CN103240053B - 一种绝缘油腐蚀性硫脱除剂的生产方法 - Google Patents
一种绝缘油腐蚀性硫脱除剂的生产方法 Download PDFInfo
- Publication number
- CN103240053B CN103240053B CN201310183430.7A CN201310183430A CN103240053B CN 103240053 B CN103240053 B CN 103240053B CN 201310183430 A CN201310183430 A CN 201310183430A CN 103240053 B CN103240053 B CN 103240053B
- Authority
- CN
- China
- Prior art keywords
- insulating oil
- adsorbent
- molecular sieve
- zeolite molecular
- gained
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000011593 sulfur Substances 0.000 title claims abstract description 39
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 239000003463 adsorbent Substances 0.000 claims abstract description 25
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 23
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002808 molecular sieve Substances 0.000 claims abstract description 23
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000010457 zeolite Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910001868 water Inorganic materials 0.000 claims abstract description 15
- 238000005342 ion exchange Methods 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 9
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000012545 processing Methods 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 6
- 238000001914 filtration Methods 0.000 claims abstract description 5
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims abstract description 5
- 229940048086 sodium pyrophosphate Drugs 0.000 claims abstract description 5
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims abstract description 5
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 5
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 239000004411 aluminium Substances 0.000 claims description 8
- 210000002966 serum Anatomy 0.000 claims description 8
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 6
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 5
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 238000001694 spray drying Methods 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 46
- 230000008901 benefit Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 235000019198 oils Nutrition 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 150000003464 sulfur compounds Chemical class 0.000 description 7
- 239000000243 solution Substances 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000010616 electrical installation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- JBGWMRAMUROVND-UHFFFAOYSA-N 1-sulfanylidenethiophene Chemical class S=S1C=CC=C1 JBGWMRAMUROVND-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- AQMRBJNRFUQADD-UHFFFAOYSA-N copper(I) sulfide Chemical compound [S-2].[Cu+].[Cu+] AQMRBJNRFUQADD-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310183430.7A CN103240053B (zh) | 2013-05-17 | 2013-05-17 | 一种绝缘油腐蚀性硫脱除剂的生产方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310183430.7A CN103240053B (zh) | 2013-05-17 | 2013-05-17 | 一种绝缘油腐蚀性硫脱除剂的生产方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103240053A CN103240053A (zh) | 2013-08-14 |
CN103240053B true CN103240053B (zh) | 2014-11-19 |
Family
ID=48920136
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310183430.7A Active CN103240053B (zh) | 2013-05-17 | 2013-05-17 | 一种绝缘油腐蚀性硫脱除剂的生产方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103240053B (zh) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105126748B (zh) * | 2015-08-14 | 2018-07-31 | 国网山东省电力公司临沂供电公司 | 处理变压器废油的吸附剂及其生产方法 |
CN105032024B (zh) * | 2015-08-17 | 2017-01-04 | 国家电网公司 | 一种绝缘油中二苄基二硫的脱除方法 |
CN107446689B (zh) * | 2017-08-08 | 2020-09-29 | 国网江苏省电力公司盐城供电公司 | 一种变压器绝缘油的修复方法 |
CN107523408A (zh) * | 2017-08-28 | 2017-12-29 | 国网江苏省电力公司电力科学研究院 | 一种消除绝缘油中腐蚀性硫化物的化学处理方法 |
CN107638867A (zh) * | 2017-10-24 | 2018-01-30 | 国网黑龙江省电力有限公司电力科学研究院 | 一种用于去除绝缘油中二苄基二硫醚的吸附剂制备方法 |
CN109603312A (zh) * | 2019-01-25 | 2019-04-12 | 广东电网有限责任公司 | 一种绝缘油腐蚀性硫脱除滤板 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1068049A (zh) * | 1991-06-27 | 1993-01-20 | 吴凤义 | 绝缘油纯化剂 |
-
2013
- 2013-05-17 CN CN201310183430.7A patent/CN103240053B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN103240053A (zh) | 2013-08-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103240053B (zh) | 一种绝缘油腐蚀性硫脱除剂的生产方法 | |
Kumar et al. | Preparation and characterization of acid and alkaline treated kaolin clay | |
CN101486784A (zh) | 有效降低聚醚醚酮中金属含量的方法 | |
CN102186959A (zh) | 从变压器油除去腐蚀性含硫化合物的方法 | |
CN103566867B (zh) | 变压器油脱硫吸附剂的制备方法 | |
CN105032024A (zh) | 一种绝缘油中二苄基二硫的脱除方法 | |
CN107638867A (zh) | 一种用于去除绝缘油中二苄基二硫醚的吸附剂制备方法 | |
CN111974341B (zh) | 一种镁铝双金属氢氧化物负载硫化亚铁复合材料及其制备方法与应用 | |
CN103805794A (zh) | 酸法粉煤灰提取氧化铝粗精液中镓的回收方法 | |
CN102623113A (zh) | 一种提高变压器油浸纸绝缘性能的方法 | |
CN103816865A (zh) | 一种有机废气吸附净化剂及其制备方法 | |
CN111215025A (zh) | 一种复合吸附剂及其制备方法和应用 | |
CN101985764A (zh) | 电解制钙用石墨阳极的抗氧化处理方法 | |
Wan et al. | Removal of corrosive sulfur from insulating oil with adsorption method | |
CN107034005B (zh) | 一种劣化变压器油的再生方法 | |
CN102626559A (zh) | 一种从电气设备绝缘油中去除铜离子的方法 | |
CN112058243A (zh) | 一种壳聚糖改性的脱硫吸附剂的制备方法及其在变压器油处理中的应用 | |
CN103418339A (zh) | 一种降低劣化油中微量金属含量的吸附剂及其生产方法 | |
CN111704152A (zh) | 一种防潮型防火电缆用氧化镁及其用途 | |
CN105195083A (zh) | 一种用氯化钠改性重质碳酸钙制备重金属吸附剂的方法 | |
CN102371144A (zh) | 用于苯的脱硫剂 | |
CN111921500B (zh) | 一种吸附剂的制备方法和应用 | |
CN110465261B (zh) | 一种对废变压器油进行回收再生吸附剂的制作工艺及应用 | |
CN107446689B (zh) | 一种变压器绝缘油的修复方法 | |
CN101992059A (zh) | 一种对废变压器油进行精制脱色的吸附剂 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CB03 | Change of inventor or designer information |
Inventor after: Pan Hua Inventor after: Wan Tao Inventor after: Zhou Zhou Inventor after: Zhou Weihua Inventor after: Feng Bing Inventor after: Qian Hui Inventor after: Gong Shangkun Inventor before: Wan Tao Inventor before: Qian Hui Inventor before: Feng Bing Inventor before: He Tiexiang Inventor before: Gong Shangkun Inventor before: Zhou Zhou Inventor before: Chang Yan Inventor before: Liu Xiaoling |
|
COR | Change of bibliographic data |