CN103253804B - The Microwave photocatalytic wastewater degradation device expansion method of agglomeration tendency self-detection - Google Patents

Abstract

The present invention relates to the Microwave photocatalytic wastewater degradation device expansion method of a kind of agglomeration tendency self-detection, belong to technical field of waste water processing.In existing correlation technique, have that catalyst runs off, reactor list tank wastewater treatment capacity is less than normal, repetitive operation frequency is high, degradation reaction terminal moment difficulty is distinguished, agglomeration thing cannot strength dissipates in situ, agglomeration occurs to be perceived in time etc. problem, and this case is intended to solve above-mentioned series of problems totally.Its key step of this case method includes: cut off microwave exposure spatial domain；Significantly extend, expand reactor size；Pack, guiding bubble stream so that it is intensively discharge towards emphasis degradation reaction region；Catalyst particles is finely intercepted by external cascade filter；By the ultrasonic in situ strong catalyst agglomerate from reactor bottom recess, incidentally clean quartz ampoule simultaneously；Degrade terminal with ozone sensor perception, and be automatically switched off line related at this terminal；Actively detect agglomeration main inducement parameter.

Description

The Microwave photocatalytic wastewater degradation device expansion method of agglomeration tendency self-detection

Technical field

The present invention relates to the Microwave photocatalytic wastewater degradation device expansion method of a kind of agglomeration tendency self-detection, belong to C02F Technical field of waste water processing.

Background technology

Microwave and photo catalysis degradation treatment technology, as a kind of effective for the harmless treatment skill containing organic pollution industrial wastewater Art, the most interesting.

About microwave and photo catalysis degradation technique, as an example, may refer to the Chinese patent Shen of Publication No. CN102260003A Please case.

The disclosure number is the Chinese patent application case of CN102260003A, is using microwave as excitaton source, excites electrodeless ultraviolet lamp Launching ultraviolet, irradiate the suspension mixed with photocatalyst titanium dioxide in liquid internal, this electrodeless ultraviolet lamp is by quartz ampoule institute cage Cover protects, and is free air pump persistently to inject air to this quartz ampoule inner chamber, quartz cavity the air overflowed via pipeline be positioned at anti- Answering the micro porous aeration head UNICOM bottom device, the lower zone of this inside reactor is aeration zone, the upper area of this inside reactor Being microwave and photo catalysis reaction zone, the program also with the membrane separation assemblies that reactor is built-in, carries the water after analysis purifies, and with this film Separation assembly realizes retaining of photocatalyst titanium dioxide fine particles and uses；The program also non-polar ultraviolet light source and membrane separation assemblies it Between set up dividing plate, for preventing the ultraviolet radiation damage to organic membrane separation assemblies；It is passed through the air of inside reactor, Part the most directly participates in relying on the photocatalytic degradation of photocatalyst titanium dioxide to react, some air, direct at ultraviolet light Under irradiation, generating a certain amount of ozone, the ozone of this generation the most also plays the direct oxidative degradation for organic pollution Effect.

The disclosure number is that the Chinese patent application case of CN102260003A is certainly for microwave and photo catalysis wastewater degradation technology Progress serves very important impetus, and the work that its research staff is launched in this field is admirable.

Meaning based on sincere admiration, and, common striving direction, to be talked below us is problem.

The problem below will spoken of, has 11；These 11 problems are arranged side by side 11 problems；The priority of its sequence Consider easily merely for the sake of discussing.

One of problem:

The disclosure number is the Chinese patent application case of CN102260003A, and it divides for the film intercepting catalyst titanium dioxide fine particles It is to be placed in reactor inner chamber from assembly, is immersed among process object liquid, and relies on washing away containing ozone bubbles of ascension Membrane separation assemblies, the institute's catalyst particles that adsorbs, be detained that thereby removes its surface, reach the recovery of catalyst particles, recycling Purpose, meanwhile, it is self-cleaning and keep its separating power that membrane separation assemblies is also dependent on this mode, then, based on this structure, only Business curtain hollow fiber film assembly or plate film assembly can be selected, and, this membrane separation assemblies is to need to be immersed in ozone In the context of the strong oxidizing property of bubble ascension, therefore, the tolerance against oxidative power of membrane separation assemblies is necessarily required, common material The organic membrane separation assembly of matter is not resistant to such use environment, therefore can only select the membrane separation assemblies of PVDF material, this Point clearly illustrates in the 0009th section of word of this case disclosure and claim 3；This kind needs special tolerance against oxidative power Its material of filter membrane is relatively costly, and its commercially available price is certainly also above common organic micro-filtration membrane module of non-oxidation durability requirements；Change Sentence is talked about, and the frame mode of this case causes the material of membrane separation assemblies to be limited to PVDF material costly.Further, dress Putting interior possible ultraviolet light to reveal, may touch organic membrane assembly, this organic membrane assembly material also required that in device can be resisted Ultraviolet light irradiation, from the point of view of this, organization plan based on this device, the material of organic membrane separation assembly also can only be limited in PVDF material costly.

Organic membrane assembly, compared to ceramic filter assemblies, has its obvious advantage；About this point, special for filtering technique For the personage of industry, it is known, does not the most launch to repeat.

So, under the premise using organic material membrane module, this PVDF filter membrane material limitation can be bypassed？This is One needs the problem solved, and this is one of problem.

The two of problem:

In view of scouring force, the cleaning capacity of described ascension bubble are more weak, therefore, with this cleaning mode with the use of membrance separation The filter opening aperture of bigger microfiltration rank can only be selected in its aperture of assembly, and the filter opening aperture of this microfiltration rank is 0.1-0.2 micron, About this point, have in the 0009th section of word of this case disclosure and claim 3 equally and clearly limit, this kind of filter opening aperture Limit, from the type selecting of the such membrane separation assemblies of this case, built-in and soak from the point of view of occupation mode, the self-cleaning method of ascension bubble, be Inevitable, its filter opening aperture can only be limited in microfiltration rank.In other words, this in the way of ascension bubble washes away its scouring force, Cleaning force is the most weak, to such an extent as to cannot tackle the filter membrane of more small-bore at all, and thus, in this case device, filter sizes limits Between 0.1 micron-0.2 micron, it it is the inevitable choice not discussing leeway.

The filter opening aperture of so-called 0.1-0.2 micron, if changing a measurement unit, corresponding is exactly the filter opening hole of 100-200 nanometer Footpath；That is any concept？For 100 nanometer filter opening apertures of its lower limit, its size of catalyst particles that it can intercept Must be more than 100 nanometers, and cannot be intercepted less than the catalyst particles of 100 nanometers；In other words, less than 100 The catalyst particles of nanometer by being directed through, by the filter opening of membrane module, be mixed into so-called water purification that degradation reaction device exported it In.

Need now to have a talk the particle diameter of photocatalyst involved by ultraviolet catalytic degradation reaction and photocatalyst dosage form selection.

The professional person being engaged in photocatalytic degradation research both knows about, and reacts with the photochemical degradating of uv light induction, and its catalyst is many Select titanium dioxide fine particles catalyst；At present, laboratory level has been developed for various in style urging based on titanium-dioxide photo Changing the light degradation particle catalyst of characteristic, certainly, the light degradation catalyst that these different preparation methods are formed, its particle diameter is also It is various；Its particle diameter of photocatalyst that different preparation methoies are made is little to 20 nanometers, greatly to 100000 nanometers namely 100 microns, Have, be wherein no lack of the photocatalyst kind of excellent performance；But, due to performance long-time stability evaluate, preparation cost and The restriction of market expansion etc. aspect factor, most of its deliverability of described photocatalyst is limited only to laboratory level, And do not have to form the most commercially available level of production；The most known can make a big purchase in large quantities commercially available can be actual a large amount of The photocatalyst for ultraviolet light wave band used is famous gas phase titanium dioxide P25；Its concrete skill of gas phase titanium dioxide P25 Art implication, insider both knows about, and does not the most launch to repeat；The mean diameter of gas phase titanium dioxide P25 is 21 nanometers；Gas Phase titanic oxide P25 performance not very optimum, but, its stable performance, it is important to can commercially make a big purchase in large quantities and obtain, and Can use the most in a large number, therefore, the most usually be used as weighing respectively with P25 catalyst in photocatalysis specialized laboratory Plant reference pointer or the contrast pointer of self-made photocatalyst catalytic performance, it is true that in view of the feature of ultraviolet catalytic degradation reaction, The photocatalyst that dispersion is the highest, is suitable for the needs of this type reaction, say, that mean diameter is at the light of 21 ran Catalyst its catalyst interfacial area that can provide, anti-settling ability, catalytic performance long-time stability etc. aspect, comprehensive and Speech, is optimal.Simply, at present, good and cheap, it is possible to the actual ready-made commercially available business making a big purchase in large quantities, using The photocatalyst of the ultraviolet light wave band of grade, it is simply that mean diameter is the gas phase titanium dioxide P25 catalyst of 21 nanometers；In industry The application of scale, this mean diameter be the photocatalyst of 21 nanometers be actual first-selection.

Already described above and, the disclosure number is the Chinese patent application case of CN102260003A, and it is for intercepting the film of photocatalyst Assembly, is the catalyst particles that stripping film assembly surface adsorbs, deposits that washes away with ascension bubble, but, this kind is to rise Rise its scouring force of mode that bubble washes away, cleaning force the most weak, to such an extent as to the filter membrane of more small-bore cannot be tackled at all, therefore, In this case device, filter sizes is limited at microfiltration filter opening rank between 0.1 micron-0.2 micron, for changing a measurement unit, In this case device, filter sizes is limited at the microfiltration filter opening rank between 100 nanometer-200 nanometers, and this is not discuss leeway Inevitable choice；This case certainly cannot intercept as above flat without the microfiltration filter opening between selectable 100 nanometer-200 nanometers All particle diameters are the gas phase titanium dioxide P25 granule of 21 nanometers；So, if using P25 photocatalyst, this catalyst will completely Cannot intercept, and flow in so-called water purification, form secondary pollution, certainly also result in the heavy losses of catalyst and unrenewable； Even if using the titanium dioxide optical catalyst of the big particle diameter special for this of other kind, it collides because of mutual during using Or collide with wall, inevitable also can produce a large amount of small particle fragment, wherein particle diameter is less than the fragment of 100 nanometers, equally can not be by Microfiltration filter opening between 100 nanometer-200 nanometers is intercepted, these fractionlets also can through its membrane module enter so-called water purification it In, form secondary pollution.

Visible, the disclosure number is the Chinese patent application case of CN102260003A, and it is for the interception structure of photocatalyst microgranule The cleaning solution of scheme and related film assembly is the most undesirable.

Therefore, how under the premise of this case advantage of incorporating things of diverse nature, reach the fine interception for photocatalyst microgranule and return Receiving use again, be a important topic the most worth thinking deeply about, this is the two of problem.

The three of problem:

It is known that liquid water body itself also is able to absorb the energy of microwave, and cause the liquid water body that is processed itself Temperature-rise effect, and this with wastewater treatment process the temperature-rise effect that occurs, be not the most our situation of being expected, in other words Saying, the microwave energy from magnetron is used for exciting electrodeless ultraviolet lamp the most completely, and has quite a few should be served only for swashing The microwave energy sending out electrodeless ultraviolet lamp is dissipated in described temperature-rise effect, and it is unnecessary that the temperature-rise effect that this kind is not fond of causes Microwave energy waste, in view of disclosed above number be CN102260003A the apparatus structure side that shown of Chinese patent application case Case, its rational approach, can only be to reduce single tank process capacity in other words by the volume of minimizing microwave and photo catalysis reactor to come Reach the purpose weakening the unnecessary dissipation of microwave, about this point, in this its detailed description of the invention of CN102260003A application case Clearly have expressed the suitable size overall about this apparatus structure, what its expressed preferred size was corresponding is exactly that a profile is the least Device, then, consequently, it is possible to the distance of reactor wall and microwave radiation source is little, the wastewater flow rate contacted with microwave is little, The microwave energy that waste water is absorbed is the least, corresponds ground, and the wastewater treatment capacity of single tank is the least, more specifically Ground is said, the internal capacity corresponding to device suitable size expressed in embodiment is 40 liters, namely single tank wastewater treatment capacity is 40 liters, i.e. 0.04 cube, in other words, its once a complete set of, substantial length of operation solve only the industrial wastewater of 0.04 cube, then, Being accomplished by the repetition operated by a complete set of head to tail carried out many times, the cumulative of its treating capacity just has plant-scale meaning, So to say, the most individual analogy substantially, 0.04 cube of such waste water of single tank that its preferred structure size of this case is generally corresponding to Treating capacity, need to repeat 1000 times by a complete set of head to tail, substantial length of operation, its accumulation amount, can be only achieved 40 cubes such one Individual have industrial level wastewater treatment capacity, the most loaded down with trivial details repetitive operation will cause the serious waste of human and material resources, Visible, the wastewater degradation treatment effeciency of its reality of scheme that this kind is shown by CN102260003A may not be fully up to expectations. Therefore, how on the premise of not causing the waste of more microwave energy or reducing microwave energy waste, increase single tank wastewater treatment capacity, Reduce the unnecessary too many by the repetitive operation number of times of head to tail of this batch (-type) wastewater treatment equipment, improve its waste water and process effect Rate, is a significant technical problem merited attention.

On the other hand, according to the literature, some system, in the case of microwave direct irradiation wastewater liquid, photochemical catalysis is dropped Solve efficiency and truly have raising, say, that in some system, between microwave direct irradiation wastewater liquid and photochemical catalysis degraded, There is certain coupling.

Therefore, how on the premise of taking into account described coupling, improve the treatment effeciency of wastewater degradation device, be worth inquiring into, This is the three of problem.

The four of problem:

The scheme that this kind is shown by CN102260003A, the bubble of the internal unrestrained cloth ascension of its retort, for driving a reaction tank The shuttling movement of the relatively large yardstick of internal liquid, contributes the most inadequate；Certainly, this weak point, for CN102260003A In scheme such as its detailed description of the invention the fact that clear expression for upper corresponding small size, low capacity device, almost without what Observable impact.From the point of view of plant-scale application demand, undersized can not the device of divergence process amount certainly the most much Captivation；So, as a kind of probability, if there being certain mode to be capable of the significantly expansion for the treatment of capacity, under this situation, Its importance of shuttling movement of the relatively large yardstick of retort internal liquid will highlight naturally；Imagine the most this process The probability that amount is significantly expanded, then, how to strengthen the shuttling movement of the relatively large yardstick of retort internal liquid, be certainly exactly Individual problem, this is the four of problem.

The five of problem:

For the photochemical catalysis oxidation reaction of ultraviolet light wave band, this kind of oxidation is anti-to have the most several following key element to influence whether The efficiency answered, first ultraviolet wavelength, intensity, it two is photocatalyst in the particle diameter of photocatalyst, unit volume reactant liquor Usage amount, himself catalytic performance etc. of photocatalyst, it three is organic concentration in oxidized object i.e. water body, has Oxidation complexity that machine thing molecular structure is determined himself etc., it four is the sufficient degree of oxygen atmosphere, in other condition In the case of identical, the sufficient degree of oxygen atmosphere, will become and affect an act foot of photochemical catalysis oxidative degradation ability gently The key element of weight.

The scheme shown such as CN102260003A, its numerous micro porous aeration heads being placed in reactor inner chamber bottom overflow cloth the end of at Portion, and by its alleged water distributing plate so that this micro porous aeration head overflows the effect of cloth arrangement and becomes more very, certainly, this for For using the situation of oarse-grained micron-sized photocatalyst of relatively easy sedimentation, really there is its favourable one side, but, From the point of view of another side, this micro porous aeration head overflows the mode that cloth arranges, and the supply of oxygen atmosphere excessively disperses, and needs most The region that need to strengthen oxygen supply is the most effective region of photochemical catalysis oxidation, due to effective in liquid water body of short wave ultraviolet Penetration depth only has 20 cm, therefore, needs most enhanced oxygen blowing real with the effective coverage promoting photochemical catalysis oxidation course It is exactly the region within quartz ampoule periphery about 20 cm distance on border, in other words, within quartz ampoule periphery about 20 cm distance Region be the region really needing the supply of enriched with oxygen atmosphere to ensure, oxygen atmosphere supply in this region is the strongest, and oxidation reaction is also Just it is proceeded more quickly；The most especially, producing electrodeless ultraviolet emission in microwave excitation mode, its feature can be accomplished greatly exactly Power, high intensity, this is the strong point of this lamp-type of electrodeless ultraviolet lamp, but, just because of its purple extraradial high power, high-strength Degree, just mates with greater need for powerful oxygen atmosphere supply capacity, and otherwise, that powerful ultraviolet radiation energy power is just Really major part is wasted.Above it is stated that, the scheme shown such as CN102260003A, factors limits Its reactor size, limits its actual treatment capacity, as its specific embodiment clearly illustrates, that Can be a single tank single treatment amount little reactor that only has about 40 liters, in the case of such little reactor, little inner chamber, Because size is the least, then, its shortcoming in terms of photochemical catalysis oxidation effective coverage oxygen supply concentration degree, would not The most obvious, it might even be possible to ignore, a problem the most non-existent can be regarded the most completely as, in the face of such Undersized little reactor, the shortcoming problem in terms of oxygen supply concentration degree, not may float mind；However, it is contemplated that Once, if described many limiting factors can be overcome, if can have that way actual implementation one is large-scale, high throughput anti- Answer device, then within above-mentioned quartz ampoule periphery 20 cm distance, effective coverage oxygen supply strengthening problem will show especially out, particularly with Using electrodeless ultraviolet lamp as the situation of UV source, within above-mentioned quartz ampoule periphery 20 cm distance, effective coverage oxygen supply is strengthened Problem is not more allowed to despise, therefore, how among the structure of possible large-scale photo-catalytical oxidation degradation reaction device, Strengthen the oxygen supply concentration degree of described effective coverage, improve the usefulness of wastewater degradation equipment, it is simply that the problem that individual needs are kept a close watch on, this is The five of problem.

The six of problem:

Within this CN102260003A scheme pumps air into the quartz ampoule including electrodeless ultraviolet lamp, reach the logical of electrodeless ultraviolet lamp Wind cooling, the purpose of cooling, and those flowings are through the air of quartz ampoule, because of by ultraviolet irradiation, some air meeting Being changed into ozone, therefore, the air flowed out from quartz ampoule is exactly the air containing some ozone certainly, and this is contained smelly by the program Oxygen air is transferred to be positioned at micro porous aeration head below reactor, and disengages from micro porous aeration head, these containing ozone bubbles from lower On ascension during, ozone contained therein can meet with the organic molecule that runs among distance and redox reaction occurs, This redox reaction can consume a part of ozone certainly, this be do not have doubt, but, above it is stated that, as The scheme that CN102260003A is shown, the many factors that cannot ignore certainly existed limit its reactor size, Limiting its actual treatment capacity, as clearly illustrating in its specific embodiment, that can only be a single tank single Treating capacity only has the little reactor of about 40 liters, in the case of such little reactor, little inner chamber, because overall dimension itself The least, then, the longitudinal size of its reactor inner chamber or regard as with reckoning in every item contain the liquid degree of depth also can only be one the least Size, clearly illustrates among this size such as its detailed description of the invention, the most about 40 centimetres, and the Sheng that reckons in every item liquid is deep Spend the most only 40 centimetres, actually contain the liquid degree of depth and be certainly less than this number, just analyze with the Sheng liquid degree of depth of 40 centimetres, that , this Sheng liquid degree of depth of 40 centimetres is what concept？That is to say, containing ozone-air ascension by the path of waste water only Having short 40 centimetre, this path is the shortest, passes through at a gallop containing ozone-air bubble and only only has 40 centimetres of deep water bodys, The shortest for time of contact with water body, contained in bubble ozone, can only have small part to be used for oxidative degradation Organic substance, And most ozone actually simply passes by liquid simply, effusion emptying through exhaust port from liquid level, briefly, The Oxidation potentiality major part of these ozone is wasted, and, effusion, the ozone that is wasted actually can cause need not The air pollution wanted；This case main inventive people once beat via micro porous aeration head with normal domestic use ozone machine in one meter of deep tank Enter containing ozone-air, in the case of the depth of water degree of depth reaches one meter, remain able to substantially smell the abnormal smells from the patient of ozone near the water surface, can See, that 40 centimetres of deep Sheng liquid degree of depth, it is clear that be to be not enough to fully utilized ozone；Visible, electrodeless ultraviolet light chemistry is urged For changing the such equipment of wastewater degradation reactor, ozone utilizes incomplete problem to be also required to pay close attention to, it is clear that Ren Mengeng It is contemplated that the reactor of wastewater degradation without extreme ultraviolet that ozone utilizes more completely, contaminative exhaust emissions is less, this is the six of problem.

The seven of problem:

Its running of waste water catalytic degradation reaction device, requires the expenditure of energy, and therefore, operator are bound to wish, work as wastewater degradation When reaction proceeds to terminal, it is possible to impartially, the most lately immediately stop continuing to inject to inside reactor Energy；If the moment stopping Implantation Energy is too early, then wastewater degradation is incomplete；And if reaching reaction end already, the most still The most unceasingly to inside reactor Implantation Energy, that is certainly the energy in waste preciousness.As this case technical background Its structure of CN102260003A scheme can not provide any instant information to the wastewater degradation reaction end moment, then, just The terminal that wastewater degradation reacts can only be estimated by experience；And estimate, by experience, the terminal that wastewater degradation reacts, that obviously can not Satisfactory；So, how to make neither the most undelayed instant information output for the wastewater degradation reaction end moment, And immediately close the energy input to reactor in the just right moment, it is simply that a technical threshold that can not despise, this is The seven of problem.

The eight of problem:

Accept the described industrial wastewater of microwave and photo catalysis degradation treatment, be mingled with some the most unavoidably and originate from mechanical system abrasion process The material of metal particle and carbon granules etc, even if quantity is small, its existence is almost difficult to avoid that, the disclosure number is Described organic membrane separation assemblies in the Chinese patent application case of CN102260003A is installed in microwave and photo catalysis reaction zone, its In be installed between quartz ampoule and membrane separation assemblies certainly do not stop microwave for intercepting the dividing plate of ultraviolet, so, micro- The practical function region of ripple necessarily covers organic membrane separation assemblies institute installation area described in the program, based on membrane separation assemblies Working mechanism, its accumulation process on membrane separation assemblies organic matter top layer of the microgranule of metal particle as above and carbon granules etc It is difficult to avoid that, and the microgranule of this type of described metal particle and carbon granules etc, exactly the good absorption medium of microwave energy, inhale The microgranule of described metal particle and the carbon granules of having received the accumulation state of microwave energy etc, its organic plasma membrane being close to can be divided by nature Produce from the top layer of assembly and based on heat penetration erosion mechanism lasting pierce destruction, be as noted previously, as this CN102260003A The structures shape of its device of application case can only select polyvinylidene fluoride film material, this polyvinylidene fluoride film material heatproof about 140 degrees Celsius, More certain than general film material heatproof high much, but, described metal particle and carbon granules of absorbing the accumulation state of microwave energy etc Its point-like of microgranule pierce the heat penetration erosion effect of formula and the most easily break through the heatproof temperature limit of this polyvinylidene fluoride film material, due to above-mentioned former Cause, well imagines, the pvdf membrane material in this its device of CN102260003A application case its actual life will be the lowest In the preferable service life expected, the structure of this CN102260003A its device of application case, determine in this structural frames Under frame, above-mentioned point-like pierce formula heat penetration erosion destruction problem cannot avoid；Therefore, how to get around this point-like and pierce the heat penetration erosion of formula Destruction problem, also needs to consider, and this is the eight of problem.

The nine of problem:

The disclosure number is the Chinese patent application case of CN102260003A, the 0008th section of word of its description disclosure text And claim Section 2, the catalyst particle size scope being suitable for for its device, there is a restriction, this particle size range limits It is that 20 nanometers are to 100 microns.It is known that some pH value be pre-adjusted not in place, pH value inappropriate in the case of, Titanium dioxide fine particles is susceptible to reunite, and then affects its effective working interface area, affects its photocatalysis usefulness；Particularly with The section of those the relatively small particle diameters among this particle size range, easily occurs because of presetting not in place, the pH value of pH value not especially Appropriate and the agglomeration traits that causes: for this catalyst particles in the case of of reuniting, is immediately to adopt an effective measure, enters The depolymerization of aggregate is operated by the hand-manipulating of needle；But, we, among this CN102260003A scheme, do not see any having Help immediately dissolve the structure of this problem or can immediately dissolve the scheme prompting of this problem.For such as CN102260003A scheme can only be the reactor of small scale structures because factors limits just like that, still can the most directly carry React device, carries out toppling over and inspecting outside reactor, process above-mentioned reunion situation, then, hold if likely expanding it Amount, the most so to say, if being the several cubes of large-scale reactors to dozens of cube or huge reactor, that is the most not It is manual to topple over it and operate the problem that can tackle, then, for this catalyst particles in the case of of mutually reuniting, how Realize instant disposal in situ, it is simply that a technical problem, this is the nine of problem.

The ten of problem:

The disclosure number be CN102260003A Chinese patent application case expressed by apparatus structure in, protect electrodeless purple for screen The quartz ampoule of outer lamp, its outer wall, refer to the outer wall of quartz ampoule, through for a long time with the contacting, unavoidably of processed industrial wastewater Gradually dirty, the material that dirt amasss the most mainly is difficult to the mineral-type impurity touched by light-catalyzed reaction, because of the formation of this mechanism Dirty phenomenon, is easy to be observed after equipment long-play；It is attached to the dirty lamination of described quartz ampoule outer wall, although The veryyest thin one layer, also be enough to cause the ultraviolet radiation of electrodeless ultraviolet lamp significantly stop, and this will cause this microwave light to be urged The actual treatment effect changing reaction treating device significantly reduces；In its reactor, the bubble of unrestrained cloth ascension is because excessively disperseing, scouring force Measuring more weak, if only relying on this more scattered bubble to maintain the bright and clean of quartz ampoule surface, really undertaking to do what is apparently beyond one's ability, in other words Saying, this more scattered bubble, what it was more weak wash away strength is still not enough to stop completely the dirty process on this quartz ampoule surface；? During the use of laboratory yardstick, above-mentioned fouling problem is subtle, but, on commercial Application yardstick, this fouling problem Certainly will highlight；Therefore, how on the premise of not tearing machine open, immediately, effectively remove on this quartz ampoule outer wall Dirt lamination, maintains the lasting high efficiency of this microwave and photo catalysis processing means, and this problem is the most very important, and this is the ten of problem.

The 11 of problem:

Nine its problems derived of this problem problem by addressing above.Above speak of, some pH value be pre-adjusted less than In the case of position, pH value are inappropriate, titanium dioxide fine particles is susceptible to reunite, and then affects its effective working interface area, Affect its photocatalysis usefulness；Particularly with among its suitable catalyst particle size range that this CN102260003A scheme is touched upon The section of those relatively small particle diameters, easily occur especially because of pH value presetting not in place, pH value is incorrect and the group that causes Poly-problem；For this catalyst particles in the case of of reuniting, it is immediately to adopt an effective measure, carries out for aggregate Depolymerization operates；Based on this its framework of CN102260003A scheme, operator cannot immediately perceive inside reactor and institute occurs State the situation of reunion, thus also cannot make instant disposal, thus, should be limited by factors and can only be small scale structures Its limited usefulness of reactor can reduce further；Therefore, among the application of reactor operates, particularly, for example, Among the application of possible large-scale reactor or huge reactor operates, the most immediately awareness inside reactor catalyst particles The main inducing parameter reunited, is a key issue, and this is the 11 of problem.

Summary of the invention

The technical problem to be solved is, with CN102260003A scheme as technical background, for address above One of this its existing problem of technical background scheme, two, three, four, five, six, seven, eight, nine, ten, 11, and hold concurrently Turning round and look at collaborative, the coupling of microwave exposure excitation and photochemical catalysis degraded, research and development one can solve this series totally and ask The new method of topic.

The present invention solves described technical problem by following scheme, and the program provides the microwave light of a kind of agglomeration tendency self-detection to urge Changing wastewater degradation device expansion method, the key step of the method is as follows: a, with the microwave exposure spatial domain of the caged of metal material The quartz ampoule that its inner bay is provided with electrodeless ultraviolet lamp is wrapped up by constrainer so that the microwave exposure that quartz ampoule is in this caged is empty The inside of region constraint device, the locations of structures of microwave exposure spatial domain its entirety of constrainer of this caged is in wastewater degradation reactor Portion, the microwave exposure spatial domain constrainer of the caged of this metal material is exactly a metal cage, is a mass of hole in its structure of this metal cage Hole or mesh, the function of the microwave exposure spatial domain constrainer of this caged is to retrain therein, microwave exposure spatial domain thereby at cage Build microwave weak irradiation spatial domain between outer wall and the inwall of reactor of the microwave exposure spatial domain constrainer of shape or microwave zero irradiation is empty Territory；B, probes into the inside of wastewater degradation reactor by the waveguide being derived from magnetron, and this waveguide is probeed into wastewater degradation That one end of inside reactor and the inner chamber of described metal cage carry out UNICOM, and described UNICOM refers to the connection in microwave channel meaning With through；C, by a profile shape like the circulation guide major part arranged orthogonal facing downward of the through simple cone in two ends in institute Stating the underface of metal cage, and make its major part horn mouth of this circulation guide be in vacant state, the function of this circulation guide is Pack is from the ascension path containing ozone-air bubble of micro porous aeration head, and by the bubble stream of the ascension because being strengthened by pack Pull strength to lead inside reactor liquid to make the shuttling movement of relatively large yardstick；D, follows described in micro porous aeration head immigration Its major part horn mouth edge of ring guide is within the scope of vertical projection in reactor inner chamber bottom surface is drawn a circle to approve；E, at three-dimensional Microwave weak irradiation spatial domain or the size in microwave zero irradiation spatial domain described in upper extension, expansion inside reactor；F, in the outside of reactor Setting up booster pump, this booster pump is mixed with the water after the degradation reaction of catalyst suspension grain for supercharging pumping, and by this booster pump Water inlet end couple with the inner chamber of reactor；G, by the water side of described booster pump and the preposition prefilter of back flush type Water inlet couples, and the filter opening aperture of the preposition prefilter of this back flush type is between 5 microns and 300 microns；H, will The pure water inlet of the preposition prefilter of described back flush type filters with back flush type doughnut membrane microfiltration via first water purifying valve The water inlet of device couples, and the filter opening aperture of this back flush type doughnut membrane microfiltration filter is received with 1000 between 25 nanometers Between meter；I, by the pure water inlet of described back flush type doughnut membrane microfiltration filter via second water purifying valve and back flush type The water inlet of hollow-fibre membrane ultra filtration filter couples, and the filter opening aperture of this back flush type hollow-fibre membrane ultra filtration filter is situated between Between 15 nanometers and 2 nanometers；J, by the outlet of sewer of preposition for described back flush type prefilter via first sewage valve with The inner chamber of reactor couples；K, by the outlet of sewer of described back flush type doughnut membrane microfiltration filter via second Sewage valve couples with the inner chamber of reactor；L, by the outlet of sewer of back flush type hollow-fibre membrane ultra filtration filter via the 3rd Individual sewage valve couples with the inner chamber of reactor；M, sets up ozone sensor in reactor tail gas floss hole position；N, should The probe tube of ozone sensor shifts near reactor tail gas floss hole or stretches into the inside of reactor tail gas floss hole；O, by this ozone Its ozone faradism signal output circuit of sensor and ozone content display, ozone attention device or ozone content display and ozone The composite structure of attention device couples；P, by this ozone sensor its ozone faradism signal output circuit and power-supply controller of electric Coupling, this power-supply controller of electric is the power supply control that can carry out on and off switch action according to its described electric signal received Device；Q, is coupled this power-supply controller of electric with magnetron by cable；R, by this power-supply controller of electric by another cable with Air pump couples；S, moulds this reactor inner chamber bottom surface and makes it present the pattern the most hollow to central area by periphery, institute State its gradient hollow between 5 degree and 35 degree；T, in the part corresponding to this its hollow bosom, reactor inner chamber bottom surface Ultrasonic transducer is installed in the lateral surface position of reactor diapire or medial surface position；U, passes through high frequency by this ultrasonic transducer Vibration electric signal transmission cable couples with higher-order of oscillation electric signal generator；V, stretches pH probe through the top of reactor Enter reactor inner chamber, and with the micropore rustless steel sleeve of the cap for brush shape made through powder metallurgical technique this pH popped one's head in it extend into The part of reactor inner chamber carries out suit and goes along with sb. to guard him；W, couples this pH probe with pH analyser；X, analyzes this pH Instrument couples with siren, and this siren is for the pH value situation of transfiniting is sent alarm；Y, this cap for brush shape micropore not Fluorubber or the buffering isolating pad of silicone rubber material are wedged in rust junction between steel bushing its opening end and reactor head.

Involved pH probe is commercially available；Described pH probe also known as pH sensor；PH probe or say itself skill of pH sensor Art is meant that known.

Involved pH analyser is commercially available；Itself art-recognized meanings of pH analyser is known.This case pH analyser one word is general Refer to pH can be utilized to detect, picking up, showing pH value information of any model, and can externally export pH and be correlated with electric signal Instrument, market is sold simple or complicated but all meet the pH correlate meter of this basic demand it is various in style, Can select as required.

Involved buffering its thickness of isolating pad does not limits；But, have a preferred range, the preferred scope of this buffering its thickness of isolating pad Between 1 millimeter to 8 millimeter.

Themselves art-recognized meanings of involved fluorubber and involved silicone rubber is known；Involved fluorubber and involved silicone rubber, city Field is the most on sale.

Involved micropore its wall thickness of rustless steel sleeve does not limits；But, also have an associated preferred scope, this micropore rustless steel The preferred scope of its wall thickness of sleeve is between 3 millimeters to 30 millimeters.

An involved powder sintered word, the art-recognized meanings of itself, for the professional of metallurgical technology field, is known.

Involved micropore rustless steel sleeve, can customize to relevant powder metallurgy specialized factory.

The sleeve-shaped micropore stainless steel filter conversion that can be made by powder sintering process is the micropore stainless steel sleeve described in this case Cylinder；The sleeve-shaped micropore stainless steel filter that described powder sintering process is made is commercially available.

The aperture of involved micropore rustless steel its micropore of sleeve does not limits；But, the aperture of this micropore is also to have a preferred range, should The preferred scope of micropore size is between 0.5 micron to 50 micron.

Described siren is can to send audio frequency warning message or the device of optical frequency warning message according to its received electric signal； Itself art-recognized meanings of described siren is known；Described siren is commercially available.

Itself art-recognized meanings of ultrasonic transducer one word is known for the professional in ultrasonic technology field.

Itself art-recognized meanings of higher-order of oscillation electric signal transmission cable one word is for the professional in ultrasonic technology field Also it is known.

Ultrasonic transducer and higher-order of oscillation electric signal transmission cable market are the most on sale；Described ultrasonic transducer and higher-order of oscillation electricity Signal transmission cables etc. also can customize to ultrasonic transducer specialized factory and cable specialized factory.

Itself art-recognized meanings of higher-order of oscillation electric signal generator one word for the professional in ultrasonic technology field also It is known；Various higher-order of oscillation electric signal generator is commercially available；Described higher-order of oscillation electric signal generator also can be to ultrasound wave Equipment specialized factory customizes.

Involved ozone sensor is commercially available；Customize to ozone sensor specialized factory also dependent on needs.

Involved ozone content monitor market is on sale；Also dependent on needs to the customization of ozone content display specialized factory；Ozone passes Matching used ozone content display is generally also sold by sensor producer.

Involved ozone attention device, refers to warn that sound or alarm flashing or warning sound combines with alarm flashing that both are double And have for warning mechanism；Ozone attention device is commercially available；Also can be to the customization of ozone attention device specialized factory；Ozone passes Matching used ozone attention device generally also can be sold by sensor producer.

This power-supply controller of electric involved is the power-supply controller of electric that can carry out on and off switch action according to its described electric signal received； The power-supply controller of electric of on and off switch action can be carried out only with regard to its circuit engineering itself according to its electric signal received, be Through ripe, known technology；Described power-supply controller of electric is commercially available；It is possible with commercially available power-supply controller of electric to enter as required The row transformation of the way；Described power-supply controller of electric also can customize to power-supply controller of electric specialised manufacturers；The electronic device of power-supply controller of electric etc its Specialised manufacturers spreads all over the world.

Described in this case, spatial domain one word refers to space, territory, boundary.

Described its outline shape of circulation guide or also can be described as the profile shape cooling tower like thermal power plant.

Can be any metal material for making the material of metal cage；But, in view of wastewater degradation operation faced by special Environmental condition, the preferred material of this metal cage is stainless steel.

In the case of selecting to use stainless steel, the step of this case the method can also include the making step of metal cage: should Step is with rustless steel punched-plate as raw material, through molding, weld, rivet or splicing process by screw, nut making described gold Belong to cage.

In the case of selecting to use stainless steel, the step making metal cage will be such that this step is with rustless steel Silk is raw material, and woven technique makes described metal cage.

Distance between inwall and the quartz ampoule outer wall of metal cage is arbitrary, any distance all be allow, enforceable, so And, preferred scheme is, in step a, control between the inwall of metal cage and the outer wall of quartz ampoule wrapped up in it away from From, make this distance between 3.0 centimetres and 30.0 centimetres.

Further preferably scheme about the distance between metal cage inwall and quartz ampoule outer wall is, in step a, controls Distance between the inwall of metal cage and the outer wall of quartz ampoule wrapped up in it, make this distance between 10.0 centimetres with 20.0 lis Between meter.

Any metal material with sufficiently conductive property, can select and be used as waveguide material, but, in view of wastewater degradation The special environment of operation, corrosion resisting property is top-priority factor, so, the preferred material of waveguide is stainless steel.

The material of described circulation guide does not limits, and the material of described circulation guide can be such as politef material, glass Material, ceramic material, metal material, etc., but, circulation its preferred material of guide is rustless steel.

Described booster pump, is the machinery for booster pump liquor charging body, and certainly, its pumping pressure can be as desired to carry out arbitrarily Selection, and, various booster pump market is the most on sale.

Described water purifying valve, sewage valve, be all water valve, and various water valve market is the most on sale；About water valve, itself technology of this word It is meant that known；This case uses different titles, is intended merely to conveniently state, conveniently distinguish the water of each different structure position Valve.

The preposition prefilter of described back flush type is also referred to as back flush type fore filter or back flush type prefilter, described backwash Itself art-recognized meanings of the preposition prefilter of formula is known；The preposition prefilter of described back flush type is commercially available.

Described back flush type doughnut membrane microfiltration filter is adapted for the filter of microfiltration；Itself technology of described microfiltration one word It is meant that known；Itself art-recognized meanings of described back flush type doughnut membrane microfiltration filter is for technical field of membrane separation Professional for, be known；Described back flush type doughnut membrane microfiltration filter is commercially available.

Described back flush type hollow-fibre membrane ultra filtration filter is adapted for the filter of ultrafiltration；Itself technology of described ultrafiltration one word It is meant that known；Itself art-recognized meanings of described back flush type hollow-fibre membrane ultra filtration filter is for technical field of membrane separation Professional for, be known；Described back flush type hollow-fibre membrane ultra filtration filter is commercially available.

Described back flush type hollow-fibre membrane ultra filtration filter can be an only back flush type hollow-fibre membrane ultra filtration filter The form of monomer；Certainly, this back flush type hollow-fibre membrane ultra filtration filter can also be in more than one backwash by quantity Formula hollow-fibre membrane ultra filtration filter monomer is parallel with one another couples composition.

Expressing an involved word in parallel, the art-recognized meanings itself referred to is clearly.

Express involved monomer one word, refer to itself function and structure equipment completely is individual.

Similarly, described back flush type doughnut membrane microfiltration filter can be an only back flush type doughnut membrane microfiltration The form of filter monomer；Certainly, this back flush type doughnut membrane microfiltration filter can also be more than one by quantity Back flush type doughnut membrane microfiltration filter monomer is parallel with one another couples composition.

The method can also comprise the following steps: at described back flush type doughnut its pure water inlet of membrane microfiltration filter with described On the connecting pipeline of the water inlet of back flush type hollow-fibre membrane ultra filtration filter, concatenate into second booster pump, this second increasing Press pump is for augmenting hydraulic pressure to meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter；This step is not Required.

The preferred scope of the bore of its hole of described metal cage or mesh is between 0.5 centimetre and 3.0 centimetres；But, as Fruit must select to use other bore value outside this preferred scope, is also that this case is allowed, although so, it is not recommended that make By the bore value beyond this preferred scope.

This case method can further include some other steps, other step described such as: metal cage with its in wrapped up The regulating step of relative distance between quartz ampoule；Other step described is the most such as: metal cage is in the peace of wastewater degradation inside reactor The regulating step of holding position；Other step described is more such as: the change step of breather line, is installing metal cage described in this case In the case of, needing penetrating metal cage with the breather line of quartz ampoule two ends UNICOM, breather line to be carried out changes step；Institute State other step the most such as: be used for the filter of impurity screening in reactor waste water input concatenation, in order to avoid impurity particle enters anti- Answer device inner chamber；Other step described is the most such as: concatenate sedimentation tank at reactor waste water input front end, precipitable for sediment fraction Impurity；Other step described is the most such as: concatenate waste water pH value regulating reservoir at reactor waste water input front end, so that input The waste water pH value of reactor reaches equipment needs level；Other step described is the most such as: remove external being used for of that reactor The suction pump coupled with built-in membrane separation assemblies, for this step is for background technology scheme；Etc..

It is an advantage of the invention that the microwave exposure spatial domain to wastewater degradation inside reactor carries out forcing partition, this case metal cage Electrodeless ultraviolet lamp and screen thereof being protected shrouds in it with quartz ampoule, and metal cage retrains the effect spatial domain of microwave simultaneously, so, at quartz Spatial domain between pipe outer wall and metal cage inwall defines the wastewater degradation region of a microwave and photochemical catalysis coupling, and And, the multiple hole of metal cage or the structure of many meshes, do not affect waste water and reactor bottom bubbling and on air freely into and out of This spatial domain；And the spatial domain between metal cage and reactor wall, the simple pyrogenicity of microwave is absorbed by waste water water body to be contained, The most significantly weaken the unhelpful dissipation of microwave energy；This case method forces the microwave exposure cutting off wastewater degradation inside reactor empty Territory, based on this, this case method allows by significantly expanding this design volume without microwave exposure spatial domain, it is achieved one-pot reaction body Long-pending significantly expansion；This case method allows reactor list tank wastewater treatment capacity to be substantially improved, and need not worry that microwave energy is too much again Dissipate in unhelpful waste water water body temperature-rise effect.

Relying on this case method, the most single tank wastewater treatment capacity of the design volume of wastewater degradation reactor can be expanded to several cubes to number Ten cubes；The volume of hundreds of cubes of even single tank, is also to allow；Rely on this case method, expand reactor for treatment capacity After, a complete set, the frequency of omnidistance wastewater degradation equipment operation, the beneficially saving of human and material resources can be greatly reduced.

This case method is on the premise of taking into account described microwave and photochemical catalysis coupling, and for relevant wastewater degradation reactor, it sets The significantly expansion of meter capacity provides a broad space.

On the other hand, this case method makees the shuttling movement of relatively large yardstick with described circulation guide guided liquid-flow, rises in reactor The liquid stream that can pull, guide inside reactor containing ozone bubbles stream risen along the inner passage rapid increase of this circulation guide, And impact, by microwave and photo catalysis coupled reaction region after, by top area to surrounding spread, via neighboring area sink, Arrival reactor intracavity bottom region, then the inner passage of guide is converged to circulate through circulating the horn mouth of guide, continue it Circulation；The liquid shuttling movement of this relatively large yardstick guided, contributes to guaranteeing inside reactor liquid degradation reaction process Homogenization, this, for large-scale degradation reaction device, is necessary.

Its UV source of this case method is to rely on microwave excited electrodeless ultraviolet lamp, and the ultraviolet radiation feature of this lamp-type is exactly permissible Accomplish high-power, high intensity, but the Effective depth penetration that ultraviolet is in liquid water body only has about 20 centimetres, therefore, stone Region within English pipe periphery about 20 cm distance is effective coverage, and this region is exactly photochemical catalysis oxidative degradation Efficient region；This case method is with described circulation guide, and pack is from the bubble stream of numerous micro porous aeration heads so that it is concentrate Ground discharges towards quartz ampoule peripheral light chemical catalytic oxidation effective coverage, and the method is favorably improved effective district described in quartz ampoule periphery The oxygen atmosphere supply intensity in territory, helps speed up ultraviolet catalytic oxidation degradation reaction process.

Can significantly expand based on this case method, the capacity of reactor or treating capacity, described significantly expand, be by significantly expanding The design volume of microwave zero irradiation zone or the weak irradiation zone of microwave realizes, then, the lateral dimension of reactor, longitudinal ruler Very little is all significantly to expand certainly, and therefore, inside reactor is contained the liquid degree of depth and can be deepened significantly similarly, such as, and can To deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, etc., containing the feelings that the liquid degree of depth is the deepest Under condition, containing ozone-air bubble ascension path long enough, steep the time long enough contacted with water body, its ascension process containing ozone-air In just can be with abundant reducing substances fortune, and thoroughly or be close to and exhaust ozone contained in bubble up hill and dale, thus, Incomplete problem is utilized to be solved containing ozone composition oxidation potential in ozone-air bubble, and, due to long Ascension path cause ozone depletion, reactor tail gas re-entrainment would not have the ozone that can cause environmental pollution.

This case method is with external multistage filter, reaches little from aggregate bulky grain to ten number nanometer to catalyst particles The interception step by step of the collision fragment of yardstick, is close to recovery, reuse photocatalyst up hill and dale, is close to and takes precautions against catalyst loss up hill and dale And the secondary pollution caused；This hold-up interception method secondary filter can be protected to make its filtration passage from bulky grain thing step by step The rigid obstruction of matter；Wherein the pre-filtering aperture of the first order is between 5 microns and 300 microns, and its aperture of the microfiltration of the second level exists Between 25 nanometers and 1000 nanometers, its aperture of the ultrafiltration of the third level is between 15 nanometers and 2 nanometers；Such hold-up interception method, Can fully intercept nano level photocatalyst, it can be close to interception gas phase this average particle of titanium dioxide P25 up hill and dale certainly Footpath is the catalyst of 21 nanometers；Address above, the gas phase titanium deoxide catalyst of nano level P25 etc, be can be a large amount of The commercially available catalyst buied, is also durability, stability, the known excellent photocatalyst of ultraviolet light wave band photocatalysis performance, Certainly, it is also the photocatalyst in fact paying the utmost attention in industrial scale applications select；This case catalyst hold-up interception method and catalyst The practical capacity of market supply, actual kind match, blend.

Further, in this case method, it is external mechanism that catalyst intercepts mechanism, and based on the method, its filter element need not be soaked in reaction In Strong oxdiative within device, the liquid of strong ultraviolet irradiation, therefore, it can need not consider completely ultraviolet irradiation, Strong oxdiative condition Tolerance, so, just without the restriction in terms of extraordinary tolerance in the selection of filter element material, can more vast Select in selection matter kind, and entirely without the material of the PVDF must being confined to again costly etc.

Involved filters at different levels are commercially available, commercially available filters at different levels, the discharge of draining-off sewage when its sewage draining exit is exactly backwash Mouthful, this case uses this kind of back flush type equipment, is used to intercept step by step catalyst particles, the sewage draining exit of the most commercially available relevant device, The recycling delivery outlet or backflow that are used as by retaining catalyst particles by conversion in this case method use delivery outlet again.

Already described above and, can significantly expand based on this case method, the capacity of reactor or treating capacity, described significantly expand, be Realized by the design volume significantly expanding microwave zero irradiation zone or the weak irradiation zone of microwave, then, from the appearance, The lateral dimension of reactor, longitudinal size are the most all significantly to expand, and therefore, inside reactor contains the liquid degree of depth similarly Can deepen significantly, for example, it is possible to deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, etc. Deng, in the case of the Sheng liquid degree of depth is enough deep, containing ozone-air bubble ascension path long enough, the bubble containing ozone-air contacts with water body Time long enough, just can be with abundant reducing substances fortune during its ascension, and thoroughly or be close to and exhaust up hill and dale Ozone contained in bubble, thus, utilizes incomplete problem to obtain containing ozone composition oxidation potential in ozone-air bubble Thoroughly solve, and, owing to long ascension path causes ozone depletion, reactor tail gas re-entrainment would not have and can cause The ozone of environmental pollution；Only when being subject to processing reducing substances in water body i.e. organic pollution is degraded totally, in water body Through again without being available for the organic pollution of ozone oxidation reaction, those unnecessary ozone it is possible to no longer consume and pass through long Ascension path effusion liquid level；Having spoken of, among the some problem that this case solves simultaneously, is enhanced reactor The circulation of the relatively large yardstick of internal liquid, the systemic circulation mechanism that this enhances facilitates the organic dirt contained by it of inside reactor liquid The uniformity of dye thing degradation reaction process, thus, several cubes allowed at its corresponding framework of this case method are stood to dozens of Under the process capacity framework of the most hundreds of the cube volume in side, when inside reactor ullage has ozone effusion, i.e. show The degradation reaction of inside reactor has reached terminal, and be internal liquid entirety uniformity reach the terminal of degradation reaction, this One terminal point determining factor is the matching criteria that can be provided by with this case scheme；This case fills in its exhaust port position of reactor If ozone sensor, ozone detected in this locations of structures, just mean that inside reactor degradation reaction is reached home, ozone Sensor and the composite structure connection with ozone attention device or ozone content display or ozone attention device and ozone content display Connect, for providing the information that indicates accurately, this case and the electric signal by ozone sensor output to be passed by cable to operator Giving power-supply controller of electric, this power-supply controller of electric is also coupled with magnetron and air pump respectively by cable, and power-supply controller of electric is according to it Received described electric signal carries out on and off switch action, and certainly, its function mode is to receive ozone at power-supply controller of electric When the signal of the ozone effusion that sensor sends, it is automatically switched off and leads to magnetron and the power supply of air pump；This case method according to this, The terminal of inside reactor degradation reaction process can be known in time；And method according to this, when reaction reaches terminal, it is automatically switched off magnetic Keyholed back plate and the power supply of air pump, stop to inside reactor Implantation Energy in time, so can avoid unnecessary energy waste；And And, this case method according to this, when degradation reaction is reached home, it is possible to close described magnetron and the power supply of air pump in time, This power-off action also synchronizes, the same generation process terminating in a flash ozone, owing to ozone generation process is terminated in time, The a large amount of ozone that would not have more than needs disengage from described exhaust port, thus avoid unnecessary secondary pollution or say secondary Raw pollution；This case method determines the ozone that its corresponding framework do not has more than needed and is available for discharge.

Relying on this case method, the microwave exposure spatial domain of inside reactor is cut off by forcing, limits, this case and use external level Join multistage backwash filter and carry out the fine interception for catalyst particles, among this method, back flush type doughnut microfiltration Membrane module and back flush type polysulfone hollow fiber ultrafiltration membrane system are all by external and away from reactor core, and microwave can not be irradiated to institute completely Stating membrane module, based on this case the method, got around described point-like completely and pierced the heat penetration erosion destruction problem of formula, this problem thus obtains To good solution.

This case method moulds reactor inner chamber bottom surface makes it the most hollow to central area by periphery, and described its gradient hollow is between 5 Between degree and 35 degree；This case method in the lateral surface position of the part reactor diapire corresponding to described its bosom hollow Or ultrasonic transducer is installed on medial surface position；Addressing above, this case method and beneficially driving a reaction device internal liquid make phase Shuttling movement to large scale, the mode of this liquid shuttling movement is that peripheral liquid sinks, and middle liquid rises, the most constantly Move in circles；Address above, some pH value be pre-adjusted not in place, pH value inappropriate in the case of, titanium dioxide is micro- Grain is susceptible to reunite, and then affects its effective working interface area, affects its photocatalysis usefulness；Particularly with this particle size range Among the section of those relatively small particle diameters, easily occur especially because of pH value presetting not in place, pH value is incorrect and cause Agglomeration traits；For this catalyst particles in the case of of reuniting, it is immediately to adopt an effective measure, carries out for aggregate Depolymerization running；When catalyst particles generation serious agglomeration, the heavier macro aggregate of some of which is due to gravity Effect, it is intended to gradually settling to reactor intracavity bottom, this case method moulds reactor inner chamber bottom surface makes it be hollow pattern, Further, this case method its implement to make the shuttling movement of described relatively large yardstick by driving a reaction device internal liquid, this systemic circulation is transported Dynamic effect, can be by the macro aggregate that settled along the bottom surface of described hollow pattern together with the effect of ubiquitous natural gravity Slope pushes away to be swept to hollow bosom and makes them be gathered in there, and the ultrasonic transducer that this case method is installed just is being in this low-lying area Fall into innermost position, this hollow innermost region, be the region finally assembled of described macro aggregate, be also ultrasonic simultaneously Wave energy enough minimum damply, minimum distance ground, carry out depolymerization operating area the most consumingly, most effectively for macro aggregate；This Case the method can allow for minimum ultrasonic energy loss, it is achieved maximized ultrasonic depolymerization effect；This case method according to this, energy Enough converge aggregate precipitum, and the region concentrated most at aggregate precipitum, implement depolymerization running；Based on the method, it is derived from The ultrasound wave of reactor bottom also is able to other region being radiated in inside reactor liquid of course simultaneously, smaller to those The aggregate being still within suspended state plays depolymerisation；Its running of this case associated ultrasonic Splitting by radiation, is can be according to need The running started or close；This case method achieves to be disposed in situ for the instant of catalyst particles aggregate.

Photocatalytic degradation reactor protects for screen the quartz ampoule of electrodeless ultraviolet lamp, its outer wall, refers to the outer wall of quartz ampoule, warp For a long time with the contacting of processed industrial wastewater, the most gradually dirty, the material that dirt amasss the most mainly is difficult to by photocatalysis anti- Answer touched mineral-type impurity, the dirty phenomenon formed because of this mechanism, it is easy to be observed after equipment long-play； It is attached to the dirty lamination of described quartz ampoule outer wall, although the veryyest thin one layer, also be enough to the ultraviolet radiation to electrodeless ultraviolet lamp Causing significantly stop, the actual treatment effect causing this microwave and photo catalysis reaction treating device is significantly reduced by this；This case method Its step be included in reactor bottom install ultrasonic transducer step, this ultrasonic transducer irregular for accidental Among the depolymerization running that catalyst particles serious agglomeration situation is carried out, its ultrasound wave radiated, the most also can arrive quartz ampoule Position, this ultrasound wave, while carrying out depolymerization running in situ, carries out amassing the super of thing for quartz ampoule surface dirt the most in the lump Sound cleaning scale removal work；Further, this ultrasonic transducer is away from quartz ampoule position, when ultrasonic radiation arrives quartz ampoule position Having decayed, therefore, the ultrasonic impact suffered by quartz ampoule surface is low intensive ultrasonic impact, and this is low intensive Ultrasonic impact can leniently scale removal, be avoided that again or significantly weaken its quartz ampoule surface being likely to result in of ultrasonic cavitation Fineness is lost；Based on this case method, it is possible on the premise of not tearing machine open, immediately, effectively remove on this quartz ampoule outer wall Dirt lamination, this case method contributes to safeguarding the lasting high efficiency of this photocatalytic degradation reactor.

The pH value of wastewater degradation inside reactor water body, is the key factor affecting catalyst dispersion stabilization；This case method introduces The pH value of pH probe and association thereof shows instrument and the siren etc. being associated, based on this, it is possible to divide beyond catalyst at pH value In the case of dissipating stability range, actively sending alarm, based on this case the method, associative operation personnel can the reactor of awareness immediately Internal agglomeration tendency, and make instant disposal.Micropore rustless steel sleeve involved by this case method, be and this case principle and this case The indispensable important component that method matches.

In short, this case method takes into account collaborative, the coupling of microwave exposure excitation and photochemical catalysis degraded, by utilizing gold Belong to the method that cage retrains microwave more closely, reach the target allowing reactor design capacity significantly to expand；Meanwhile, its side Method also enhances the shuttling movement of the relatively large yardstick of inside reactor liquid；The method solves ozone oxidation potentiality simultaneously and utilizes Incomplete problem；The method and having reached for nm-class catalyst microgranule from its aggregate bulky grain to ten number the touching of nanometer Crash sheet widely, fine interception；Based on the method, the selection face of its filter element material also thus expanded；Its degraded Reaction end information can be known in time；The energy input to reactor can be automatically switched off when its degradation reaction terminal；Its When degradation reaction terminal, terminate the generation process of ozone the most in time, it is to avoid unnecessary secondary pollution；The method And accidental catalyst particles serious agglomeration situation can be disposed the most in situ, the most incidentally with weak through teletransmission appropriateness Quartz ampoule surface described in the supersonic cleaning of the low intensive gentleness after change, keeps the ultraviolet light transparent performance that it is excellent；The party Method also can actively detect agglomeration tendency, and send alarm when relevant parameter exceeds standard.

This case method solves described series of problems totally.

Detailed description of the invention

The enforcement of this case method, key step is as follows:

A, wraps up the quartz ampoule that its inner bay is provided with electrodeless ultraviolet lamp by the microwave exposure spatial domain constrainer of the caged of metal material, Making quartz ampoule be in the inside of microwave exposure spatial domain constrainer of this caged, it is overall for the microwave exposure spatial domain constrainer of this caged Locations of structures be in the inside of wastewater degradation reactor, the microwave exposure spatial domain constrainer of the caged of this metal material is exactly one Metal cage, is a mass of hole or mesh in its structure of this metal cage, and the function of the microwave exposure spatial domain constrainer of this caged is by micro- Amplitude retrains therein according to spatial domain, thereby structure between outer wall and the inwall of reactor of the microwave exposure spatial domain constrainer of caged Build microwave weak irradiation spatial domain or microwave zero irradiation spatial domain；

B, probes into the waveguide being derived from magnetron the inside of wastewater degradation reactor, and is reacted by the wastewater degradation that probes into of this waveguide The inner chamber of that one end within device and described metal cage carries out UNICOM, and described UNICOM refers to connection in microwave channel meaning and passes through Logical；

C, by a profile shape like the circulation guide major part arranged orthogonal facing downward of the through simple cone in two ends at described metal cage Underface, and make its major part horn mouth of this circulation guide be in vacant state, the function of this circulation guide be pack from The ascension path containing ozone-air bubble of micro porous aeration head, and the drag force of the bubble stream by the ascension because being strengthened by pack Amount leads inside reactor liquid to make the shuttling movement of relatively large yardstick；

D, moves into micro porous aeration head its major part horn mouth edge of described circulation guide and is drawn a circle to approve in the projection of reactor inner chamber bottom surface vertical Within the scope of；

E, extends on three-dimensional, expands the weak irradiation spatial domain of microwave described in inside reactor or the size in microwave zero irradiation spatial domain；

F, outside at reactor sets up booster pump, after this booster pump is mixed with the degradation reaction of catalyst suspension grain for supercharging pumping Water, and the water inlet end of this booster pump is coupled with the inner chamber of reactor；

G, couples the water inlet of the preposition prefilter of water side and back flush type of described booster pump, and this back flush type is preposition pre- The filter opening aperture of filter is between 5 microns and 300 microns；

H, by the pure water inlet of preposition for described back flush type prefilter via first water purifying valve and back flush type doughnut membrane microfiltration The water inlet of filter couples, and the filter opening aperture of this back flush type doughnut membrane microfiltration filter is between 25 nanometers and 1000 Between nanometer；

I, by the pure water inlet of described back flush type doughnut membrane microfiltration filter via second water purifying valve and back flush type doughnut The water inlet of membrane ultrafiltration filter couples, and the filter opening aperture of this back flush type hollow-fibre membrane ultra filtration filter is received between 15 Between rice and 2 nanometers；

J, couples the outlet of sewer of preposition for described back flush type prefilter with the inner chamber of reactor via first sewage valve；

K, enters the outlet of sewer of described back flush type doughnut membrane microfiltration filter via the inner chamber of second sewage valve with reactor Row couples；

L, joins the outlet of sewer of back flush type hollow-fibre membrane ultra filtration filter via the inner chamber of the 3rd sewage valve with reactor Connect；

M, sets up ozone sensor in reactor tail gas floss hole position；

N, shifts near the probe tube of this ozone sensor reactor tail gas floss hole or stretches into the inside of reactor tail gas floss hole；

O, by its ozone faradism signal output circuit of this ozone sensor and ozone content display, ozone attention device or ozone content Display couples with the composite structure of ozone attention device；

P, couples its ozone faradism signal output circuit of this ozone sensor with power-supply controller of electric, and this power-supply controller of electric is energy Enough power-supply controller of electric carrying out on and off switch action according to its described electric signal received；

Q, is coupled this power-supply controller of electric with magnetron by cable；

R, is coupled this power-supply controller of electric with air pump by another cable；

S, moulds this reactor inner chamber bottom surface and makes it present the pattern the most hollow to central area by periphery, described its gradient hollow between Between 5 degree and 35 degree；

T, in lateral surface position or the medial surface position of the part reactor diapire corresponding to this its hollow bosom, reactor inner chamber bottom surface Ultrasonic transducer is installed；

U, is coupled this ultrasonic transducer with higher-order of oscillation electric signal generator by higher-order of oscillation electric signal transmission cable；

V, stretches into reactor inner chamber by pH probe through the top of reactor, and with the micropore of the cap for brush shape made through powder metallurgical technique Rustless steel sleeve its part extending into reactor inner chamber of popping one's head in this pH carries out suit and goes along with sb. to guard him；

W, couples this pH probe with pH analyser；

X, couples this pH analyser with siren, and this siren is for the pH value situation of transfiniting is sent alarm；

Y, the junction wedging fluorubber between micropore rustless steel sleeve its opening end and reactor head of this cap for brush shape or silicon rubber The buffering isolating pad of glue material.

Involved pH probe is commercially available；Described pH probe also known as pH sensor；PH probe or say itself skill of pH sensor Art is meant that known.

Involved pH analyser is commercially available；Itself art-recognized meanings of pH analyser is known.This case pH analyser one word is general Refer to pH can be utilized to detect, picking up, showing pH value information of any model, and can externally export pH and be correlated with electric signal Instrument, market is sold simple or complicated but all meet the pH correlate meter of this basic demand it is various in style, Can select as required.

Involved buffering its thickness of isolating pad does not limits；But, have a preferred range, the preferred scope of this buffering its thickness of isolating pad Between 1 millimeter to 8 millimeter.

Themselves art-recognized meanings of involved fluorubber and involved silicone rubber is known；Involved fluorubber and involved silicone rubber, city Field is the most on sale.

Involved micropore its wall thickness of rustless steel sleeve does not limits；But, also have an associated preferred scope, this micropore rustless steel The preferred scope of its wall thickness of sleeve is between 3 millimeters to 30 millimeters.

An involved powder sintered word, the art-recognized meanings of itself, for the professional of metallurgical technology field, is known.

Involved micropore rustless steel sleeve, can customize to relevant powder metallurgy specialized factory.

The sleeve-shaped micropore stainless steel filter conversion that can be made by powder sintering process is the micropore stainless steel sleeve described in this case Cylinder；The sleeve-shaped micropore stainless steel filter that described powder sintering process is made is commercially available.

The aperture of involved micropore rustless steel its micropore of sleeve does not limits；But, the aperture of this micropore is also to have a preferred range, should The preferred scope of micropore size is between 0.5 micron to 50 micron.

Described siren is can to send audio frequency warning message or the device of optical frequency warning message according to its received electric signal； Itself art-recognized meanings of described siren is known；Described siren is commercially available.

Described its gradient enforcement value hollow is between 5 degree and 35 degree, and the arbitrarily selected value within this range of grade is all this The enforcement value that can use that case allows；This its gradient enforcement value hollow can be such as 5 degree, 8 degree, 10 degree, 15 degree, 20 Degree, 25 degree, 30 degree, 35 degree, etc..

Itself art-recognized meanings of ultrasonic transducer one word is known for the professional in ultrasonic technology field.

Itself art-recognized meanings of higher-order of oscillation electric signal transmission cable one word is for the professional in ultrasonic technology field Also it is known.

Ultrasonic transducer and higher-order of oscillation electric signal transmission cable market are the most on sale；Described ultrasonic transducer and higher-order of oscillation electricity Signal transmission cables etc. also can customize to ultrasonic transducer specialized factory and cable specialized factory.

Itself art-recognized meanings of higher-order of oscillation electric signal generator one word for the professional in ultrasonic technology field also It is known；Various higher-order of oscillation electric signal generator is commercially available；Described higher-order of oscillation electric signal generator also can be to ultrasound wave Equipment specialized factory customizes.

Implement involved ozone sensor commercially available；Customize to ozone sensor specialized factory also dependent on needs.

Implement involved ozone content monitor market on sale；Also dependent on needs to the customization of ozone content display specialized factory；Smelly Matching used ozone content display is generally also sold by oxygen sensor producer.

Implement involved ozone attention device, refer to warn sound or alarm flashing or warning sound to combine with alarm flashing two The mechanism for warning that person haves both at the same time；Ozone attention device is commercially available；Also can be to the customization of ozone attention device specialized factory；Smelly Matching used ozone attention device generally also can be sold by oxygen sensor producer.

Implementing this power-supply controller of electric involved is the power supply control that can carry out on and off switch action according to its described electric signal received Device processed；The power-supply controller of electric of on and off switch action can be carried out only with regard to its circuit engineering itself according to its electric signal received Speech, is ripe, known technology；Described power-supply controller of electric is commercially available；It is possible with commercially available power-supply controller of electric root Change a social system according to needs；Described power-supply controller of electric also can customize to power-supply controller of electric specialised manufacturers；The electricity of power-supply controller of electric etc Its specialised manufacturers of sub-device spreads all over the world.

This case the method is launched to describe with CN102260003A scheme for technical background；Its series of steps of this case method The final result formed is then unrelated with this CN102260003A scheme.

The preferred material of this metal cage is stainless steel.

Implement the bore scope of involved its hole of this metal cage or mesh between 0.5 centimetre and 3.0 centimetres；Within the scope of this Arbitrarily selected value is all the most available enforcement value.

In the case of selecting to use stainless steel, the step of this case the method can also include the making step of metal cage: should Step is with rustless steel punched-plate as raw material, through molding, weld, rivet or splicing process by screw, nut making described gold Belong to cage.

In the case of selecting to use stainless steel, the step making metal cage will be such that this step is with rustless steel Silk is raw material, and woven technique makes described metal cage.

In step a, its value of being preferable to carry out of distance between the inwall of metal cage and the outer wall of quartz ampoule wrapped up in it between Between 3.0 centimetres and 30.0 centimetres；Any distance value within the scope of Gai is all the described preferred enforcement value that can allow.

Further preferred embodiment about the distance between metal cage inwall and quartz ampoule outer wall is, in step a, Distance between the inwall controlling metal cage and the outer wall of the quartz ampoule wrapped up in it, makes this distance between 10.0 centimetres and 20.0 Between centimetre；Any distance value within the scope of Gai is all the described further preferably enforcement value that can allow.

Additionally, the material that is preferable to carry out of waveguide is stainless steel.

Implement involved circulation its material of guide not limit, the material of described circulation guide can be such as politef material, Glass material, ceramic material, metal material, etc., but, circulation its preferred material of guide is rustless steel.

Its enforcement of the method can also comprise the following steps: at described back flush type doughnut its pure water inlet of membrane microfiltration filter With on the connecting pipeline of the water inlet of described back flush type hollow-fibre membrane ultra filtration filter, concatenating into second booster pump, this is years old Two booster pumps are for augmenting hydraulic pressure to meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter；This step The most optional.

Other step described is the most such as: the regulating step of relative distance between metal cage and the quartz ampoule wrapped up in it；Described its Its step is the most such as: metal cage is at the regulating step of the installation site of wastewater degradation inside reactor；Other step described is more such as: The change step of breather line, in the case of installing metal cage described in this case, needs with the breather line of quartz ampoule two ends UNICOM Penetrating metal cage, breather line to be carried out changes step；Other step described is the most such as: at reactor waste water input string Connect the filter for impurity screening, in order to avoid impurity particle enters reactor inner chamber；Other step described is the most such as: at reactor Waste water input front end concatenation sedimentation tank, for the impurity that sediment fraction is precipitable；Other step described is the most such as: give up at reactor Water input front end concatenation waste water pH value regulating reservoir, so that the waste water pH value of input reactor reaches equipment and needs level；Described Other step is the most such as: remove that reactor external for the suction pump coupled with built-in membrane separation assemblies, this step is pin For background technology scheme；Etc..

Its enforcement of this case method is not limited to above-mentioned steps.

From the point of view of this case visual angle, as the CN102260003A scheme of this case background technology, its institute related in this case structure The components such as the water distributing plate of appellation, ripple dividing plate, built-in membrane separation assemblies and the external suction pump associated with membrane separation assemblies, It is all unnecessary component, is required for giving removal；Certainly, the housing of its reactor is also required to be torn down, and anticipates according to this case Figure rebuilds；In other words, if built with this CN102260003A scheme for starting point, then this case method The removal step for described unnecessary component can also be included, and, the step that its reactor shell is torn down, and, It is intended to carry out the details step that reactor shell rebuilds according to this case.

Claims (10)

1. the Microwave photocatalytic wastewater degradation device expansion method of agglomeration tendency self-detection, the key step of the method is as follows: a, By the microwave exposure spatial domain constrainer of the caged of metal material, the quartz ampoule that its inner bay is provided with electrodeless ultraviolet lamp is wrapped up, make Obtain the inside that quartz ampoule is in the microwave exposure spatial domain constrainer of this caged, microwave exposure spatial domain its entirety of constrainer of this caged Locations of structures is in the inside of wastewater degradation reactor, and the microwave exposure spatial domain constrainer of the caged of this metal material is exactly a gold Belonging to cage, be a mass of hole or mesh in its structure of this metal cage, the function of the microwave exposure spatial domain constrainer of this caged is by microwave Irradiation spatial domain retrains therein, thereby builds between outer wall and the inwall of reactor of the microwave exposure spatial domain constrainer of caged Microwave weak irradiation spatial domain or microwave zero irradiation spatial domain；B, probes into the inside of wastewater degradation reactor by the waveguide being derived from magnetron, And the inner chamber of that one end and described metal cage of probeing into wastewater degradation inside reactor of this waveguide is carried out UNICOM, described UNICOM Refer to the connection in microwave channel meaning with through；It is characterized in that, remaining key step of the method is as follows: c, by one Individual profile shape like the through simple cone in two ends circulation guide major part arranged orthogonal facing downward described metal cage just under Side, and make its major part horn mouth of this circulation guide be in vacant state, the function of this circulation guide is that pack exposes from micropore The ascension path containing ozone-air bubble of gas head, and the strength that pulls by the bubble stream of the ascension because being strengthened by pack carries Neck inside reactor liquid makees the shuttling movement of relatively large yardstick；D, moves into described its major part of circulation guide by micro porous aeration head Horn mouth edge is within the scope of vertical projection in reactor inner chamber bottom surface is drawn a circle to approve；E, extends on three-dimensional, expands instead Answer the internal described microwave weak irradiation spatial domain of device or the size in microwave zero irradiation spatial domain；F, outside at reactor sets up booster pump, should Booster pump water after the degradation reaction that supercharging pumping is mixed with catalyst suspension grain, and by the water inlet end of this booster pump and reaction The inner chamber of device couples；G, couples the water inlet of the preposition prefilter of water side and back flush type of described booster pump, The filter opening aperture of the preposition prefilter of this back flush type is between 5 microns and 300 microns；H, by preposition for described back flush type The pure water inlet of prefilter joins via the water inlet of first water purifying valve with back flush type doughnut membrane microfiltration filter Connecing, the filter opening aperture of this back flush type doughnut membrane microfiltration filter is between 25 nanometers and 1000 nanometers；I, by described The pure water inlet of back flush type doughnut membrane microfiltration filter is via second water purifying valve and back flush type doughnut membrane ultrafiltration The water inlet of filter couples, and the filter opening aperture of this back flush type hollow-fibre membrane ultra filtration filter is between 2 nanometers and 15 Between nanometer；J, enters the outlet of sewer of preposition for described back flush type prefilter via the inner chamber of first sewage valve with reactor Row couples；K, by the outlet of sewer of described back flush type doughnut membrane microfiltration filter via second sewage valve and reactor Inner chamber couple；L, by the outlet of sewer of back flush type hollow-fibre membrane ultra filtration filter via the 3rd sewage valve and reaction The inner chamber of device couples；M, sets up ozone sensor in reactor tail gas floss hole position；N, taking this ozone sensor Sample pipe shifts near reactor tail gas floss hole or stretches into the inside of reactor tail gas floss hole；O, by its ozone sense of this ozone sensor Answer the compounding machine of electric signal output circuit and ozone content display, ozone attention device or ozone content display with ozone attention device Structure couples；P, couples its ozone faradism signal output circuit of this ozone sensor with power-supply controller of electric, this electricity Source controller is the power-supply controller of electric that can carry out on and off switch action according to its described electric signal received；Q, by this power supply Controller is coupled with magnetron by cable；R, is coupled this power-supply controller of electric with air pump by another cable； S, moulds this reactor inner chamber bottom surface and makes it present the pattern the most hollow to central area by periphery, described its gradient hollow between Between 5 degree and 35 degree；T, in the outside of the part reactor diapire corresponding to this its hollow bosom, reactor inner chamber bottom surface Ultrasonic transducer is installed in position, face or medial surface position；U, by this ultrasonic transducer by higher-order of oscillation electric signal transmission electricity Cable couples with higher-order of oscillation electric signal generator；V, stretches into reactor inner chamber by the top that pH probe passes through reactor, and Popping one's head in this pH with the micropore rustless steel sleeve of the cap for brush shape made through powder metallurgical technique, it extend into the part of reactor inner chamber Carry out suit to go along with sb. to guard him；W, couples this pH probe with pH analyser；X, joins this pH analyser with siren Connecing, this siren is for the pH value situation of transfiniting is sent alarm；Y, at micropore its opening end of rustless steel sleeve of this cap for brush shape And the junction wedging fluorubber between reactor head or the buffering isolating pad of silicone rubber material；Involved its thickness of buffering isolating pad Degree is between 1 millimeter and 8 millimeters, and involved micropore its wall thickness of rustless steel sleeve is between 3 millimeters and 30 millimeters, involved The aperture of micropore rustless steel its micropore of sleeve is between 0.5 micron and 50 microns.

The Microwave photocatalytic wastewater degradation device expansion method of agglomeration the most according to claim 1 tendency self-detection, it is special Levying and be, it is stainless steel that this metal cage selectes material.

The Microwave photocatalytic wastewater degradation device expansion method of agglomeration the most according to claim 1 tendency self-detection, it is special Levy and be, in step a, control the distance between the inwall of metal cage and the outer wall of quartz ampoule wrapped up in it, make this away from From between 3.0 centimetres and 30.0 centimetres.

The Microwave photocatalytic wastewater degradation device expansion method of agglomeration the most according to claim 3 tendency self-detection, it is special Levy and be, in step a, control the distance between the inwall of metal cage and the outer wall of quartz ampoule wrapped up in it, make this away from From between 10.0 centimetres and 20.0 centimetres.

The Microwave photocatalytic wastewater degradation device expansion method of agglomeration the most according to claim 1 tendency self-detection, it is special Levying and be, material selected by this waveguide is stainless steel.

The Microwave photocatalytic wastewater degradation device expansion method of agglomeration the most according to claim 1 tendency self-detection, it is special Levying and be, this profile shape is rustless steel like its material of circulation guide of the through simple cone in two ends.

The Microwave photocatalytic wastewater degradation device expansion method of agglomeration the most according to claim 1 tendency self-detection, it is special Levying and be, this back flush type hollow-fibre membrane ultra filtration filter is at more than one back flush type doughnut membrane ultrafiltration by quantity Filter monomer is parallel with one another couples composition.

The Microwave photocatalytic wastewater degradation device expansion method of agglomeration the most according to claim 1 tendency self-detection, it is special Levying and be, this back flush type doughnut membrane microfiltration filter is at more than one back flush type doughnut membrane microfiltration by quantity Filter monomer is parallel with one another couples composition.

The Microwave photocatalytic wastewater degradation device expansion method of agglomeration the most according to claim 1 tendency self-detection, it is special Levying and be, the method is further comprising the steps of: at described back flush type doughnut its pure water inlet of membrane microfiltration filter with described On the connecting pipeline of the water inlet of back flush type hollow-fibre membrane ultra filtration filter, concatenate into second booster pump, this second increasing Press pump is for augmenting hydraulic pressure to meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter.

The Microwave photocatalytic wastewater degradation device expansion method of agglomeration the most according to claim 1 tendency self-detection, its Being characterised by, the size of its hole of this metal cage or mesh is between 0.5 centimetre and 3.0 centimetres.