CN103265334A - Method for cladding glaze and colors on ceramic whiteware by using laser - Google Patents
Method for cladding glaze and colors on ceramic whiteware by using laser Download PDFInfo
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- CN103265334A CN103265334A CN2013102034544A CN201310203454A CN103265334A CN 103265334 A CN103265334 A CN 103265334A CN 2013102034544 A CN2013102034544 A CN 2013102034544A CN 201310203454 A CN201310203454 A CN 201310203454A CN 103265334 A CN103265334 A CN 103265334A
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- glaze
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- ceramic whiteware
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- laser apparatus
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Abstract
The invention relates to a method for cladding glaze and colors on ceramic whiteware by using a laser. The method comprises the following steps of: adding a transparent solvent glaze material in ceramic pigment and drying so as to form a structure with the transparent solvent glaze at the upper layer and the ceramic pigment at the lower layer, wherein the proportion of the transparent solvent glaze material is smaller than that of the ceramic pigment; and cladding colored glaze by utilizing high energy of lasers so as to obtain colored ceramic glaze and colors. With the method for cladding the glaze and colors on the ceramic whiteware by using the laser, the laser is used as a burning heat source of the ceramic glaze and colors, and patterns of the glaze and colors are designed and formed by a computer connected with the laser. The method is simple in technology, short in manufacturing time and small in energy consumption, and is suitable for manufacturing single-piece or a small quantity of ceramic glaze and colors decorations by matching with the control of the computer. The production efficiency is improved, and the effects of energy conservation and emission reduction are also achieved.
Description
Technical field
The invention belongs to the technical field of ceramic glaze decoration firing processing method processed, relate in particular to the method for using laser apparatus cladding muffle painting on ceramic whiteware.
Background technology
The making method that traditional ceramic muffle painting is decorated is to adopt color glaze or color base and solvent to cooperate the beramic color of making, by certain processing method (comprise pallet, repeatedly chromatography or describe etc.) constitute pattern at ceramic, fire and form muffle painting and decorate through burning color kiln again.Therefore this making processes complex process and cause power consumption source height needs a kind of high temperature rapid technology of exploitation change the technological problems that the traditional ceramics muffle painting is fired.Along with the raising of The development in society and economy and living standards of the people, people more are tending towards personalized to the pursuit of U.S., and the ceramic glaze illuminated product of " the thousand people one side " of production in enormous quantities can not satisfy the more and more higher culture and arts demand of people.Make the direction that will become high-grade ceramic decoration Future Development by customized pattern, short run even single-piece, popularizing of internet also brought bigger convenience for client's personalized customization simultaneously.Making method energy consumption for the ceramic glaze illuminated product of single-piece or short run that traditional ceramic muffle painting is decorated is excessive, and cost is too high, therefore more needs a kind of technology of the novel ceramic muffle painting of cladding on ceramic whiteware.
Laser technology is the fine selection of high temperature rapid firing, and the laser processing parameter of controlling well can reduce the Production Time of ceramic muffle painting, has improved labour productivity, simultaneously the more energy-conservation cost that reduces personalized product.Yet do not find domestic and international report with laser cladding muffle painting on ceramic whiteware up to now as yet.
Summary of the invention
To be solved by this invention is to improve ceramic glaze illuminated product production efficiency and technical problem such as energy-conservation, thereby a kind of method of using laser apparatus cladding muffle painting on ceramic whiteware is provided.
In order to address the above problem by the following technical solutions: a kind of method of using laser apparatus cladding muffle painting on ceramic whiteware, by in beramic color, adding the transparent solvent glaze, the proportion of transparent solvent glaze is less than the proportion of beramic color, on drying forms later on be the transparent solvent glaze, below be the structure of beramic color, the cladding that utilizes the high-energy of laser to carry out colour glaze can obtain the ceramic muffle painting of in-glaze decoration.
Concrete grammar is as follows: the first step, and getting weight ratio is transparent solvent glaze and the beramic color of 3:2, transparent solvent glaze and beramic color are ground to form powder and mixes; Second step, the powder that mixes is put into ball grinder, add CMC dilute solution and water, fire ball grinds into colour glaze; In the 3rd step, the colour glaze that ball milling is good is sprayed on the ceramic whiteware surface, puts in the loft drier ceramic whiteware goods that sprayed colour glaze dry; The 4th step was placed on dried ceramic whiteware goods on the worktable of laser apparatus, carried out laser melting coating pottery muffle painting.
In the first step, transparent solvent glaze powder and beramic color powder are crossed 200 mesh sieves and evenly mixing respectively.
The melt temperature of transparent solvent glaze is 1200
oC.
In second step, the additional proportion of powder, CMC dilute solution and water is: the CMC dilute solution of the powder of 1g: 1ml: the water of 0.2ml.
The powder weighing 20g that mixes is put into ball grinder, add 20ml CMC dilute solution and 4ml water, ball milling 30min obtains the color glaze slurry after 200 mesh sieves fast.
The preparation method of CMC dilute solution is for being that the hydroxylated cellulose of C1000 is added to the water and makes with the viscosity model, and the weight ratio of hydroxylated cellulose and water is 1:200.
Be that the hydroxylated cellulose 5g of C1000 joins and makes the CMC dilute solution in the 1000ml water with the viscosity model.
In the 3rd step, the color glaze slurry is sprayed on the ceramic whiteware surface thickness between 0.1mm-0.25mm, and drying temperature is 40 in the loft drier
oC.
Laser apparatus every machined parameters be laser output power 30W-80W, laser scanning speed 100mm/min-600mm/min, laser spot diameter 1mm-2.5mm.
Adopt the present invention to use the method for laser apparatus cladding muffle painting on ceramic whiteware, use laser to be the thermal source of firing of ceramic muffle painting, the muffle painting pattern is that the computer design that laser apparatus connects forms, technology is simple, Production Time is short, energy consumption is little, and matching computer control is fit to the making of the ceramic glaze illuminated product of single-piece or short run.Production efficiency energy-saving and emission-reduction have again namely been improved.
Embodiment
Embodiment 1: a kind of method of using laser apparatus cladding muffle painting on ceramic whiteware, by in beramic color, adding the transparent solvent glaze, the proportion of transparent solvent glaze is less than the proportion of beramic color, on drying forms later on be the transparent solvent glaze, below be the structure of beramic color, the cladding that utilizes the high-energy of laser to carry out colour glaze can obtain the ceramic muffle painting of in-glaze decoration.
The transparent solvent glaze has the feedstock production of following weight part and becomes 8 parts in 45 parts of clear frits, Suzhou soil, calcite 12wt part, 30 parts of lithium feldspars and quartzy 5 parts, and the proportion of transparent solvent glaze is 1.36 g/cm
3The ratio weight average of used beramic color is higher than the proportion of transparent solvent glaze, for example peacock blue 1.59 g/cm
3, cobalt black 2.10g/cm
3
Embodiment 2: a kind of method of using laser apparatus cladding muffle painting on ceramic whiteware.The first step is crossed 200 mesh sieves respectively with transparent solvent glaze and the beramic color of pulverizing; Getting weight ratio is transparent solvent glaze and the beramic color of 3:2, and mixes; Second step, the powder that mixes is put into ball grinder, add CMC dilute solution and water, fire ball grinds into colour glaze; In the 3rd step, the colour glaze that ball milling is good is sprayed on the ceramic whiteware surface, puts in the loft drier ceramic whiteware goods that sprayed colour glaze dry; The 4th step was placed on dried ceramic whiteware goods on the worktable of laser apparatus, carried out laser melting coating pottery muffle painting.
Embodiment 3: a kind of method of using laser apparatus cladding muffle painting on ceramic whiteware.
The first step, getting beramic color and melt temperature is 1200
oThe transparent solvent glaze of C is crossed 200 mesh sieves respectively, and by weight for 3:2 transparent solvent glaze powder and beramic color powder evenly being mixed.
Second step, the powder weighing 20g that mixes is put into ball grinder, add 20ml CMC dilute solution and 4ml water, color glaze slurry behind the quick ball milling 30min that ball milling is good is after 200 mesh sieves; The preparation method of CMC dilute solution is for being that the hydroxylated cellulose 5g of C1000 joins in the 1000ml water with the viscosity model.
In the 3rd step, the color glaze slurry that ball milling is good is sprayed on the ceramic whiteware surface, and colour glaze is sprayed on the ceramic whiteware surface thickness between 0.1mm-0.25mm, and the ceramic whiteware goods that sprayed colour glaze are put into drying in the loft drier, and drying temperature is 40
oC.
The 4th step was placed on dried ceramic whiteware goods on the worktable of laser apparatus, carried out laser melting coating pottery muffle painting; Laser apparatus every machined parameters be laser output power 30W-80W, laser scanning speed 100mm/min-600mm/min, laser spot diameter 1mm-2.5mm.
Embodiment 4: a kind of method of using laser apparatus cladding muffle painting on ceramic whiteware.Wherein, the additional proportion of powder, CMC dilute solution and water is: the CMC dilute solution of the powder of 1g: 1ml: the water of 0.2ml.The weight ratio of hydroxylated cellulose and water is 1:200.
Other steps are with embodiment 2.
Embodiment 5: a kind of method of using laser apparatus cladding muffle painting on ceramic whiteware.
(1), selecting for use of laser apparatus: should select low-power laser for use, as 80W CO
2Laser engraving machine.
(2), the preparation of colour glaze: colour glaze is made up of transparent solvent glaze and beramic color, ground transparent solvent glaze and beramic color are crossed 200 mesh sieves respectively, then by weight carrying out proportioning for the ratio of 3:2, be in harmonious proportion with Walocel MT 20.000PV (CMC) aqueous solution and the pure water that prepare again, obtain finally obtaining the color glaze slurry after 200 mesh sieves after mixing liquid is put into the ball milling that ball grinder carries out half hour.
(3), glazing: the color glaze slurry for preparing is sprayed to existing ceramic whiteware product surface in the mode of spraying, will spray uniform ceramic whiteware sample and put into drying baker and dry, temperature should not be too high during oven dry, is advisable for 40 ℃.
(4), draw the muffle painting pattern: carrying out the drafting of pattern with mapping software on the computer that connects laser engraving machine, can be that character and graphic also can be other pattern.
(5), laser processing: the ceramic whiteware goods of the good color glaze of the coating that drying is good are placed on the processing platform of laser engraving machine, the machined parameters of laser engraving machine is set to: laser power (30W-80W), sweep velocity (100mm/min-600mm/min), laser spot diameter (1mm-2.5mm).Just can realize the laser melting coating of ceramic muffle painting on ceramic whiteware according to the good figure of rendering computer then.
Claims (10)
1. method of using laser apparatus cladding muffle painting on ceramic whiteware, it is characterized in that: by in beramic color, adding the transparent solvent glaze, the proportion of transparent solvent glaze is less than the proportion of beramic color, on drying forms later on be the transparent solvent glaze, below be the structure of beramic color, the cladding that utilizes the high-energy of laser to carry out colour glaze can obtain the ceramic muffle painting of in-glaze decoration.
2. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 1, it is characterized in that concrete grammar is as follows: the first step, getting weight ratio is transparent solvent glaze and the beramic color of 3:2, transparent solvent glaze and beramic color are ground to form powder and mixes; Second step, the powder that mixes is put into ball grinder, add CMC dilute solution and water, fire ball grinds quality glaze slurry; In the 3rd step, the color glaze slurry that ball milling is good is sprayed on the ceramic whiteware surface, puts in the loft drier ceramic whiteware goods that sprayed colour glaze dry; The 4th step was placed on dried ceramic whiteware goods on the worktable of laser apparatus, carried out laser melting coating pottery muffle painting.
3. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 2, it is characterized in that: in the first step, transparent solvent glaze powder and beramic color powder are crossed 200 mesh sieves respectively and evenly mix.
4. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 3, it is characterized in that: the melt temperature of transparent solvent glaze is 1200
oC.
5. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 2, it is characterized in that: in second step, the additional proportion of powder, CMC dilute solution and water is: the CMC dilute solution of the powder of 1g: 1ml: the water of 0.2ml.
6. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 5, it is characterized in that: the powder weighing 20g that mixes is put into ball grinder, add 20ml CMC dilute solution and 4ml water, ball milling 30min obtains the color glaze slurry after 200 mesh sieves fast.
7. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 5 or 6, it is characterized in that: the preparation method of CMC dilute solution is for being that the hydroxylated cellulose of C1000 is added to the water and makes with the viscosity model, and the weight ratio of hydroxylated cellulose and water is 1:200.
8. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 7, it is characterized in that: be that the hydroxylated cellulose 5g of C1000 joins and makes the CMC dilute solution in the 1000ml water with the viscosity model.
9. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 2, it is characterized in that: in the 3rd step, the color glaze slurry is sprayed on the ceramic whiteware surface thickness between 0.1mm-0.25mm, and drying temperature is 40 in the loft drier
oC.
10. according to the method for use laser apparatus cladding muffle painting on ceramic whiteware of claim 2, it is characterized in that:
Laser apparatus every machined parameters be laser output power 30W-80W, laser scanning speed 100mm/min-600mm/min, laser spot diameter 1mm-2.5mm.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104961500A (en) * | 2015-06-01 | 2015-10-07 | 重庆大学 | Ceramic glaze decoration method |
| CN105799412A (en) * | 2016-03-07 | 2016-07-27 | 温州职业技术学院 | Single-color automatic line drawing machine for ceramic |
| CN106626849A (en) * | 2016-09-13 | 2017-05-10 | 山东镭泽智能科技有限公司 | Color laser marking method for ceramic |
| CN109249140A (en) * | 2018-11-27 | 2019-01-22 | 杜拉维特（中国）洁具有限公司 | A kind of laser marking method |
| CN110255907A (en) * | 2019-08-06 | 2019-09-20 | 淄博中升机械有限公司 | A kind of wide bandgap semiconductor nanometer enamel and enamel firing method for reaction kettle |
| JP2021187725A (en) * | 2020-06-01 | 2021-12-13 | 洋二 丸谷 | Method for painting on porcelain |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101372422A (en) * | 2008-10-09 | 2009-02-25 | 傅涛 | In-glaze decoration method for bright red glazed ceramic |
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2013
- 2013-05-28 CN CN201310203454.4A patent/CN103265334B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101372422A (en) * | 2008-10-09 | 2009-02-25 | 傅涛 | In-glaze decoration method for bright red glazed ceramic |
Non-Patent Citations (1)
| Title |
|---|
| JIWEI FAN.ET.AL: "A New Method for Processing Ceramics with Cracked Glaze", 《ADVANCED MATERIALS RESEARCH》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104961500A (en) * | 2015-06-01 | 2015-10-07 | 重庆大学 | Ceramic glaze decoration method |
| CN105799412A (en) * | 2016-03-07 | 2016-07-27 | 温州职业技术学院 | Single-color automatic line drawing machine for ceramic |
| CN105799412B (en) * | 2016-03-07 | 2019-05-03 | 温州职业技术学院 | A kind of monochromatic automatic line drawing machine of ceramics |
| CN106626849A (en) * | 2016-09-13 | 2017-05-10 | 山东镭泽智能科技有限公司 | Color laser marking method for ceramic |
| CN109249140A (en) * | 2018-11-27 | 2019-01-22 | 杜拉维特（中国）洁具有限公司 | A kind of laser marking method |
| CN109249140B (en) * | 2018-11-27 | 2021-01-26 | 杜拉维特（中国）洁具有限公司 | Laser marking method |
| CN110255907A (en) * | 2019-08-06 | 2019-09-20 | 淄博中升机械有限公司 | A kind of wide bandgap semiconductor nanometer enamel and enamel firing method for reaction kettle |
| JP2021187725A (en) * | 2020-06-01 | 2021-12-13 | 洋二 丸谷 | Method for painting on porcelain |
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