CN103265763A - Ethylene-propylene-diene-monome rubber cable sheath material made from modified carbon fibers and preparation method of sheath material - Google Patents

Ethylene-propylene-diene-monome rubber cable sheath material made from modified carbon fibers and preparation method of sheath material Download PDF

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CN103265763A
CN103265763A CN2013101974410A CN201310197441A CN103265763A CN 103265763 A CN103265763 A CN 103265763A CN 2013101974410 A CN2013101974410 A CN 2013101974410A CN 201310197441 A CN201310197441 A CN 201310197441A CN 103265763 A CN103265763 A CN 103265763A
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sheath material
modified carbon
carbon fiber
ethylene
cable sheath
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CN103265763B (en
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莫连松
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Anhui Changyuan Zhihao Electric Power Science & Technology Co Ltd
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Anhui Changyuan Zhihao Electric Power Science & Technology Co Ltd
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Abstract

The invention discloses an ethylene-propylene-diene-monomer rubber cable sheath material made from modified carbon fibers and a preparation method of the sheath material. The sheath material is made from the following raw materials: ethylene-propylene-diene-monomer rubber, ethylene-vinyl acetate copolymer, modified carbon fibers, siliceous lime powder, polyamide fibers, a zinc oxide, an accelerant TETD (Tetraethyl thiuram disulfide), isopropyl tri(dioctyl pyrophosphoric acid acyloxy) titanate, butyl epoxy stearate, an antioxidant 168, xylitan monostearate and nanoscale concrete powder. According to the ethylene-propylene-diene-monomer rubber cable sheath material, the ethylene-propylene-diene-monomer rubber is adopted as the main ingredient, so that the sheath material has the characteristics of low smoke, no halogen, high mechanical strength and high insulating resistance; and by microwave and ultrasonic wave modification treatments to the reinforcing agent, namely the carbon fibers, the strength of the cable sheath can be greatly improved; and besides, the polyamide fibers are adopted as fire retardants, so that the fire retardant effect is remarkable.

Description

EPT rubber cable sheath material of a kind of modified carbon fiber and preparation method thereof
Technical field
The present invention relates to EPT rubber cable sheath material of a kind of modified carbon fiber and preparation method thereof, belong to cable jacket material and make the field.
Background technology
Along with rapid economic development, electric wire is at industry-by-industry, all be widely used in the field, the frequent generation of electrical fire accident, the fire-retardant problem of electric wire causes the attention of countries in the world gradually, discharge a large amount of smog and poisonous during cable fire, corrosive gas is Hazard Factor in the fire, people's safe escape and fire-fighting work in fire, have been hindered, make lives and properties suffer heavy losses, simultaneously along with communication career, the development of automotive industry and computer industry, specification of quality to cable jacket material increases day by day, the invention provides EPT rubber cable sheath material of a kind of modified carbon fiber and preparation method thereof.
Summary of the invention
The object of the present invention is to provide EPT rubber cable sheath material of a kind of modified carbon fiber and preparation method thereof.
To achieve these goals, the present invention adopts following technical scheme:
The EPT rubber cable sheath material of modified carbon fiber, the weight part of its constitutive material is: terpolymer EP rubber 85-90, ethylene-vinyl acetate copolymer 25-30, modified carbon fiber 3.5-4.0, silica ashes 30-35, tynex 1.0-1.5, zinc oxide 2.0-2.5, promotor TETD 3.0-3.5, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 5.0-6.0, butyl epoxy stearate 1.8-2.2, oxidation inhibitor 168 0.8-1.0, xylitan monostearate 0.3-0.5 and nanometer concrete powder 0.6-1.0.
The EPT rubber cable sheath material of modified carbon fiber, the weight part of its constitutive material is: terpolymer EP rubber 88, ethylene-vinyl acetate copolymer 28, modified carbon fiber 3.8, silica ashes 32, tynex 1.2, zinc oxide 2.2, promotor TETD 3.2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 5.5, butyl epoxy stearate 2.0, oxidation inhibitor 168 0.9, xylitan monostearate 0.4 and nanometer concrete powder 0.8.
The preparation method of the EPT rubber cable sheath material of modified carbon fiber may further comprise the steps:
(1) preparation of modified carbon fiber: with in the carbon fiber soybean oil, taking-up drains namely with carbon fiber;
(2) take by weighing the modified carbon fiber of step (1) by the weight part of constitutive material and other remain each raw material, under the normal temperature stirring at low speed 8-10 minute, make to mix, then at temperature 140-160 ℃ of following banburying 1.5-2.5 minute, play the triangle bag 10-12 time, grind page or leaf section and cooling after finishing.
Beneficial effect of the present invention:
The present invention adopts terpolymer EP rubber as major ingredient, characteristic with low cigarette, Halogen, high mechanical strength, high insulation resistance, and by microwave and ultrasonically-modified processing to the strengthening agent carbon fiber, can improve the intensity of cable jacket material greatly, and to adopt tynex be fire retardant, and flame retardant effect is obvious.
Embodiment
Embodiment 1: the EPT rubber cable sheath material of modified carbon fiber, the weight part of its constitutive material (kg) is: terpolymer EP rubber 88, ethylene-vinyl acetate copolymer 28, modified carbon fiber 3.8, silica ashes 32, tynex 1.2, zinc oxide 2.2, promotor TETD 3.2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 5.5, butyl epoxy stearate 2.0, oxidation inhibitor 168 0.9, xylitan monostearate 0.4 and nanometer concrete powder 0.8.
The preparation method of the EPT rubber cable sheath material of modified carbon fiber may further comprise the steps:
(1) preparation of modified carbon fiber: with in the carbon fiber soybean oil, taking-up drains namely with carbon fiber;
(2) take by weighing the modified carbon fiber of step (1) by the weight part of constitutive material and other remain each raw material, under the normal temperature stirring at low speed 8-10 minute, make to mix, then 150 ℃ of following banburyings of temperature 2.0 minutes, play the triangle bag 11 times, grind page or leaf section and cooling after finishing.
The CABLE MATERIALS performance data that makes by embodiments of the invention 1:
Figure 2013101974410100002DEST_PATH_IMAGE002

Claims (3)

1. the EPT rubber cable sheath material of a modified carbon fiber is characterized in that the weight part of its constitutive material is: terpolymer EP rubber 85-90, ethylene-vinyl acetate copolymer 25-30, modified carbon fiber 3.5-4.0, silica ashes 30-35, tynex 1.0-1.5, zinc oxide 2.0-2.5, promotor TETD 3.0-3.5, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 5.0-6.0, butyl epoxy stearate 1.8-2.2, oxidation inhibitor 168 0.8-1.0, xylitan monostearate 0.3-0.5 and nanometer concrete powder 0.6-1.0.
2. the EPT rubber cable sheath material of modified carbon fiber according to claim 1 is characterized in that the weight part of its constitutive material is: terpolymer EP rubber 88, ethylene-vinyl acetate copolymer 28, modified carbon fiber 3.8, silica ashes 32, tynex 1.2, zinc oxide 2.2, promotor TETD 3.2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 5.5, butyl epoxy stearate 2.0, oxidation inhibitor 168 0.9, xylitan monostearate 0.4 and nanometer concrete powder 0.8.
3. the preparation method of the EPT rubber cable sheath material of a modified carbon fiber as claimed in claim 1 is characterized in that may further comprise the steps:
(1) preparation of modified carbon fiber: in the carbon fiber soybean oil, taking-up drains namely;
(2) take by weighing the modified carbon fiber of step (1) by the weight part of constitutive material and other remain each raw material, under the normal temperature stirring at low speed 8-10 minute, make to mix, then at temperature 140-160 ℃ of following banburying 1.5-2.5 minute, play the triangle bag 10-12 time, grind page or leaf section and cooling after finishing.
CN201310197441.0A 2013-05-24 2013-05-24 EPT rubber cable protective cover material of a kind of modified carbon fiber and preparation method thereof Expired - Fee Related CN103265763B (en)

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CN201310197441.0A CN103265763B (en) 2013-05-24 2013-05-24 EPT rubber cable protective cover material of a kind of modified carbon fiber and preparation method thereof

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CN103265763B CN103265763B (en) 2016-05-18

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106751012A (en) * 2016-11-23 2017-05-31 宁夏宝塔石化科技实业发展有限公司 One kind waste and old fibre reinforced wind power generation cable sheath and preparation method thereof
CN107434888A (en) * 2017-09-14 2017-12-05 安徽天大铜业有限公司 A kind of cable jacket material of good combination property
CN110483905A (en) * 2019-09-17 2019-11-22 安徽电缆股份有限公司 A kind of rubber cable material of easy processing high abrasion
CN112553547A (en) * 2020-12-07 2021-03-26 深圳市博迪科技开发有限公司 Preparation method of high-thermal-conductivity metal-based carbon fiber heating body material
CN112795102A (en) * 2019-11-13 2021-05-14 江苏河阳电气有限公司 Flame-retardant cable for electric vehicle charging system and preparation method thereof

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CN1629216A (en) * 2003-12-16 2005-06-22 深圳市沃尔热缩材料有限公司 Halogen-free flame-retardant thermal-shrinkage sleeve materials and sleeve prepared thereby
CN101225199A (en) * 2007-01-16 2008-07-23 深圳市沃尔核材股份有限公司 Material used for halogen-free flame retardant heat shrinkable sheathing and cross-linking cable wire and preparation method thereof
EP2343334A2 (en) * 2010-01-07 2011-07-13 King Abdulaziz City for Science and Technology Clean flame retardant compositions for flame retardancy and enhancing mechanical properties to insulate wire and cable
CN102977467A (en) * 2012-11-05 2013-03-20 安徽金桥电缆有限公司 Cross-linked low-smoke and zero-halogen flame retardant cable material for nuclear power stations, and its preparation method
CN103093873A (en) * 2012-12-28 2013-05-08 深圳市沃尔核材股份有限公司 Halogen-free high-flame-retardant cable
CN103275401A (en) * 2013-05-23 2013-09-04 宝胜科技创新股份有限公司 Halogen-free low-smoke flame retardant double-layer insulating outer layer material for area-1 cable of AP1000 nuclear power station and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1629216A (en) * 2003-12-16 2005-06-22 深圳市沃尔热缩材料有限公司 Halogen-free flame-retardant thermal-shrinkage sleeve materials and sleeve prepared thereby
CN101225199A (en) * 2007-01-16 2008-07-23 深圳市沃尔核材股份有限公司 Material used for halogen-free flame retardant heat shrinkable sheathing and cross-linking cable wire and preparation method thereof
EP2343334A2 (en) * 2010-01-07 2011-07-13 King Abdulaziz City for Science and Technology Clean flame retardant compositions for flame retardancy and enhancing mechanical properties to insulate wire and cable
CN102977467A (en) * 2012-11-05 2013-03-20 安徽金桥电缆有限公司 Cross-linked low-smoke and zero-halogen flame retardant cable material for nuclear power stations, and its preparation method
CN103093873A (en) * 2012-12-28 2013-05-08 深圳市沃尔核材股份有限公司 Halogen-free high-flame-retardant cable
CN103275401A (en) * 2013-05-23 2013-09-04 宝胜科技创新股份有限公司 Halogen-free low-smoke flame retardant double-layer insulating outer layer material for area-1 cable of AP1000 nuclear power station and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106751012A (en) * 2016-11-23 2017-05-31 宁夏宝塔石化科技实业发展有限公司 One kind waste and old fibre reinforced wind power generation cable sheath and preparation method thereof
CN107434888A (en) * 2017-09-14 2017-12-05 安徽天大铜业有限公司 A kind of cable jacket material of good combination property
CN110483905A (en) * 2019-09-17 2019-11-22 安徽电缆股份有限公司 A kind of rubber cable material of easy processing high abrasion
CN112795102A (en) * 2019-11-13 2021-05-14 江苏河阳电气有限公司 Flame-retardant cable for electric vehicle charging system and preparation method thereof
CN112553547A (en) * 2020-12-07 2021-03-26 深圳市博迪科技开发有限公司 Preparation method of high-thermal-conductivity metal-based carbon fiber heating body material

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