascension path effusion liquid level；Having spoken of, among the some problem that this case solves simultaneously, is enhanced reactor The circulation of the relatively large yardstick of internal liquid, the systemic circulation mechanism that this enhances facilitates the organic dirt contained by it of inside reactor liquid The uniformity of dye thing degradation reaction process, thus, several cubes allowed in this case structure the most hundreds of to dozens of cube Under the process capacity framework of individual cube volume, when inside reactor ullage has ozone effusion, i.e. show inside reactor Degradation reaction reached terminal, and be internal liquid entirety uniformity reach the terminal of degradation reaction, this terminal point determining Factor is the matching criteria that can be provided by with this case organization plan；Ozone is installed in this case in its exhaust port position of reactor Sensor, detects ozone in this locations of structures, just means that inside reactor degradation reaction is reached home, ozone sensor And couple with the composite structure of ozone content display with ozone attention device or ozone content display or ozone attention device, be used for The information that indicates accurately, this case and the electric signal by ozone sensor output is provided to send power supply to by cable to operator Controller, this power-supply controller of electric is also coupled with magnetron and air pump respectively by cable, and power-supply controller of electric is according to received by it Described electric signal carry out on and off switch action, certainly, its function mode is, receives ozone sensor at power-supply controller of electric and sends out When the signal of the ozone effusion sent, it is automatically switched off and leads to magnetron and the power supply of air pump；This case organization plan according to this, can and The terminal of Shi Zhixiao inside reactor degradation reaction process；And organization plan according to this, when reaction reaches terminal, it is automatically switched off magnetic Keyholed back plate and the power supply of air pump, stop to inside reactor Implantation Energy in time, so can avoid unnecessary energy waste；And And, this case structure according to this, when degradation reaction is reached home, it is possible to close described magnetron and the power supply of air pump in time, This power-off action also synchronizes, the same generation process terminating in a flash ozone, owing to ozone generation process is terminated in time, The a large amount of ozone that would not have more than needs disengage from described exhaust port, thus avoid unnecessary secondary pollution or say secondary Raw pollution；Its framework of this case determines the ozone that it does not have more than needed and is available for discharge.

Among this case structure, the microwave exposure spatial domain of its inside reactor is cut off by forcing, limits, this case and use external Cascading multiple stages backwash filter structure intercepts catalyst particles, back flush type hollow fiber microfiltration membrane assembly therein subtly And back flush type polysulfone hollow fiber ultrafiltration membrane system is the most external and away from reactor core, microwave can not be irradiated to described film group completely Part, based on this structure of this case, has got around described point-like completely and has pierced the heat penetration erosion destruction problem of formula, and this problem thus obtains well Solution.

This case reactor inner chamber bottom surface is the most hollow to central area by periphery, described its gradient hollow between 5 degree with 35 degree it Between, this case ultrasonic transducer is to be installed in its part reaction corresponding to hollow bosom of this reactor inner chamber bottom surface with attaching The lateral surface position of device diapire or medial surface position；Addressing above, this case structure and beneficially driving a reaction device internal liquid make phase Shuttling movement to large scale, the mode of this liquid shuttling movement is that peripheral liquid sinks, and middle liquid rises, the most constantly Move in circles；Address above, some pH value be pre-adjusted not in place, pH value inappropriate in the case of, titanium dioxide is micro- Grain is susceptible to reunite, and then affects its effective working interface area, affects its photocatalysis usefulness；Particularly with this particle size range Among the section of those relatively small particle diameters, easily occur especially because of pH value presetting not in place, pH value is incorrect and cause Agglomeration traits；For this catalyst particles in the case of of reuniting, it is immediately to adopt an effective measure, carries out for aggregate Depolymerization running；When catalyst particles generation serious agglomeration, the heavier macro aggregate of some of which is due to gravity Effect, it is intended to gradually settling to reactor intracavity bottom, in this case structure, reactor intracavity bottom is hollow structure, and, This case structure can make the shuttling movement of described relatively large yardstick by driving a reaction device internal liquid, the effect of this systemic circulation campaign together with The effect of ubiquitous natural gravity, the macro aggregate settled can be pushed away along the slope of described hollow structure sweep to hollow Depths also makes them be gathered in there, and in this case structure, ultrasonic transducer is just being in this hollow innermost locations of structures, should Hollow innermost region, is the region finally assembled of described macro aggregate, be also simultaneously ultrasound wave can minimum damply, Minimum distance ground, carry out depolymerization operating area the most consumingly, most effectively for macro aggregate；This structure of this case can allow for Minimum ultrasonic energy loss, it is achieved maximized ultrasonic depolymerization effect；This case structure according to this, it is possible to converge aggregate precipitum, And the region concentrated most at aggregate precipitum, implement depolymerization running；The ultrasound wave being derived from reactor bottom also is able to of course simultaneously Other region being radiated in inside reactor liquid, plays the aggregate being still within suspended state that those are smaller and solves Poly-effect；This case associated ultrasonic radiates mechanism, is the mechanism that can start as required or close；This case thus achieve for The instant of this catalyst particles agglomeration traits is disposed in situ.

Structure is protected for screen the quartz ampoule of electrodeless ultraviolet lamp, its outer wall, refers to the outer wall of quartz ampoule, through long and quilt Processing the contact of industrial wastewater, the most gradually dirty, the material that dirt amasss the most mainly is difficult to the nothing touched by light-catalyzed reaction Machine class impurity, the dirty phenomenon formed because of this mechanism, it is easy to be observed after equipment long-play；It is attached to described The dirty lamination of quartz ampoule outer wall, although the veryyest thin one layer, also be enough to cause the ultraviolet radiation of electrodeless ultraviolet lamp significantly Stopping, the actual treatment effect causing this microwave and photo catalysis reaction treating device is significantly reduced by this；This case structure is positioned at reaction Ultrasonic transducer bottom device, in the irregular depolymerization running carried out for accidental catalyst particles serious agglomeration situation Among, its ultrasound wave radiated, the most also can arrive quartz ampoule place locations of structures, this ultrasound wave is carrying out depolymerization fortune in situ While work, carry out amassing for quartz ampoule surface dirt the ultrasonic clean scale removal work of thing the most in the lump；Further, ultrasonic transducer Installation position away from quartz ampoule place locations of structures, ultrasonic radiation has decayed when arriving quartz ampoule position, therefore, stone Ultrasonic impact suffered by English tube-surface is low intensive ultrasonic impact, and this low intensive ultrasonic impact can leniently remove Dirt, is avoided that again or significantly weakens its quartz ampoule surface smoothness loss being likely to result in of ultrasonic cavitation；Should based on this case Structure, it is possible on the premise of not tearing machine open, removes the dirty lamination on this quartz ampoule outer wall immediately, effectively, thereby safeguards that this is micro- The lasting high efficiency of glistening light of waves catalytic degradation reaction device.

The pH value of wastewater degradation inside reactor water body, is the key factor affecting catalyst dispersion stabilization；This case structure fills If pH probe and the pH value display instrument of association and the siren etc. that is associated, it is possible to steady beyond catalyst dispersion at pH value In the case of determining scope, actively sending alarm, based on this structure of this case, associative operation personnel can the inside reactor of awareness immediately Agglomeration is inclined to, and makes instant disposal.Described micropore rustless steel sleeve in this case structure and installing mode thereof, be and this The indispensable important component that case principle and this case structure match.

In short, the target allowing reactor design capacity significantly to expand has been reached in this case；Meanwhile, its structure also enhances reaction The systemic circulation campaign of the relatively large yardstick of device internal liquid；Its structure solves ozone oxidation potentiality simultaneously and utilizes incomplete asking Topic；Its structure and reached for nm-class catalyst microgranule from its aggregate bulky grain to ten number nanometer collision fragment wide General, fine interception；The selection face of its filter element material also expanded because of this structure；Its degradation reaction endpoint information can Known in time；The energy input to reactor can be automatically switched off when its degradation reaction terminal；When its degradation reaction terminal, Terminate the generation process of ozone the most in time, it is to avoid unnecessary secondary pollution；Its structure also can be disposed the most in situ Accidental catalyst particles serious agglomeration situation, the most incidentally the low intensive temperature after weakening through teletransmission appropriateness Quartz ampoule surface described in the supersonic cleaning of sum, keeps the ultraviolet light transparent performance that it is excellent；Its structure also can actively detect catalyst Reunite and be inclined to, and send alarm when relevant parameter exceeds standard.

This case structure solve totally one of described problem, two, three, four, five, six, seven, eight, nine, ten, 11.

Accompanying drawing explanation

Fig. 1 is the brief perspective diagram of this case structure of reactor.

In figure, 1 is water pump, and 2 is circulation guide, and 3,13 is two breather lines that locations of structures is different respectively, and 4 are The osculum end of circulation guide, 5,14 is the closure headkerchief at quartz ampoule two ends respectively, and 6 is quartz ampoule, and 7 is metal cage, also The i.e. microwave constrainer of the caged of metal material, 8 is electrodeless ultraviolet lamp, and 9 is exhaust port, and 10 is waveguide, and 11 is magnetic Keyholed back plate, 12 is air pump, and 15 is not by the spatial domain of microwave exposure inside described container, and 16 is micro porous aeration head, and 17 is to follow The big opening end of ring guide, 18 is blowoff valve, and 19 is sewage draining exit, and 20 is back flush type hollow-fibre membrane ultra filtration filter, 21 Being back flush type doughnut membrane microfiltration filter, 22 is water purifying tank, and 23 is the preposition prefilter of back flush type, and 24 is waste water Pond, 25 is booster pump, and 26 is the probe tube of ozone sensor, and 27 is that ozone content display, ozone attention device or ozone contain Amount display and the composite structure of ozone attention device, 28 is ozone sensor, and 29 is power-supply controller of electric, and 30 is ultrasonic wave transducer Device, 31 is higher-order of oscillation electric signal transmission cable, and 32 is siren, and 33 is electricity pH analyser and siren linked up Cable, 34 is pH analyser, and 35 is the cable linked up with pH probe by pH analyser, and 36 is pH probe, and 37 is micro- Hole rustless steel sleeve, the some arrows in figure indicate it adjacent to pipeline liquid flow direction when in an ON state.

Detailed description of the invention

In this case embodiment that Fig. 1 is shown, the structure of this reactor includes a container, its appearance profile of described container in Cube shaped, cuboid, cylindrical, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form, in described appearance The bottom position of device inner chamber is equiped with the micro porous aeration head 16 of many, and, quartz ampoule 6, this quartz ampoule 6 is erected at described appearance The cavity position of device, the two ends of this quartz ampoule 6 are equiped with closure headkerchief 5,14, lay respectively at the described envelope at quartz ampoule 6 two ends All offer ventilation interface on blanking cover head 5,14, and, electrodeless ultraviolet lamp 8, this electrodeless ultraviolet lamp 8 in bar-shaped, ring-type, Spherical, Asterias amurensis Lutken shape or Hemicentrotus seu Strongylocentrotus shape, the quantity of this electrodeless ultraviolet lamp 8 is at least at more than one, and this quantity is at least more than one Electrodeless ultraviolet lamp 8 is all erected at the inside of described quartz ampoule 6, and, air pump 12, this air pump 12 is installed in described appearance The outside of device, the ventilation interface on described quartz ampoule 6 one end seal blanking cover head 14 is via breather line 13 and through described container Wall couple with the gas outlet of described air pump 12, described its other end of quartz ampoule 6 closure headkerchief 5 on ventilation interface via Another breather line 3 couples with the micro porous aeration head 16 being positioned at bottom described container intracavity, and, microwave generator, should Microwave generator is installed in the outside of described container, and this microwave generator is magnetron 11, and, waveguide 10, this waveguide Pipe 10 is the component for transmitting microwave, one end of this waveguide 10 and described magnetron 11 UNICOM, this waveguide 10 another One end passes through the described wall of a container inner chamber towards described container, and, water pump 1, this water pump 1 is in described container The chamber pumping described waste water containing organic pollution, this water pump is positioned at the outside of described container, and the outlet of this water pump 1 is via water flowing Pipeline also leads to the inner chamber of described container through described wall of a container, and the top of described container offers exhaust port 9, emphasis Being that one end through described wall of a container of this waveguide 10 extends much further into the inner chamber of described container, this gos deep into institute That one end stating the waveguide 10 of container intracavity and the closure headkerchief 14 further passing through described quartz ampoule 6 probe into stone The inside of English pipe 6, and, the structure of this reactor also includes the microwave constrainer 7 of the caged of metal material, this caged micro- Containing many holes or mesh in ripple constrainer 7, the function of the microwave constrainer 7 of this caged is constraint microwave, contains its nothing Benefit dissipates, simultaneously, it is allowed to major part ultraviolet light penetrates, and the installation position of the microwave constrainer 7 of this caged is positioned at described quartz ampoule That one end UNICOM probeing into quartz ampoule 6 of the inside of 6, its inner chamber of microwave constrainer 7 of this caged and described waveguide 10, institute State and be erected at the electrodeless ultraviolet lamp 8 within quartz ampoule 6 and be all rolled in wherein by the microwave constrainer 7 of cage-like, this caged micro- Ripple constrainer 7 is exactly a metal cage 7, and what label 7 was referred to is same component, and, circulating guide 2, this follows The function of ring guide 2 is the pack ascension path containing ozone-air bubble from micro porous aeration head 16, and by because of by poly- Bundle and the bubble stream of ascension strengthened pull strength to lead described container internal liquid to make the shuttling movement of relatively large yardstick, should Circulation guide 2 is installed in the cavity position of described container, and its profile shape of this circulation guide 2 is like the through simple loudspeaker in two ends Cylinder, its osculum end of this circulation guide 2 vertically upward, this its big opening end of circulation guide 2 vertically downward, this circulation guide 2 its axis are mutually perpendicular to the inner chamber bottom surface of described container, its structure of osculum end 4 vertically upward of this circulation guide 2 Position is in the underface of described quartz ampoule 6, its edge of big opening end 17 vertically downward of this circulation guide 2 and described appearance Lateral separation between device inwall is between 5 centimetres and 300 centimetres, and the arbitrarily selected value within the scope of this lateral separation is all Available enforcement value, this lateral separation can be such as 5 centimetres, 55 centimetres, 99 centimetres, 152.5 centimetres, 222 centimetres, 260 centimetres, 300 centimetres, etc., its edge of big opening end 17 vertically downward of this circulation guide 2 and described container intracavity Fore-and-aft distance between bottom surface is between 5 centimetres and 100 centimetres, and the arbitrarily selected value within the scope of this fore-and-aft distance is all can Enforcement value, this fore-and-aft distance can be such as 5 centimetres, 26 centimetres, 33 centimetres, 52.5 centimetres, 77 centimetres, 88 lis Rice, 100 centimetres, etc., and, the micro porous aeration head 16 of described many is to install described circulation guide 2 with gathering it is big Mouthful end 17 edge within the scope of vertical projection in described container intracavity bottom surface is drawn a circle to approve, and, booster pump 25, this booster pump 25 are mixed with the water after the degraded of a large amount of catalyst particles for supercharging pumping, and this its water inlet of booster pump 25 leads to via another Waterpipe also couples with the inner chamber of described container through described wall of a container, and, the preposition prefilter of back flush type 23, this is anti- Its water inlet of the preposition prefilter of flushing type 23 couples with the outlet of described booster pump 25, and, back flush type doughnut Membrane microfiltration filter 21, its pure water inlet of the preposition prefilter of described back flush type 23 is via first water purifying valve and this backwash The water inlet of formula doughnut membrane microfiltration filter 21 couples, and, back flush type hollow-fibre membrane ultra filtration filter 20, institute State back flush type its pure water inlet of doughnut membrane microfiltration filter 21 via second water purifying valve and this back flush type doughnut The water inlet of membrane ultrafiltration filter 20 couples, this back flush type its pure water inlet of hollow-fibre membrane ultra filtration filter 20 and the 3rd The entrance point of water purifying valve couples, and the water side of the 3rd water purifying valve is the water side of outlet terminal water purification, the 3rd water purifying valve Water side can couple with water purifying tank 22, certainly, water purifying tank 22 not necessarily component, the water outlet of the 3rd water purifying valve End directly can also lead to water purification water mechanism via pipeline, its outlet of sewer of the preposition prefilter of described back flush type 23 via First sewage valve couples with the inner chamber of described container, described back flush type its outlet of sewer of doughnut membrane microfiltration filter 21 Couple with the inner chamber of described container via second sewage valve, described back flush type its sewage of hollow-fibre membrane ultra filtration filter 20 Outlet couples with the inner chamber of described container via the 3rd sewage valve, and each described filter 23,21,20 is used to retain catalysis Agent microgranule, each described its outlet of sewer of filter 23,21,20 is all converted as being exported by the recycling retaining catalyst particles Delivery outlet is used in mouth or backflow again, and, ozone sensor 28, the sampling port of this its probe tube 26 of ozone sensor 28 is neighbouring Described exhaust port 9 or probe into the inside of described exhaust port 9, and, ozone content display, ozone attention device or Ozone content display and the composite structure 27 of ozone attention device, this ozone sensor 28 contains with this ozone via Article 1 cable Amount display, ozone attention device or ozone content display couple with the composite structure 27 of ozone attention device, and, power supply control Device 29 processed, this its output electric signal of ozone sensor 28 couples with this power-supply controller of electric 29 via Article 2 cable, this power supply control Device 29 processed couples with described magnetron 11 via Article 3 cable, and this power-supply controller of electric 29 is via Article 4 cable and described sky Air pump 12 couples, and this power-supply controller of electric 29 is the power supply that can carry out on and off switch action according to its described electric signal received Controller, and, ultrasonic transducer 30, this ultrasonic transducer 30 is bottom outside position or the end being installed in this container Portion's inner side, this container intracavity bottom surface is the most hollow to central area by periphery, and described its gradient hollow is between 5 degree and 35 Between degree, this ultrasonic transducer 30 is to be installed in its part corresponding to hollow bosom of this container intracavity bottom surface with attaching The lateral surface position of vessel bottom wall or medial surface position, show in legend is the example being installed in lateral surface position, does not has in legend Have and show the example being installed in medial surface position, and, higher-order of oscillation electric signal transmission cable 31, this higher-order of oscillation electric signal passes One end of transmission cable 31 couples with this ultrasonic transducer 30, and, higher-order of oscillation electric signal generator, the described higher-order of oscillation The other end of electric signal transmission cable 31 couples with this higher-order of oscillation electric signal generator, and, pH probe 36, and, pH Analyser 34, this pH probe 36 is coupled to each other with pH analyser 34, this pH analyser 34 and coupling with siren 32, This siren 32 is for sending alarm to the pH value situation of transfiniting, and this pH probe 36 stretches into described appearance through the top of described container Device inner chamber, and, through the micropore rustless steel sleeve 37 that powder sintering process is made, this micropore rustless steel sleeve 37 in cap for brush shape, This micropore rustless steel sleeve 37 is positioned at described container intracavity, and down, this micropore is stainless for this its blind end of micropore rustless steel sleeve 37 Upward, this its opening upward of micropore rustless steel sleeve 37 is via buffering isolating pad and described container for its opening of steel bushing 37 Top attachment, is depicted without that buffering isolating pad described in legend, this pH probe 36 its stretch into that of described container intracavity Within individual part probes into this micropore rustless steel sleeve 37, this its material of buffering isolating pad is fluorubber or silicone rubber.Legend does not has Draw this higher-order of oscillation electric signal generator.

Involved pH probe is commercially available；Described pH probe also known as pH sensor；PH probe or say itself skill of pH sensor Art is meant that known.

Involved pH analyser is commercially available；Itself art-recognized meanings of pH analyser is known.This case pH analyser one word is general Refer to pH can be utilized to detect, picking up, showing pH value information of any model, and can externally export pH and be correlated with electric signal Instrument, market is sold simple or complicated but all meet the pH correlate meter of this basic demand it is various in style, Can select as required.

Involved buffering its thickness of isolating pad does not limits；But, have a preferred range, the preferred scope of this buffering its thickness of isolating pad Between 1 millimeter to 8 millimeter.

Themselves art-recognized meanings of involved fluorubber and involved silicone rubber is known；Involved fluorubber and involved silicone rubber, city Field is the most on sale.

Involved micropore its wall thickness of rustless steel sleeve does not limits；But, also have an associated preferred scope, this micropore rustless steel The preferred scope of its wall thickness of sleeve is between 3 millimeters to 30 millimeters.

An involved powder sintered word, the art-recognized meanings of itself, for the professional of metallurgical technology field, is known.

Involved micropore rustless steel sleeve, can customize to relevant powder metallurgy specialized factory.

The sleeve-shaped micropore stainless steel filter conversion that can be made by powder sintering process is the micropore stainless steel sleeve described in this case Cylinder；The sleeve-shaped micropore stainless steel filter that described powder sintering process is made is commercially available.

The aperture of involved micropore rustless steel its micropore of sleeve does not limits；But, the aperture of this micropore is also to have a preferred range, should The preferred scope of micropore size is between 0.5 micron to 50 micron.

This its opening upward of micropore rustless steel sleeve couples with described container top via buffering isolating pad, refers to this connection Connecing is flexible connection, in place of this connection, has described buffer compartment mediate from pad.

Described siren is can to send audio frequency warning message or the device of optical frequency warning message according to its received electric signal； Itself art-recognized meanings of described siren is known；Described siren is commercially available.

Described its gradient enforcement value hollow is between 5 degree and 35 degree, and the arbitrarily selected value within this range of grade is all this The enforcement value that can use that case allows；This its gradient enforcement value hollow can be such as 5 degree, 8 degree, 10 degree, 15 degree, 20 Degree, 25 degree, 30 degree, 35 degree, etc..

Itself art-recognized meanings of involved ultrasonic transducer one word is known for the professional in ultrasonic technology field 's.

Itself art-recognized meanings of involved higher-order of oscillation electric signal transmission cable one word is for the professional in ultrasonic technology field For be also known.

Involved ultrasonic transducer and higher-order of oscillation electric signal transmission cable market are the most on sale；Described ultrasonic transducer and high frequency vibrating Swing electric signal transmission cable etc. also to customize to ultrasonic transducer specialized factory and cable specialized factory.

Involved higher-order of oscillation electric signal generator one word itself art-recognized meanings for ultrasonic technology field professional and Speech is also known；Various higher-order of oscillation electric signal generator is commercially available；Described higher-order of oscillation electric signal generator also can be to super The customization of sound wave equipment specialized factory.

Involved ozone sensor 28 is commercially available；Customize to ozone sensor specialized factory also dependent on needs.

Involved ozone content monitor market is on sale；Also dependent on needs to the customization of ozone content display specialized factory；Ozone passes Matching used ozone content display is generally also sold by sensor producer.

Involved ozone attention device, refers to warn that sound or alarm flashing or warning sound combines with alarm flashing that both are double And have for warning mechanism；Ozone attention device is commercially available；Also can be to the customization of ozone attention device specialized factory；Ozone passes Matching used ozone attention device generally also can be sold by sensor producer.

This power-supply controller of electric 29 involved is the power supply control that can carry out on and off switch action according to its described electric signal received Device；The power-supply controller of electric of on and off switch action can be carried out only with regard to its circuit engineering itself according to its electric signal received, It it is ripe, known technology；Described power-supply controller of electric is commercially available；It is possible with commercially available power-supply controller of electric according to need Change a social system；Described power-supply controller of electric also can customize to power-supply controller of electric specialised manufacturers；The electronics device of power-supply controller of electric etc Its specialised manufacturers of part spreads all over the world.

Described its outline shape of circulation guide 2 or also can be described as the profile shape cooling tower like thermal power plant.

Described metal material one word, the art-recognized meanings of itself, is known.

Its material of microwave constrainer 7 i.e. metal cage of this caged can be any selected metal, but, in view of it is residing The ozone gaseous mixture environment formed by strong ultraviolet radiation, and, for as much as possible by complicated direct reflection mechanism The considering of ultraviolet light that the output of limits ground is launched by electrodeless ultraviolet lamp 8, is suitable to make microwave constrainer 7 excellent of this caged The metal material of choosing is the rustless steel processed through mirror finish.

Itself art-recognized meanings of described punching rustless steel one word, for stainless steel industry, is known.

Can welded with bright finished punching corrosion resistant plate, splicing or mould pressing process make described microwave constrainer 7.

The microwave constrainer 7 of this caged can also be made with the braiding of bright finished stainless steel silk.

For convenience of periodic inspection or the cleaning of equipment, sewage draining exit 19 can be offered in the bottom of described container, at sewage draining exit 19 Position is it is of course possible to install blowoff valve 18.Described sewage draining exit 19 and blowoff valve 18 are not necessarily.

The material of described circulation guide 2 does not limits, the material of described circulation guide 2 can be such as politef material, Glass material, ceramic material, metal material, etc., but, circulation its preferred material of guide 2 is rustless steel.

In legend occur wastewater disposal basin 24 not necessarily because pending waste water can also select as the case may be without Cross wastewater disposal basin and be directly communicated to described container.

In this this case example structure, the micro porous aeration head 16 of described many be installed in gathering described circulation guide 2 its Big opening end 17 edge is within the scope of vertical projection in described container intracavity bottom surface is drawn a circle to approve.It is positioned at the projection of described vertical to be drawn a circle to approve Within the scope of the micro porous aeration head 16 of described many, both can be installed in bottom described container intracavity with tiling and drawn a circle to approve Within the scope of, certainly, within the scope of this is drawn a circle to approve, it is also possible to take the most intensive another kind of installing mode, described more Intensive installing mode, refers to and can be set, with this in three-dimensional enterprising windrow superimposed by the micro porous aeration head of described many They are gathered formation and have the cluster-shaped micro porous aeration head cluster of three-dimensional stacked framework by mode；This kind of cluster-shaped micro porous aeration head collection Group can accommodate the micro porous aeration head that quantity is the hugest；This kind of mode can carry bigger air flux.Institute in this case legend Show is exactly the structural configuration of above-mentioned this cluster-shaped micro porous aeration head cluster；The level of its actual stacked architecture the most also may be used Being that the level than legend is shown is more to allow, in the stacked architecture that this is multi-level, each micro porous aeration head can offset one from another Ground arrangement, can not block, certainly, even if having part mutually block, even hinder.

The preferred scope in its filter opening aperture of the preposition prefilter of described back flush type 23 is between 5 microns and 300 microns, Certainly, other the preposition pre-filtering aperture outside this preferred scope selects also is that this case is allowed；Described back flush type hollow The preferred scope in its filter opening aperture of fibrous membrane microfiltration filter 21 is between 25 nanometers and 1000 nanometers, certainly, and this Preferably other microfiltration aperture outside scope selects also is that this case is allowed；Described back flush type hollow-fibre membrane ultra filtration filter The preferred scope in 20 its filter opening apertures is between 15 nanometers and 2 nanometers, certainly, and other ultrafiltration hole outside this scope It is also that this case is allowed that footpath selects.

The preposition prefilter of described back flush type 23 also referred to as back flush type fore filter or back flush type prefilter, described instead Itself art-recognized meanings of the preposition prefilter of flushing type 23 is known；Described back flush type preposition prefilter 23 market has Sell.

Described back flush type doughnut membrane microfiltration filter 21 is adapted for the filter of microfiltration；Described microfiltration one word itself Art-recognized meanings is known；Itself art-recognized meanings of described back flush type doughnut membrane microfiltration filter 21 is for membrance separation For the professional of technical field, it is known；Described back flush type doughnut membrane microfiltration filter 21 is commercially available.

Described back flush type hollow-fibre membrane ultra filtration filter 20 is adapted for the filter of ultrafiltration；Described ultrafiltration one word itself Art-recognized meanings is known；Itself art-recognized meanings of described back flush type hollow-fibre membrane ultra filtration filter 20 is for membrance separation For the professional of technical field, it is known；Described back flush type hollow-fibre membrane ultra filtration filter 20 is commercially available.

In ultrafiltration link, this back flush type hollow-fibre membrane ultra filtration filter 20 can be an only back flush type doughnut The form of membrane ultrafiltration filter monomer；Certainly, this back flush type hollow-fibre membrane ultra filtration filter can also be at one by quantity Above back flush type hollow-fibre membrane ultra filtration filter monomer is parallel with one another couples composition.In legend, do not show this kind of parallel connection Configuration.

Expressing an involved word in parallel, the art-recognized meanings itself referred to is clearly.

Express involved monomer one word, refer to itself function and structure equipment completely is individual.

Similarly, in microfiltration link, this back flush type doughnut membrane microfiltration filter 21 can be an only back flush type The form of doughnut membrane microfiltration filter monomer；Certainly, this back flush type doughnut membrane microfiltration filter can also be by counting Measure and form in more than one back flush type doughnut membrane microfiltration filter monomer parallel with one another connection.Not showing in legend should Plant parallel-connection structure situation.

At described back flush type its pure water inlet of doughnut membrane microfiltration filter 21 and described back flush type doughnut membrane ultrafiltration Can install second booster pump on the connecting pipeline of the water inlet of filter 20 further, this second booster pump is used for augmenting Hydraulic pressure is to meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter；This second booster pump is not necessary to 's.Legend not shown, this kind uses the architectural scenarios of second booster pump.

Himself structure of microwave constrainer 7 of the i.e. cage-like of described metal cage is a mass of hole or mesh, described hole or net The preferred scope of its bore of eye is between 0.5 centimetre and 3.0 centimetres；Certainly, if preferred scope at this must be selected Outside the hole of other bore or mesh, that is also that this case is allowed.

Implement legend is depicted without other adnexa described.

The embodiment of this case is not limited to legend mode.

Its enforcement of this case structure and application, if using mean diameter at the nano level photocatalyst of 20 ran, have Reasonable matching；Certainly, its particle size range of nano-scale photocatalyst that corresponding this case structure may select use is not limited to described The mean diameter of 20 ran；Described nano-scale photocatalyst, both can be commercially available gas phase titanium dioxide P25 catalysis Agent, it is also possible to the J25 catalyst that the performance being domestic is suitable, it is of course also possible to allow to select to use the commercially available of other or from The nano-scale photocatalyst of system includes the nano-scale photocatalyst of modification.

Claims (9)

1. the High-capacity waste water degradation reactor of the main inducement parameter Auto-Sensing of photocatalyst reunion, the structure of this reactor includes an appearance Device, its appearance profile of described container is cube shaped, cuboid, cylindrical, the cylindroid bodily form, the polygon prism bodily form, ball The bodily form or the ellipsoid bodily form, the bottom position at described container intracavity is equiped with the micro porous aeration head of many, and, quartz ampoule, should Quartz ampoule is erected at the cavity position of described container, and the two ends of this quartz ampoule are equiped with closure headkerchief, lays respectively at quartz ampoule two ends Described closure headkerchief on all offer ventilation interface, and, electrodeless ultraviolet lamp, this electrodeless ultraviolet lamp is bar-shaped, ring-type, ball Shape, Asterias amurensis Lutken shape or Hemicentrotus seu Strongylocentrotus shape, the quantity of this electrodeless ultraviolet lamp is at least at more than one, and this quantity is at least more than one electrodeless Uviol lamp is all erected at the inside of described quartz ampoule, and, air pump, this air pump is installed in the outside of described container, described Ventilation interface on quartz ampoule one end seal blanking cover head via breather line and passes through going out of described wall of a container and described air pump QI KOU couple, its other end of described quartz ampoule closure headkerchief on ventilation interface via another breather line be positioned at described container The micro porous aeration head of intracavity bottom couples, and, microwave generator, this microwave generator is installed in the outside of described container, should Microwave generator is magnetron, and, waveguide, this waveguide is the component for transmitting microwave, one end of this waveguide with Described magnetron UNICOM, the other end of this waveguide passes through the described wall of a container inner chamber towards described container, and, water pump, This water pump for pumping the described waste water containing organic pollution to the inner chamber of described container, and this water pump is positioned at the outside of described container, The outlet of this water pump leads to the inner chamber of described container via ventilating water pipe and through described wall of a container, and the top of described container is opened Being provided with exhaust port, that one end through described wall of a container of this waveguide extends much further into the inner chamber of described container, This gos deep into that one end of waveguide of described container intracavity and further probes into through one of described quartz ampoule closure headkerchief The inside of quartz ampoule, and, the microwave constrainer of the caged of metal material, containing many holes in the microwave constrainer of this caged Hole or mesh, the function of the microwave constrainer of this caged is constraint microwave, contains its unhelpful dissipation, simultaneously, it is allowed to major part is purple Outer light penetrates, and the installation position of the microwave constrainer of this caged is positioned at the inside of described quartz ampoule, the microwave constrainer of this caged its That one end UNICOM probeing into quartz ampoule of inner chamber and described waveguide, described in be erected at the electrodeless ultraviolet lamp within quartz ampoule all by institute The microwave constrainer stating caged is rolled in wherein, it is characterised in that the structure of this reactor also includes circulating guide, and this circulation is drawn The function leading device is the pack ascension path containing ozone-air bubble from micro porous aeration head, and by because being strengthened by pack The bubble stream of ascension pull strength to lead described container internal liquid to make the shuttling movement of relatively large yardstick, this circulation guide Being installed in the cavity position of described container, its profile shape of this circulation guide guides like the through simple cone in two ends, this circulation Its osculum end of device vertically upward, this its big opening end of circulation guide vertically downward, this its axis of circulation guide and described container Inner chamber bottom surface be mutually perpendicular to, its locations of structures of osculum end vertically upward of this circulation guide be described quartz ampoule just under Side, the lateral separation between its edge of big opening end vertically downward and the described container inner wall of this circulation guide between 5 centimetres with Between 300 centimetres, between its edge of big opening end vertically downward and the described container intracavity bottom surface of this circulation guide longitudinally away from From between 5 centimetres and 100 centimetres, and, the micro porous aeration head of described many is to be installed in described circulation with gathering guide Its big opening end edge of device described container intracavity bottom surface vertical projection drawn a circle to approve within the scope of, and, booster pump, this booster pump Water after supercharging pumping is mixed with the degraded of a large amount of catalyst particles, its water inlet of this booster pump is via another ventilating water pipe And couple with the inner chamber of described container through described wall of a container, and, the preposition prefilter of back flush type, before this back flush type Put its water inlet of prefilter to couple with the outlet of described booster pump, and, back flush type doughnut membrane microfiltration filter, Described back flush type its pure water inlet of preposition prefilter is via first water purifying valve and this back flush type doughnut membrane microfiltration mistake The water inlet of filter couples, and, back flush type hollow-fibre membrane ultra filtration filter, described back flush type doughnut membrane microfiltration Its pure water inlet of filter couples via the water inlet of second water purifying valve with this back flush type hollow-fibre membrane ultra filtration filter, should The entrance point of back flush type hollow-fibre membrane its pure water inlet of ultra filtration filter and the 3rd water purifying valve couples, the 3rd water purifying valve Water side be the water side of outlet terminal water purification, described back flush type its outlet of sewer of preposition prefilter is via first sewage Valve couples with the inner chamber of described container, and described back flush type doughnut its outlet of sewer of membrane microfiltration filter is via second sewage Valve couples with the inner chamber of described container, and described back flush type hollow-fibre membrane its outlet of sewer of ultra filtration filter is via the 3rd sewage Valve couples with the inner chamber of described container, and each described filter is used to retain catalyst particles, each its outlet of sewer of described filter All conversions are to be used delivery outlet again by the recycling delivery outlet or backflow retaining catalyst particles, and, ozone sensor, this is smelly The sampling port of its probe tube of oxygen sensor adjacent to described exhaust port or the inside that probes into described exhaust port, and, smelly The composite structure of oxygen content display, ozone attention device or ozone content display and ozone attention device, this ozone sensor via Article 1, cable joins with the composite structure of this ozone content display, ozone attention device or ozone content display with ozone attention device Connect, and, power-supply controller of electric, its output electric signal of this ozone sensor couples with this power-supply controller of electric via Article 2 cable, This power-supply controller of electric couples with described magnetron via Article 3 cable, and this power-supply controller of electric is via Article 4 cable and described air Pump couples, and this power-supply controller of electric is the power-supply controller of electric that can carry out on and off switch action according to its described electric signal received, And, ultrasonic transducer, this container intracavity bottom surface is the most hollow to central area by periphery, and described its gradient hollow is between 5 Spend between 35 degree, this ultrasonic transducer be attaching be installed in corresponding to its hollow bosom, this container intracavity bottom surface that The lateral surface position of partial containers diapire or medial surface position, and, higher-order of oscillation electric signal transmission cable, this higher-order of oscillation electricity One end of signal transmission cable couples with this ultrasonic transducer, and, higher-order of oscillation electric signal generator, the described higher-order of oscillation The other end of electric signal transmission cable couples with this higher-order of oscillation electric signal generator, and, pH pops one's head in, and, pH analyzes Instrument, this pH probe is coupled to each other with pH analyser, this pH analyser and coupling with siren, and this siren is used for pH The value situation of transfiniting sends alarm, and this pH probe stretches into described container intracavity through the top of described container, and, burn through powder The micropore rustless steel sleeve that knot technique is made, this micropore rustless steel sleeve is cap for brush shape, and this micropore rustless steel sleeve is positioned at described appearance Device inner chamber, this micropore its blind end of rustless steel sleeve down, this micropore its opening of rustless steel sleeve upward, this micropore rustless steel Its opening upward of sleeve couples with described container top via buffering isolating pad, and this pH pops one's head in, and it stretches into described container intracavity That part probe into this micropore rustless steel sleeve within, this its material of buffering isolating pad is fluorubber or silicone rubber, described recoil Its filter opening aperture of the preposition prefilter of formula of washing between 5 microns and 300 microns, described back flush type doughnut membrane microfiltration mistake Its filter opening aperture of filter between 25 nanometers and 1000 nanometers, described back flush type hollow-fibre membrane its filter opening of ultra filtration filter Aperture is between 2 nanometers and 15 nanometers, and involved its thickness of buffering isolating pad is between 1 millimeter and 8 millimeters, involved micro- Hole its wall thickness of rustless steel sleeve is between 3 millimeters and 30 millimeters, and the aperture of involved micropore rustless steel its micropore of sleeve is between 0.5 Between micron and 50 microns.

The High-capacity waste water degradation reactor of the photocatalyst the most according to claim 1 main inducement parameter Auto-Sensing of reunion, it is special Levying and be, its material of microwave constrainer of this caged is the punching rustless steel processed through mirror finish.

The High-capacity waste water degradation reactor of the photocatalyst the most according to claim 1 main inducement parameter Auto-Sensing of reunion, it is special Levying and be, the microwave constrainer of this caged is made up of the braiding of mirror finish stainless steel silk.

The High-capacity waste water degradation reactor of the photocatalyst the most according to claim 1 main inducement parameter Auto-Sensing of reunion, it is special Levying and be, the micro porous aeration head of described many is to set in three-dimensional enterprising windrow superimposed, gathers formation in this way and has three-dimensional The cluster-shaped micro porous aeration head cluster of stacked architecture.

The High-capacity waste water degradation reactor of the photocatalyst the most according to claim 1 main inducement parameter Auto-Sensing of reunion, it is special Levying and be, this profile shape is rustless steel like its material of circulation guide of the through simple cone in two ends.

The High-capacity waste water degradation reactor of the photocatalyst the most according to claim 1 main inducement parameter Auto-Sensing of reunion, it is special Levying and be, this back flush type hollow-fibre membrane ultra filtration filter is at more than one back flush type doughnut membrane ultrafiltration by quantity Filter monomer is parallel with one another couples composition.

The High-capacity waste water degradation reactor of the photocatalyst the most according to claim 1 main inducement parameter Auto-Sensing of reunion, it is special Levying and be, this back flush type doughnut membrane microfiltration filter is at more than one back flush type doughnut membrane microfiltration by quantity Filter monomer is parallel with one another couples composition.

The High-capacity waste water degradation reactor of the photocatalyst the most according to claim 1 main inducement parameter Auto-Sensing of reunion, it is special Levy and be, at described back flush type doughnut its pure water inlet of membrane microfiltration filter and described back flush type doughnut membrane ultrafiltration Being equiped with second booster pump on the connecting pipeline of the water inlet of filter, this second booster pump is used for augmenting hydraulic pressure to meet State the intake pressure demand of back flush type hollow-fibre membrane ultra filtration filter.

The High-capacity waste water degradation reactor of the photocatalyst the most according to claim 1 main inducement parameter Auto-Sensing of reunion, it is special Levying and be, the hole spread all in the microwave constrainer self structure of this caged or its magnitude range of mesh are between 0.5 centimetre and 3.0 Between centimetre.