CN103319035B

CN103319035B - The high throughput photocatalytic waste water degradation reactor of prevention light source placing chamber gushing water

Info

Publication number: CN103319035B
Application number: CN201310264295.9A
Authority: CN
Inventors: 李榕生
Original assignee: Individual
Current assignee: Chongqing Yao Qun Environmental Protection Technology Co Ltd
Priority date: 2013-06-17
Filing date: 2013-06-17
Publication date: 2016-11-23
Anticipated expiration: 2033-06-17
Also published as: CN103319035A

Abstract

The present invention relates to a kind of high throughput photocatalytic waste water degradation reactor preventing light source placing chamber gushing water, belong to technical field of waste water processing.In existing correlation technique, there is Non-polarized lamp screen and protect by quartz tube cavity gushing water problem, and, microwave energy waste, single tank wastewater treatment capacity are less than normal, catalyst particles retains that link is on the weak side, degradation reaction terminal moment difficulty is distinguished, agglomeration thing cannot strength dissipates in situ, agglomeration occurs immediately to be perceived, secondary ozone reverse channelling corrosion magnetron etc. problem, and this case is for above-mentioned series of problems.This case between air pump with this quartz tube cavity couple in gas circuit with bypass mode accessed one can with low power normality run miniature membrane pump, this miniature membrane pump can provide the air of lasting low discharge to supplement to quartz tube cavity, thereby checks quartz tube cavity gushing water；This case also retrains microwave with metal cage, and its structure allows reactor significantly dilatation；Its structure solves other described problem the most totally.

Description

The high throughput photocatalytic waste water degradation reactor of prevention light source placing chamber gushing water

Technical field

The present invention relates to a kind of high throughput photocatalytic waste water degradation reactor preventing light source placing chamber gushing water, belong to C02F and give up Water-treatment technology field.

Background technology

Microwave and photo catalysis degradation treatment technology, as a kind of effective for the harmless treatment skill containing organic pollution industrial wastewater Art, the most interesting.

About microwave and photo catalysis degradation technique, as an example, may refer to the Chinese patent Shen of Publication No. CN102260003A Please case.

The disclosure number is the Chinese patent application case of CN102260003A, is using microwave as excitaton source, excites electrodeless ultraviolet lamp Launching ultraviolet, irradiate the suspension mixed with photocatalyst titanium dioxide in liquid internal, this electrodeless ultraviolet lamp is by quartz ampoule institute cage Cover protects, and is free air pump persistently to inject air to this quartz ampoule inner chamber, quartz cavity the air overflowed via pipeline be positioned at anti- Answering the micro porous aeration head UNICOM bottom device, the lower zone of this inside reactor is aeration zone, the upper area of this inside reactor Being microwave and photo catalysis reaction zone, the program also with the membrane separation assemblies that reactor is built-in, carries the water after analysis purifies, and with this film Separation assembly realizes retaining of photocatalyst titanium dioxide fine particles and uses；The program also non-polar ultraviolet light source and membrane separation assemblies it Between set up dividing plate, for preventing the ultraviolet radiation damage to organic membrane separation assemblies；It is passed through the air of inside reactor, Part the most directly participates in relying on the photocatalytic degradation of photocatalyst titanium dioxide to react, some air, direct at ultraviolet light Under irradiation, generating a certain amount of ozone, the ozone of this generation the most also plays the direct oxidative degradation for organic pollution Effect.

The disclosure number is that the Chinese patent application case of CN102260003A is certainly for microwave and photo catalysis wastewater degradation technology Progress serves very important impetus, and the work that its research staff is launched in this field is admirable.

Meaning based on sincere admiration, and, common striving direction, to be talked below us is problem.

The problem below will spoken of, has 16；These 16 problems are arranged side by side 16 problems；The priority of its sequence Consider easily merely for the sake of discussing.

One of problem:

The disclosure number is the Chinese patent application case of CN102260003A, and it divides for the film intercepting catalyst titanium dioxide fine particles It is to be placed in reactor inner chamber from assembly, is immersed among process object liquid, and relies on washing away containing ozone bubbles of ascension Membrane separation assemblies, the institute's catalyst particles that adsorbs, be detained that thereby removes its surface, reach the recovery of catalyst particles, recycling Purpose, meanwhile, it is self-cleaning and keep its separating power that membrane separation assemblies is also dependent on this mode, then, based on this structure, only Business curtain hollow fiber film assembly or plate film assembly can be selected, and, this membrane separation assemblies is to need to be immersed in ozone In the context of the strong oxidizing property of bubble ascension, therefore, the tolerance against oxidative power of membrane separation assemblies is necessarily required, common material The organic membrane separation assembly of matter is not resistant to such use environment, therefore can only select the membrane separation assemblies of PVDF material, this Point clearly illustrates in the 0009th section of word of this case disclosure and claim 3；This kind needs special tolerance against oxidative power Its material of filter membrane is relatively costly, and its commercially available price is certainly also above common organic micro-filtration membrane module of non-oxidation durability requirements；Change Sentence is talked about, and the frame mode of this case causes the material of membrane separation assemblies to be limited to PVDF material costly.Further, dress Putting interior possible ultraviolet light to reveal, may touch organic membrane assembly, this organic membrane assembly material also required that in device can be resisted Ultraviolet light irradiation, from the point of view of this, organization plan based on this device, the material of organic membrane separation assembly also can only be limited in PVDF material costly.

Organic membrane assembly, compared to ceramic filter assemblies, has its obvious advantage；About this point, special for filtering technique For the personage of industry, it is known, does not the most launch to repeat.

So, under the premise using organic material membrane module, this PVDF filter membrane material limitation can be bypassed？This is One needs the problem solved, and this is one of problem.

The two of problem:

In view of scouring force, the cleaning capacity of described ascension bubble are more weak, therefore, with this cleaning mode with the use of membrance separation The filter opening aperture of bigger microfiltration rank can only be selected in its aperture of assembly, and the filter opening aperture of this microfiltration rank is 0.1-0.2 micron, About this point, have in the 0009th section of word of this case disclosure and claim 3 equally and clearly limit, this kind of filter opening aperture Limit, from the type selecting of the such membrane separation assemblies of this case, built-in and soak from the point of view of occupation mode, the self-cleaning method of ascension bubble, be Inevitable, its filter opening aperture can only be limited in microfiltration rank.In other words, this in the way of ascension bubble washes away its scouring force, Cleaning force is the most weak, to such an extent as to cannot tackle the filter membrane of more small-bore at all, and thus, in this case device, filter sizes limits Between 0.1 micron-0.2 micron, it it is the inevitable choice not discussing leeway.

The filter opening aperture of so-called 0.1-0.2 micron, if changing a measurement unit, corresponding is exactly the filter opening hole of 100-200 nanometer Footpath；That is any concept？For 100 nanometer filter opening apertures of its lower limit, its size of catalyst particles that it can intercept Must be more than 100 nanometers, and cannot be intercepted less than the catalyst particles of 100 nanometers；In other words, less than 100 The catalyst particles of nanometer by being directed through, by the filter opening of membrane module, be mixed into so-called water purification that degradation reaction device exported it In.

Need now to have a talk the particle diameter of photocatalyst involved by ultraviolet catalytic degradation reaction and photocatalyst dosage form selection.

The professional person being engaged in photocatalytic degradation research both knows about, and reacts with the photochemical degradating of uv light induction, and its catalyst is many Select titanium dioxide fine particles catalyst；At present, laboratory level has been developed for various in style urging based on titanium-dioxide photo Changing the light degradation particle catalyst of characteristic, certainly, the light degradation catalyst that these different preparation methods are formed, its particle diameter is also It is various；Its particle diameter of photocatalyst that different preparation methoies are made is little to 20 nanometers, greatly to 100000 nanometers namely 100 microns, Have, be wherein no lack of the photocatalyst kind of excellent performance；But, due to performance long-time stability evaluate, preparation cost and The restriction of market expansion etc. aspect factor, most of its deliverability of described photocatalyst is limited only to laboratory level, And do not have to form the most commercially available level of production；The most known can make a big purchase in large quantities commercially available can be actual a large amount of The photocatalyst for ultraviolet light wave band used is famous gas phase titanium dioxide P25；Its concrete skill of gas phase titanium dioxide P25 Art implication, insider both knows about, and does not the most launch to repeat；The mean diameter of gas phase titanium dioxide P25 is 21 nanometers；Gas Phase titanic oxide P25 performance not very optimum, but, its stable performance, it is important to can commercially make a big purchase in large quantities and obtain, and Can use the most in a large number, therefore, the most usually be used as weighing respectively with P25 catalyst in photocatalysis specialized laboratory Plant reference pointer or the contrast pointer of self-made photocatalyst catalytic performance, it is true that in view of the feature of ultraviolet catalytic degradation reaction, The photocatalyst that dispersion is the highest, is suitable for the needs of this type reaction, say, that mean diameter is at the light of 21 ran Catalyst its catalyst interfacial area that can provide, anti-settling ability, catalytic performance long-time stability etc. aspect, comprehensive and Speech, is optimal.Simply, at present, good and cheap, it is possible to the actual ready-made commercially available business making a big purchase in large quantities, using The photocatalyst of the ultraviolet light wave band of grade, it is simply that mean diameter is the gas phase titanium dioxide P25 catalyst of 21 nanometers；In industry The application of scale, this mean diameter be the photocatalyst of 21 nanometers be actual first-selection.

Already described above and, the disclosure number is the Chinese patent application case of CN102260003A, and it is for intercepting the film of photocatalyst Assembly, is the catalyst particles that stripping film assembly surface adsorbs, deposits that washes away with ascension bubble, but, this kind is to rise Rise its scouring force of mode that bubble washes away, cleaning force the most weak, to such an extent as to the filter membrane of more small-bore cannot be tackled at all, therefore, In this case device, filter sizes is limited at microfiltration filter opening rank between 0.1 micron-0.2 micron, for changing a measurement unit, In this case device, filter sizes is limited at the microfiltration filter opening rank between 100 nanometer-200 nanometers, and this is not discuss leeway Inevitable choice；This case certainly cannot intercept as above flat without the microfiltration filter opening between selectable 100 nanometer-200 nanometers All particle diameters are the gas phase titanium dioxide P25 granule of 21 nanometers；So, if using P25 photocatalyst, this catalyst will completely Cannot intercept, and flow in so-called water purification, form secondary pollution, certainly also result in the heavy losses of catalyst and unrenewable； Even if using the titanium dioxide optical catalyst of the big particle diameter special for this of other kind, it collides because of mutual during using Or collide with wall, inevitable also can produce a large amount of small particle fragment, wherein particle diameter is less than the fragment of 100 nanometers, equally can not be by Microfiltration filter opening between 100 nanometer-200 nanometers is intercepted, these fractionlets also can through its membrane module enter so-called water purification it In, form secondary pollution.

Visible, the disclosure number is the Chinese patent application case of CN102260003A, and it is for the interception structure of photocatalyst microgranule The cleaning solution of scheme and related film assembly is the most undesirable.

Therefore, how under the premise of this case advantage of incorporating things of diverse nature, reach the fine interception for photocatalyst microgranule and return Receiving use again, be a important topic the most worth thinking deeply about, this is the two of problem.

The three of problem:

It is known that liquid water body itself also is able to absorb the energy of microwave, and cause the liquid water body that is processed itself Temperature-rise effect, and this with wastewater treatment process the temperature-rise effect that occurs, be not the most our situation of being expected, in other words Saying, the microwave energy from magnetron is used for exciting electrodeless ultraviolet lamp the most completely, and has quite a few should be served only for swashing The microwave energy sending out electrodeless ultraviolet lamp is dissipated in described temperature-rise effect, and it is unnecessary that the temperature-rise effect that this kind is not fond of causes Microwave energy waste, in view of disclosed above number be CN102260003A the apparatus structure side that shown of Chinese patent application case Case, its rational approach, can only be to reduce single tank process capacity in other words by the volume of minimizing microwave and photo catalysis reactor to come Reach the purpose weakening the unnecessary dissipation of microwave, about this point, in this its detailed description of the invention of CN102260003A application case Clearly have expressed the suitable size overall about this apparatus structure, what its expressed preferred size was corresponding is exactly that a profile is the least Device, then, consequently, it is possible to the distance of reactor wall and microwave radiation source is little, the wastewater flow rate contacted with microwave is little, The microwave energy that waste water is absorbed is the least, corresponds ground, and the wastewater treatment capacity of single tank is the least, more specifically Ground is said, the internal capacity corresponding to device suitable size expressed in embodiment is 40 liters, namely single tank wastewater treatment capacity is 40 liters, i.e. 0.04 cube, in other words, its once a complete set of, substantial length of operation solve only the industrial wastewater of 0.04 cube, then, Being accomplished by the repetition operated by a complete set of head to tail carried out many times, the cumulative of its treating capacity just has plant-scale meaning, So to say, the most individual analogy substantially, 0.04 cube of such waste water of single tank that its preferred structure size of this case is generally corresponding to Treating capacity, need to repeat 1000 times by a complete set of head to tail, substantial length of operation, its accumulation amount, can be only achieved 40 cubes such one Individual have industrial level wastewater treatment capacity, the most loaded down with trivial details repetitive operation will cause the serious waste of human and material resources, Visible, the wastewater degradation treatment effeciency of its reality of scheme that this kind is shown by CN102260003A may not be fully up to expectations. Therefore, how on the premise of not causing the waste of more microwave energy or reducing microwave energy waste, increase single tank wastewater treatment capacity, Reduce the unnecessary too many by the repetitive operation number of times of head to tail of this batch (-type) wastewater treatment equipment, improve its waste water and process effect Rate, is a significant technical problem merited attention, and this is the three of problem.

The four of problem:

The scheme that this kind is shown by CN102260003A, the bubble of the internal unrestrained cloth ascension of its retort, for driving a reaction tank The shuttling movement of the relatively large yardstick of internal liquid, contributes the most inadequate；Certainly, this weak point, for CN102260003A In scheme such as its detailed description of the invention the fact that clear expression for upper corresponding small size, low capacity device, almost without what Observable impact.From the point of view of plant-scale application demand, undersized can not the device of divergence process amount certainly the most much Captivation；So, as a kind of probability, if there being certain mode to be capable of the significantly expansion for the treatment of capacity, under this situation, Its importance of shuttling movement of the relatively large yardstick of retort internal liquid will highlight naturally；Imagine the most this process The probability that amount is significantly expanded, then, how to strengthen the shuttling movement of the relatively large yardstick of retort internal liquid, be certainly exactly Individual problem, this is the four of problem.

The five of problem:

For the photochemical catalysis oxidation reaction of ultraviolet light wave band, this kind of oxidation is anti-to have the most several following key element to influence whether The efficiency answered, first ultraviolet wavelength, intensity, it two is photocatalyst in the particle diameter of photocatalyst, unit volume reactant liquor Usage amount, himself catalytic performance etc. of photocatalyst, it three is organic concentration in oxidized object i.e. water body, has Oxidation complexity that machine thing molecular structure is determined himself etc., it four is the sufficient degree of oxygen atmosphere, in other condition In the case of identical, the sufficient degree of oxygen atmosphere, will become and affect an act foot of photochemical catalysis oxidative degradation ability gently The key element of weight.

The scheme shown such as CN102260003A, its numerous micro porous aeration heads being placed in reactor inner chamber bottom overflow cloth the end of at Portion, and by its alleged water distributing plate so that this micro porous aeration head overflows the effect of cloth arrangement and becomes more very, certainly, this for For using the situation of oarse-grained micron-sized photocatalyst of relatively easy sedimentation, really there is its favourable one side, but, From the point of view of another side, this micro porous aeration head overflows the mode that cloth arranges, and the supply of oxygen atmosphere excessively disperses, and needs most The region that need to strengthen oxygen supply is the most effective region of photochemical catalysis oxidation, due to effective in liquid water body of short wave ultraviolet Penetration depth only has 20 cm, therefore, needs most enhanced oxygen blowing real with the effective coverage promoting photochemical catalysis oxidation course It is exactly the region within quartz ampoule periphery about 20 cm distance on border, in other words, within quartz ampoule periphery about 20 cm distance Region be the region really needing the supply of enriched with oxygen atmosphere to ensure, oxygen atmosphere supply in this region is the strongest, and oxidation reaction is also Just it is proceeded more quickly；The most especially, producing electrodeless ultraviolet emission in microwave excitation mode, its feature can be accomplished greatly exactly Power, high intensity, this is the strong point of this lamp-type of electrodeless ultraviolet lamp, but, just because of its purple extraradial high power, high-strength Degree, just mates with greater need for powerful oxygen atmosphere supply capacity, and otherwise, that powerful ultraviolet radiation energy power is just Really major part is wasted.Above it is stated that, the scheme shown such as CN102260003A, factors limits Its reactor size, limits its actual treatment capacity, as its specific embodiment clearly illustrates, that Can be a single tank single treatment amount little reactor that only has about 40 liters, in the case of such little reactor, little inner chamber, Because size is the least, then, its shortcoming in terms of photochemical catalysis oxidation effective coverage oxygen supply concentration degree, would not The most obvious, it might even be possible to ignore, a problem the most non-existent can be regarded the most completely as, in the face of such Undersized little reactor, the shortcoming problem in terms of oxygen supply concentration degree, not may float mind；However, it is contemplated that Once, if described many limiting factors can be overcome, if can have that way actual implementation one is large-scale, high throughput anti- Answer device, then within above-mentioned quartz ampoule periphery 20 cm distance, effective coverage oxygen supply strengthening problem will show especially out, particularly with Using electrodeless ultraviolet lamp as the situation of UV source, within above-mentioned quartz ampoule periphery 20 cm distance, effective coverage oxygen supply is strengthened Problem is not more allowed to despise, therefore, how among the structure of possible large-scale photo-catalytical oxidation degradation reaction device, Strengthen the oxygen supply concentration degree of described effective coverage, improve the usefulness of wastewater degradation equipment, it is simply that the problem that individual needs are kept a close watch on, this is The five of problem.

The six of problem:

Within this CN102260003A scheme pumps air into the quartz ampoule including electrodeless ultraviolet lamp, reach the logical of electrodeless ultraviolet lamp Wind cooling, the purpose of cooling, and those flowings are through the air of quartz ampoule, because of by ultraviolet irradiation, some air meeting Being changed into ozone, therefore, the air flowed out from quartz ampoule is exactly the air containing some ozone certainly, and this is contained smelly by the program Oxygen air is transferred to be positioned at micro porous aeration head below reactor, and disengages from micro porous aeration head, these containing ozone bubbles from lower On ascension during, ozone contained therein can meet with the organic molecule that runs among distance and redox reaction occurs, This redox reaction can consume a part of ozone certainly, this be do not have doubt, but, above it is stated that, as The scheme that CN102260003A is shown, the many factors that cannot ignore certainly existed limit its reactor size, Limiting its actual treatment capacity, as clearly illustrating in its specific embodiment, that can only be a single tank single Treating capacity only has the little reactor of about 40 liters, in the case of such little reactor, little inner chamber, because overall dimension itself The least, then, the longitudinal size of its reactor inner chamber or regard as with reckoning in every item contain the liquid degree of depth also can only be one the least Size, clearly illustrates among this size such as its detailed description of the invention, the most about 40 centimetres, and the Sheng that reckons in every item liquid is deep Spend the most only 40 centimetres, actually contain the liquid degree of depth and be certainly less than this number, just analyze with the Sheng liquid degree of depth of 40 centimetres, that , this Sheng liquid degree of depth of 40 centimetres is what concept？That is to say, containing ozone-air ascension by the path of waste water only Having short 40 centimetre, this path is the shortest, passes through at a gallop containing ozone-air bubble and only only has 40 centimetres of deep water bodys, The shortest for time of contact with water body, contained in bubble ozone, can only have small part to be used for oxidative degradation Organic substance, And most ozone actually simply passes by liquid simply, effusion emptying through exhaust port from liquid level, briefly, The Oxidation potentiality major part of these ozone is wasted, and, effusion, the ozone that is wasted actually can cause need not The air pollution wanted；This case main inventive people once beat via micro porous aeration head with normal domestic use ozone machine in one meter of deep tank Enter containing ozone-air, in the case of the depth of water degree of depth reaches one meter, remain able to substantially smell the abnormal smells from the patient of ozone near the water surface, can See, that 40 centimetres of deep Sheng liquid degree of depth, it is clear that be to be not enough to fully utilized ozone；Visible, electrodeless ultraviolet light chemistry is urged For changing the such equipment of wastewater degradation reactor, ozone utilizes incomplete problem to be also required to pay close attention to, it is clear that Ren Mengeng It is contemplated that the reactor of wastewater degradation without extreme ultraviolet that ozone utilizes more completely, contaminative exhaust emissions is less, this is the six of problem.

The seven of problem:

Its running of waste water catalytic degradation reaction device, requires the expenditure of energy, and therefore, operator are bound to wish, work as wastewater degradation When reaction proceeds to terminal, it is possible to impartially, the most lately immediately stop continuing to inject to inside reactor Energy；If the moment stopping Implantation Energy is too early, then wastewater degradation is incomplete；And if reaching reaction end already, the most still The most unceasingly to inside reactor Implantation Energy, that is certainly the energy in waste preciousness.As this case technical background Its structure of CN102260003A scheme can not provide any instant information to the wastewater degradation reaction end moment, then, just The terminal that wastewater degradation reacts can only be estimated by experience；And estimate, by experience, the terminal that wastewater degradation reacts, that obviously can not Satisfactory；So, how to make neither the most undelayed instant information output for the wastewater degradation reaction end moment, And immediately close the energy input to reactor in the just right moment, it is simply that a technical threshold that can not despise, this is The seven of problem.

The eight of problem:

Accept the described industrial wastewater of microwave and photo catalysis degradation treatment, be mingled with some the most unavoidably and originate from mechanical system abrasion process The material of metal particle and carbon granules etc, even if quantity is small, its existence is almost difficult to avoid that, the disclosure number is Described organic membrane separation assemblies in the Chinese patent application case of CN102260003A is installed in microwave and photo catalysis reaction zone, its In be installed between quartz ampoule and membrane separation assemblies certainly do not stop microwave for intercepting the dividing plate of ultraviolet, so, micro- The practical function region of ripple necessarily covers organic membrane separation assemblies institute installation area described in the program, based on membrane separation assemblies Working mechanism, its accumulation process on membrane separation assemblies organic matter top layer of the microgranule of metal particle as above and carbon granules etc It is difficult to avoid that, and the microgranule of this type of described metal particle and carbon granules etc, exactly the good absorption medium of microwave energy, inhale The microgranule of described metal particle and the carbon granules of having received the accumulation state of microwave energy etc, its organic plasma membrane being close to can be divided by nature Produce from the top layer of assembly and based on heat penetration erosion mechanism lasting pierce destruction, be as noted previously, as this CN102260003A The structures shape of its device of application case can only select polyvinylidene fluoride film material, this polyvinylidene fluoride film material heatproof about 140 degrees Celsius, More certain than general film material heatproof high much, but, described metal particle and carbon granules of absorbing the accumulation state of microwave energy etc Its point-like of microgranule pierce the heat penetration erosion effect of formula and the most easily break through the heatproof temperature limit of this polyvinylidene fluoride film material, due to above-mentioned former Cause, well imagines, the pvdf membrane material in this its device of CN102260003A application case its actual life will be the lowest In the preferable service life expected, the structure of this CN102260003A its device of application case, determine in this structural frames Under frame, above-mentioned point-like pierce formula heat penetration erosion destruction problem cannot avoid；Therefore, how to get around this point-like and pierce the heat penetration erosion of formula Destruction problem, also needs to consider, and this is the eight of problem.

The nine of problem:

The disclosure number is the Chinese patent application case of CN102260003A, the 0008th section of word of its description disclosure text And claim Section 2, the catalyst particle size scope being suitable for for its device, there is a restriction, this particle size range limits It is that 20 nanometers are to 100 microns.It is known that some pH value be pre-adjusted not in place, pH value inappropriate in the case of, Titanium dioxide fine particles is susceptible to reunite, and then affects its effective working interface area, affects its photocatalysis usefulness；Particularly with The section of those the relatively small particle diameters among this particle size range, easily occurs because of presetting not in place, the pH value of pH value not especially The agglomeration traits appropriately caused；For this catalyst particles in the case of of reuniting, it is immediately to adopt an effective measure, enters The depolymerization of aggregate is operated by the hand-manipulating of needle；But, we, among this CN102260003A scheme, do not see any having Help immediately dissolve the structure of this problem or can immediately dissolve the scheme prompting of this problem.For such as CN102260003A scheme can only be the reactor of small scale structures because factors limits just like that, still can the most directly carry React device, carries out toppling over and inspecting outside reactor, process above-mentioned reunion situation, then, hold if likely expanding it Amount, the most so to say, if being the several cubes of large-scale reactors to dozens of cube or huge reactor, that is the most not It is manual to topple over it and operate the problem that can tackle, then, for this catalyst particles in the case of of mutually reuniting, how Realize instant disposal in situ, it is simply that a technical problem, this is the nine of problem.

The ten of problem:

The disclosure number be CN102260003A Chinese patent application case expressed by apparatus structure in, protect electrodeless purple for screen The quartz ampoule of outer lamp, its outer wall, refer to the outer wall of quartz ampoule, through for a long time with the contacting, unavoidably of processed industrial wastewater Gradually dirty, the material that dirt amasss the most mainly is difficult to the mineral-type impurity touched by light-catalyzed reaction, because of the formation of this mechanism Dirty phenomenon, is easy to be observed after equipment long-play；It is attached to the dirty lamination of described quartz ampoule outer wall, although The veryyest thin one layer, also be enough to cause the ultraviolet radiation of electrodeless ultraviolet lamp significantly stop, and this will cause this microwave light to be urged The actual treatment effect changing reaction treating device significantly reduces；In its reactor, the bubble of unrestrained cloth ascension is because excessively disperseing, scouring force Measuring more weak, if only relying on this more scattered bubble to maintain the bright and clean of quartz ampoule surface, really undertaking to do what is apparently beyond one's ability, in other words Saying, this more scattered bubble, what it was more weak wash away strength is still not enough to stop completely the dirty process on this quartz ampoule surface；? During the use of laboratory yardstick, above-mentioned fouling problem is subtle, but, on commercial Application yardstick, this fouling problem Certainly will highlight；Therefore, how on the premise of not tearing machine open, immediately, effectively remove on this quartz ampoule outer wall Dirt lamination, maintains the lasting high efficiency of this microwave and photo catalysis processing means, and this problem is the most very important, and this is the ten of problem.

The 11 of problem:

Nine its problems derived of this problem problem by addressing above.Above speak of, some pH value be pre-adjusted less than In the case of position, pH value are inappropriate, titanium dioxide fine particles is susceptible to reunite, and then affects its effective working interface area, Affect its photocatalysis usefulness；Particularly with among its suitable catalyst particle size range that this CN102260003A scheme is touched upon The section of those relatively small particle diameters, easily occur especially because of pH value presetting not in place, pH value is incorrect and the group that causes Poly-problem；For this catalyst particles in the case of of reuniting, it is immediately to adopt an effective measure, carries out for aggregate Depolymerization operates；Based on this its framework of CN102260003A scheme, operator cannot immediately perceive inside reactor and institute occurs State the situation of reunion, thus also cannot make instant disposal, thus, should be limited by factors and can only be small scale structures Its limited usefulness of reactor can reduce further；Therefore, among the application of reactor operates, particularly, for example, Among the application of possible large-scale reactor or huge reactor operates, the most immediately awareness inside reactor catalyst particles The main inducing parameter reunited, is a key issue, and this is the 11 of problem.

The 12 of problem:

Based on this its framework of CN102260003A scheme, due to it is stated that the restriction of factors, its reactor can only Being the smaller reactor of undersized treating capacity, the useful size of reactor inner chamber is smaller, its knot of reactor inner chamber The spatial altitude that can be used in disposing curtain type film assembly among structure is also about at 30 cm, so, even if only It is the curtain type film assembly using very small breadth, the most almost can only head on plug inside reactor in two up and down, little due to reactor Treating capacity, small size, then, after its degradation reaction completes, under the situation getting rid of liquid from inside to outside, its curtain type membrane Assembly exposes in atmosphere unavoidably, although the time every time exposed can not be grown, but, the accumulation result often bought and sold, it is simply that Make this curtain type film assembly too much with air contact, curtain type film assembly its normally use requirement, be intended under being totally submerged state Use, say, that, it is necessary to be hygrometric state use, if curtain type film assembly too much with air contact, can be made it relatively quickly Aging, Performance comparision is decayed rapidly, and this curtain type film assembly too much with the situation of air contact, at this Under its framework of CN102260003A scheme, it is impossible to avoid；Therefore, how to protect the membrane module for intercepting catalyst, make It can use in normal conditions so that it is it can be avoided that with too much the contacting of air, to safeguard its normal usage energy, really Protecting its normal service life, it is simply that the problem that needs are faced, this is the 12 of problem.

The 13 of problem:

Based on this its framework of CN102260003A scheme, among its running, the catalyst granules intercepted by curtain type film assembly, A part is at curtain type film assembly surface deposition, and another part is then trapped among liquid object phase, catalysis in thus causing liquid object mutually Agent granule density is stepped up along with the progressively reduction of liquid phase volume, and this is for follow-up membrance separation, and its membrance separation load is also Can gradually rise therewith, the problem that before and after this membrance separation load, difference is excessive needs to solve, and this is the 13 of problem.

The 14 of problem:

Based on this its framework of CN102260003A scheme, among its running, to the water pump of reactor inner chamber filling waste water, its Itself cannot differentiate inside reactor water level height, operator can only rely on experience or range estimation to close this filling waste water in time Pump motor, if experience error or range estimation response are not prompt enough, it is easy to occur overflowing reactor because of waste water filling excess Situation, thereby results in unnecessary trouble；On the other hand, after degradation reaction terminates, need by inside via curtain type membrane group Part, to extracardiac pumping, is failing to know under the situation of inside reactor water level, completely can only rule of thumb or range estimation judges pass Cut off the water opportunity of pump, and so operate, hence it is evident that be unreliable, easily because of experience error or range estimation response not in time, cause this to draw water Cannot shut down in time with water pump, and this dry tap, idle running easily cause this pump motor that draws water and burns, this problem can not be neglected Depending on, this is the 14 of problem.

The 15 of problem:

Based on this its framework of CN102260003A scheme, among its running, the air pumped into quartz tube chamber, by ultraviolet Irradiating, a portion can be converted into ozone, be thusly-formed containing ozone-air, major part can be by force feed to micro porous aeration head Discharge, but, it is known that magnetron structures itself does not have vacuum-tightness, and, waveguide and magnetron Junction does not typically the most have vacuum-tightness, therefore, has the described of relative normal pressure and necessarily has sub-fraction containing ozone-air Inversely can scurry into magnetron place structural region with taking advantage of a situation, and generally speaking its structural member material of magnetron includes its case material The most do not possess the ability resisting ozone corrosion, then, consequently, it is possible to that inversely scurries into magnetron structures region must containing ozone-air So forming the corrosiveness to magnetron component, the power of this corrosiveness may be difficult to feel within the short time of laboratory yardstick Examine, but, the time is the longest, certainly manifests, and this contains the reverse channelling of ozone-air the problem corroding magnetron component, it is impossible to quilt Avoiding, this is the 15 of problem.

The 16 of problem:

Based on this its framework of CN102260003A scheme, within electrodeless ultraviolet lamp is disposed upon the tube chamber of quartz ampoule, in order to really Protecting the normal luminous work of this electrodeless ultraviolet lamp, its inwall of this quartz ampoule must keep clean to maintain the permeability to ultraviolet light Can, and, based on the requirement in terms of similar light penetrability, himself lamp wall lateral surface of involved electrodeless ultraviolet lamp also must be protected Hold cleaning；But, this its framework of CN102260003A scheme is difficult to avoid this quartz tube cavity region that gushing water problem occurs； Gushing water alleged by this case, refers to the water in reactor not by treating that insight protrudes into the lumen area of this quartz ampoule；Cause this gushing water shape The reason of condition generally has following so two: first quartz tube cavity regional air expands with heat and contract with cold and causes quartz tube cavity region Under-voltage, it two is that quartz tube cavity regional air is escaped and to cause quartz tube cavity region under-voltage, and so, water body is relative around Under the promotion of normal pressure, the water in reactor progressively charges into the lumen area of this quartz ampoule, forms gushing water situation；At air pump In the case of power-off and quartz ampoule outboard side portion are submerged by water or portion is submerged by water greatly, it is particularly susceptible the described gushing water situation of generation； Specifically, this gushing water problem is easiest to the period occurred, and is the following two period, and first period is to fill in reactor When pending waste water and air pump not yet start, second period is that after air pump cuts out, water purification extraction procedure not yet completes When；When described gushing water situation occurs, the water being mingled with many inorganic impurities charging into this quartz tube cavity is easy to pollute this Himself lamp wall lateral surface of quartz tube cavity inwall and electrodeless ultraviolet lamp, causes its UV light permeability of relevant translucent construction position Rate is greatly reduced, and then the overall wastewater light degradation treatment efficiency of the relevant wastewater degradation reactor of impact, and therefore, this gushing water is asked Topic should not be avoided, and this is the 16 of problem.

Summary of the invention

The technical problem to be solved is, for one of problem addressed above, two, three, four, five, six, seven, Eight, nine, ten, 11,12,13,14,15,16, research and development one can solve described series totally The novel waste water microwave and photo catalysis degradation treatment device of problem.

The present invention solves described technical problem by following scheme, and the program provides a kind of big process preventing light source placing chamber gushing water Amount photocatalytic waste water degradation reactor, the structure of this reactor include a container, its appearance profile of described container be cube shaped, Cuboid, cylindrical, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form, under described container intracavity Region, portion is equiped with the micro porous aeration head of many, and, quartz ampoule, this quartz ampoule is erected at the cavity position of described container, should The two ends of quartz ampoule are equiped with closure headkerchief, lay respectively at and all offer ventilation interface on the described closure headkerchief at quartz ampoule two ends, And, electrodeless ultraviolet lamp, this electrodeless ultraviolet lamp is bar-shaped, ring-type, spherical, Asterias amurensis Lutken shape or Hemicentrotus seu Strongylocentrotus shape, this electrodeless ultraviolet lamp Quantity is at least at more than one, and this quantity is at least all erected at the inside of described quartz ampoule at more than one electrodeless ultraviolet lamp, with And, air pump, this air pump is installed in the outside of described container, the ventilation interface warp on described quartz ampoule one end seal blanking cover head Couple by breather line and through described wall of a container with the gas outlet of described air pump, its other end of described quartz ampoule closure headkerchief On ventilation interface couple with the micro porous aeration head being positioned at described container intracavity lower area via another breather line, and, Microwave generator, this microwave generator is installed in the outside of described container, and this microwave generator is magnetron, and, waveguide, This waveguide is the component for transmitting microwave, and one end of this waveguide and described magnetron UNICOM, the other end of this waveguide is saturating Cross the described wall of a container inner chamber towards described container, and, water pump, this water pump is positioned at the outside of described container, and this water pump is used In the waste water that pumping is pending, its outlet of this water pump leads to the inner chamber of described container, and the top of described container offers tail gas row Put mouth, it is characterised in that one end through described wall of a container of this waveguide extends much further into the inner chamber of described container, This gos deep into that one end of waveguide of described container intracavity and further probes into through one of described quartz ampoule closure headkerchief The inside of quartz ampoule, and, the structure of this reactor also includes the microwave constrainer of the caged of metal material, and the microwave of caged is about Bundle device is exactly a metal cage, containing many holes or mesh, the microwave constrainer of this caged in the microwave constrainer of this caged Function be constraint microwave, contain its unhelpful dissipation, simultaneously, it is allowed to major part ultraviolet light penetrate, the microwave constrainer of this caged Installation position be positioned at the inside of described quartz ampoule, its inner chamber of microwave constrainer of this caged probes into quartz ampoule with described waveguide That one end UNICOM, described UNICOM refers to couple with through in microwave channel meaning, described in be erected within quartz ampoule electrodeless Uviol lamp is all rolled in wherein by the microwave constrainer of cage-like, and, booster pump, this booster pump is mixed with big for supercharging pumping Water after the degraded of amount catalyst particles, its water inlet of this booster pump is via ventilating water pipe and passes through described wall of a container with described The inner chamber of container couples, and, the preposition prefilter of back flush type, this back flush type its water inlet of preposition prefilter is with described The outlet of booster pump couples, and, back flush type doughnut membrane microfiltration filter, the preposition prefilter of described back flush type Its pure water inlet couples via the water inlet of first water purifying valve with this back flush type doughnut membrane microfiltration filter, and, instead Flushing type hollow-fibre membrane ultra filtration filter, described back flush type doughnut its pure water inlet of membrane microfiltration filter is via second Water purifying valve couples with the water inlet of this back flush type hollow-fibre membrane ultra filtration filter, this back flush type hollow-fibre membrane ultra-filtration filters The entrance point of its pure water inlet of device and the 3rd water purifying valve couples, and the water side of the 3rd water purifying valve is going out of outlet terminal water purification Water end (W.E.), and, catalyst underflow transition tank, this catalyst underflow transition tank is the tank body of a hollow, and this catalyst underflow transition tank is used In temporarily depositing the water body that catalyst concentration that its backwashing procedures of described filter discharged is higher, it is positioned at this catalyst underflow transition The catalyst underflow refluxing opening of its intracavity bottom of tank leads to the inner chamber of described container via catalyst underflow reflux inlet, and this catalyst underflow refluxes Valve is the valve body for this catalyst return flow line of on-off control, and described back flush type its outlet of sewer of preposition prefilter is via first Individual sewage valve leads to the inner chamber of this catalyst underflow transition tank, described back flush type its outlet of sewer warp of doughnut membrane microfiltration filter The inner chamber of this catalyst underflow transition tank, described back flush type hollow-fibre membrane its sewage of ultra filtration filter is led to by second sewage valve Exporting the inner chamber leading to this catalyst underflow transition tank via the 3rd sewage valve, it is micro-that each described filter is used to retain catalyst Grain, each its outlet of sewer of described filter is all converted as by retaining the recycling delivery outlet of catalyst particles, and, described permitted Many micro porous aeration heads mutually assemble formation cluster-shaped micro porous aeration head cluster, and this cluster-shaped micro porous aeration head cluster sets up vacantly At the lower area of described container intracavity, this cluster-shaped its bottom edge of micro porous aeration head cluster is vertical with described container intracavity bottom surface To distance between 10 centimetres and 50 centimetres, this cluster-shaped micro porous aeration head cluster is edge and described container intracavity side arround it The lateral separation of wall is between 20 centimetres and 300 centimetres, and this its center of cluster-shaped micro porous aeration head cluster or center of gravity are positioned at institute State the underface of quartz ampoule, and, ozone sensor, the sampling port of this its probe tube of ozone sensor is arranged adjacent to described tail gas Put mouth or probe into the inside of described exhaust port, and, ozone content display, ozone attention device or ozone content display With the composite structure of ozone attention device, this ozone sensor is via Article 1 cable and this ozone content display, ozone attention device Or ozone content display couples with the composite structure of ozone attention device, and, power-supply controller of electric, its output of this ozone sensor Electric signal couples with this power-supply controller of electric via Article 2 cable, and this power-supply controller of electric joins with described magnetron via Article 3 cable Connecing, this power-supply controller of electric couples with described air pump via Article 4 cable, and this power-supply controller of electric can be received according to it Described electric signal carries out the power-supply controller of electric of on and off switch action, and, one group of ultrasonic transducer, this group of ultrasonic wave transducer Device at least contains a ultrasonic transducer individuality, and this group of ultrasonic transducer is used for radiating low-frequency ultrasonic waves, this low frequency ultrasound Ripple refers to the frequency ultrasound wave in 20kHz-60kHz scope, and this container intracavity bottom surface is the most hollow to central area by periphery, Described its gradient hollow is between 5 degree and 35 degree, and this group of ultrasonic transducer is to be installed at the bottom of this container intracavity with attaching The lateral surface position of its part vessel bottom wall corresponding to hollow bosom of face or medial surface position, and, higher-order of oscillation telecommunication Number transmission cable, the one group of ultrasonic transducer in one end of this higher-order of oscillation electric signal transmission cable and this couples, and, high frequency vibrating Swinging electric signal generator, the other end of described higher-order of oscillation electric signal transmission cable couples with this higher-order of oscillation electric signal generator, And, pH pop one's head in, and, pH analyser, this pH probe be coupled to each other with pH analyser, this pH analyser and with police Report device couples, and this siren is for sending alarm to the pH value situation of transfiniting, and this pH probe stretches into institute through the top of described container State container intracavity, and, through the micropore rustless steel sleeve that powder sintering process is made, this micropore rustless steel sleeve is cap for brush shape, This micropore rustless steel sleeve is positioned at described container intracavity, this micropore its blind end of rustless steel sleeve down, this micropore rustless steel sleeve Upward, this its opening upward of micropore rustless steel sleeve couples with described container top its opening via buffering isolating pad, should PH pops one's head within its that part stretching into described container intracavity probes into this micropore rustless steel sleeve, and this its material of buffering isolating pad is Fluorubber or silicone rubber, and, two pairs of dry-reed type ball float level controllers, these two pairs of dry-reed type ball float level controllers all pass through The top of reactor extend into the inner chamber of reactor, and a pair dry-reed type ball float level controller therein passes through a relay and institute The power cable stating water pump couples, and dry-reed type ball float level controller is passed through another relay and described supercharging by therein another The power cable of pump couples, and its part going deep into this container intracavity of this waveguide is to be made up of two sections of stainless steel tubes, and these two sections are not Rust steel pipe docks with flange connection each other, in place of this Flange joint, uses two-layer teflon gasket, And, wave transparent gas-tight bulkhead plate, this wave transparent gas-tight bulkhead plate is that quartz glass plate, polyfluortetraethylene plate or dense sintering form Ceramic wafer, this wave transparent gas-tight bulkhead plate be used for air-tightness this waveguide of cross-section separation, the board plane of this wave transparent gas-tight bulkhead plate with should Axis in place of this Flange joint of waveguide is mutually perpendicular to, this wave transparent its periphery edge of gas-tight bulkhead plate wedging two-layer polytetrafluoroethyl-ne Locations of structures between alkene pad, and, first check valve, this first check valve is installed in described air pump, and it supplies gas logical On road, neighbouring described air pumps out the position of QI KOU, and, quartz tube cavity malleation maintains pump, and this quartz tube cavity malleation maintains Pump be one lower powered for low discharge pumped air and only to maintain the miniature membrane pump for the purpose of quartz tube cavity malleation, This quartz tube cavity malleation maintains its power of pump between 5 watts and 50 watts, and this quartz tube cavity malleation maintains its gas outlet of pump Operating pressure between 1 meter water column and 5 meter water columns, this quartz tube cavity malleation maintain its gas output of pump per minute 1 liter with Between 80 liters per minute, this quartz tube cavity malleation maintains its gas outlet of pump to make also with described air pump through second check valve Connection connects, and, the 3rd check valve, the 3rd check valve is installed between this quartz tube cavity and described micro porous aeration head Connection gas circuit on, another breather line that this connection gas circuit is namely described.

Check valve is commercially available.

Miniature membrane pump is commercially available.

This catalyst underflow reflux inlet is the valve body for this catalyst return flow line of on-off control；The switch of commercially available various fluid lines Valve, may be suitable for the needs of this locations of structures, and its concrete type selecting can determine as required.

Described dry-reed type ball float level controller, the art-recognized meanings of itself for liquid level controller manufacturing professional and Speech is known；Described dry-reed type ball float level controller is commercially available.

Described relay is commercially available.Described relay includes high power relay certainly.Relay described in this case refers to function class Same or some close circuit connection of function controls device, and described circuit connection controls device such as relay, catalyst, open circuit Device etc.；Described circuit connection controller the most such as relay adds the assembling device of catalyst.Described relay, catalyst, disconnected Road device etc. device market is the most on sale.

Involved stainless steel tube is commercially available.

Involved quartz glass plate is commercially available.

The involved market such as polyfluortetraethylene plate and teflon gasket is the most on sale.

The ceramic wafer of involved dense sintering is commercially available；This ceramic wafer also can customize to Ceramics Majors producer.

Itself art-recognized meanings of involved Flange joint one word, for pipeline engineering technical staff, is known.

Valve body on all fluid passages of this case, can select to use electromagnetic valve, in the case of selecting to use electromagnetic valve, passes through Long-range cable is concentrated and is arranged on a control panel, so, long-distance centralized control can be conveniently realized.

Involved pH probe is commercially available；Described pH probe also known as pH sensor；PH probe or say itself skill of pH sensor Art is meant that known.

Involved pH analyser is commercially available；Itself art-recognized meanings of pH analyser is known.This case pH analyser one word is general Refer to pH can be utilized to detect, picking up, showing pH value information of any model, and can externally export pH and be correlated with electric signal Instrument, market is sold simple or complicated but all meet the pH correlate meter of this basic demand it is various in style, Can select as required.

Involved buffering its thickness of isolating pad does not limits；But, have a preferred range, the preferred scope of this buffering its thickness of isolating pad Between 1 millimeter to 8 millimeter.

Themselves art-recognized meanings of involved fluorubber and involved silicone rubber is known；Involved fluorubber and involved silicone rubber, city Field is the most on sale.

Involved micropore its wall thickness of rustless steel sleeve does not limits；But, also have an associated preferred scope, this micropore rustless steel The preferred scope of its wall thickness of sleeve is between 3 millimeters to 30 millimeters.

An involved powder sintered word, the art-recognized meanings of itself, for the professional of metallurgical technology field, is known.

Involved micropore rustless steel sleeve, can customize to relevant powder metallurgy specialized factory.

The sleeve-shaped micropore stainless steel filter conversion that can be made by powder sintering process is the micropore stainless steel sleeve described in this case Cylinder；The sleeve-shaped micropore stainless steel filter that described powder sintering process is made is commercially available.

The aperture of involved micropore rustless steel its micropore of sleeve does not limits；But, the aperture of this micropore is also to have a preferred range, should The preferred scope of micropore size is between 0.5 micron to 50 micron.

This its opening upward of micropore rustless steel sleeve couples with described container top via buffering isolating pad, refers to this connection Connecing is flexible connection, in place of this connection, has described buffer compartment mediate from pad.

Described siren is can to send audio frequency warning message or the device of optical frequency warning message according to its received electric signal； Itself art-recognized meanings of described siren is known；Described siren is commercially available.

Itself art-recognized meanings of involved ultrasonic transducer one word is known for the professional in ultrasonic technology field 's.

Itself art-recognized meanings of involved higher-order of oscillation electric signal transmission cable one word is for the professional in ultrasonic technology field For be also known.

Involved ultrasonic transducer and higher-order of oscillation electric signal transmission cable market are the most on sale；Described ultrasonic transducer and high frequency vibrating Swing electric signal transmission cable etc. also to customize to ultrasonic transducer specialized factory and cable specialized factory.

Itself art-recognized meanings of higher-order of oscillation electric signal generator one word for the professional in ultrasonic technology field also It is known；Various higher-order of oscillation electric signal generator is commercially available；Described higher-order of oscillation electric signal generator also can be to ultrasound wave Equipment specialized factory customizes.

Involved ozone sensor is commercially available；Customize to ozone sensor specialized factory also dependent on needs.

Involved ozone content monitor market is on sale；Also dependent on needs to the customization of ozone content display specialized factory；Ozone passes Matching used ozone content display is generally also sold by sensor producer.

Involved ozone attention device, refers to warn that sound or alarm flashing or warning sound combines with alarm flashing that both are double And have for warning mechanism；Ozone attention device is commercially available；Also can be to the customization of ozone attention device specialized factory；Ozone passes Matching used ozone attention device generally also can be sold by sensor producer.

This power-supply controller of electric involved is the power-supply controller of electric that can carry out on and off switch action according to its described electric signal received； The power-supply controller of electric of on and off switch action can be carried out only with regard to its circuit engineering itself according to its electric signal received, be Through ripe, known technology；Described power-supply controller of electric is commercially available；It is possible with commercially available power-supply controller of electric to enter as required The row transformation of the way；Described power-supply controller of electric also can customize to power-supply controller of electric specialised manufacturers；The electronic device of power-supply controller of electric etc its Specialised manufacturers spreads all over the world.

Described metal material one word, the art-recognized meanings of itself, is known.

Described magnetron, and, waveguide device, its art-recognized meanings is known for the professional of microwave technical field. Described magnetron, and, waveguide etc., it is commercially available；Described waveguide can certainly self manufacture, this system as required Making for the professional of microwave technical field, the making of waveguide device is simple.

Described quartz ampoule, its art-recognized meanings is known；Described quartz ampoule is commercially available；Described quartz ampoule also can be to specialized factory Customization.

Described electrodeless ultraviolet lamp, its art-recognized meanings is known for the professional of light sources technical field；Described electrodeless purple Outer lamp is commercially available；Its shape of described electrodeless ultraviolet lamp, size, internal filled gas, lamp wall material, lamp wall thickness, etc. Deng, it is also possible to according to specific design needs, customize to electric light source manufacturing enterprise.It is of course also possible to self manufacture.Without extreme ultraviolet Making for possessing the professional of electric light source Professional knowledge of lamp, its manufacturing technology is simple.

Its material of microwave constrainer of this caged can be any selected metal, but, in view of it is residing by strong ultraviolet light The ozone gaseous mixture environment that radiation is formed, and, for the most defeated by complicated direct reflection mechanism as much as possible Going out considering of the ultraviolet light launched by electrodeless ultraviolet lamp, the preferred metal material being suitable to make the microwave constrainer of this caged is Through the punching rustless steel that mirror finish processes.

Can welded with bright finished punching corrosion resistant plate, splicing or mould pressing process make described microwave constrainer.

The microwave constrainer of this caged can certainly be made with the braiding of bright finished stainless steel silk.

For convenience of runnings such as the cleaning periodically carried out for inside reactor and maintenance, blowdown can be offered in the bottom of described container Mouthful, this sewage draining exit is used for deslagging, removes contamination, and can install blowoff valve at this Location for Sewage, and described blowoff valve is for blowdown control The valve of system；If desired, it is possible to use described container internal liquid is emptied completely by this sewage draining exit being positioned at described container bottom； This sewage draining exit and blowoff valve are not necessarily.

Described water pump and booster pump, be all the pump for carrying clear or turbid all kinds of water, and certainly, its pumping pressure can As desired to select arbitrarily, and, various pump market is the most on sale；This case uses different names, is intended merely to conveniently Statement, the convenient pump distinguishing each different structure position.

Described water purifying valve, sewage valve, blowoff valve, be all water valve, and various water valve market is the most on sale；About water valve, this word its The art-recognized meanings of body is known；This case uses different titles, is intended merely to conveniently state, conveniently distinguish each different structure The water valve of position.

The preferred scope in its filter opening aperture of the preposition prefilter of described back flush type is between 5 microns and 300 microns, certainly, It is also that this case is allowed that other preposition pre-filtering aperture outside this preferred scope selects；Described back flush type hollow-fibre membrane The preferred scope in its filter opening aperture of microfiltration filter is between 25 nanometers and 1000 nanometers, certainly, this preferred scope it It is also that this case is allowed that other outer microfiltration aperture selects；Described its filter opening aperture of back flush type hollow-fibre membrane ultra filtration filter Preferred scope be between 15 nanometers and 2 nanometers, certainly, other ultrafiltration aperture outside this scope selects also to be this Case is allowed.

The preposition prefilter of described back flush type is also referred to as back flush type fore filter or back flush type prefilter, described backwash Itself art-recognized meanings of the preposition prefilter of formula is known；The preposition prefilter of described back flush type is commercially available.

Described back flush type doughnut membrane microfiltration filter is adapted for the filter of microfiltration；Itself technology of described microfiltration one word It is meant that known；Itself art-recognized meanings of described back flush type doughnut membrane microfiltration filter is for technical field of membrane separation Professional for, be known；Described back flush type doughnut membrane microfiltration filter is commercially available.

Described back flush type hollow-fibre membrane ultra filtration filter is adapted for the filter of ultrafiltration；Itself technology of described ultrafiltration one word It is meant that known；Itself art-recognized meanings of described back flush type hollow-fibre membrane ultra filtration filter is for technical field of membrane separation Professional for, be known；Described back flush type hollow-fibre membrane ultra filtration filter is commercially available.

In ultrafiltration link, this back flush type hollow-fibre membrane ultra filtration filter can be that only a back flush type hollow-fibre membrane surpasses Filter the form of filter monomer；Certainly, this back flush type hollow-fibre membrane ultra filtration filter can also be at more than one by quantity Back flush type hollow-fibre membrane ultra filtration filter monomer parallel with one another couple composition.

Expressing an involved word in parallel, the art-recognized meanings itself referred to is clearly.

Express involved monomer one word, refer to itself function and structure equipment completely is individual.

Similarly, in microfiltration link, this back flush type doughnut membrane microfiltration filter can be an only back flush type hollow The form of fibrous membrane microfiltration filter monomer；Certainly, this back flush type doughnut membrane microfiltration filter can also be to be existed by quantity More than one back flush type doughnut membrane microfiltration filter monomer is parallel with one another couples composition.

At described back flush type doughnut its pure water inlet of membrane microfiltration filter and described back flush type hollow-fibre membrane ultra filtration Second booster pump can be installed on the connecting pipeline of the water inlet of filter further, this second booster pump be used for augmenting hydraulic pressure with Meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter；This second booster pump is not necessarily.

The microwave constrainer of cage-like is exactly a metal cage；Himself structure of microwave constrainer of this caged is a mass of hole Or the preferred scope of mesh, described hole or its bore of mesh is between 0.5 centimetre and 3.0 centimetres；Certainly, if one Surely to select at this hole or the mesh of other bore outside preferred scope, that is also that this case is allowed.

The structure of this case device, it is also possible to include some adnexaes, described adnexa such as: the cooling being connected with magnetron cooling pipe Water circulation system or air cooling system；Described adnexa the most such as electrodeless ultraviolet lamp is fixed on cage-like microwave constrainer it Interior fixed support；Described adnexa the most such as being fixed on the support within described quartz ampoule by the microwave constrainer of cage-like Component；Described adnexa can certainly include being fixed on described quartz ampoule the support within described container or fixed mount；Described attached Part is the most such as installed in the filter for intercepting impurity of reactor influent waste water end, etc..

Can also be on this case architecture basics, development this case scheme further, for example, it is possible to give the charging characteristic of catalyst particles To pay close attention to, and it is greatly utilized, considers based on this, back flush type doughnut membrane microfiltration filter described in this case its include Hollow fiber microfiltration membrane can specify use bear electricity hollow fiber microfiltration membrane, back flush type hollow-fibre membrane ultra filtration described in this case Its hollow fiber ultrafiltration membrane included of filter can specify use bear electricity hollow fiber ultrafiltration membrane.In the situation using bear electrolemma Under, Coulomb repulsion effect can be given full play to, its effect of this Coulomb repulsion, can suppress catalyst particles on membrane module Intractable adheres to, and facilitates the cleaning of its backwashing procedures of membrane module to operate.Only with regard to itself skill of bear electricity hollow-fibre membrane one word For art implication, for the research worker in charged membrane field, know.Only with regard to bear electricity hollow-fibre membrane itself For technology of preparing, for the expert in charged membrane field, know.

Its structure of this case can also allow for farther including tank, described back flush type doughnut membrane microfiltration filter and described Within the back flush type hollow-fibre membrane equal submergence of ultra filtration filter is placed in this tank, it is equiped with bottom its sidewall of this tank or its Another organizes ultrasonic transducer, and this another group ultrasonic transducer at least contains a ultrasonic transducer individuality, and this another group surpasses Acoustic wave transducer is used for radiating high-frequency ultrasonic, and this high-frequency ultrasonic refers to ultrasonic in 100kHz-12MHz scope of frequency Ripple, this another group ultrasonic transducer couples with another higher-order of oscillation electric signal generator；Operate in this case membrane module backwash In program, by means of there is no cavitation damage or the most weak described high-frequency ultrasonic of cavitation damage, it is possible to more mildly assist recoil Washing procedure releases those catalyst of obstinate attachment on membrane module working interface.

It is an advantage of the invention that to be placed in the microwave constrainer of the caged of the metal material within described quartz ampoule, by electrodeless purple Outer lamp is wrapped among its inner chamber, its inner chamber of microwave constrainer of caged and with the waveguide UNICOM goed deep within described container, Described UNICOM refers to the UNICOM in microwave channel meaning, by this structure, is constrained in by the microwave come via waveguide transmissions Within its effective working area, containing the microwave unhelpful dissipation to periphery waste water water body, this case structure allows reactor significantly to expand it Design volume, it is allowed to reactor list tank wastewater treatment capacity is substantially improved, and need not worry that microwave energy dissipates too much in unhelpful again Waste water water body temperature-rise effect.

Bright finished punching rustless steel is being used to make microwave constrainer, or, use bright finished stainless steel silk cylinder mould to make In the case of microwave constrainer, via complicated direct reflection mechanism, both of which can be to greatest extent by from electrodeless ultraviolet The ultra-violet light transmission of lamp is gone out, and makes up described himself entity of microwave constrainer to greatest extent and block light, absorb and made The loss become.

Structure based on this case, the most single tank wastewater treatment capacity of the design volume of reactor can be expanded to several cubes and stand to dozens of Side；The volume of hundreds of cubes of even single tank, is also to allow；Based on this structure of this case, can be greatly reduced a complete set, The saving of the frequency of substantial length of operation, beneficially human and material resources.

This case reactor its run among, its high density ascension bubble stream discharged of described cluster-shaped micro porous aeration head cluster, While upwards ascension, and wrapped folder, carry, guided liquid-flow, form a kind of motion being similar to fountain form, this kind fortune Disorder of internal organs, be derived from the high density bubble stream wrapped folder of described cluster-shaped micro porous aeration head cluster liquid gush to quartz ampoule region and On, and then more intensively impact, by the effective coverage of the described photochemical catalysis oxidation reaction of quartz ampoule periphery, by described High density bubble stream wrapped folder, the liquid stream carried impact, by the described effective coverage of quartz ampoule periphery after, by top area Liquid layer to surrounding spread, via neighboring area sink, arrive reactor intracavity bottom region, then through described cluster-shaped micropore expose The wrapped folder of its high density ascension bubble stream discharged of gas head cluster, carry, continue its motion being similar to fountain form, so Circulation is endlessly；The liquid shuttling movement of this relatively large yardstick guided, contributes to guaranteeing that inside reactor liquid degradation is reacted The homogenization of process, this, for large-scale electrodeless ultraviolet light catalysis degradation reaction device, is necessary.

Its UV source of this case reactor is to rely on microwave excited electrodeless ultraviolet lamp, and the ultraviolet radiation feature of this lamp-type is exactly can To accomplish high-power, high intensity, but the Effective depth penetration that ultraviolet is in liquid water body only has 20 cm, therefore, Region within quartz ampoule periphery about 20 cm distance is effective coverage, and this region is exactly photochemical catalysis oxidative degradation Efficient region；This case method, to be positioned at the described cluster-shaped micro porous aeration head cluster immediately below quartz ampoule, is intensively released Put highdensity ascension bubble stream so that it is intensively release towards quartz ampoule peripheral light chemical catalytic oxidation effective coverage as fountain Putting, the method is favorably improved the oxygen atmosphere supply intensity of effective coverage described in quartz ampoule periphery, helps speed up ultraviolet light and urges Change oxidative degradation process.

Can significantly expand based on this case structure, the capacity of reactor or treating capacity, described significantly expand, be by significantly expanding The design volume of microwave zero irradiation zone or the weak irradiation zone of microwave realizes, then, the lateral dimension of reactor, longitudinal ruler Very little is all significantly to expand certainly, and therefore, inside reactor is contained the liquid degree of depth and can be deepened significantly similarly, such as, and can To deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, etc., containing the feelings that the liquid degree of depth is the deepest Under condition, containing ozone-air bubble ascension path long enough, steep the time long enough contacted with water body, its ascension process containing ozone-air In just can be with abundant reducing substances fortune, and thoroughly or be close to and exhaust ozone contained in bubble up hill and dale, thus, Incomplete problem is utilized to be solved containing ozone composition oxidation potential in ozone-air bubble, and, due to long Ascension path cause ozone depletion, reactor tail gas re-entrainment would not have the ozone that can cause environmental pollution.

This case is with external multistage filter, reaches the little yardstick from aggregate bulky grain to ten number nanometer to catalyst particles Collision fragment interception step by step, be close to up hill and dale reclaim, reuse photocatalyst, be close to up hill and dale take precautions against catalyst loss and make The secondary pollution become；This intercepts scheme step by step and secondary filter can be protected to make its filtration passage from large particulate matter Rigid obstruction；Wherein the pre-filtering aperture of the first order is between 5 microns and 300 microns, and its aperture of the microfiltration of the second level is 25 Between nanometer and 1000 nanometers, its aperture of the ultrafiltration of the third level is between 15 nanometers and 2 nanometers；Such interception scheme, Can fully intercept nano level photocatalyst, it can be close to interception gas phase this average particle of titanium dioxide P25 up hill and dale certainly Footpath is the catalyst of 21 nanometers；Address above, the gas phase titanium deoxide catalyst of nano level P25 etc, be can be a large amount of The commercially available catalyst buied, is also durability, stability, the known excellent photocatalyst of ultraviolet light wave band photocatalysis performance, Certainly, it is also the photocatalyst in fact paying the utmost attention in industrial scale applications select；This case catalyst intercepts scheme and catalyst The practical capacity of market supply, actual kind match, blend.

Further, due to this case catalyst intercept mechanism be external mechanism, its filter element just need not be soaked in inside reactor Strong oxdiative, In the liquid of strong ultraviolet irradiation, therefore, it can to consider ultraviolet irradiation, the tolerance of Strong oxdiative condition completely, so, Just without the restriction in terms of extraordinary tolerance in the selection of filter element material, can carry out in more vast optional material kind Select, and entirely without the material of the PVDF must being confined to again costly etc.

Involved filters at different levels are commercially available, commercially available filters at different levels, the discharge of draining-off sewage when its sewage draining exit is exactly backwash Mouthful, this case uses this kind of back flush type equipment, is used to intercept step by step catalyst particles, the sewage draining exit of the most commercially available relevant device, The recycling delivery outlet or backflow that are used as by retaining catalyst particles by conversion in the present case use delivery outlet again.

Already described above and, can significantly expand based on this case structure, the capacity of reactor or treating capacity, described significantly expand, be Realized by the design volume significantly expanding microwave zero irradiation zone or the weak irradiation zone of microwave, then, from the appearance, The lateral dimension of reactor, longitudinal size are the most all significantly to expand, and therefore, inside reactor contains the liquid degree of depth similarly Can deepen significantly, for example, it is possible to deepen to one meter, two meters, three meters, four meters, five meters, six meters, even ten meters, etc. Deng, in the case of the Sheng liquid degree of depth is enough deep, containing ozone-air bubble ascension path long enough, the bubble containing ozone-air contacts with water body Time long enough, just can be with abundant reducing substances fortune during its ascension, and thoroughly or be close to and exhaust up hill and dale Ozone contained in bubble, thus, utilizes incomplete problem to obtain containing ozone composition oxidation potential in ozone-air bubble Thoroughly solve, and, owing to long ascension path causes ozone depletion, reactor tail gas re-entrainment would not have and can cause The ozone of environmental pollution；Only when being subject to processing reducing substances in water body i.e. organic pollution is degraded totally, in water body Through again without being available for the organic pollution of ozone oxidation reaction, those unnecessary ozone it is possible to no longer consume and pass through long Ascension path effusion liquid level；Having spoken of, among the some problem that this case solves simultaneously, is enhanced reactor The circulation of the relatively large yardstick of internal liquid, the systemic circulation mechanism that this enhances facilitates the organic dirt contained by it of inside reactor liquid The uniformity of dye thing degradation reaction process, thus, several cubes allowed in this case structure the most hundreds of to dozens of cube Under the process capacity framework of individual cube volume, when inside reactor ullage has ozone effusion, i.e. show inside reactor Degradation reaction reached terminal, and be internal liquid entirety uniformity reach the terminal of degradation reaction, this terminal point determining Factor is the matching criteria that can be provided by with this case organization plan；Ozone is installed in this case in its exhaust port position of reactor Sensor, detects ozone in this locations of structures, just means that inside reactor degradation reaction is reached home, ozone sensor And couple with the composite structure of ozone content display with ozone attention device or ozone content display or ozone attention device, be used for The information that indicates accurately, this case and the electric signal by ozone sensor output is provided to send power supply to by cable to operator Controller, this power-supply controller of electric is also coupled with magnetron and air pump respectively by cable, and power-supply controller of electric is according to received by it Described electric signal carry out on and off switch action, certainly, its function mode is, receives ozone sensor at power-supply controller of electric and sends out When the signal of the ozone effusion sent, it is automatically switched off and leads to magnetron and the power supply of air pump；This case organization plan according to this, can and The terminal of Shi Zhixiao inside reactor degradation reaction process；And organization plan according to this, when reaction reaches terminal, it is automatically switched off magnetic Keyholed back plate and the power supply of air pump, stop to inside reactor Implantation Energy in time, so can avoid unnecessary energy waste；And And, this case structure according to this, when degradation reaction is reached home, it is possible to close described magnetron and the power supply of air pump in time, This power-off action also synchronizes, the same generation process terminating in a flash ozone, owing to ozone generation process is terminated in time, The a large amount of ozone that would not have more than needs disengage from described exhaust port, thus avoid unnecessary secondary pollution or say secondary Raw pollution；Its framework of this case determines the ozone that it does not have more than needed and is available for discharge.

Among this case structure, the microwave exposure spatial domain of its inside reactor is cut off by forcing, limits, this case and use external Cascading multiple stages backwash filter structure intercepts catalyst particles, back flush type hollow fiber microfiltration membrane assembly therein subtly And back flush type polysulfone hollow fiber ultrafiltration membrane system is the most external and away from reactor core, microwave can not be irradiated to described film group completely Part, based on this structure of this case, has got around described point-like completely and has pierced the heat penetration erosion destruction problem of formula, and this problem thus obtains well Solution.

This case reactor inner chamber bottom surface is the most hollow to central area by periphery, described its gradient hollow between 5 degree with 35 degree it Between, this case ultrasonic transducer is to be installed in its part reaction corresponding to hollow bosom of this reactor inner chamber bottom surface with attaching The lateral surface position of device diapire or medial surface position；Addressing above, this case structure and beneficially driving a reaction device internal liquid make phase Shuttling movement to large scale, the mode of this liquid shuttling movement is that peripheral liquid sinks, and middle liquid rises, the most constantly Move in circles；Address above, some pH value be pre-adjusted not in place, pH value inappropriate in the case of, titanium dioxide is micro- Grain is susceptible to reunite, and then affects its effective working interface area, affects its photocatalysis usefulness；Particularly with this particle size range Among the section of those relatively small particle diameters, easily occur especially because of pH value presetting not in place, pH value is incorrect and cause Agglomeration traits；For this catalyst particles in the case of of reuniting, it is immediately to adopt an effective measure, carries out for aggregate Depolymerization running；When catalyst particles generation serious agglomeration, the heavier macro aggregate of some of which is due to gravity Effect, it is intended to gradually settling to reactor intracavity bottom, in this case structure, reactor intracavity bottom is hollow structure, and, This case structure can make the shuttling movement of described relatively large yardstick by driving a reaction device internal liquid, the effect of this systemic circulation campaign together with The effect of ubiquitous natural gravity, the macro aggregate settled can be pushed away along the slope of described hollow structure sweep to hollow Depths also makes them be gathered in there, and in this case structure, ultrasonic transducer is just being in this hollow innermost locations of structures, should Hollow innermost region, is the region finally assembled of described macro aggregate, be also simultaneously ultrasound wave can minimum damply, Minimum distance ground, carry out depolymerization operating area the most consumingly, most effectively for macro aggregate；This structure of this case can allow for Minimum ultrasonic energy loss, it is achieved maximized ultrasonic depolymerization effect；This case structure according to this, it is possible to converge aggregate precipitum, And the region concentrated most at aggregate precipitum, implement depolymerization running；The ultrasound wave being derived from reactor bottom also is able to of course simultaneously Other region being radiated in inside reactor liquid, plays the aggregate being still within suspended state that those are smaller and solves Poly-effect；This case associated ultrasonic radiates mechanism, is the mechanism that can start as required or close；This case thus achieve for The instant of this catalyst particles agglomeration traits is disposed in situ.

Structure is protected for screen the quartz ampoule of electrodeless ultraviolet lamp, its outer wall, refers to the outer wall of quartz ampoule, through long and quilt Processing the contact of industrial wastewater, the most gradually dirty, the material that dirt amasss the most mainly is difficult to the nothing touched by light-catalyzed reaction Machine class impurity, the dirty phenomenon formed because of this mechanism, it is easy to be observed after equipment long-play；It is attached to described The dirty lamination of quartz ampoule outer wall, although the veryyest thin one layer, also be enough to cause the ultraviolet radiation of electrodeless ultraviolet lamp significantly Stopping, the actual treatment effect causing this microwave and photo catalysis reaction treating device is significantly reduced by this；This case structure is positioned at reaction Ultrasonic transducer bottom device, in the irregular depolymerization running carried out for accidental catalyst particles serious agglomeration situation Among, its ultrasound wave radiated, the most also can arrive quartz ampoule place locations of structures, this ultrasound wave is carrying out depolymerization fortune in situ While work, carry out amassing for quartz ampoule surface dirt the ultrasonic clean scale removal work of thing the most in the lump；Further, ultrasonic transducer Installation position away from quartz ampoule place locations of structures, ultrasonic radiation has decayed when arriving quartz ampoule position, therefore, stone Ultrasonic impact suffered by English tube-surface is low intensive ultrasonic impact, and this low intensive ultrasonic impact can leniently remove Dirt, is avoided that again or significantly weakens its quartz ampoule surface smoothness loss being likely to result in of ultrasonic cavitation；Should based on this case Structure, it is possible on the premise of not tearing machine open, removes the dirty lamination on this quartz ampoule outer wall immediately, effectively, thereby safeguards that this is micro- The lasting high efficiency of glistening light of waves catalytic degradation reaction device.

The pH value of wastewater degradation inside reactor water body, is the key factor affecting catalyst dispersion stabilization；This case structure fills If pH probe and the pH value display instrument of association and the siren etc. that is associated, it is possible to steady beyond catalyst dispersion at pH value In the case of determining scope, actively sending alarm, based on this structure of this case, associative operation personnel can the inside reactor of awareness immediately Agglomeration is inclined to, and makes instant disposal.Described micropore rustless steel sleeve in this case structure and installing mode thereof, be and this The indispensable important component that case principle and this case structure match.

Membrane module in this case structure, is to be in all the time to be totally submerged among the operating mode of use, and membrane module therein has no chance to connect Touch air, be always maintained at hygrometric state and the state being totally submerged, therefore, there will be no the film group easily occurred in that background technology Part is often exposed to the situation in air, and its applying working condition of the membrane module in this case structure more conforms to membrane module, and itself is intrinsic Use condition requirement, is more conducive to safeguard its normal usage energy of membrane module, is more conducive to guarantee its normal service life of membrane module.

This case structure arranges catalyst underflow transition tank, for temporarily depositing from each its backwashing procedures of back flush type filter The liquid that the concentration containing catalyst washed away is higher, thus avoid liquid higher for this catalyst concentration is directly filled back reaction Device, so, it is to avoid the problem that in inside reactor liquid, catalyst concentration is stepped up along with the extraction process of water purification, this can Extract with the water purification follow-up to it and reduce the heavy burdens, had so one catalyst underflow transition tank structure, it is possible to extract journey at water purification After sequence completes, then within catalyst underflow is filled back reactor.

The dry-reed type ball float liquid that in this case structure a pair couples with its power cable of water pump of described transport wastewater through relay Level controller, its exist, it is possible to automatically avoid excess filling waste water to reactor inner chamber, and thus avoid waste water overflow reactor； Another dry-reed type ball float level controller to coupling with its power cable of described booster pump through another relay, its existence, It can be avoided that the liquid of inside reactor is excessively extracted and causes the idle running of this booster pump, dry turns, booster motor so can be avoided Burn.

Any valve body on all fluid passages in this case structure, can select to use electromagnetic valve, can be by these cable collection Middle arrangement is on a panel, and this structure allows the valve body switch action corresponding to each program of long-distance centralized control.

Its part going deep into this container intracavity of this waveguide in this case structure is to be made up of two sections of stainless steel tubes, and these two sections stainless Steel pipe docks with flange connection each other, in place of this Flange joint, uses two-layer teflon gasket, with And, wave transparent gas-tight bulkhead plate, this wave transparent gas-tight bulkhead plate is the pottery of quartz glass plate, polyfluortetraethylene plate or dense sintering Porcelain plate, this wave transparent gas-tight bulkhead plate is used for air-tightness this waveguide of cross-section separation, the board plane of this wave transparent gas-tight bulkhead plate and this ripple Axis in place of this Flange joint of conduit is mutually perpendicular to, this wave transparent its periphery edge of gas-tight bulkhead plate wedging two-layer politef Locations of structures between pad；The passage that reverse for ozone channelling enters magnetron structures region is blocked by this structure completely, this structure It is effectively protected magnetron structures component and protects it from the corrosion attack of Strong oxdiative power ozone.

Described quartz tube cavity malleation in this case structure maintains pump, be one lower powered for low discharge pumped air and only To maintain the miniature membrane pump for the purpose of quartz tube cavity malleation, this quartz tube cavity malleation maintain its power of pump between 5 watts with Between 50 watts, this quartz tube cavity malleation maintain its gas outlet operating pressure of pump between 1 meter water column and 5 meter water columns, this stone English pipe tube chamber malleation maintains its gas output of pump between 1 liter and 80 liters per minute per minute, and this quartz tube cavity malleation maintains pump Its gas outlet is connected in parallel with described air pump through second check valve, in other words, this quartz tube cavity malleation maintenance pump its Gas outlet is to access in described breather line with bypass mode；This quartz tube cavity malleation in structure maintains pump, its function, is When the most powerful described air pump quits work, this quartz tube cavity malleation maintains pump can start, with relatively low in good time Power attenuation much, relatively low air mass flow much and relatively low gas outlet operating pressure much, resist because of quartz The quartz tube cavity atmospheric pressure decay that pipe pipe chamber air expands with heat and contract with cold and the reason such as air escape is likely to result in, the most in advance Prevent, check the generation of quartz tube cavity gushing water situation；Described first check valve, second check valve and the 3rd check valve Maintain pump to cooperate with described quartz tube cavity malleation, define a resulting structure taking precautions against quartz tube cavity gushing water；This stone English pipe tube chamber malleation maintains pump, and based on its relatively low power consumption much, actually it can also be in the shape of normally opened operation all the time State, provides the barrier of a normality for prevention quartz tube cavity gushing water.

In short, this case structure utilizes metal cage to retrain microwave more closely, reach permission reactor design capacity and significantly expanded The target opened；Meanwhile, this case structure also enhances the shuttling movement of the relatively large yardstick of inside reactor liquid；This case structure is also To be set up in its highdensity bubble stream discharged of described cluster-shaped micro porous aeration head cluster immediately below quartz ampoule, it is achieved for Being substantially improved of the oxygen supply concentration degree of emphasis reaction zone；This case structure and reached for nm-class catalyst microgranule from its reunite Body bulky grain to ten number nanometers collision fragments widely, fine interception；The selection face of filter element material involved by it also thus To expand；Based on this case structure, its degradation reaction endpoint information can be known in time；Can be certainly when its degradation reaction terminal The dynamic energy input closed reactor；When its degradation reaction terminal, terminate the generation process of ozone the most in time, keep away Exempt from unnecessary secondary pollution；Its structure also can dispose accidental catalyst particles serious agglomeration situation the most in situ, the most same Time incidentally with through teletransmission appropriateness weaken after low intensive gentleness supersonic cleaning described in quartz ampoule surface, keep Its excellent ultraviolet light transparent performance；Its structure also can actively detect agglomeration tendency, and send police when relevant parameter exceeds standard Report；Its structure beneficially membrane module are being totally submerged use among operating mode；Its structure and by catalyst underflow transition tank structure The appropriate transition realizing catalyst underflow is deposited, and overcomes the problem that difference before and after membrance separation load is excessive；Its structure and can be real Show automatically controlling of waste water perfusion water level；Its structure also automatically, can be closed when water purification extraction to restricted water supply position in time Close the protection of the power supply of described booster pump, beneficially booster motor；The wave transparent gas-tight bulkhead structure of its waveguide is conducive to protecting magnetic Keyholed back plate structural elements protects it from the corrosion attack of reverse channelling ozone；Its bypass access Miniature diaphragm pump together with the use of Check valve, it is possible to stop quartz tube cavity gushing water.

This case structure of reactor solves described series of problems totally.

Accompanying drawing explanation

Fig. 1 is the brief perspective diagram of this case structure of reactor.

Fig. 2 is its mutual flange connection brief schematic diagram of longitudinal section form of two sections of stainless steel tubes constituting waveguide.

In figure, 1 is described container, and described container is also the main component of this reactor, and 2,12 is that locations of structures is different respectively Two breather lines, 3,7 is the closure headkerchief at quartz ampoule two ends respectively, and 4 is quartz ampoule, and 5 is the caged of metal material Microwave constrainer, 6 is electrodeless ultraviolet lamp, and 8 is exhaust port, and 9 is waveguide, and 10 is magnetron, and 11 is air pump, 13 indicate this case reactors in the rough position of liquid level contained under liquid status, 14 indicate internal microwave zero irradiation zones of described containers or The weak irradiation zone of microwave, 15 indicate micro porous aeration heads, labelling 15 only indicates micro porous aeration head individuality and individual morphology, 16 Being blowoff valve, 17 is sewage draining exit, and 18 is back flush type hollow-fibre membrane ultra filtration filter, and 19 is back flush type hollow-fibre membrane Microfiltration filter, 20 is the preposition prefilter of back flush type, and 21 is booster pump, and 22 is water pump, and 23 is ozone sensor Probe tube, 24 is the composite structure of ozone content display, ozone attention device or ozone content display and ozone attention device, 25 Being ozone sensor, 26 is power-supply controller of electric, and 27 is ultrasonic transducer, and 28 is higher-order of oscillation electric signal transmission cable, 29 Being siren, 30 is cable pH analyser and siren linked up, and 31 is pH analyser, and 32 is by pH analyser The cable linked up with pH probe, 33 is pH probe, and 34 is micropore rustless steel sleeve, and 35 is catalyst underflow transition tank, 36 is catalyst underflow reflux inlet, and 37,43 is the stainless steel tube that two-stage structure position is different respectively, and 38,42 is two knots respectively The ring flange that structure position is different, 39,41 is the teflon gasket that two locations of structures are different respectively, and 40 is described wave transparent Gas-tight bulkhead plate, the some arrows in figure indicate it adjacent to pipeline liquid flow direction when in an ON state.

Detailed description of the invention

In this case embodiment that Fig. 1 is shown, the structure of this reactor includes a container 1, and described its profile of container 1 is taken turns Wide in cube shaped, cuboid, cylindrical, the cylindroid bodily form, the polygon prism bodily form, spherical or the ellipsoid bodily form, in institute The lower area stating container 1 inner chamber is equiped with the micro porous aeration head 15 of many, and it is individual that this label 15 only indicates micro porous aeration head And form, and, quartz ampoule 4, this quartz ampoule 4 is erected at the cavity position of described container 1, the two ends of this quartz ampoule 4 It is equiped with closure headkerchief 3,7, lays respectively at and all offer ventilation interface on the described closure headkerchief 3,7 at quartz ampoule two ends, with And, electrodeless ultraviolet lamp 6, this electrodeless ultraviolet lamp 6 is in bar-shaped, ring-type, spherical, Asterias amurensis Lutken shape or Hemicentrotus seu Strongylocentrotus shape, this electrodeless ultraviolet lamp The quantity of 6 is at least at more than one, and this quantity is at least all erected at described quartz ampoule 4 at more than one electrodeless ultraviolet lamp 6 Inside, and, air pump 11, this air pump 11 is installed in the outside of described container 1, and described quartz ampoule 4 one end seal is blocked up The ventilation interface on headkerchief 7 wall via breather line 12 and through described container 1 couples with the gas outlet of described air pump 11, Described its other end of quartz ampoule 4 closure headkerchief 3 on ventilation interface via another breather line 2 be positioned at described container 1 The micro porous aeration head 15 of chamber lower area couples, and, microwave generator, this microwave generator is installed in described container 1 Outside, this microwave generator is magnetron 10, and, waveguide 9, this waveguide 9 is the component for transmitting microwave, should One end of waveguide 9 and described magnetron 10 UNICOM, the other end of this waveguide 9 passes through the wall of described container 1 towards described The inner chamber of container 1, and, water pump 22, this water pump 22 is positioned at the outside of described container 1, and this water pump 22 is used for pumping to be waited to locate The waste water of reason, this its outlet of water pump 22 leads to the inner chamber of described container 1, and the top of described container 1 offers exhaust emissions Mouth 8, it is important that, that one end through the wall of described container 1 of this waveguide 9 extends much further in described container 1 Chamber, this go deep into described container 1 inner chamber waveguide 9 that one end and further through a closure of described quartz ampoule 4 Headkerchief 7 probes into the inside of quartz ampoule 4, and, the structure of this reactor also includes the microwave constrainer 5 of the caged of metal material, The microwave constrainer 5 of caged is exactly a metal cage, containing many holes or mesh in the microwave constrainer 5 of this caged, and should The function of the microwave constrainer 5 of caged is constraint microwave, contains its unhelpful dissipation, simultaneously, it is allowed to major part ultraviolet light penetrates, The installation position of the microwave constrainer 5 of this caged is positioned at the inside of described quartz ampoule 4, its inner chamber of microwave constrainer 5 of this caged With that one end UNICOM probeing into quartz ampoule 4 of described waveguide 9, described UNICOM refers to couple with through in microwave channel meaning, The described electrodeless ultraviolet lamp 6 being erected within quartz ampoule 4 is all rolled in wherein by the microwave constrainer 5 of cage-like, and, increase Press pump 21, this booster pump 21 is mixed with the water after the degraded of a large amount of catalyst particles for supercharging pumping, this booster pump 21 its enter The mouth of a river wall via ventilating water pipe and through described container 1 couples with the inner chamber of described container 1, and, back flush type is preposition pre- Filter 20, its water inlet of the preposition prefilter of this back flush type 20 couples with the outlet of described booster pump 21, and, instead Flushing type doughnut membrane microfiltration filter 19, its pure water inlet of the preposition prefilter of described back flush type 20 is clean via first Water valve couples with the water inlet of this back flush type doughnut membrane microfiltration filter 19, and, back flush type hollow-fibre membrane surpasses Filtering filter 18, described back flush type its pure water inlet of doughnut membrane microfiltration filter 19 is anti-with this via second water purifying valve The water inlet of flushing type hollow-fibre membrane ultra filtration filter 18 couples, and it is clean for this back flush type hollow-fibre membrane ultra filtration filter 18 The entrance point of water out and the 3rd water purifying valve couples, and the water side of the 3rd water purifying valve is the water side of outlet terminal water purification, And, catalyst underflow transition tank 35, this catalyst underflow transition tank 35 is the tank body of a hollow, this catalyst underflow transition tank 35 For temporarily depositing the water body that catalyst concentration that described its backwashing procedures of filter 18,19,20 discharged is higher, it is positioned at The catalyst underflow refluxing opening of this catalyst its intracavity bottom of underflow transition tank 35 leads to described container 1 via catalyst underflow reflux inlet 36 Inner chamber, this catalyst underflow reflux inlet 36 is the valve body for this catalyst return flow line of on-off control, and described back flush type is preposition Its outlet of sewer of prefilter 20 leads to the inner chamber of this catalyst underflow transition tank 35, described back flush type via first sewage valve Its outlet of sewer of doughnut membrane microfiltration filter 19 leads to the inner chamber of this catalyst underflow transition tank 35 via second sewage valve, Described back flush type its outlet of sewer of hollow-fibre membrane ultra filtration filter 18 leads to this catalyst underflow transition via the 3rd sewage valve The inner chamber of tank 35, each described filter 20,19,18 is used to retain catalyst particles, each described filter 20,19,18 Its outlet of sewer is all converted as by retaining the recycling delivery outlet of catalyst particles, and, the micro porous aeration head 15 of described many Mutually assembling and form cluster-shaped micro porous aeration head cluster, this cluster-shaped micro porous aeration head cluster is erected in described container 1 vacantly The fore-and-aft distance of the lower area in chamber, this cluster-shaped its bottom edge of micro porous aeration head cluster and described container intracavity bottom surface is between 10 Centimetre and 50 centimetres between, the arbitrarily selected distance value within the scope of this fore-and-aft distance is all available enforcement value, and this is longitudinally Distance value can be such as 10 centimetres, 20 centimetres, 30 centimetres, 40 centimetres, 50 centimetres, etc., this cluster-shaped micropore exposes The lateral separation of edge and described container intracavity sidewall is between 20 centimetres and 300 centimetres arround it for gas head cluster, and this is horizontal Arbitrarily selected value within distance range is all available enforcement value, this lateral separation value can be such as 20 centimetres, 40 centimetres, 100 centimetres, 160 centimetres, 220 centimetres, 300 centimetres, etc., this its center of cluster-shaped micro porous aeration head cluster or center of gravity position In the underface of described quartz ampoule, and, ozone sensor 25, the sampling port of this its probe tube 23 of ozone sensor 25 is adjacent Nearly described exhaust port 8 or probe into the inside of described exhaust port 8, and, ozone content display, ozone attention device Or the composite structure 24 of ozone content display and ozone attention device, this ozone sensor 25 is via Article 1 cable and this ozone Content display, ozone attention device or ozone content display couple with the composite structure 24 of ozone attention device, and, power supply Controller 26, this its output electric signal of ozone sensor 25 couples with this power-supply controller of electric 26 via Article 2 cable, this power supply Controller 26 couples with described magnetron 10 via Article 3 cable, this power-supply controller of electric 26 via Article 4 cable with described Air pump 11 couples, and this power-supply controller of electric 26 is the electricity that can carry out on and off switch action according to its described electric signal received Source controller, and, one group of ultrasonic transducer 27, this group of ultrasonic transducer 27 at least contains a ultrasonic wave transducer Device is individual, and this group of ultrasonic transducer 27 is used for radiating low-frequency ultrasonic waves, and this low-frequency ultrasonic waves refers to frequency at 20kHz- The ultrasound wave of 60kHz scope, this container 1 inner chamber bottom surface is the most hollow to central area by periphery, described its gradient hollow between Between 5 degree and 35 degree, this group of ultrasonic transducer 27 is to be installed in this its hollow bosom, container 1 inner chamber bottom surface with attaching The lateral surface position of corresponding part vessel bottom wall or medial surface position, that shows in legend is installed in lateral surface position Situation, does not has diagram to be installed in the situation of medial surface position in legend, and, higher-order of oscillation electric signal transmission cable 28, this height Frequency vibration is swung one group of ultrasonic transducer 27 in one end and this of electric signal transmission cable 28 and is coupled, and, higher-order of oscillation electric signal is sent out Raw device, the other end of described higher-order of oscillation electric signal transmission cable 28 couples with this higher-order of oscillation electric signal generator, and, PH probe 33, and, pH analyser 31, this pH probe 33 is coupled to each other with pH analyser 31, this pH analyser 31 And coupling with siren 29, this siren 29 is for sending alarm to the pH value situation of transfiniting, and this pH probe 33 is through institute Described container 1 inner chamber is stretched at the top stating container 1, and, through the micropore rustless steel sleeve 34 that powder sintering process is made, should Micropore rustless steel sleeve 34 is in cap for brush shape, and this micropore rustless steel sleeve 34 is positioned at described container 1 inner chamber, this micropore stainless steel sleeve Cylinder 34 its blind ends down, this its opening of micropore rustless steel sleeve 34 upward, this micropore rustless steel sleeve 34 its upward Opening, via buffering isolating pad and described container 1 top attachment, is depicted without that described buffering isolating pad in legend, should Within pH probe 33 its those parts stretching into described container 1 inner chamber probe into this micropore rustless steel sleeve 34, this buffering isolating pad Its material is fluorubber or silicone rubber, and, two pairs of dry-reed type ball float level controllers, these two pairs of dry-reed type Floating Ball Liquid Level Control Device all tops through reactor 1 extend into the inner chamber of reactor 1, and a pair dry-reed type ball float level controller therein passes through one Individual relay couples with the power cable of described water pump 22, and dry-reed type ball float level controller is passed through another by therein another Relay couples with the power cable of described booster pump 21, and its part going deep into this container 1 inner chamber of this waveguide 9 is by two Section stainless steel tube 37,43 is constituted, and these two sections of stainless steel tubes 37,43 dock with flange connection, each other at this In place of Flange joint, use two-layer teflon gasket 39,41, and, wave transparent gas-tight bulkhead plate 40, this wave transparent is airtight Partition panel 40 is the ceramic wafer of quartz glass plate, polyfluortetraethylene plate or dense sintering, and this wave transparent gas-tight bulkhead plate 40 is used In place of this waveguide 9 of the cross-section separation of air-tightness, the board plane of this wave transparent gas-tight bulkhead plate 40 and this this Flange joint of waveguide 9 Axis be mutually perpendicular to, this its periphery edge of wave transparent gas-tight bulkhead plate 40 wedging two-layer teflon gasket 39,41 between Locations of structures, and, first check valve, this first check valve is installed on its plenum duct 12 of described air pump 11 The position of neighbouring described air pump 11 gas outlet, and, quartz tube cavity malleation maintains pump, and this quartz tube cavity malleation maintains Pump be one lower powered for low discharge pumped air and only to maintain the miniature barrier film for the purpose of quartz ampoule 4 tube chamber malleation Pump, this quartz tube cavity malleation maintains its power of pump between 5 watts and 50 watts, and this quartz tube cavity malleation maintains pump, and it goes out QI KOU operating pressure is between 1 meter water column and 5 meter water columns, and this quartz tube cavity malleation maintains its gas output of pump per minute 1 Rising between 80 liters per minute, this quartz tube cavity malleation maintains its gas outlet of pump through second check valve and described air pump 11 are connected in parallel, and in other words, this quartz tube cavity malleation maintains its gas outlet of pump with bypass mode and described breather line 12 Connect, and, the 3rd check valve, the 3rd check valve is installed in this quartz ampoule 4 tube chamber and described micro porous aeration head 15 Between connection gas circuit on, another breather line 2 that this connection gas circuit is namely described, legend is depicted without described quartz Pipe tube chamber malleation maintains pump and described first check valve, second check valve and the 3rd check valve.

Implement involved check valve commercially available.

Implement involved miniature membrane pump commercially available.

Involved stainless steel tube is commercially available.

Involved quartz glass plate is commercially available.

Legend is depicted without described dry-reed type ball float level controller.

Legend is depicted without this higher-order of oscillation electric signal generator.

Described its gradient enforcement value hollow is between 5 degree and 35 degree, and the arbitrarily selected value within this range of grade is all this The enforcement value that can use that case allows；This its gradient enforcement value hollow can be such as 5 degree, 8 degree, 10 degree, 15 degree, 20 Degree, 25 degree, 30 degree, 35 degree, etc..

Involved higher-order of oscillation electric signal generator one word itself art-recognized meanings for ultrasonic technology field professional and Speech is also known；Various higher-order of oscillation electric signal generator is commercially available；Described higher-order of oscillation electric signal generator also can be to super The customization of sound wave equipment specialized factory.

Involved ozone sensor 25 is commercially available；Customize to ozone sensor specialized factory also dependent on needs.

This power-supply controller of electric 26 involved is the power supply control that can carry out on and off switch action according to its described electric signal received Device；The power-supply controller of electric of on and off switch action can be carried out only with regard to its circuit engineering itself according to its electric signal received, It it is ripe, known technology；Described power-supply controller of electric is commercially available；It is possible with commercially available power-supply controller of electric according to need Change a social system；Described power-supply controller of electric also can customize to power-supply controller of electric specialised manufacturers；The electronics device of power-supply controller of electric etc Its specialised manufacturers of part spreads all over the world.

Its material of microwave constrainer 5 of this caged can be any selected metal, but, in view of it is residing by strong ultraviolet The ozone gaseous mixture environment that light radiation is formed, and, for as much as possible by complicated direct reflection mechanism to greatest extent Considering of the ultraviolet light that output is launched by electrodeless ultraviolet lamp 6, is suitable to make the preferred metal of the microwave constrainer 5 of this caged Material is the rustless steel processed through mirror finish.

Itself art-recognized meanings of described punching rustless steel one word, for stainless steel industry, is known.

Can welded with bright finished punching corrosion resistant plate, splicing or mould pressing process make described microwave constrainer 5.

The microwave constrainer 5 of this caged can also be made with the braiding of bright finished stainless steel silk.

Can offer sewage draining exit 17 in the bottom of described container 1, this sewage draining exit 17 may be used for deslagging, removes contamination, in this blowdown Blowoff valve 16 can be installed in mouth 17 positions, and described blowoff valve 16 is the valve controlled for blowdown.Described sewage draining exit 17 and Blowoff valve 16 is not necessarily.

Described water pump 22 and booster pump 21, be all the pump for carrying clear or turbid all kinds of water, certainly, its pumping pressure Can as desired to select arbitrarily, and, various pump market is the most on sale；This case uses different names, is simply Facilitate statement, the convenient pump distinguishing each different structure position.

The preferred scope in its filter opening aperture of the preposition prefilter of described back flush type 20 is between 5 microns and 300 microns, Arbitrarily selected value within the scope of this is all the most available enforcement value, and certainly, other outside this preferred scope is preposition It is also that this case is allowed that pre-filtering aperture selects；Described its filter opening aperture of back flush type doughnut membrane microfiltration filter 19 Preferably scope is between 25 nanometers and 1000 nanometers, and the arbitrarily selected value within the scope of this is preferred is all the most available Enforcement value, certainly, it is also that this case is allowed that other microfiltration aperture outside this preferred scope selects；Described back flush type The preferred scope in its filter opening aperture of hollow-fibre membrane ultra filtration filter 18 is between 15 nanometers and 2 nanometers, this preferred model Arbitrarily selected value within enclosing is all the most available enforcement value, and certainly, other ultrafiltration aperture outside this scope selects also It is that this case is allowed.

The preposition prefilter of described back flush type 20 also referred to as back flush type fore filter or back flush type prefilter, described instead Itself art-recognized meanings of the preposition prefilter of flushing type 20 is known；Described back flush type preposition prefilter 20 market has Sell.

Described back flush type doughnut membrane microfiltration filter 19 is adapted for the filter of microfiltration；Described microfiltration one word itself Art-recognized meanings is known；Itself art-recognized meanings of described back flush type doughnut membrane microfiltration filter 19 is for membrance separation For the professional of technical field, it is known；Described back flush type doughnut membrane microfiltration filter 19 is commercially available.

Described back flush type hollow-fibre membrane ultra filtration filter 18 is adapted for the filter of ultrafiltration；Described ultrafiltration one word itself Art-recognized meanings is known；Itself art-recognized meanings of described back flush type hollow-fibre membrane ultra filtration filter 18 is for membrance separation For the professional of technical field, it is known；Described back flush type hollow-fibre membrane ultra filtration filter 18 is commercially available.

In ultrafiltration link, this back flush type hollow-fibre membrane ultra filtration filter 18 can be an only back flush type doughnut The form of membrane ultrafiltration filter monomer；Certainly, this back flush type hollow-fibre membrane ultra filtration filter can also be at one by quantity Above back flush type hollow-fibre membrane ultra filtration filter monomer is parallel with one another couples composition.

Similarly, in microfiltration link, this back flush type doughnut membrane microfiltration filter 19 can be an only back flush type The form of doughnut membrane microfiltration filter monomer；Certainly, this back flush type doughnut membrane microfiltration filter can also be by counting Measure and form in more than one back flush type doughnut membrane microfiltration filter monomer parallel with one another connection.

At described back flush type its pure water inlet of doughnut membrane microfiltration filter 19 and described back flush type doughnut membrane ultrafiltration Can install second booster pump on the connecting pipeline of the water inlet of filter 18 further, this second booster pump is used for augmenting Hydraulic pressure is to meet the intake pressure demand of described back flush type hollow-fibre membrane ultra filtration filter；This second booster pump is not necessary to 's.

The microwave constrainer of cage-like is exactly a metal cage；Himself structure of microwave constrainer of this caged is a mass of hole Or the preferred scope of mesh, described hole or its bore of mesh is between 0.5 centimetre and 3.0 centimetres, this preferred scope it In arbitrarily selected value be all preferably available bore value, this bore value can be such as 0.5 centimetre, 1.0 centimetres, 1.75 Centimetre, 2.2 centimetres, 3.0 centimetres, etc.；Certainly, if other bore outside preferred scope must be selected at this Hole or mesh, that is also that this case is allowed.

The structure of this case device embodiment, it is also possible to include some adnexaes, described adnexa such as: with magnetron 10 cooling tube The cooling water recirculation system of road connection or air cooling system；Described adnexa is the most such as being fixed on cage-like by electrodeless ultraviolet lamp 6 Microwave constrainer 5 within fixed support；Described adnexa is the most such as being fixed on institute by the microwave constrainer 5 of cage-like State the support member within quartz ampoule 4；Described adnexa can certainly include being fixed on described quartz ampoule 4 described container 1 it Interior support or fixed mount；Described adnexa is the most such as installed in the filter for intercepting impurity of reactor influent waste water end, etc. Deng.

Among enforcement, it is also possible on this case architecture basics, development this case scheme further, for example, it is possible to catalyst particles Charging characteristic is paid close attention to, and greatly utilizes it, considers based on this, and described in this case, back flush type doughnut membrane microfiltration filters Its hollow fiber microfiltration membrane included of device can specify use bear electricity hollow fiber microfiltration membrane, and back flush type hollow described in this case is fine Dimension its hollow fiber ultrafiltration membrane included of membrane ultrafiltration filter can specify use bear electricity hollow fiber ultrafiltration membrane.Using bear In the case of electrolemma, Coulomb repulsion effect can be given full play to, and its effect of this Coulomb repulsion, is to suppress catalyst particles to exist Intractable attachment on membrane module, facilitates the cleaning of its backwashing procedures of membrane module to operate.Only with regard to bear electricity hollow-fibre membrane one word For the art-recognized meanings of itself, for the research worker in charged membrane field, know.Only with regard to bear electricity doughnut For itself technology of preparing of film, for the expert in charged membrane field, know.

Among enforcement, its structure of this case can also allow for farther including tank, and described back flush type doughnut membrane microfiltration filters Within device and the described back flush type hollow-fibre membrane equal submergence of ultra filtration filter are placed in this tank, its sidewall of this tank or its Bottom is equiped with another group ultrasonic transducer, and this another group ultrasonic transducer at least contains a ultrasonic transducer individuality, This another group ultrasonic transducer is used for radiating high-frequency ultrasonic, and this high-frequency ultrasonic refers to frequency at 100kHz-12MHz The ultrasound wave of scope, this another group ultrasonic transducer couples with another higher-order of oscillation electric signal generator；At this case membrane module In backwash operation procedure, by means of there is no cavitation damage or the most weak described high-frequency ultrasonic of cavitation damage, it is possible to ratio is milder Ground assists backwashing procedures to release those catalyst of obstinate attachment on membrane module working interface.

Implement legend is depicted without described adnexa.

The embodiment of this case is not limited to legend mode.

Claims

1. preventing the high throughput photocatalytic waste water degradation reactor of light source placing chamber gushing water, the structure of this reactor includes an appearance Device, its appearance profile of described container is cube shaped, cuboid, cylindrical, the cylindroid bodily form, the polygon prism bodily form, ball The bodily form or the ellipsoid bodily form, the lower area at described container intracavity is equiped with the micro porous aeration head of many, and, quartz ampoule, should Quartz ampoule is erected at the cavity position of described container, and the two ends of this quartz ampoule are equiped with closure headkerchief, lays respectively at quartz ampoule two ends Described closure headkerchief on all offer ventilation interface, and, electrodeless ultraviolet lamp, this electrodeless ultraviolet lamp is bar-shaped, ring-type, ball Shape, Asterias amurensis Lutken shape or Hemicentrotus seu Strongylocentrotus shape, the quantity of this electrodeless ultraviolet lamp is at least at more than one, and this quantity is at least more than one electrodeless Uviol lamp is all erected at the inside of described quartz ampoule, and, air pump, this air pump is installed in the outside of described container, described Ventilation interface on quartz ampoule one end seal blanking cover head via breather line and passes through going out of described wall of a container and described air pump QI KOU couple, its other end of described quartz ampoule closure headkerchief on ventilation interface via another breather line be positioned at described container The micro porous aeration head of inner chamber lower area couples, and, microwave generator, this microwave generator is installed in the outside of described container, This microwave generator is magnetron, and, waveguide, this waveguide is the component for transmitting microwave, one end of this waveguide With described magnetron UNICOM, the other end of this waveguide passes through the described wall of a container inner chamber towards described container, and, water pump, This water pump is positioned at the outside of described container, and this water pump is for pumping pending waste water, and its outlet of this water pump leads to described container Inner chamber, the top of described container offers exhaust port, and that one end through described wall of a container of this waveguide is further Extend into the inner chamber of described container, this go deep into described container intracavity waveguide that one end and further through described stone One closure headkerchief of English pipe probes into the inside of quartz ampoule, and, the structure of this reactor also includes the micro-of the caged of metal material Ripple constrainer, the microwave constrainer of caged is exactly a metal cage, containing many holes or net in the microwave constrainer of this caged Eye, the function of the microwave constrainer of this caged is constraint microwave, contains its unhelpful dissipation, simultaneously, it is allowed to major part ultraviolet light is worn Thoroughly, the installation position of the microwave constrainer of this caged is positioned at the inside of described quartz ampoule, its inner chamber of microwave constrainer of this caged with That one end UNICOM probeing into quartz ampoule of described waveguide, described UNICOM refers to couple with through in microwave channel meaning, described It is erected at the electrodeless ultraviolet lamp within quartz ampoule to be all rolled in wherein by the microwave constrainer of cage-like, and, booster pump, this increasing Press pump is mixed with the water after the degraded of a large amount of catalyst particles for supercharging pumping, and its water inlet of this booster pump is via ventilating water pipe also Inner chamber through described wall of a container with described container couples, and, the preposition prefilter of back flush type, this back flush type is preposition Its water inlet of prefilter couples with the outlet of described booster pump, and, back flush type doughnut membrane microfiltration filter, institute State back flush type its pure water inlet of preposition prefilter to filter with this back flush type doughnut membrane microfiltration via first water purifying valve The water inlet of device couples, and, back flush type hollow-fibre membrane ultra filtration filter, described back flush type doughnut membrane microfiltration mistake Its pure water inlet of filter couples via the water inlet of second water purifying valve with this back flush type hollow-fibre membrane ultra filtration filter, and this is anti- The entrance point of flushing type hollow-fibre membrane its pure water inlet of ultra filtration filter and the 3rd water purifying valve couples, the 3rd water purifying valve Water side is the water side of outlet terminal water purification, and each described filter is used to retain catalyst particles, its dirt of each described filter Water out is all converted as by retaining the recycling delivery outlet of catalyst particles, and, the micro porous aeration head of described many is mutually interpolymerized Collection forms cluster-shaped micro porous aeration head cluster, and this cluster-shaped micro porous aeration head cluster is erected at the bottom of described container intracavity vacantly Region, the fore-and-aft distance of this cluster-shaped its bottom edge of micro porous aeration head cluster and described container intracavity bottom surface between 10 centimetres with Between 50 centimetres, this cluster-shaped micro porous aeration head cluster arround it lateral separation of edge and described container intracavity sidewall between 20 Centimetre and 300 centimetres between, this its center of cluster-shaped micro porous aeration head cluster or center of gravity are positioned at the underface of described quartz ampoule, with And, ozone sensor, the sampling port of this its probe tube of ozone sensor is adjacent to described exhaust port or probes into described tail gas row Put the inside of mouth, and, ozone content display, ozone attention device or ozone content display and the compounding machine of ozone attention device Structure, this ozone sensor via Article 1 cable with this ozone content display, ozone attention device or ozone content display with smelly The composite structure of oxygen attention device couples, and, power-supply controller of electric, its output electric signal of this ozone sensor is via Article 2 cable Coupling with this power-supply controller of electric, this power-supply controller of electric couples with described magnetron via Article 3 cable, this power-supply controller of electric via Article 4 cable couples with described air pump, and this power-supply controller of electric is can to carry out power supply according to its described electric signal received to open The power-supply controller of electric of pass action, it is characterised in that the structure of this reactor also includes catalyst underflow transition tank, this catalyst underflow mistake Crossing the tank body that tank is a hollow, this catalyst underflow transition tank is discharged for temporarily depositing each its backwashing procedures of described filter The higher water body of catalyst concentration, the catalyst underflow refluxing opening being positioned at this catalyst underflow its intracavity bottom of transition tank is dense via catalyst Slurry reflux inlet leads to the inner chamber of described container, and this catalyst underflow reflux inlet is the valve body for this catalyst return flow line of on-off control, Described back flush type its outlet of sewer of preposition prefilter leads to the inner chamber of this catalyst underflow transition tank, institute via first sewage valve State back flush type doughnut its outlet of sewer of membrane microfiltration filter and lead to this catalyst underflow transition tank via second sewage valve Inner chamber, described back flush type hollow-fibre membrane its outlet of sewer of ultra filtration filter leads to this catalyst underflow mistake via the 3rd sewage valve Cross the inner chamber of tank, and, one group of ultrasonic transducer, this group of ultrasonic transducer at least contains a ultrasonic transducer Body, this group of ultrasonic transducer is used for radiating low-frequency ultrasonic waves, and this low-frequency ultrasonic waves refers to frequency at 20kHz-60kHz The ultrasound wave of scope, this container intracavity bottom surface is the most hollow to central area by periphery, and described its gradient hollow is between 5 degree and 35 Between degree, this group of ultrasonic transducer is to be installed in its part corresponding to hollow bosom of this container intracavity bottom surface with attaching The lateral surface position of vessel bottom wall or medial surface position, and, higher-order of oscillation electric signal transmission cable, this higher-order of oscillation electric signal One end of transmission cable couples with this ultrasonic transducer, and, higher-order of oscillation electric signal generator, described higher-order of oscillation telecommunication The other end of number transmission cable couples with this higher-order of oscillation electric signal generator, and, pH pops one's head in, and, pH analyser, This pH probe is coupled to each other with pH analyser, this pH analyser and coupling with siren, and this siren is used for pH value The situation of transfiniting sends alarm, and this pH probe stretches into described container intracavity through the top of described container, and, through powder sintered The micropore rustless steel sleeve that technique is made, this micropore rustless steel sleeve is cap for brush shape, and this micropore rustless steel sleeve is positioned at described container Inner chamber, this micropore its blind end of rustless steel sleeve down, this micropore its opening of rustless steel sleeve upward, this micropore stainless steel sleeve Its opening upward of cylinder couples with described container top via buffering isolating pad, and this pH pops one's head in, and it stretches into described container intracavity Within that part probes into this micropore rustless steel sleeve, this its material of buffering isolating pad is fluorubber or silicone rubber, and, two is right Dry-reed type ball float level controller, these two pairs of dry-reed type ball float level controllers all tops through reactor extend into reactor Inner chamber, a pair dry-reed type ball float level controller therein is coupled, wherein with the power cable of described water pump by a relay Another dry-reed type ball float level controller is coupled with the power cable of described booster pump by another relay, this waveguide Its part going deep into this container intracavity is to be made up of two sections of stainless steel tubes, and these two sections of stainless steel tubes are each other with Flange joint side Formula is docked, and in place of this Flange joint, uses two-layer teflon gasket, and, wave transparent gas-tight bulkhead plate, this is saturating Ripple gas-tight bulkhead plate is the ceramic wafer of quartz glass plate, polyfluortetraethylene plate or dense sintering, and this wave transparent gas-tight bulkhead plate is used Axis in place of air-tightness this waveguide of cross-section separation, the board plane of this wave transparent gas-tight bulkhead plate and this Flange joint of this waveguide Line is mutually perpendicular to, the locations of structures between this wave transparent its periphery edge of gas-tight bulkhead plate wedging two-layer teflon gasket, and, First check valve, this first check valve is installed on described its plenum duct of air pump neighbouring described air and pumps out the position of QI KOU Put, and, quartz tube cavity malleation maintain pump, this quartz tube cavity malleation maintain pump be one lower powered for low discharge pump Sending air and only to maintain the miniature membrane pump for the purpose of quartz tube cavity malleation, this quartz tube cavity malleation maintains its power of pump Between 5 watts and 50 watts, this quartz tube cavity malleation maintains its gas outlet operating pressure of pump between 1 meter water column and 5 meters of water Between post, this quartz tube cavity malleation maintain its gas output of pump between 1 liter and 80 liters per minute per minute, this quartz ampoule pipe Chamber malleation maintains its gas outlet of pump to be connected in parallel with described air pump through second check valve, and, the 3rd check valve, What the 3rd check valve was installed between this quartz tube cavity with described micro porous aeration head couples in gas circuit, and this connection gas circuit is the most just Another described breather line, its filter opening aperture of the preposition prefilter of described back flush type between 5 microns with 300 microns it Between, described its filter opening aperture of back flush type doughnut membrane microfiltration filter between 25 nanometers and 1000 nanometers, described instead Its filter opening aperture of flushing type hollow-fibre membrane ultra filtration filter between 2 nanometers and 15 nanometers, this micropore rustless steel sleeve its Wall thickness is between 3 millimeters to 30 millimeters, and this micropore its micropore size of rustless steel sleeve, should between 0.5 micron to 50 micron Buffering its thickness of isolating pad is between 1 millimeter to 8 millimeter.

The high throughput photocatalytic waste water degradation reactor of prevention light source placing chamber gushing water the most according to claim 1, its feature Being, its material of microwave constrainer of this caged is the punching rustless steel processed through mirror finish.

The high throughput photocatalytic waste water degradation reactor of prevention light source placing chamber gushing water the most according to claim 1, its feature Being, the microwave constrainer of this caged is made up of the braiding of mirror finish stainless steel silk.

The high throughput photocatalytic waste water degradation reactor of prevention light source placing chamber gushing water the most according to claim 1, its feature Being, offer sewage draining exit in the bottom of described container, this sewage draining exit is used for deslagging, removes contamination, and is equiped with at this Location for Sewage Blowoff valve, described blowoff valve is the valve controlled for blowdown.

The high throughput photocatalytic waste water degradation reactor of prevention light source placing chamber gushing water the most according to claim 1, its feature Being, this back flush type hollow-fibre membrane ultra filtration filter is at more than one back flush type hollow-fibre membrane ultra filtration by quantity Filter monomer is parallel with one another couples composition.

The high throughput photocatalytic waste water degradation reactor of prevention light source placing chamber gushing water the most according to claim 1, its feature Being, this back flush type doughnut membrane microfiltration filter is in more than one back flush type doughnut membrane microfiltration mistake by quantity Filter monomer is parallel with one another couples composition.

The high throughput photocatalytic waste water degradation reactor of prevention light source placing chamber gushing water the most according to claim 1, its feature It is, at described back flush type doughnut its pure water inlet of membrane microfiltration filter and described back flush type hollow-fibre membrane ultra filtration Being equiped with second booster pump on the connecting pipeline of the water inlet of filter, it is described to meet that this second booster pump is used for augmenting hydraulic pressure The intake pressure demand of back flush type hollow-fibre membrane ultra filtration filter.

The high throughput photocatalytic waste water degradation reactor of prevention light source placing chamber gushing water the most according to claim 1, its feature Being, the hole spread all in the microwave constrainer self structure of this caged or its magnitude range of mesh are between 0.5 centimetre and 3.0 Between centimetre.